CN103073348B - Compound water-soluble fertilizer that a kind of citrus crop is special and preparation application process thereof - Google Patents
Compound water-soluble fertilizer that a kind of citrus crop is special and preparation application process thereof Download PDFInfo
- Publication number
- CN103073348B CN103073348B CN201210449361.5A CN201210449361A CN103073348B CN 103073348 B CN103073348 B CN 103073348B CN 201210449361 A CN201210449361 A CN 201210449361A CN 103073348 B CN103073348 B CN 103073348B
- Authority
- CN
- China
- Prior art keywords
- soluble fertilizer
- water
- citrus
- solution
- fertilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 142
- 241000207199 Citrus Species 0.000 title claims abstract description 65
- 235000020971 citrus fruits Nutrition 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 52
- 150000001875 compounds Chemical class 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 235000001014 amino acid Nutrition 0.000 claims abstract description 52
- 150000001413 amino acids Chemical class 0.000 claims abstract description 52
- 229910052796 boron Inorganic materials 0.000 claims abstract description 27
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 239000011573 trace mineral Substances 0.000 claims abstract description 11
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 11
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 9
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 230000009286 beneficial effect Effects 0.000 claims abstract description 7
- 239000000470 constituent Substances 0.000 claims abstract description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 7
- 239000007858 starting material Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 46
- 239000000243 solution Substances 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- 235000013399 edible fruits Nutrition 0.000 claims description 25
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 24
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- 239000000843 powder Substances 0.000 claims description 19
- 239000003002 pH adjusting agent Substances 0.000 claims description 18
- 239000007921 spray Substances 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 14
- 239000010413 mother solution Substances 0.000 claims description 13
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 12
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 12
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 12
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 12
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229940099596 manganese sulfate Drugs 0.000 claims description 11
- 239000011702 manganese sulphate Substances 0.000 claims description 11
- 235000007079 manganese sulphate Nutrition 0.000 claims description 11
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 239000011777 magnesium Substances 0.000 claims description 10
- 239000011701 zinc Substances 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 9
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 9
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 9
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical group [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 8
- 230000007062 hydrolysis Effects 0.000 claims description 8
- 238000006460 hydrolysis reaction Methods 0.000 claims description 8
- 239000012452 mother liquor Substances 0.000 claims description 8
- 239000004302 potassium sorbate Substances 0.000 claims description 8
- 235000010241 potassium sorbate Nutrition 0.000 claims description 8
- 229940069338 potassium sorbate Drugs 0.000 claims description 8
- 239000003755 preservative agent Substances 0.000 claims description 8
- 230000002335 preservative effect Effects 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 8
- 229960001763 zinc sulfate Drugs 0.000 claims description 8
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 7
- 239000011609 ammonium molybdate Substances 0.000 claims description 7
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 7
- 229940010552 ammonium molybdate Drugs 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- HPDFFVBPXCTEDN-UHFFFAOYSA-N copper manganese Chemical compound [Mn].[Cu] HPDFFVBPXCTEDN-UHFFFAOYSA-N 0.000 claims description 7
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 7
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 7
- 238000009792 diffusion process Methods 0.000 claims description 7
- 239000011790 ferrous sulphate Substances 0.000 claims description 7
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 5
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 4
- 238000000855 fermentation Methods 0.000 claims description 4
- 230000004151 fermentation Effects 0.000 claims description 4
- 230000035784 germination Effects 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims 2
- 235000015097 nutrients Nutrition 0.000 abstract description 13
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000013589 supplement Substances 0.000 abstract description 6
- 241000196324 Embryophyta Species 0.000 abstract description 4
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 description 24
- 230000004720 fertilization Effects 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 16
- 241001672694 Citrus reticulata Species 0.000 description 15
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 230000012010 growth Effects 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 240000002319 Citrus sinensis Species 0.000 description 10
- 235000005976 Citrus sinensis Nutrition 0.000 description 10
- 238000007792 addition Methods 0.000 description 10
- RZLVQBNCHSJZPX-UHFFFAOYSA-L zinc sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Zn+2].[O-]S([O-])(=O)=O RZLVQBNCHSJZPX-UHFFFAOYSA-L 0.000 description 10
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 230000034303 cell budding Effects 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 238000003306 harvesting Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 235000016709 nutrition Nutrition 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 4
- 230000008485 antagonism Effects 0.000 description 4
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 230000009920 chelation Effects 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 210000003746 feather Anatomy 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 239000004283 Sodium sorbate Substances 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229960000355 copper sulfate Drugs 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229960001781 ferrous sulfate Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 2
- 235000019250 sodium sorbate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 229940108928 copper Drugs 0.000 description 1
- 238000012272 crop production Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 229960003390 magnesium sulfate Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229940074146 orange peel wax Drugs 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses the special compound water-soluble fertilizer of a kind of citrus crop, preparation method and application technique, being mainly used in plant nutrient field, its water-soluble fertilizer constituent includes: amino acid starting material, a great number of elements P and K, moderate-element Mg and Ca, trace element Fe, Mn, Zn, B, Mo and Cu, beneficial element Si, auxiliary agent, PH regulator and aqueous solution.It is prepared by by aminoacids complex 15 DEG C at normal temperatures--35 DEG C of water-soluble fertilizers made by particular order chelating Mn, Fe, Cu, Mg, Ca and Zn and six kinds of metallic elements, and in the different growing stages of crop, have for the rational application of fertilizer, realize the various nutrient elements balance needed for citrus crop to supplement, improve yield and the quality of citrus crop.
Description
Technical field:
The invention belongs to the water-soluble fertilizer of fruit tree in agricultural production, be specifically related to the special compound water-soluble fertilizer of a kind of citrus crop, preparation method and application technique.
Technical background:
China is one of important country of origin of Citrus, and cultivation history is long, and Citrus resource and improved seeds enrich, and are described as " world's Citrus resource treasure-house ".Since entering for 20th century, China's Citrus development is swift and violent, all occupies first place in the world in grown worldwide area, yield.At present, owing to the single of fertilizer type and irrational cropping system cause the nutrient in soil and crop extremely uneven, seriously result in the decline of the yield of China's Citrus and fruit quality.Therefore efficiently, the rational application of fertilizer has become the important channel realizing Citrus high yield, high-quality.
