CN102101809B - Preparation process and using method for amino acid rare-earth zinc micro-fertilizer - Google Patents
Preparation process and using method for amino acid rare-earth zinc micro-fertilizer Download PDFInfo
- Publication number
- CN102101809B CN102101809B CN2010106050063A CN201010605006A CN102101809B CN 102101809 B CN102101809 B CN 102101809B CN 2010106050063 A CN2010106050063 A CN 2010106050063A CN 201010605006 A CN201010605006 A CN 201010605006A CN 102101809 B CN102101809 B CN 102101809B
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- amino acid
- earth
- zinc
- rare
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 74
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 55
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 46
- 150000002910 rare earth metals Chemical class 0.000 title claims abstract description 41
- 239000011701 zinc Substances 0.000 title claims abstract description 41
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- -1 rare earth chloride Chemical class 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 12
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 230000000149 penetrating effect Effects 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000001110 calcium chloride Substances 0.000 claims abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 5
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000001014 amino acid Nutrition 0.000 claims description 48
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 239000007921 spray Substances 0.000 claims description 16
- 238000005516 engineering process Methods 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 239000012467 final product Substances 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 239000003905 agrochemical Substances 0.000 claims description 6
- AXKBOWBNOCUNJL-UHFFFAOYSA-M sodium;2-nitrophenolate Chemical compound [Na+].[O-]C1=CC=CC=C1[N+]([O-])=O AXKBOWBNOCUNJL-UHFFFAOYSA-M 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 4
- 240000005373 Panax quinquefolius Species 0.000 claims description 3
- 235000003140 Panax quinquefolius Nutrition 0.000 claims description 3
- 238000007796 conventional method Methods 0.000 claims description 3
- 235000021049 nutrient content Nutrition 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 244000037666 field crops Species 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims description 2
- 230000035800 maturation Effects 0.000 claims description 2
- 230000008635 plant growth Effects 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 238000011161 development Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 239000011573 trace mineral Substances 0.000 description 11
- 235000013619 trace mineral Nutrition 0.000 description 11
- 235000013399 edible fruits Nutrition 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 235000007164 Oryza sativa Nutrition 0.000 description 5
- 235000009566 rice Nutrition 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 239000010871 livestock manure Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000018997 Growth Hormone Human genes 0.000 description 1
- 108010051696 Growth Hormone Proteins 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 208000002720 Malnutrition Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000000122 growth hormone Substances 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000018343 nutrient deficiency Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 230000007226 seed germination Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- NESLWCLHZZISNB-UHFFFAOYSA-M sodium phenolate Chemical compound [Na+].[O-]C1=CC=CC=C1 NESLWCLHZZISNB-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- UOXSXMSTSYWNMH-UHFFFAOYSA-L zinc;2-aminoacetate Chemical compound [Zn+2].NCC([O-])=O.NCC([O-])=O UOXSXMSTSYWNMH-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to a preparation process and a using method for an amino acid rare-earth zinc micro-fertilizer, and belongs to the technical field of fertilizer preparation. The process comprises the following steps of: 1, adding water in an amount of 50 to 60 percent based on the weight of the total prepared solution of the amino acid rare-earth zinc micro-fertilizer into a reaction kettle, and heating to the temperature of between 80 and 90 DEG C; 2, adding 25 to 35 percent of composite amino acid powder; 3, adding 2.5 to 5 percent of zinc oxide; 4, adding 4 to 8 percent of calcium chloride or 2 to 5 percent of magnesium oxide; 5, adding 3 to 6 percent of rare earth chloride, and keeping the temperature of the solution more than or equal to 95 DEG C for 4 to 10 hours; and 6, adding 0.5 to 1.5 percent of compound sodium nitrophenolate and 0.5 to 1.5 percent of penetrating agent JFC, keeping the temperature of higher than 95 DEG C for more than 4 hours, and completely chelating to obtain the amino acid rare-earth zinc micro-fertilizer. By the invention, the coexistence of microelements such as rare earth, zinc and the like is achieved; the using method that the amino acid rare-earth zinc serves as a partner of a compound fertilizer can make farmers use a microelement fertilizer popularly and promote the agricultural sustainable development; and a balanced fertilizing method is realized in a real sense, the consumption of an amino acid micro-fertilizer is reduced, resources are saved, the fertilizer effect and crop quality are improved and the yield is improved.
