CN108329079A - A kind of special chelated microelements water-soluble fertilizer of navel orange and preparation method thereof - Google Patents
A kind of special chelated microelements water-soluble fertilizer of navel orange and preparation method thereof Download PDFInfo
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- CN108329079A CN108329079A CN201810394180.4A CN201810394180A CN108329079A CN 108329079 A CN108329079 A CN 108329079A CN 201810394180 A CN201810394180 A CN 201810394180A CN 108329079 A CN108329079 A CN 108329079A
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- C05—FERTILISERS; MANUFACTURE THEREOF
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- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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Abstract
The invention discloses a kind of special chelated microelements water-soluble fertilizers of navel orange, including：Chelating amino acids manganese, amino acid chelated iron, copper amino acid chelate, zinc-amino acid chelate, four water, eight Boratex, ammonium molybdate, potassium dihydrogen phosphate, urea and potassium sulfate.The object of the present invention is to provide a kind of special chelated microelements water-soluble fertilizers of navel orange, the trace element water-soluble fertilizer contains iron, zinc, copper, manganese, boron, molybdenum, nitrogen, phosphorus and potassium element containing scientific matching simultaneously, while microelement-supplementing, a great number of elements needed for plant is supplemented.Manganese, copper, iron and the Zn-ef ficiency of the trace element water-soluble fertilizer all select chelating amino acids state, with quick-acting releases, quick the characteristics of absorbing, and have long-acting slow-release, the advantages of not easily runing off, and be not likely to produce interaction between element and generate antagonism and absorb or precipitate.
Description
Technical field
The invention belongs to a kind of fertilizer, and in particular to a kind of special chelated microelements water-soluble fertilizer of navel orange and its preparation
Method.
Background technology
In existing fertilizer, the dedicated chelated microelements water-soluble fertilizer of navel orange is directed to currently without a, and
Trace element water-soluble fertilizer is all inorganic states or organic complex state mostly.
Common inorganic states trace element water-soluble fertilizer is mostly with inorganic ion state or slightly solubility slag oxide form
Based on, for example sulfate, slag, waste residue, glassy state silicate etc.；Organic complex state trace element water-soluble fertilizer is mostly with lemon
The complicated molecule or ion that the ligands such as acid, oxalic acid and EDTA are combined into metal ion with coordinate bond.It is miscellaneous
Trace element chemistry property differs widely, some ease of solubility trace elements are easy to generate antagonism between trace element, very
It is precipitated to generating, while ease of solubility trace element, easily by rainwater leaching loss, utilization rate is low；Some slightly solubility trace elements apply soil
On earth or blade face, extremely indissoluble is not absorbed；Also some trace elements are suitable for existing different solute environment, simply
Mixing can change the chemical property of itself.Existing common inorganic states trace element water-soluble fertilizer contain a large amount of sulfate radical from
Son, chlorion and phosphate anion etc., long-term a large amount of applications can lead to soil hardening, acidification.
Invention content
The object of the present invention is to provide a kind of special chelated microelements water-soluble fertilizer of navel orange, trace element water-soluble fertilizer
Expect the iron containing scientific matching, zinc, copper, manganese, boron and molybdenum trace element and nitrogen, phosphorus, potassium a great number of elements simultaneously, the micro member
Manganese, copper, iron and the Zn-ef ficiency of plain water-soluble fertilizer all select chelating amino acids state, have the characteristics of quick-acting releases, quick absorption,
The advantages of having long-acting slow-release again, not easily runing off, and be not likely to produce interaction between element and generate antagonism and absorb or precipitate.
The invention also discloses a kind of preparation methods of the special chelated microelements water-soluble fertilizer of navel orange.
In order to achieve the above object, the technical solution adopted by the present invention is：A kind of special chelated microelements of navel orange are water-soluble
Fertilizer, including：Chelating amino acids manganese, amino acid chelated iron, copper amino acid chelate, zinc-amino acid chelate, four water, eight Boratex, molybdenum
Sour ammonium, potassium dihydrogen phosphate, urea and potassium sulfate.