In nutrient needed for 16 kind of plant, the contribution rate of crop yield is 90% by big moderate-element, and the contributive rate of the quality of crop can be reached more than 90% by trace element, and the demand of nutrient all be there are differences by Different Crop.Use same that in traditional fertilization mode, peasant household is only single or same class fertilizer, cause Citrus crop alimentary element serious unbalance, and life-time service will be very big to fruit tree harm.According to statistics, in current China Citrus cultivated area, 100% area Citrus crop alimentary is unbalance, ubiquity medium trace element such as the disappearance of Ca, Mg, Zn, B, the phenomenon that a great number of elements such as N is excessive, cause that citrus disease is frequent, yield poorly down, fruit drop, fruity thin, the series of problems such as fruit quality degradation.
The advantage that water soluble fertilizer has minimizing nutrient loss, utilization rate of fertilizer is high, has been listed in the fertilization mode that state key is advocated.Applications of water soluble fertilizers can supplement Citrus desired nutritional in time, takes effect rapidly；Some medium trace element can dramatically increase its absorbance by after complexation, can reach tens times of root fertilising absorption；Therefore water-soluble fertilizer is the important fertilization mode of one improving Citrus quality.But existing water-soluble fertilizer generally still suffers from series of problems in product quality and manufacture process, as: (1) water-soluble fertilizer kind is a lot of on the market at present, but it mostly is single big-and-middle or trace compound, specific aim is not strong, nutrition is comprehensive not, without the specific complex type water-soluble fertilizer being specifically designed for Citrus crop, Mg in the patent of publication number CN1314327A and needed for not mentioned interpolation Citrus crop, Zn, the important elements such as B, and at publication number: the patent of CN102206120A adopt boric acid as the main component of B element, but boric acid is poorly soluble, effective content is low, can not effectively supplement Citrus nutrition, improve Quality Parameters in Orange；(2) fertilizer element is ionic state, and the easy antagonism of each nutritional labeling, nutritional labeling utilization rate is low；(3) fertilizer metal element chelate process needs the environment of continuous high temperature carries out, cause production cost high；(4) Citrus crop leaf wax coat oil is thick, and the water-soluble fertilizer absorption without specific adjuvant is too poor.Limit the Field information of water soluble fertilizer.
Accordingly, it would be desirable to one is for the distinctive aminoacids complex water-soluble fertilizer of citrus crop, the method adopting convenient and simple preparation, it is equipped with rational application technique, supplements the deficiencies in the prior art, meet Field information and the actual production demand of citrus crop production.
Summary of the invention:
The present invention is according to the growth characteristic of citrus crop, Planting status and containing aminoacid water-soluble fertilizer application characteristic and Production requirement, develop the compound water-soluble fertilizer that a kind of citrus crop is special, and it is equipped with proprietary preparation method and application technique, its purpose can better overcome Problems existing and the shortcoming of above-mentioned prior art, realize the various nutrient elements balance needed for citrus crop to supplement, the room temperature chelating of metallic element, the efficient and rational of fertilizer are used, thus improving orange yield and quality.
Technical scheme is as follows:
1, the compound water-soluble fertilizer that a kind of citrus crop is special, it is characterised in that: described fertilizer constituent includes amino acid starting material, a great number of elements P and K, moderate-element Mg and Ca, trace element Fe, Mn, Zn, B, Mo and Cu, beneficial element Si, auxiliary agent, pH adjusting agent and aqueous solution；Described fertilizer is by aminoacids complex 15 DEG C at normal temperatures--the water-soluble fertilizer that 35 DEG C of chelating Mg, Ca, Fe, six kinds of metallic elements of Mn, Zn and Cu are made.This Composite amino-acid-containinwater-soluble water-soluble fertilizer is according to China's Citrus crop fertilizer requirement special formulation composition, and rich in 18 seed amino acids and 11 kinds of nutrients, and at normal temperatures by 6 kinds of whole chelatings of metallic element, each composition steady dissolution, without antagonism sedimentation problem.This formula water-soluble fertilizer both can supplement Citrus crop alimentary targetedly, improve yield, also can improve the activity of relevant enzyme further and improve the stability of cell, promote robust plant growth, strengthen plant drought, cold-resistant and resistance against diseases, simultaneously for the crop meeting with poisoning, fertilizer damage or other injuries, can effectively alleviate hazard symptoms, promote that crop recovers life.
2, the compound water-soluble fertilizer that citrus crop according to technical scheme 1 is special, its composition chemical composition is as follows by mass percentage: compounded amino acid starting material 25-35%, a great number of elements P and K composition are 3-5%, moderate-element Mg and Ca composition are 12-20%, trace element Fe, Mn, Zn, B, Mo and Cu composition are 12-20%, and beneficial element Si composition is 0.1%-2%, and auxiliary component is 3-8%, pH adjusting agent composition is 2-4%, and all the other compositions are water.This component and ratio are that the growth characteristic according to citrus crop selects suitable component and proportioning, can be prevented effectively from and cause degradation series of problems under citrus crop yield reduction, quality due to element imbalance.Wherein N element is excessive, so avoiding adding N element raw material；Moderate-element Ca, Mg, trace element B, Zn disappearance is serious, so increasing content, and improves its utilization rate with chelating amino acids；Because of the beneficial element Si effect to Quality Parameters in Orange, the useful elements Si of special interpolation；Because of the physiological characteristics that orange peel wax coat is thicker, increase auxiliary component kind and ratio；A great number of elements P, K, trace element Fe, Mn, Mo, Cu are also element needed for Citrus routine, add each element raw material.
3, the compound water-soluble fertilizer that citrus crop according to technical scheme 1 is special, it is characterised in that: described compounded amino acid starting material includes one or more mixture in animal hair hydrolysis Aminoacids complex powder, bean cake, oil cake, yeast fermentation broth, fermented gournet powder liquid；Described a great number of elements P and K ingredient origin are potassium dihydrogen phosphate；Described moderate-element Mg and Ca ingredient origin be: magnesium sulfate and calcium nitrate；Described trace element Fe, Mn, Zn, Mo and Cu ingredient origin respectively ferrous sulfate, manganese sulfate, zinc sulfate, ammonium molybdate and copper sulfate；Described trace element B component source is instant boron, and described beneficial element Si ingredient origin is silicon dioxide.The present invention adopts aminoacids complex, and its amino acid whose effective ingredient substantially increases, it is possible to decrease production cost.Adopting potassium dihydrogen phosphate as raw material, it contains phosphorus and two kinds of a great number of elements of potassium, with low cost, easy to use.The element such as calcium, magnesium, ferrum, manganese, zinc, molybdenum, copper, silicon source uses calcium nitrate, magnesium sulfate, ferrous sulfate, manganese sulfate, zinc sulfate, ammonium molybdate, copper sulfate and silicon dioxide, raw material easily to obtain respectively, cheap；The phenomenon of absorption it addition, spy solves problem for the indissoluble in the processing technology containing aminoacid water-soluble fertilizer of boron element in prior art, adopts the instant boron of Novel boron compound, has dissolubility height, and Crop is fast, the feature that utilization rate is high.