Description
Technical field
The present invention relates to a kind of preparation technology and using method of amino acid rare-earth zinc micro-fertilizer, belong to the Production of manure technical field.
Background technology
Trace element more and more comes into one's own as one of essential element of farm crop, and the trace element that China uses mostly is simple inorganic salt.Be easy to fertilizer or soil in phosphate radical, carbonate react, form highly stable compound, unfavorable Crop, therefore, developed country utilizes EDTA, citric acid, xanthohumic acid, tartrate as sequestrant, and trace element is prepared into microelement chelate, Effective Raise micro-stability, the promotion farm crop absorb trace element, and the generation of the enzyme in the promotion crop, VITAMIN, hormone obviously improves crop yield and quality.
The cost that EDTA etc. trace element chelated dose is relatively expensive, mostly utilize now discarded albumen, adopt hydrolysis, chelating single stage method and comprehensive use, produce cheap Chelates of Amino Acids And Trace Elements, such as amino-acid rare earth, amino-acid zinc, magnesium, the inner complexs such as iron, amino-acid rare earth can effectively promote photosynthesis of plant, promote root growth and seed germination, favourable plant strain growth improves crop anti-adversity, improve plant quality, improve melon or fruit type crops product sugar, protein, VC content, amino-acid zinc can participate in the formation of growth hormone, rice plant is increased, the increase of tillering, grain number and grain heavily increase, and empty flat grain descends, to wheat, cotton, fruit tree, the farm crop such as vegetables all can increase yield and quality.
Because fertility and the result of use of aminoacid chelating microelement fertilizer, with preparation technology and micro-addition manner and trace element and raw-material selection and using method direct relation is arranged, therefore, preparation technology and using method to little fertilizer such as amino-acid rare earths are studied and are improved, optimization technological process, the quality and the result of use that improve little fertilizer are significant.
Summary of the invention
One of purpose of the present invention has been to solve the coexistence of the trace element such as rare earth and zinc, replaces zinc sulfate with zinc oxide, reaching the preparation of the amino-acid trace element fertilizer that zinc and rare earth coexist, thereby provides a kind of preparation technology of amino acid rare-earth zinc micro-fertilizer.
Two of purpose of the present invention is " companion " of amino acid rare-earth zinc as composite fertilizer used, adopt composite fertilizer to add " 1+1 " use pattern of " fertilizer mate "-amino acid rare-earth zinc micro-fertilizer, realized Balanced fertilization method truly, reduced the usage quantity of Amino Acid Chelated Mineral Fertilizer, saved resource, improve the quality of fertilizer efficiency and crop, increased output.
One of purpose of the present invention is achieved in that its processing step is as follows:
1. press amino acid rare-earth zinc micro-fertilizer total obtain solution weight 50%-65% add water, water is added in the reaction kettle, be heated to 80-90 ℃;
2. press 25%-35% interpolation compound amino acid powder of the weight of total obtain solution, continue heating and also be stirred to whole dissolvings, require aminoacids content in the compound amino acid powder 〉=45%, moisture content≤3% is heated to 85-95 ℃;
3. add zinc oxide in the reaction kettle by 2.5%-5% of the weight of total obtain solution, require zinc in zinc oxide constituent content 〉=75%; Continue to be stirred to fully dissolving; Or be heated to 90-98 ℃ of restir to fully dissolving;
4. press 4%-8% adding calcium chloride of the weight of total obtain solution, continue to be heated to 85-95 ℃, be stirred to fully dissolving; Or press 2%-5% adding magnesium oxide of the weight of total obtain solution, and continue heating and keep 90-98 ℃, be stirred to fully and dissolve;
5. add rare earth chloride by 3%-6% of the weight of total obtain solution, require Rare Earth Elements in Rare Earth Chloride content 〉=45%, be stirred to fully dissolving, and keep solution temperature 〉=95 ℃, continue 4-10 hours;
6. press 0.5%-1.5% interpolation sodium nitrophenolate of the weight of total obtain solution, require sodium nitrophenolate content 〉=95%; Press again 0.5%-1.5% interpolation penetrating agent JFC of the weight of total obtain solution, require penetrating agent JFC content 〉=70%, be stirred to fully dissolving; The temperature of maintenance more than 95 ℃ treated that chelating gets final product to get amino acid rare-earth zinc micro-fertilizer fully more than 4 hours.