Preferably, the amino acid be alanine, glycine, leucine, methionine, tyrosine, histidine, threonine,
Isoleucine, tryptophan, cystine, lysine, tianmenine, valine, phenylalanine, proline, serine, glutamic acid and
It is arginic one or more.
Preferably, including chelating amino acids manganese, amino acid chelated iron, copper amino acid chelate, zinc-amino acid chelate, four water eight
Boratex and ammonium molybdate；The above components in terms of number be respectively：2~9 parts of chelating amino acids manganese, amino acid chelated iron 15~30
Part, 2~10 parts of copper amino acid chelate, 10~30 parts of zinc-amino acid chelate, 4~10 parts of four water, eight Boratex and ammonium tetramolybdate 0.2
2~7 parts of~1 part, 9~15 parts of potassium dihydrogen phosphate, 15~30 parts of urea and potassium sulfate.
Preferably, it in the water-soluble fertilizer, counts in mass ratio, manganese：Iron：Copper：Zinc：Boron：Molybdenum=0.5~2：3~9：1~4：2
~9：2~4：0.02~0.10.
Preferably, in the Water soluble fertilizer, micronutrient levels (Mn+Fe+Cu+Zn+B+Mo) >=10.0%.
Preferably, in the Water soluble fertilizer, a great number of elements content（N+P2O5+K2O）≥15.0%.
A kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange, includes the following steps：
1）, prepare chelated microelements；
2）, raw material crushed respectively, cross 16 mesh, extracting screen underflow is spare；
3）, in proportion raw material distinguished into accurate weighing, and all disposable input premixing machines are sufficiently stirred, are uniformly mixed；
4）, after sampling Detection qualification, packaging and warehousing.
Preferably, the step 1）, prepare chelated microelements and be：By amino acid starting material and inorganic microelement press than
Example is added to the water, and after being 3~10 with hydrochloric acid or sodium hydroxide adjusting pH value, is warming up to 30 DEG C~100 DEG C, is sufficiently stirred reaction
0.5h~3h, pressure when reaction are 1~5 atmospheric pressure, are filtered while hot after the completion of reaction, filtrate is dense in being slowly heated in water-bath
It is reduced to epitaxial appearance, it is cooling, a large amount of white crystals are precipitated, filter, are dried to get the micro member of chelating amino acids after being washed with ethyl alcohol
Element.
Preferably, the molar ratio of the inorganic microelement and amino acid is 1: 1~1: 3.
Preferably, the inorganic microelement be zinc sulfate, zinc chloride, copper sulphate, copper chloride, manganese sulfate, manganese chloride,
It is one or more in ferrous sulfate, frerrous chloride.
1, amino acid is to constitute organism protein and the related most basic substance with vital movement, is to constitute in vivo
The base unit of protein molecule has close relationship with the vital movement of biology.It has special physiology in antibody
Function is one of indispensable nutritional ingredient in organism.Amino acid can promote the formation of photosynthesis and chlorophyll, to oxygen
Compound activity, enzymes activity, germination, absorption of nutrient ingredients, the physiological and biochemical procedures such as root growth and development have significantly
Promote and activation, especially its affinity with plant is that other any type substances can not be than.Amino acid adds people
Microelement substance required for growth and development of plants (iron, copper, manganese, zinc etc.), by chelating the organic and inorganic chelate formed,
Can keep a great number of elements slow release and make full use of, also can guarantee trace element it is steady effect with it is long-acting.
2, trace element refers to necessary to plant growth, but is comparatively a small amount of element, mainly have iron, copper, zinc,
Manganese, molybdenum, boron etc..Though trace element is few in crop in-vivo content, since they are often the composition of enzyme or coenzyme in plant
Part has very strong specificity, is that crop growth institute is indispensable and not replaceable.
3, the trophism of boron：Boron compares in plant to be concentrated in stem apex, the tip of a root, blade and floral organ, dicotyledonous
Content in plant is usually above monocotyledon.Boron can promote the normal development of reproductive organs, an important symptom of boron deficiency
It is that seed is unable to normal development, or even cannot be formed, to influence the harvest of crop, boron is to synthesis and transport sugared in crop body
There is a facilitation, chloroplaset is degenerated when boron deficiency, influences photosynthesis.Boron can improve the nitrogenase activity of legume rhizobium,
Increase amount of nitrogen fixation, when boron deficiency, root stays undeveloped, influences amount of nitrogen fixation.Boron can also enhance crop anti-adversity.