4, the compound water-soluble fertilizer that citrus crop according to technical scheme 3 is special, its constituent is as follows by weight percentage, and potassium dihydrogen phosphate is 3-5%, and magnesium sulfate is 5-12%, calcium nitrate 5-12%；Ferrous sulfate 1-2%, manganese sulfate 1-2%, zinc sulfate 3-6%, ammonium molybdate 0.1-2%, copper sulfate 1-3%, instant boron 5-10%,；Silicon dioxide 0.1%-2%.Magnesium sulfate, calcium nitrate, instant boron, zinc sulfate composition more compared with all the other component contents, be owing to Citrus crop is relatively big to the demand of the elements such as B, Ca, Mg, Zn, with the addition of the primary raw material silicon dioxide of beneficial element Si needed for citrus plant growth simultaneously.Meanwhile, appropriate proportioning is taked, it is ensured that the demand of multiple element is balanced by Citrus crop, meets the Field information of citrus crop.
5, the compound water-soluble fertilizer that citrus crop according to technical scheme 1 is special, its auxiliary agent includes dispersant, wetting agent, diffusion agent and preservative, it is characterized in that: described dispersant is calcium lignosulfonate, described wetting agent is glycerol, described diffusion agent is the modified trisiloxanes of ethyoxyl, and described preservative is potassium sorbate.Above-mentioned auxiliary agent all not with add nutrient substance generation antagonism and other reagentias, and auxiliary agent all contains some nutrients needed for plant, can also supplementing the nutrients on the basis of water-soluble fertilizer stability improving, above-mentioned auxiliary agent adopts food grade materials, green safety.
6, auxiliary agent according to technical scheme 5, it is characterized in that: each constituent content accounts for water-soluble fertilizer weight ratio, and to be respectively as follows: dispersant calcium lignosulfonate be 0.01-2%, wetting agent glycerol is 0.01-2%, the modified trisiloxanes of diffusion agent ethyoxyl is 2-6%, and potassium sorbate preservative is 0.1-0.5%.Interpolation calcium lignosulfonate, potassium sorbate can increase the liquid stability of water-soluble fertilizer, and to avoid liquid precipitation, the resting period is more of a specified duration；And glycerol is when spraying fertilizer, can strengthening drop wettability on blade, the modified trisiloxanes of ethyoxyl is the special composition added for the physiological characteristics of Citrus waxiness thickness, brute force can penetrate wax coat, increase infiltration and the diffusion of solution, improve the utilization rate of fertilizer, and effectively economize on water.
7, the compound water-soluble fertilizer that a kind of citrus crop according to technical scheme 1 is special, it is characterised in that: described pH adjusting agent is one or more in sodium hydroxide, potassium hydroxide, phosphoric acid or nitric acid.
8, the preparation method of the compound water-soluble fertilizer that citrus crop according to technical scheme 1 is special, its step is as follows:
(1) mother solution configuration: Aminoacids complex powder 250-350 part, solution 200-400 part, stirs, shakes up, be configured to the span amino acid mother liquor that pH is 2-5；
(2) chelatropic reaction one: room temperature 15 DEG C--at 35 DEG C, add pH adjusting agent 5-25 part, stirring is to shaking up, solution ph is adjusted to 3-7, again manganese sulfate, copper sulfate and ferrous sulfate 30-60 part altogether is added the span amino acid mother liquor that step (1) obtains, stirring 1-5h, copper-manganese ferrum chelating completes；
(3) chelatropic reaction two: room temperature 15 DEG C--at 35 DEG C, add pH adjusting agent 5-25 part, and be stirred continuously to shaking up, solution ph is adjusted to 6-10, again calcium nitrate, magnesium sulfate, zinc sulfate 130-260 part altogether is added in the solution that step (2) obtains, stirring 1-5h, completes；
(4) all the other elements add: potassium dihydrogen phosphate 20-150 part added in the solution that step (3) obtains, and are eventually adding boron raw material, ammonium molybdate 50-120 part, silica 1-20 parts altogether, stir 0.1-2h；
(5) auxiliary agent adds: auxiliary agent 30-80 part is added in the solution that step (4) obtains, stirs 0.1-2h, filters, formed product.
This water-soluble fertilizer preparation method, innovative point is in that: all chelatropic reactions carry out all at normal temperatures, and chelation percent can reach more than 95%, it is not necessary to increases heating equipment, greatly reduces production cost；In all the other element adding procedures, by the conservative control of order of addition and time, solve dissolving and the sedimentation problem of important phosphatic raw materials potassium dihydrogen phosphate, make impurity level control below 0.5%.
9, the compound water-soluble fertilizer that citrus crop according to technical scheme 1 is special, its application technique is:
(1) the citrus crop germination phase, this compound water-soluble fertilizer dilutes 800 times, adopts foliage-spray method to use, uses 60-80g for every mu；
(2) citrus crop bears fruit the phase, and this compound water-soluble fertilizer dilutes 500 times, adopts foliage-spray method to use, uses 90-120g for every mu；
(3) citrus crop and fruit expanding stage, this compound water-soluble fertilizer dilutes 500 times, adopts foliage-spray method to use, used once at interval of 30 days, totally 3 times, use 90-120g for each every mu.
Adopt above application technique, be according to the Citrus crop different growth phases difference to nutrient demand, respectively budding period, the phase of bearing fruit and fruit expanding period carry out reasonable, apply fertilizer efficiently, to reach to improve the effect of crop yield and quality.
In sum, the invention provides the compound water-soluble fertilizer that a kind of citrus crop is special, and be equipped with proprietary preparation method and application technique, overcome current citrus crop alimentary element unbalance, the series of problems such as boron raw material indissoluble solution, high temperature chelating.In the preparation method of the compound water-soluble fertilizer that citrus crop of the present invention is special, by Comprehensive Control pH value, chelating time, dispensing ratio, chelating temperature, filter out the chelating condition of a kind of the best so that it is when heating, it is also possible to realize the chelation percent of each element more than 95%；By screening each metal element chelate order, time, form the water-soluble fertilizer of multi-element chelate, liquid stabilising, without precipitation after placement, spray and process also causes without antagonism between each element element difficulty absorb problem；The present invention containing aminoacid water-soluble fertilizer, filter out the instant boron of boron raw material of the best, its dissolubility be common Borax, 10 times of boron acid, and solve the sedimentation problem in producing at present.Meanwhile, adopt rational application technique, citrus crop different growing stages is applied fertilizer targetedly, better to ensure fertilization effect, reach to improve the purpose of crop quality and yield.