Two of purpose of the present invention is achieved in that its using method is as follows:
The amino acid rare-earth zinc micro-fertilizer amino acid rare-earth zinc micro-fertilizer of technique preparation of the present invention uses as " companion " of formula compound fertilizer, described formula compound fertilizer is according to the demand of different crops to nutrient, in conjunction with nutrient content in the soil, in nitrogen: phosphorus: potassium is the composite fertilizer that the ratio of 10-30:5-15:10-20 is produced, wherein the nitrogen content in the composite fertilizer is 10%-30%, composite fertilizer uses according to a conventional method, and amino acid rare-earth zinc micro-fertilizer is as foliage-spray; Amino acid rare-earth zinc micro-fertilizer uses as " companion " of formula compound fertilizer, described formula compound fertilizer is according to the demand of different crops to nutrient, in conjunction with nutrient content in the soil, in nitrogen: phosphorus: potassium is the composite fertilizer that the ratio of 10-30:5-15:10-20 is produced, wherein the nitrogen content in the composite fertilizer is 10%-30%, composite fertilizer uses according to a conventional method, and amino acid rare-earth zinc micro-fertilizer is as foliage-spray; For the then crop of maturation of concentrating the rear transplanting of growing seedlings, every mu of ground adopts formula compound fertilizer to add the little fertilizer of chelating amino acids rare earth zinc and is used, foliage-spray requires nursery stage to use 1-2 times, 30-50 milliliters of every mu of consumptions, and extension rate is advisable with 500-800 times; Use 1-3 times after transplanting the land for growing field crops, every mu of each consumption 50-75 milliliter, extension rate is advisable with 300-500 times; Every mu of each consumption 50-75 milliliter of perennial crop uses by 500-800 times of weaker concns, and per season crop use 1-3 time will be avoided full-bloom stage and use, and uses in the plant growth Sheng phase as far as possible; The mode that sprays sprays for spraying separately or adding in the agricultural chemicals.
Preparation technology of the present invention has solved that rare earth and vitriol metallic compound can not coexist and the difficult problem that can't produce the amino-acid rare earth chelates of zinc, because the conventional little fertile preparation technology of vitriol chelating amino acids, can make rare earth and sulfate radical be combined into highly stable sulfuric acid rare earth and precipitate, make the rare earth can't be by plant absorbing, therefore the amino-acid rare earth inner complex generally can not mix the chelating coexistence simultaneously with zinc-amino acid chelate, the present invention adopts zinc oxide to substitute zinc sulfate, has avoided rare earth and SO
4 -2Combination, make rare earth ion and Zn
+ 2(zine ion) can be jointly and chelating amino acids generate amino acid rare-earth zinc micro-fertilizer, do not produce a large amount of throw outs, and shortened the chelating time.
The superiority of using method of the present invention shows as:
1. the peasant generally can initiatively not remove to use trace element fertilizer, adopts " 1+1 " use pattern, can popularize the peasant to the use of trace element fertilizer, promotes agricultural sustainable development;
2. use by " 1+1 " type method, its consumption of amino acid rare-earth zinc micro-fertilizer is directly to add 1/20 ~ 50 of using method consumption in the composite fertilizer to, and usage quantity is scientific and reasonable, cuts the waste, and has saved social resources;
3. in this using method " fertilizer mate " can with agricultural chemicals mixing foliage-spray, do not increase the peasant and spray and use the recruitment cost;
4. make more comprehensively science of farm crop Absorption of nourishment material, reduce crop nutritional deficiency physiological disease;
5. improve chemical fertilizer utilization ratio, reduce fertilizer amount, save the chemical fertilizer resource, improve crops quality, increase output, economic and social benefits are obvious.
Embodiment
The present invention can be by the technology implementation that illustrates in the summary of the invention, and by can conducting further description the present invention the following examples, yet scope of the present invention is not limited to following embodiment.
Embodiment 1: to produce the 1000kg amino acid rare-earth zinc micro-fertilizer as example, its whole preparation technology is as follows:
1. after reacting the kettle cleaning, directly in the reaction kettle, add tap water 605kg, be heated to about 85 ± 1 ℃;
2. in the reaction kettle, add amino acid powder 250kg, be heated to 85-95 ℃ and be stirred to fully dissolving;
3. in the reaction kettle, add zinc oxide 40kg, continue heating and keep 90-98 ℃, be stirred to fully dissolving;
4. in the reaction kettle, add calcium chloride 50kg, continue to be heated to 85-95 ℃, be stirred to fully dissolving;
5. in the reaction kettle, add rare earth chloride 40kg, be stirred to fully dissolving, keep solution temperature 〉=95 ℃, continue 4-10 hours;
6. behind the complete chelating of above material (4-5 hours), add in the reaction kettle and sell again phenol sodium 5kg and penetrating agent JFC 10kg, stir, keep that temperature got final product more than 4 hours more than 95 ℃.