4, the trophism of iron：Iron is that chlorophyll formation is indispensable, is difficult transfer in plant body, so blade
" chlorosis " is the performance of plant iron deficiency, and this chlorosis is shown on young leaflet tablet first.In addition, iron is to the photosynthetic of plant
Effect, respiration all have an impact.
5, the trophism of copper：The photosynthesis of copper participation plant, respiration, nitrogen metabolism, the resistance for enhancing plant.It lacks
When copper, plant strain growth is thin and weak, young leaves jaundice, wilting withered, and blade tip curling is whitened, and has necrotic spot.
6, the trophism of zinc：Zinc can promote crop to carry out photosynthesis, it is the constituent of a variety of enzymes, and when zinc-deficiency is made
Object growth and development is stagnated.
7, the trophism of manganese：Contain manganese in plant chloroplast, manganese can promote germination and seedling period to grow, manganese deficiency
When influence the photosynthesis of crop, respiration, the accumulation of nitrate nitrogen in vivo.Chlorosis yellow between blade arteries and veins is shown as, is had brown
Color spot point, and gradually increase and intersperse among full leaf, so that blade is become cervinus, leaf-shrinkage.
8, the trophism of molybdenum：Molybdenum is nitrogen-fixing microorganism, especially fixes atmospheric nitrogen with the rhizobium of legume symbiosis
It is necessary when plain.It can promote leaf photosynthesis intensity again simultaneously.Plant is short and small when lacking molybdenum, chlorosis between blade arteries and veins, and leaf margin is withered
Coke, inward curl, at wilting state.
Beneficial effects of the present invention：（1）The present invention researches and develops one kind and being directed to the dedicated trace element water-soluble fertilizer of navel orange；This is micro
Element water-soluble fertilizer contains iron, zinc, copper, manganese, boron and molybdenum element and a great number of elements nitrogen, phosphorus, potassium containing scientific matching simultaneously.
Manganese, copper, iron and the Zn-ef ficiency of the trace element water-soluble fertilizer all select chelating amino acids state.
（2）Trace element in the navel orange special microelement water-soluble fertilizer（Iron, zinc, copper, manganese）Belong to chelating amino acids
State, and finished product chelation percent >=80%；Sulfate ion, chlorion in the chelated microelements navel orange Water-soluble fertilizer special and
Phosphate anion content is ≤5%；The dedicated trace element water-soluble fertilizer of the navel orange meets " NY 1428-2010 trace element water
Molten fertilizer material -- solid product " standard.
（3）The amino acid of the special aminoacid chelating microelement water-soluble fertilizer of the navel orange preferentially selects glycine and the third ammonia
Acid, relative to other amino acid, both amino acid molecular amounts are minimum, preferably both amino acid, are easy to plant and directly absorb.
(4) amino-acid chelate in the special aminoacid chelating microelement water-soluble fertilizer of the navel orange, be by amino acid with
Metal ion exists in the form of coordinate bond combines, and chelates moderate strength, and stable system after water dissolution has quick-acting releases, soon
The characteristics of victory absorbs, and the advantages of have long-acting slow-release, not easily run off, and be not likely to produce interaction between element and generate short of money
Anti- absorption or precipitation.
（5）Sulfate ion, chlorion and phosphate radical are low in the special aminoacid chelating microelement water-soluble fertilizer of the navel orange,
Long-term a large amount of applications are effectively avoided to lead to soil hardening, acidification.
（6）Aminoacid chelating microelement can pass through gel filtration chromatography elution separation, can be first by Atomic absorption
The chelation percent of its amino-acid chelate is determined in pacing, and the carboxyl and amino of amino acid participate in complexation reaction, therefore, amino-acid chelate
With distinctive closed loop configuration characteristic.