Therefore, the present invention operates facility, reduces its production cost, and chelation percent is high, substantially increases the citrus crop comprehensive absorption rate to each nutrient, according to it have been experienced that, improve comprehensive absorption rate and reach 60%-80%.After field is used, its effect of increasing production can reach more than 12%.This is notable containing aminoacid water-soluble fertilizer fertilizer efficiency, stable performance, low production cost, be a efficiently, the water-soluble fertilizer of environmental protection, be especially suitable for and promote the use of.
Detailed description of the invention:
By embodiment, the present invention is further illustrated, and embodiment should not be regarded as limitation of the present invention.
Embodiment one:
Mother solution configures: Aminoacids complex powder includes animal hair hydrolysis Aminoacids complex powder and totally 250 parts of bean cake animal feather hydrolysis amino acid powder, 200 parts of water, stirs, shakes up, is configured to the span amino acid mother liquor that pH is 3.5；
Chelatropic reaction one: at room temperature 15 DEG C, add pH adjusting agent sodium hydroxide to stir to shaking up, solution ph is adjusted to 5.6, then manganese sulfate 10 parts, copper sulphate pentahydrate 10 parts and 20 parts of priorities of ferrous sulfate heptahydrate are added above-mentioned mother solution (1), stirring 1h, copper-manganese ferrum chelating completes；
Chelatropic reaction two: at room temperature 20 DEG C, add pH adjusting agent sodium hydroxide, phosphoric acid and be stirred continuously to shaking up, solution ph being adjusted to 8.3, then calcium nitrate 50 parts, 50 parts of magnesium sulfate, 60 parts of priorities of zinc sulphate heptahydrate are added above-mentioned solution (2), stirring 2.5h, completes；
All the other elements add: by potassium dihydrogen phosphate 30 parts, stir, and finally by instant boron 50 parts, ammonium heptamolybdate 20 parts, silica 1 part adds above-mentioned solution, stirs 0.1h；
Auxiliary agent adds: by calcium lignosulfonate, glycerol, the modified trisiloxanes of ethyoxyl and the potassium sorbate preservative totally 30 parts of above-mentioned solution of additions (4), stirs 1h, filters, formed product, it is thus achieved that the compound water-soluble fertilizer of the present invention.
The mandarin orange of Yichang City, Hubei Province Zigui County is tested.Process as water-soluble fertilizer of the present invention, existing Citrus water-soluble fertilizer A and clear water.
Test method: test is set to three and processes four repetitions.
Process 1.: it is compound containing aminoacid water soluble fertilizer that conventional fertilizer application+the present embodiment produces, in the mandarin orange budding period, this Term Fertilization 60g/ mu, dilutes 800 times；In the phase of bearing fruit, this Term Fertilization 120g/ mu, dilutes 500 times；At fruit expanding period, this Term Fertilization 90g/ mu, dilute 500 times, used once at interval of 30 days, totally 3 times；Below foliage-spray method is all adopted to carry out.
Processing 2.: conventional fertilizer application+water-soluble fertilizer A, water-soluble fertilizer is according to use is described.
Process 3.: conventional fertilizer application+foliage-spray equivalent clear water.Between each process except measures of fertilizer, other control measures keep consistent.Yield is measured when fruit harvesting.
Test results and analysis: spraying the embodiment of the present invention one compound containing after aminoacid water soluble fertilizer, substantially (table 1), yield is the highest in all process, compares with compareing clear water for the increase of mandarin orange yield, and every mu is increased production 446 kilograms, and rate of growth reaches 13.1%.；Comparing with water-soluble fertilizer A, every mu is increased production 284 kilograms, and rate of growth is 8%.
The impact on mandarin orange yield (kg/acre) of table 1 different disposal
Conclusion: compared with other water-soluble fertilizers, mandarin orange is had the effect of increasing both production and income by the Composite amino-acid-containinwater-soluble water-soluble fertilizer in the present invention.
Embodiment two:
Mother solution configures: Aminoacids complex powder includes totally 350 parts of the several amino acids powder of oil cake, yeast fermentation broth, 400 parts of water, stirs, shakes up, is configured to the span amino acid mother liquor that pH is 2.6；
Chelatropic reaction one: at room temperature 35 DEG C, add pH adjusting agent potassium hydroxide to stir to shaking up, solution ph is adjusted to 4.5, then manganese sulfate 20 parts, copper sulphate pentahydrate 30 parts and 10 parts of priorities of ferrous sulfate heptahydrate are added above-mentioned mother solution (1), stirring 5h, copper-manganese ferrum chelating completes；
Chelatropic reaction two: at room temperature 25 DEG C, add pH adjusting agent potassium hydroxide, nitric acid and be stirred continuously to shaking up, solution ph being adjusted to 6.8, then calcium nitrate, magnesium sulfate, zinc sulphate heptahydrate totally 130 parts of priorities are added above-mentioned solution (2), stirring 1h, completes；
All the other elements add: add potassium dihydrogen phosphate totally 50 parts, stir, and finally by instant boron, ammonium heptamolybdate totally 120 parts, silica 15 parts adds above-mentioned solution, stirs 2h；
Auxiliary agent adds: by sodium lignin sulfonate, glycerol, the modified trisiloxanes of ethyoxyl and the sodium sorbate totally 80 parts of above-mentioned solution of additions (4), stirs 0.1h, filters, formed product, it is thus achieved that the compound water-soluble fertilizer of the present invention.
The test carried out on Hunan Province's Huaihua City Citrus sinensis Osbeck.
Process as water-soluble fertilizer of the present invention, prior art water-soluble fertilizer B and clear water object.
Test method: test is set to three and processes four repetitions.Process 1.: it is compound containing aminoacid water soluble fertilizer that conventional fertilizer application+the present embodiment produces, in the Citrus sinensis Osbeck budding period, this Term Fertilization 70g/ mu, dilutes 800 times；In the phase of bearing fruit, this Term Fertilization 110g/ mu, dilutes 500 times；At fruit expanding period, this Term Fertilization 100g/ mu, dilute 500 times, used once at interval of 30 days, totally 3 times；Below foliage-spray method is all adopted to carry out.