Embodiment 2: take produce 1000 kg amino acid rare-earth zinc micro-fertilizers as example illustrates whole preparation technology's flow process:
1. after reacting the kettle cleaning, directly in the reaction kettle, add tap water 585 kg, be heated to about 85 ± 2 ℃;
2. add amino acid powder 300 kg to the reaction kettle, be heated to 85-95 ℃, be stirred to fully dissolving;
3. add zinc oxide 35 kg to the reaction kettle, heating keeps 90-98 ℃, is stirred to fully dissolving;
4. add magnesium oxide 30 kg to the reaction kettle, heating keeps 90-98 ℃ to be stirred to fully dissolving;
5. add rare earth chloride 35 kg to the reaction kettle, heated and stirred is to fully dissolving, and keeps more than 95 ℃ temperature 4-5 hours;
6. add sodium nitrophenolate 5 kg and penetrating agent JFC 10 kg to the reaction kettle, keep more than 95 ℃ temperature to treat that chelating gets final product fully more than 4 hours.
The using method of amino acid rare-earth zinc micro-fertilizer now is described as an example of one mu of rice terrace example:
The used formula compound fertilizer of this rice terrace is with nitrogen+phosphorus+potassium 〉=38%, nitrogen: phosphorus: potassium is the product of 18:9:11, consumption is that 50 kg/mus are example, rice terrace is for transplanting early rice field, the rice transplanting arrangement that began to plough a field in front 2-3 days, and the disposable holostrome of previous crops base manure spreads fertilizer over the fields harrowing a field, and harrow a field to smooth, keep below the water layer 3cm, transplanted afterwards in 1-2 days and to get final product, the later stage does not need supplementary fertilizer.Also can make base manure by 30 kg, 20 kg imposed in transplanting in rear about 7 days, and the little fertilizer of chelating amino acids rare earth zinc uses once at nursery stage, 50 milliliters of every mu of consumptions, and extension rate is with 700 times; General peasant household needed pesticide insect protected diseases prevention in 10-15 days after transplanting, can add in the agricultural chemicals simultaneously to spray, and consumption is 50ml/ mu, added 50ml/ mu before the Rice Heading poplar bloassom when spraying insecticide again and sprayed and get final product, and extension rate is advisable with 300-500 times.
The using method of this amino acid rare-earth zinc micro-fertilizer now is described as example take one mu of fruit tree woods:
This fruit tree is that the Nanfeng orange of bearing fruit about 5 years is example, the formula compound fertilizer that present method is used is nitrogen+phosphorus+potassium 〉=45%, nitrogen: phosphorus: potassium is that the product of 20:10:15 is example, and apply general strain consumption 0.5-1 kg by fruit tree fertilizer applied in the spring season method and consumption, be advisable to spread manuer in holes, fruit tree before Sheng is spent 5-7 days, by 500-800 times of weaker concns in conjunction with other agricultural chemicals or spray separately and get final product, consumption with spray liquid what and decide, general every mu of each consumption 50-75 milliliter is advisable, every about 25-35 days again in conjunction with agricultural chemicals or spray separately once, be advisable by 500-800 times of weaker concns, every mu of each consumption 50-75 milliliter is advisable, and a general growth year sprays twice and gets final product, other pesticide application of best incorporated is saved labour cost.