（7）Trace elements iron, zinc, copper, manganese, boron and molybdenum needed for plant all directly participate in plant metabolism effect, Bu Nengyou
Other nutrients replace, and lack any type element, plant cannot complete the history of life.These nutritional trace elements are directly
There are mutual synergistic effects, and there are mutual antagonisms.Cooperation and resistance can occur in the soil, also may be used
To be happened in plant, and mainly interacted in the form of dissociated ion.It is micro- compared to general inorganic,
The distinctive properties such as chelated microelements are not easy to be fixed since it has, soluble easily in water, are not easy to dissociate, and release is slow, from
And biology utilization rate is high, fertilizer efficiency is good.
Specific implementation mode
In order to make those skilled in the art more fully understand technical scheme of the present invention, the present invention is retouched in detail below
It states, the description of this part is only exemplary and explanatory, should not there is any restriction effect to protection scope of the present invention.
It is specific embodiment below
Embodiment 1
A kind of special chelated microelements water-soluble fertilizer of navel orange, including：2 parts of alanine Chelated Manganese, 15 parts of alanine chelated iron,
2 parts of alanine chelated copper, 10 parts of zinc-glycine chelate, 4 parts of four water, eight Boratex and 0.2 part of ammonium tetramolybdate, potassium dihydrogen phosphate 9
2 parts of part, 15 parts of urea and potassium sulfate.
In the Water soluble fertilizer, micronutrient levels (Mn+Fe+Cu+Zn+B+Mo) >=10.0%.
In the Water soluble fertilizer, a great number of elements content（N+P2O5+K2O）≥15.0%.
A kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange, includes the following steps：
1）, prepare chelated microelements：Alanine Chelated Manganese, alanine chelated iron, alanine chelated copper, glycine chelate
Zinc；Specifically preparation process is：By amino acid starting material（Alanine, glycine）In proportion with inorganic microelement, inorganic micro member
The molar ratio of element and amino acid is 1: 1, is added to the water, and after adjusting pH value is 3, is warming up to 30 DEG C, is sufficiently stirred reaction 0.5h,
Pressure when reaction is 1 atmospheric pressure, is filtered while hot after the completion of reaction, and filtrate is concentrated into epitaxial in slow heating in water-bath and goes out
It is existing, it is cooling, a large amount of white crystals are precipitated, filter, are dried to get aminoacid chelating microelement after being washed with ethyl alcohol；It is described；
2）, raw material crushed respectively, cross 16 mesh, extracting screen underflow is spare；
3）, in proportion raw material distinguished into accurate weighing, and all disposable input premixing machines are sufficiently stirred, are uniformly mixed；
4）, after sampling Detection qualification, packaging and warehousing.
The inorganic microelement is zinc sulfate, zinc chloride, copper sulphate, copper chloride, manganese sulfate, manganese chloride, sulfuric acid Asia
Iron, frerrous chloride.
Embodiment 2
A kind of special chelated microelements water-soluble fertilizer of navel orange, including：9 parts of leucine Chelated Manganese, 30 parts of leucine chelated iron,
10 parts of glycine chelate copper, 30 parts of zinc-glycine chelate, 10 parts of four water, eight Boratex and 1 part of ammonium tetramolybdate, potassium dihydrogen phosphate 15
7 parts of part, 30 parts of urea and potassium sulfate.
In the Water soluble fertilizer, micronutrient levels (Mn+Fe+Cu+Zn+B+Mo) >=10.0%.
In the Water soluble fertilizer, a great number of elements content（N+P2O5+K2O）≥15.0%.
A kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange, includes the following steps：
1）, prepare chelated microelements：Leucine Chelated Manganese, leucine chelated iron, glycine chelate copper, glycine chelate
Zinc；Specifically preparation process is：The step 1）, prepare chelated microelements and be：By amino acid starting material（Leucine, glycine）
It is proportionally added into water with inorganic microelement, after adjusting pH value is 10, is warming up to 100 DEG C, be sufficiently stirred reaction 3h, reaction
When pressure be 5 atmospheric pressure, reaction after the completion of filter while hot, filtrate in water-bath slow heating be concentrated into epitaxial occur, it is cold
But, a large amount of white crystals are precipitated, filter, are dried to get aminoacid chelating microelement after being washed with ethyl alcohol；It is described inorganic micro
The molar ratio of element and amino acid is 1: 3.