Processing 2.: conventional fertilizer application+water-soluble fertilizer B, water-soluble fertilizer is according to use is described.
Process 3.: conventional fertilizer application+foliage-spray equivalent clear water.Between each process except measures of fertilizer, other control measures keep consistent.Yield is measured when fruit harvesting.
Test results and analysis: spraying the embodiment of the present invention one compound containing after aminoacid water soluble fertilizer, substantially (table 2), yield is the highest in all process, compares with compareing clear water for the increase of Citrus sinensis Osbeck yield, and every mu is increased production 775 kilograms, and rate of growth reaches 13.2%.；Comparing with water-soluble fertilizer B, every mu is increased production 617 kilograms, and rate of growth is 10.3%.
The impact on Citrus sinensis Osbeck yield (kg/acre) of table 2 different disposal
Conclusion: compared with other water-soluble fertilizers, Citrus sinensis Osbeck is had the effect of increasing both production and income by the Composite amino-acid-containinwater-soluble water-soluble fertilizer in the present invention.
Embodiment three:
Mother solution configures: Aminoacids complex powder includes totally 280 parts of the several amino acids powder of animal feather hydrolysis amino acid powder, bean cake, oil cake, 285 parts of water, stirs, shakes up, is configured to the span amino acid mother liquor that pH is 5；
Chelatropic reaction one: at room temperature 30 DEG C, add pH adjusting agent sodium hydroxid, stirring to shaking up, solution ph is adjusted to 7, then manganese sulfate, copper sulphate pentahydrate and ferrous sulfate heptahydrate totally 30 parts of priorities are added above-mentioned mother solution (1), stirring 3.0h, copper-manganese ferrum chelating completes；
Chelatropic reaction two: at room temperature 35 DEG C, add pH adjusting agent potassium hydroxide, nitric acid and be stirred continuously to shaking up, solution ph being adjusted to 10, then calcium nitrate, magnesium sulfate, zinc sulphate heptahydrate totally 210 parts of priorities are added above-mentioned solution (2), stirring 4.6h, completes；
The interpolation of all the other elements adds potassium dihydrogen phosphate totally 40 parts, stirs, and finally by instant boron, ammonium heptamolybdate totally 75 parts, silicon dioxide 20 parts adds above-mentioned solution, stirs 2h；
Auxiliary agent adds: by calcium lignosulfonate, glycerol, the modified trisiloxanes of ethyoxyl and the sodium sorbate totally 55 parts of above-mentioned solution of additions (4), stirs 2h, filters, formed product, it is thus achieved that the compound water-soluble fertilizer of the present invention.
Hunan Province Huaihua City Citrus chachiensis Hort. is tested.
Process as water-soluble fertilizer of the present invention, the water-soluble fertilizer C of prior art and clear water.
Test method: test is set to three and processes four repetitions.
Process 1.: conventional fertilizer application+the present embodiment produce compound containing aminoacid water soluble fertilizer, this water-soluble fertilizer adopts foliage-spray method to carry out in crop different growing stages, in the Citrus chachiensis Hort. budding period, this Term Fertilization 80g/ mu, dilute 800 times；In the phase of bearing fruit, this Term Fertilization 100g/ mu, dilutes 500 times；At fruit expanding period, this Term Fertilization 110g/ mu, dilute 500 times, used once at interval of 30 days, totally 3 times.
Processing 2.: conventional fertilizer application+water-soluble fertilizer C, water-soluble fertilizer is according to use is described.
Process 3.: conventional fertilizer application+foliage-spray equivalent clear water.Between each process except measures of fertilizer, other control measures keep consistent.Yield is measured when fruit harvesting.
Test results and analysis: spraying the embodiment of the present invention one compound containing after aminoacid water soluble fertilizer, substantially (table 3), yield is the highest in all process, compares with compareing clear water for the increase of Citrus chachiensis Hort. yield, and every mu is increased production 356 kilograms, and rate of growth reaches 20%.；Comparing with water-soluble fertilizer C, every mu is increased production 196 kilograms, and rate of growth is 10%.
The impact on Citrus chachiensis Hort. yield (kg/acre) of table 3 different disposal
Conclusion: compared with other water-soluble fertilizers, Citrus chachiensis Hort. is had the effect of increasing both production and income by the Composite amino-acid-containinwater-soluble water-soluble fertilizer in the present invention.
Embodiment four:
Mother solution configures: Aminoacids complex powder includes animal hair hydrolysis Aminoacids complex powder, yeast fermentation broth, fermented gournet powder liquid 320 parts, 345 parts of water, stirs, shakes up, is configured to the span amino acid mother liquor that pH is 2；
Chelatropic reaction one: room temperature 25 DEG C, adds pH adjusting agent, and solution ph, to shaking up, is adjusted to 3 by stirring, then by manganese sulfate, copper sulfate and the ferrous sulfate totally 50 parts of above-mentioned mother solution of additions (1), stirs 1h, and copper-manganese ferrum chelating completes；
Chelatropic reaction two: at room temperature 35 DEG C, adds pH adjusting agent and is stirred continuously to shaking up, solution ph is adjusted to 6, then by calcium nitrate, magnesium sulfate, the zinc sulfate totally 260 parts of above-mentioned solution of additions (2), stirs 5h, complete；
All the other elements add: added by potassium dihydrogen phosphate 45 parts in solution, and finally by instant boron, ammonium molybdate totally 96 parts, silicon dioxide 5 parts adds above-mentioned solution, stirs 0.1h；
Auxiliary agent adds: by calcium lignosulfonate, glycerol, the modified trisiloxanes of ethyoxyl and 7 kinds of auxiliary agents of the potassium sorbate totally 65 parts of above-mentioned solution of additions (4), stirs 0.1h, filters, formed product.
Danjiangkou, Hubei Province mandarin orange is tested.
Process respectively water-soluble fertilizer of the present invention, the existing water-soluble fertilizer B with regard to technology and clear water.
Test method: test is set to three process four repetitions.
Processing 1.: it is compound containing aminoacid water soluble fertilizer that conventional fertilizer application+the present embodiment one produces, this water-soluble fertilizer adopts foliage-spray method to carry out in crop different growing stages, in the mandarin orange budding period, this Term Fertilization 75g/ mu, dilutes 800 times；In the phase of bearing fruit, this Term Fertilization 120g/ mu, dilutes 500 times；At fruit expanding period, this Term Fertilization 120g/ mu, dilute 500 times, used once at interval of 30 days, totally 3 times.