Claims (2)
1. the preparation technology of an amino acid rare-earth zinc micro-fertilizer is characterized in that processing step is as follows:
1. press amino acid rare-earth zinc micro-fertilizer total obtain solution weight 50%-65% add water, water is added in the reaction kettle, be heated to 80-90 ℃;
2. press 25%-35% interpolation compound amino acid powder of the weight of total obtain solution, continue heating and also be stirred to whole dissolvings, require aminoacids content in the compound amino acid powder 〉=45%, moisture content≤3% is heated to 85-95 ℃;
3. add zinc oxide in the reaction kettle by 2.5%-5% of the weight of total obtain solution, require zinc in zinc oxide constituent content 〉=75%; Continue to be stirred to fully dissolving; Or be heated to 90-98 ℃ of restir to fully dissolving;
4. press 4%-8% adding calcium chloride of the weight of total obtain solution, continue to be heated to 85-95 ℃, be stirred to fully dissolving; Or press 2%-5% adding magnesium oxide of the weight of total obtain solution, and continue heating and keep 90-98 ℃, be stirred to fully and dissolve;
5. add rare earth chloride by 3%-6% of the weight of total obtain solution, require Rare Earth Elements in Rare Earth Chloride content 〉=45%, be stirred to fully dissolving, and keep solution temperature 〉=95 ℃, continue 4-10 hours;
6. press 0.5%-1.5% interpolation sodium nitrophenolate of the weight of total obtain solution, require sodium nitrophenolate content 〉=95%; Press again 0.5%-1.5% interpolation penetrating agent JFC of the weight of total obtain solution, require penetrating agent JFC content 〉=70%, be stirred to fully dissolving; The temperature of maintenance more than 95 ℃ treated that chelating gets final product to get amino acid rare-earth zinc micro-fertilizer fully more than 4 hours;
The total amount that water, compound amino acid powder, zinc oxide, calcium chloride, rare earth chloride, sodium nitrophenolate and the penetrating agent JFC that adds accounts for the percentage ratio of total obtain solution weight is 100%.
2. the using method of the amino acid rare-earth zinc micro-fertilizer of preparation technology claimed in claim 1 preparation, it is characterized in that: amino acid rare-earth zinc micro-fertilizer uses as " companion " of formula compound fertilizer, described formula compound fertilizer is according to the demand of different crops to nutrient, in conjunction with nutrient content in the soil, in nitrogen: phosphorus: potassium is the composite fertilizer that the ratio of 10-30:5-15:10-20 is produced, wherein the nitrogen content in the composite fertilizer is 10%-30%, composite fertilizer uses according to a conventional method, and amino acid rare-earth zinc micro-fertilizer is as foliage-spray;
For the then crop of maturation of concentrating the rear transplanting of growing seedlings, every mu of ground adopts formula compound fertilizer to add the little fertilizer of chelating amino acids rare earth zinc and is used, foliage-spray requires nursery stage to use 1-2 times, 30-50 milliliters of every mu of each consumptions, and extension rate is 500-800 times; Use 1-3 times after transplanting the land for growing field crops, every mu of each consumption 50-75 milliliter, extension rate is 300-500 times;
Every mu of each consumption 50-75 milliliter of perennial crop uses by 500-800 times of weaker concns, and per season crop use 1-3 time will be avoided full-bloom stage and use, and uses in the plant growth Sheng phase;
The mode that sprays sprays for spraying separately or adding in the agricultural chemicals.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106050063A CN102101809B (en) | 2010-12-25 | 2010-12-25 | Preparation process and using method for amino acid rare-earth zinc micro-fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106050063A CN102101809B (en) | 2010-12-25 | 2010-12-25 | Preparation process and using method for amino acid rare-earth zinc micro-fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102101809A CN102101809A (en) | 2011-06-22 |
| CN102101809B true CN102101809B (en) | 2013-04-24 |
Family
ID=44154899
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106050063A Active CN102101809B (en) | 2010-12-25 | 2010-12-25 | Preparation process and using method for amino acid rare-earth zinc micro-fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102101809B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102627498B (en) * | 2012-04-11 | 2014-07-16 | 湖南农业大学 | Fruit and vegetable flower and fruit protecting micro-fertilizer and preparation method thereof |
| CN104230514B (en) * | 2014-04-29 | 2016-05-04 | 宁波龙兴生态农业科技开发有限公司 | Earthworm hydrolysate and rare earth composite reactive blade face liquid fertilizer, its method of preparation and use |
| CN104402611A (en) * | 2014-11-21 | 2015-03-11 | 新疆慧尔农业科技股份有限公司 | Special amino acid drip irrigation fertilizer and preparation method thereof |