2）, raw material crushed respectively, cross 16 mesh, extracting screen underflow is spare；
3）, in proportion raw material distinguished into accurate weighing, and all disposable input premixing machines are sufficiently stirred, are uniformly mixed；
4）, after sampling Detection qualification, packaging and warehousing.
The inorganic microelement is zinc sulfate, copper sulphate, manganese sulfate, frerrous chloride.
Embodiment 3
A kind of special chelated microelements water-soluble fertilizer of navel orange, including：7 parts of alanine Chelated Manganese, 20 parts of alanine chelated iron,
8 parts of threonine chelated copper, 20 parts of threonine chelated zinc, 8 parts of four water, eight Boratex and 0.8 part of ammonium tetramolybdate, potassium dihydrogen phosphate 10
8 parts of part, 20 parts of urea and potassium sulfate.
In the Water soluble fertilizer, micronutrient levels (Mn+Fe+Cu+Zn+B+Mo) >=10.0%.
In the Water soluble fertilizer, a great number of elements content（N+P2O5+K2O）≥15.0%.
A kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange, includes the following steps：
1）, prepare chelated microelements：It is alanine Chelated Manganese, alanine chelated iron, threonine chelated copper, threonine chelated
Zinc；Specifically preparation process is：By amino acid starting material（Alanine, threonine）In proportion with inorganic microelement, described inorganic micro-
The molar ratio of secondary element and amino acid is 1:2, it is added to the water, after adjusting pH value is 7, is warming up to 50 DEG C, is sufficiently stirred reaction
2h, pressure when reaction are 3 atmospheric pressure, are filtered while hot after the completion of reaction, and filtrate is concentrated into epitaxial in slow heating in water-bath
Occur, it is cooling, a large amount of white crystals are precipitated, filter, are dried to get aminoacid chelating microelement after being washed with ethyl alcohol；
2）, raw material crushed respectively, cross 16 mesh, extracting screen underflow is spare；
3）, in proportion raw material distinguished into accurate weighing, and all disposable input premixing machines are sufficiently stirred, are uniformly mixed；
4）, after sampling Detection qualification, packaging and warehousing.
The inorganic microelement is zinc sulfate, copper sulphate, manganese sulfate, ferrous sulfate.
It should be noted that herein, the terms "include", "comprise" or its any other variant are intended to non-row
His property includes, so that the process, method, article or equipment including a series of elements includes not only those elements, and
And further include other elements that are not explicitly listed, or further include for this process, method, article or equipment institute it is intrinsic
Element.
Principle and implementation of the present invention are described for specific case used herein, the explanation of above example
It is merely used to help understand the method and its core concept of the present invention.The above is only a preferred embodiment of the present invention, it answers
When pointing out due to the finiteness of literal expression, and objectively there is unlimited concrete structure, for the common skill of the art
For art personnel, without departing from the principle of the present invention, several improvement, retouching or variation can also be made, can also incited somebody to action
Above-mentioned technical characteristic is combined in the right way；These improve retouching, variation or combination, or the not improved structure by invention
Think and technical solution directly applies to other occasions, is regarded as protection scope of the present invention.
Claims (10)
1. a kind of special chelated microelements water-soluble fertilizer of navel orange, which is characterized in that including：Chelating amino acids manganese, amino acid
Chelated iron, copper amino acid chelate, zinc-amino acid chelate, four water, eight Boratex, ammonium molybdate, potassium dihydrogen phosphate, urea and potassium sulfate.
2. the special chelated microelements water-soluble fertilizer of a kind of navel orange according to claim 1, which is characterized in that the ammonia
Base acid is alanine, glycine, leucine, methionine, tyrosine, histidine, threonine, isoleucine, tryptophan, Guang ammonia
Acid, lysine, tianmenine, valine, phenylalanine, proline, serine, glutamic acid and arginic one or more.