Processing 2.: conventional fertilizer application+water-soluble fertilizer B, water-soluble fertilizer is according to use is described.
Process 3.: conventional fertilizer application+foliage-spray equivalent clear water.Between each process except measures of fertilizer, other control measures keep consistent.Yield is measured when fruit harvesting.
Test results and analysis: spraying the embodiment of the present invention one compound containing after aminoacid water soluble fertilizer, substantially (table 4), yield is the highest in all process, compares with compareing clear water for the increase of mandarin orange yield, and every mu is increased production 502 kilograms, and rate of growth reaches 16.7%.；Comparing with water-soluble fertilizer B, every mu is increased production 285 kilograms, and rate of growth is 8.8%.
The impact on mandarin orange yield (kg/acre) of table 4 different disposal
Conclusion: compared with other water-soluble fertilizers, mandarin orange is had the effect of increasing both production and income by the Composite amino-acid-containinwater-soluble water-soluble fertilizer in the present invention.
Embodiment five:
Mother solution configures: Aminoacids complex powder includes animal hair hydrolysis Aminoacids complex powder and totally 300 parts of bean cake animal feather hydrolysis amino acid powder, 325 parts of water, stirs, shakes up, is configured to the span amino acid mother liquor that pH is 3.2；
Chelatropic reaction one: at room temperature 18 DEG C, add pH adjusting agent sodium hydroxide to stir to shaking up, solution ph is adjusted to 3.9, then manganese sulfate 12 parts, copper sulphate pentahydrate 15 parts and 10 parts of priorities of ferrous sulfate heptahydrate are added above-mentioned mother solution (1), stirring 1h, copper-manganese ferrum chelating completes；
Chelatropic reaction two: at room temperature 28 DEG C, add pH adjusting agent sodium hydroxide, phosphoric acid and be stirred continuously to shaking up, solution ph being adjusted to 8.3, then calcium nitrate 95 parts, 95 parts of magnesium sulfate, 58 parts of priorities of zinc sulphate heptahydrate are added above-mentioned solution (2), stirring 3.2h, completes；
All the other elements add: by potassium dihydrogen phosphate 48 parts, stir, and finally instant boron 92 parts, ammonium heptamolybdate 5 parts are added above-mentioned solution, and silica 12 parts adds above-mentioned solution, stirs 1.8h；
Auxiliary agent adds: by calcium lignosulfonate, glycerol, the modified trisiloxanes of ethyoxyl and the potassium sorbate preservative totally 72 parts of above-mentioned solution of additions (4), stirs 1.5h, filters, formed product, it is thus achieved that the compound water-soluble fertilizer of the present invention.
Test carries out on city of Xunwu of Jiangxi Citrus sinensis Osbeck.Process as water-soluble fertilizer of the present invention, existing Citrus water-soluble fertilizer A and clear water.
Test method: test is set to three process four repetitions.Processing 1.: it is compound containing aminoacid water soluble fertilizer that conventional fertilizer application+the present embodiment one produces, this water-soluble fertilizer adopts foliage-spray method to carry out in crop different growing stages, in the Citrus sinensis Osbeck budding period, this Term Fertilization 65g/ mu, dilutes 800 times；In the phase of bearing fruit, this Term Fertilization 105g/ mu, dilutes 500 times；At fruit expanding period, this Term Fertilization 98g/ mu, dilute 500 times, used once at interval of 30 days, totally 3 times.
Processing 2.: conventional fertilizer application+existing Citrus water-soluble fertilizer A, water-soluble fertilizer is according to use is described.
Process 3.: conventional fertilizer application+foliage-spray equivalent clear water.Between each process except measures of fertilizer, other control measures keep consistent.Yield is measured when fruit harvesting.
Test results and analysis: spraying the embodiment of the present invention one compound containing after aminoacid water soluble fertilizer, substantially (table 5), yield is the highest in all process, compares with compareing clear water for the increase of Citrus sinensis Osbeck yield, and every mu is increased production 702 kilograms, and rate of growth reaches 13.4%.；Comparing with water-soluble fertilizer A, every mu is increased production 379 kilograms, and rate of growth is 6.8%.
The impact on Citrus sinensis Osbeck yield (kg/acre) of table 5 different disposal
Conclusion: compared with other water-soluble fertilizers, Citrus sinensis Osbeck is had the effect of increasing both production and income by the Composite amino-acid-containinwater-soluble water-soluble fertilizer in the present invention.
Claims (5)
1. the compound water-soluble fertilizer that a citrus crop is special, it is characterised in that: the preparation process of described compound water-soluble fertilizer is as follows:
(1) mother solution configuration: amino acid starting material 250-350 part, solution 200-400 part, stirs, shakes up, be configured to the span amino acid mother liquor that pH is 2-5；
(2) chelatropic reaction one: at room temperature 15 DEG C-35 DEG C, add pH adjusting agent 5-25 part, stirring is to shaking up, solution ph is adjusted to 3-7, again manganese sulfate, copper sulfate and ferrous sulfate 30-60 part altogether is added in the mother solution that step (1) obtains, stirring 1-5h, copper-manganese ferrum chelating completes；
(3) chelatropic reaction two: at room temperature 15 DEG C-35 DEG C, add pH adjusting agent 5-25 part, and are stirred continuously to shaking up, solution ph is adjusted to 6-10, again calcium nitrate, magnesium sulfate, zinc sulfate 130-260 part altogether is added step (2) and obtain in solution, stir 1-5h, complete；
(4) all the other elements add: potassium dihydrogen phosphate 30-50 part added in the solution that step (3) obtains, and are eventually adding boron raw material, ammonium molybdate 50-120 part, silica 1-20 parts altogether, stir 0.1-2h；
(5) auxiliary agent adds: auxiliary agent 30-80 part is added in the solution that step (4) obtains, stirs 0.1-2h, filters, formed product；
Wherein, described auxiliary agent includes dispersant, wetting agent, diffusion agent and preservative, and described dispersant is calcium lignosulfonate, and described wetting agent is glycerol, and described diffusion agent is the modified trisiloxanes of ethyoxyl, and described preservative is potassium sorbate；
The each constituent content of described auxiliary agent accounts for water-soluble fertilizer weight ratio, and to be respectively as follows: dispersant calcium lignosulfonate be 0.01-2%, and wetting agent glycerol is 0.01-2%, and the modified trisiloxanes of diffusion agent ethyoxyl is 2-6%, and potassium sorbate preservative is 0.1-0.5%.