| CN111592386A (en) * | 2020-06-10 | 2020-08-28 | 河南中之州植保有限公司 | Preparation method of chelated rare earth |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152565A (en) * | 1995-12-20 | 1997-06-25 | 郑州大学 | Mixed amino-acid complex state multielement micro-fertilizer and making method |
| CN1175566A (en) * | 1996-09-03 | 1998-03-11 | 郎昭平 | Serial compound rare-earth trace element fertilizer and producing process thereof |
| CN1331273A (en) * | 2000-06-26 | 2002-01-16 | 王昌志 | Process for preparing soil improver from xanthohumic acid, composite amino acids and draught-resistant organic fertilizer |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8071331B2 (en) * | 2008-06-03 | 2011-12-06 | Ajinomoto U.S.A., Inc. | Method of producing amino acid metal chelates |
-
2010
- 2010-12-25 CN CN2010106050063A patent/CN102101809B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152565A (en) * | 1995-12-20 | 1997-06-25 | 郑州大学 | Mixed amino-acid complex state multielement micro-fertilizer and making method |
| CN1175566A (en) * | 1996-09-03 | 1998-03-11 | 郎昭平 | Serial compound rare-earth trace element fertilizer and producing process thereof |
| CN1331273A (en) * | 2000-06-26 | 2002-01-16 | 王昌志 | Process for preparing soil improver from xanthohumic acid, composite amino acids and draught-resistant organic fertilizer |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102101809A (en) | 2011-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102167635B (en) | Nutritious and high efficient foliar fertilizer for growth of humic acid plant and preparation method thereof | |
| CN103214317B (en) | Active amino acid water-soluble fertilizer as well as preparation method and application thereof | |
| CN102815999B (en) | Fertilizer special for hybrid rice | |
| CN105254452A (en) | Fertilizer for fruit trees and production method of fertilizer | |
| CN104557282B (en) | One cultivates peanut special inorganic fertilizer and preparation method thereof | |
| CN100546948C (en) | Plant source disease-resistant foliage fertilizer and preparation method thereof | |
| CN102826896B (en) | Special winter wheat base fertilizer and preparation method of special winter wheat base fertilizer | |
| CN102826934B (en) | Special sweet potato fertilizer and preparation method of special sweet potato fertilizer | |
| CN102815997B (en) | Special fertilizer for early rice base fertilizer | |
| CN105036926A (en) | Foliar nutrient special for tea-oil trees and application thereof | |
| CN103030460A (en) | Special liquid rooting fertilizer for vegetables as well as preparation method and application of special liquid rooting fertilizer | |
| CN105272597A (en) | Liquid organic fertilizer and preparation method | |
| CN103539575A (en) | Development method of special efficient fulvic acid liquid compound fertilizer for potatoes | |
| CN102503698B (en) | Chelated trace element fertilizer-medicament mixture | |
| CN101891520A (en) | Amino acid foliar fertilizer | |
| CN104230514A (en) | Earthworm hydrolysate and rare earth compound active foliar liquid fertilizer as well as preparation method and using method thereof | |
| CN102515885A (en) | Method for preparing humic acid by using weathered coal | |
| CN106561369A (en) | Selenium rich paddy rice planting method | |
| CN102659456A (en) | Amino-acid organic compound fertilizer and production method thereof | |
| CN106748291A (en) | It is a kind of to contain 14 kinds of composite fluid Water soluble fertilizers of element and preparation method thereof | |
| CN105061077A (en) | Special water-soluble fertilizer series for red jujubes and preparation method thereof | |
| CN104355818A (en) | Tomato soilless culture medium | |
| CN101152989A (en) | Drought resisting accretion modifying agent for yellow humic acid plants | |
| CN102101809B (en) | Preparation process and using method for amino acid rare-earth zinc micro-fertilizer | |
| CN104829356A (en) | Fertilizer for mulberry planting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: 344400 rich industrial park, Yihuang County, Jiangxi, Fuzhou Patentee after: JIANGXI RUIBOTE BIOTECHNOLOGY CO.,LTD. Address before: Six industrial park, 344400 Li County, Jiangxi, Nanchang, Yihuang Patentee before: Jiangxi Ruibote Composite Fertilizer Plant |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation process and usage method of an amino acid rare earth zinc micro fertilizer Effective date of registration: 20230602 Granted publication date: 20130424 Pledgee: Agricultural Bank of China Limited Yihuang County sub branch Pledgor: JIANGXI RUIBOTE BIOTECHNOLOGY CO.,LTD. Registration number: Y2023980042819 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20130424 Pledgee: Agricultural Bank of China Limited Yihuang County sub branch Pledgor: JIANGXI RUIBOTE BIOTECHNOLOGY CO.,LTD. Registration number: Y2023980042819 |