3. the special chelated microelements water-soluble fertilizer of a kind of navel orange according to claim 2, which is characterized in that above each
Component in terms of number be respectively：2~9 parts of chelating amino acids manganese, 15~30 parts of amino acid chelated iron, copper amino acid chelate 2~10
Part, 10~30 parts of zinc-amino acid chelate, 4~10 parts of four water, eight Boratex and 0.2~1 part of ammonium tetramolybdate, potassium dihydrogen phosphate 9~15
2~7 parts of part, 15~30 parts of urea and potassium sulfate.
4. the special chelated microelements water-soluble fertilizer of a kind of navel orange according to claim 1, which is characterized in that the water
It in molten fertilizer, counts in mass ratio, manganese：Iron：Copper：Zinc：Boron：Molybdenum=0.5~2：3~9：1~4：2~9：2~4：0.02~0.10.
5. the special chelated microelements water-soluble fertilizer of a kind of navel orange according to claim 1, which is characterized in that the water
In molten fertilizer, micronutrient levels >=10.0%.
6. the special chelated microelements water-soluble fertilizer of a kind of navel orange according to claim 1, which is characterized in that the water
In molten fertilizer, a great number of elements content >=15.0%.
7. the preparation method of the special chelated microelements water-soluble fertilizer of any one navel orange as described in claim 1-5,
It is characterized in that, includes the following steps：
1）, prepare chelated microelements；
2）, raw material crushed respectively, cross 16 mesh, extracting screen underflow is spare；
3）, in proportion raw material distinguished into accurate weighing, and all disposable input premixing machines are sufficiently stirred, are uniformly mixed；
4）, after sampling Detection qualification, packaging and warehousing.
8. a kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange according to claim 6, feature
It is, the step 1）, prepare chelated microelements and be：Amino acid starting material and inorganic microelement are proportionally added into water
In, after being 3~10 with hydrochloric acid or sodium hydroxide adjusting pH value, 30 DEG C~100 DEG C are warming up to, reaction 0.5h~3h is sufficiently stirred,
Pressure when reaction is 1~5 atmospheric pressure, is filtered while hot after the completion of reaction, and filtrate is concentrated into epitaxial in slow heating in water-bath
Occur, it is cooling, a large amount of white crystals are precipitated, filter, are dried to get aminoacid chelating microelement after being washed with ethyl alcohol.
9. a kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange according to claim 6, feature
It is, the molar ratio of the inorganic microelement and amino acid is 1: 1~1: 3.
10. a kind of preparation method of the special chelated microelements water-soluble fertilizer of navel orange according to claim 6, feature
Be, the inorganic microelement be zinc sulfate, zinc chloride, copper sulphate, copper chloride, manganese sulfate, manganese chloride, ferrous sulfate,
It is one or more in frerrous chloride.
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| CN110041122A (en) * | 2019-04-15 | 2019-07-23 | 湖南泰谷生态工程有限公司 | A kind of navel orange upgrading synergy set meal fertilizer and its method of administration |
| CN111018602A (en) * | 2019-12-27 | 2020-04-17 | 安徽辉隆集团五禾生态肥业有限公司 | Preparation method of trace and macroelement compound water-soluble fertilizer |
| CN111217636A (en) * | 2019-12-27 | 2020-06-02 | 湖北格林凯尔农业科技有限公司 | Water-soluble fertilizer formula suitable for navel orange nutrient deficiency correction under alkaline soil condition and use method thereof |
| CN111548217A (en) * | 2020-04-26 | 2020-08-18 | 深圳市五谷网络科技有限公司 | Organic high-potassium water-soluble fertilizer and preparation method thereof |
| CN112573960A (en) * | 2020-12-25 | 2021-03-30 | 海城市盛世鸿翔有机肥制造有限公司 | Plant liquid rooting agent |
| CN115304422A (en) * | 2022-08-19 | 2022-11-08 | 北京建佳农科技发展有限责任公司 | Liquid fertilizer and preparation method thereof |
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| CN115304422A (en) * | 2022-08-19 | 2022-11-08 | 北京建佳农科技发展有限责任公司 | Liquid fertilizer and preparation method thereof |
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Application publication date: 20180727 |