2. the compound water-soluble fertilizer that citrus crop according to claim 1 is special, its constituent is as follows by mass percentage: amino acid starting material 25-35%, a great number of elements P and K composition are 3-5%, moderate-element Mg and Ca composition are 12-20%, trace element Fe, Mn, Zn, B, Mo and Cu composition are 12-20%, and beneficial element Si composition is 0.1%-2%, and auxiliary component is 3-8%, pH adjusting agent composition is 2-4%, and all the other compositions are water.
3. the compound water-soluble fertilizer that citrus crop according to claim 1 is special, it is characterised in that: described amino acid starting material includes: one or more mixture in animal hair hydrolysis Aminoacids complex powder, bean cake, oil cake, yeast fermentation broth, fermented gournet powder liquid；Described boron raw material is instant boron.
4. the compound water-soluble fertilizer that citrus crop according to claim 1 or 3 is special, its constituent is as follows by weight percentage, and potassium dihydrogen phosphate is 3-5%, and magnesium sulfate is 5-12%, calcium nitrate 5-12%；Ferrous sulfate 1-2%, manganese sulfate 1-2%, zinc sulfate 3-6%, ammonium molybdate 0.1-2%, copper sulfate 1-3%, instant boron 5-10%, silicon dioxide 0.1%-2%.
5. the compound water-soluble fertilizer that citrus crop according to claim 1 is special, its application technique is:
(1) the citrus crop germination phase, this compound water-soluble fertilizer dilutes 800 times, adopts foliage-spray method to use, uses 60-80g for every mu；
(2) citrus crop bears fruit the phase, and this compound water-soluble fertilizer dilutes 500 times, adopts foliage-spray method to use, uses 90-120g for every mu；
(3) citrus crop and fruit expanding stage, this compound water-soluble fertilizer dilutes 500 times, adopts foliage-spray method to use, used once at interval of 30 days, totally 3 times, use 90-120g for each every mu.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210449361.5A CN103073348B (en) | 2012-11-12 | 2012-11-12 | Compound water-soluble fertilizer that a kind of citrus crop is special and preparation application process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210449361.5A CN103073348B (en) | 2012-11-12 | 2012-11-12 | Compound water-soluble fertilizer that a kind of citrus crop is special and preparation application process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103073348A CN103073348A (en) | 2013-05-01 |
| CN103073348B true CN103073348B (en) | 2016-07-06 |
Family
ID=48150072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210449361.5A Active CN103073348B (en) | 2012-11-12 | 2012-11-12 | Compound water-soluble fertilizer that a kind of citrus crop is special and preparation application process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103073348B (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103553760A (en) * | 2013-11-08 | 2014-02-05 | 苏州市相城区渭塘凤凰泾农业发展有限公司 | Special compound organic fertilizer for orange trees |
| CN103804058B (en) * | 2014-01-28 | 2015-11-18 | 华中农业大学 | A kind of Nanfeng orange quality-improving special fertilizer and preparation method |
| CN103864531B (en) * | 2014-03-25 | 2015-08-19 | 华中农业大学 | Plantula Brassicae chinensis blade face control cadmium agent and its preparation method and application |
| CN104058844B (en) * | 2014-06-09 | 2016-04-20 | 李学春 | Threonine mother liquor is utilized to prepare the method for multicomponent chelate thing fertilizer |
| CN104109052B (en) * | 2014-07-08 | 2016-09-07 | 深圳市芭田生态工程股份有限公司 | A kind of high-activity humic acid trace-element fertilizer and preparation method thereof |
| CN104823626B (en) * | 2015-03-31 | 2017-07-18 | 惠州市阿杨工农业科技有限公司 | A kind of prevention and control citrus yellow shoot disease harvests the Agro-ecology method of Organic Citrus simultaneously |
| CN104788208A (en) * | 2015-04-22 | 2015-07-22 | 天津贾立明蚯蚓养殖有限公司 | Chelated earthworm amino acid water-soluble micronutrient fertilizer and preparation method thereof |
| CN104829384B (en) * | 2015-05-29 | 2018-05-01 | 江西瑞博特肥业有限公司 | A kind of complete water-soluble organic-inorganic bio-bacterial manure and preparation method thereof |
| CN105010069A (en) * | 2015-07-07 | 2015-11-04 | 融安县植保植检站 | Kumquat physiological fruit drop prevention method |
| CN105130601A (en) * | 2015-08-20 | 2015-12-09 | 曹诗红 | Citrus sugar-increasing nutritional agent and use method thereof |
| CN106008085A (en) * | 2016-05-18 | 2016-10-12 | 吴健 | Water-soluble amino acid fertilizer and preparation method thereof |
| CN106631602A (en) * | 2016-12-27 | 2017-05-10 | 贵州大学 | Water-soluble fertilizer special for citrus, and preparation method thereof |
| CN107285917A (en) * | 2017-08-09 | 2017-10-24 | 合肥绿农肥业有限责任公司 | A kind of pear tree Water-soluble fertilizer special and its application |
| CN107445723A (en) * | 2017-09-21 | 2017-12-08 | 阿米巴南京生物技术有限责任公司 | A kind of preparation method of the compound water-soluble fertilizer of multielement |
| CN107721661A (en) * | 2017-11-27 | 2018-02-23 | 广西驰胜农业科技有限公司 | One planting fruit-trees special ammonia base acid foliar fertilizer and preparation method thereof |
| CN108191559A (en) * | 2018-04-03 | 2018-06-22 | 湖南省园艺研究所 | A kind of citrus foliar fertilizer and preparation method thereof |
| CN108329079A (en) * | 2018-04-27 | 2018-07-27 | 润丰达生态农业科技（随州）有限公司 | A kind of special chelated microelements water-soluble fertilizer of navel orange and preparation method thereof |
| CN109020697A (en) * | 2018-09-04 | 2018-12-18 | 四川泸天化股份有限公司 | A kind of chelated zinc borosilicate synergistic urea and preparation method thereof |
| CN109651001A (en) * | 2019-02-18 | 2019-04-19 | 福建省农业科学院土壤肥料研究所 | The suspension liquid set meal fertilizer of the sweet shaddock yellowing leaf of mitigation and its preparation and method of administration |
| CN109748624A (en) * | 2019-03-25 | 2019-05-14 | 康菲生物科技河北有限公司 | A kind of fertilizer and preparation method thereof |
| CN110041122A (en) * | 2019-04-15 | 2019-07-23 | 湖南泰谷生态工程有限公司 | A kind of navel orange upgrading synergy set meal fertilizer and its method of administration |
| CN111937552B (en) * | 2020-08-21 | 2022-03-01 | 江西省农业科学院土壤肥料与资源环境研究所 | Fertilizing method for Nanfeng mandarin oranges |
| CN111995465B (en) * | 2020-09-04 | 2022-07-19 | 上海贯发海洋生物科技有限公司 | Heavy metal blocking agent, application and use method thereof |
| CN112352521A (en) * | 2020-11-12 | 2021-02-12 | 浙江宜葆生物科技有限公司 | Navel orange nutrient element balance detection system |
| CN113717006A (en) * | 2021-10-12 | 2021-11-30 | 西安德农生物科技有限公司 | Nutrient fertilizer for beautifying and beautifying fruit surfaces of crops and preparation method thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1651358A (en) * | 2004-02-08 | 2005-08-10 | 吴永常 | Beneficial trace element enriched multi element leaf surface fertilizer |
| JP4743114B2 (en) * | 2004-02-26 | 2011-08-10 | 味の素株式会社 | Fertilizer, plant vitality agent |
| JP5373443B2 (en) * | 2008-07-11 | 2013-12-18 | 晃栄化学工業株式会社 | Liquid fertilizer for Citrus unshiu |
| CN102190522B (en) * | 2010-03-16 | 2012-12-05 | 陕西鼎华慧农生物科技有限公司 | Amino acid complexing various nutrient elements water-soluble fertilizer and preparation method thereof |
| CN101781151B (en) * | 2010-03-16 | 2013-06-26 | 北京中研美华生化研究所 | Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof |
| CN102257938B (en) * | 2011-04-14 | 2013-05-01 | 陈武茂 | Method for producing selenium-enriched bingtang oranges |
| CN102219610B (en) * | 2011-05-19 | 2013-04-17 | 湖南省中科农业有限公司 | Amino acid compound leaf fertilizer |
-
2012
- 2012-11-12 CN CN201210449361.5A patent/CN103073348B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103073348A (en) | 2013-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103073348B (en) | Compound water-soluble fertilizer that a kind of citrus crop is special and preparation application process thereof | |
| CN102964175B (en) | Composite amino-acid-containing water-soluble fertilizer and preparation method thereof | |
| CN104326817A (en) | Special foliage spray water-soluble fertilizer for apples | |
| CN102442855B (en) | Preparation method of multi-element high-concentration liquid fertilizer with stable performance | |
| CN102964163B (en) | Special dripping-irrigating fertilizer for fruit corns and preparation method and application method thereof | |
| CN105061077A (en) | Special water-soluble fertilizer series for red jujubes and preparation method thereof | |
| CN103477830A (en) | Planting method for increasing peanut yield | |
| CN106810374A (en) | A kind of fertilizer formula for improving dragon fruit growth quality and its preparation method and application | |
| CN100455551C (en) | Plant leaf fertilizer confected by hyacinth zymolysis liquid | |
| CN100448806C (en) | Special control-release fertilizer for resin coated strawberry and preparation thereof | |
| CN109111288A (en) | A kind of dedicated set meal fertilizer of citrus | |
| CN101928174A (en) | Humic acid water-soluble fertilizer | |
| CN102603400B (en) | Liquid boron-molybdenum fertilizer and preparation method thereof | |
| CN101037360A (en) | Notoginseng leaf surface fertilizer | |
| CN105541519B (en) | Highly effective chelating state liquid fertilizer | |
| CN1400197A (en) | Humic acid complex fertilizer and its production method | |
| CN107285950A (en) | A kind of liquid organic water-soluble fertilizer and preparation method thereof | |
| CN103449885B (en) | Chinese clover strong seed leaf microelement fertilizer and use method thereof | |
| CN100572334C (en) | Multifunctional liquid composite fertilizer | |
| CN103570391A (en) | Production method of base fertilizer specially for paddy rice | |
| CN102126895B (en) | Fertilizer special for turnip and preparation method thereof | |
| CN104341244A (en) | Organic nutrition regulator for tobacco | |
| CN103467196A (en) | Rosemary seedling nutrient solution | |
| CN110734335A (en) | high-calcium-content medium-element water-soluble fertilizer and preparation method thereof | |
| CN110683903A (en) | Water-soluble fertilizer special for flowering cabbage and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 100085, Beijing, Haidian District on the road No. 26, Zhongguancun venture building, Room 518 Applicant after: BEIJING ECOMAN BIOTECHNOLOGY Co.,Ltd. Address before: 100086, Beijing, Haidian District on the road No. 26, Zhongguancun venture building, Room 518 Applicant before: BEIJING ECOMAN BIOTECH Co.,Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: BEIJING YIKEMAN BIOLOGICAL TECHNOLOGY CO., LTD. TO: BEIJING ECOMAN BIOLOGICAL TECHNOLOGY CO., LTD. Free format text: CORRECT: ADDRESS; FROM: 100086 HAIDIAN, BEIJING TO: 100085 HAIDIAN, BEIJING |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180111 Address after: 430070 Hubei city of Wuhan Province, East Lake New Technology Development Zone, a road No. 1 Optics Valley Software Park A11 Building 2 floor of No. 207 Patentee after: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Address before: 100085, Beijing, Haidian District on the road No. 26, Zhongguancun venture building, Room 518 Patentee before: BEIJING ECOMAN BIOTECHNOLOGY Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Compound water soluble fertilizer used for citrus crops, preparation method and application method Effective date of registration: 20190508 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: 2019420000020 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200610 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: 2019420000020 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A compound water soluble fertilizer for citrus crops and its preparation and application method Effective date of registration: 20200803 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2020420000050 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20210623 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2020420000050 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A special compound water soluble fertilizer for citrus crops and its preparation and application method Effective date of registration: 20210630 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2021420000061 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20220622 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2021420000061 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A compound water-soluble fertilizer for citrus crops and its preparation and application method Effective date of registration: 20220627 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2022420000186 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230619 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2022420000186 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A composite water-soluble fertilizer specifically designed for citrus crops and its preparation and application method Effective date of registration: 20230628 Granted publication date: 20160706 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI GREAT BIOTECHNOLOGY Co.,Ltd. Registration number: Y2023420000267 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |