CN101696553B - Method for dying fabrics by color combination of vegetable dyes - Google Patents

Method for dying fabrics by color combination of vegetable dyes Download PDF

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Publication number
CN101696553B
CN101696553B CN2009101935481A CN200910193548A CN101696553B CN 101696553 B CN101696553 B CN 101696553B CN 2009101935481 A CN2009101935481 A CN 2009101935481A CN 200910193548 A CN200910193548 A CN 200910193548A CN 101696553 B CN101696553 B CN 101696553B
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vegetable
vegetable colour
fabrics
dyeing
reductant
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CN101696553A (en
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刘祥霞
麦卓明
狄剑锋
贾永堂
董凤春
关劲良
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Wuyi University
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Wuyi University
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Abstract

The invention discloses a method for dying fabrics by the color combination of vegetable dyes, which belongs to the technical field of the fabrics. The method comprises the following steps that two and more than two extracted vegetable dyes are mixed in a certain proportion, and a reasonable dying process is formulated according to the dying properties of various vegetable dyes to dye different colors on the different fabrics. The method breaks through the defect of single color variety of the vegetable dyes, enriches the color variety of the vegetable dyes on the fabrics, enlarges the use range of the vegetable dyes, enables the fabrics to be bright in color, colorful in colors and elegant in hues, and lays the foundation for the wide application of the vegetable dyes on the fabrics.

Description

A kind of method of vegetable colour dying fabrics by color combination
Technical field
The present invention relates to a kind of vegetable colour color matching method; Specifically with two kinds and abovely mix according to a certain percentage through the vegetable colour that extracts; Again according to the dyeability of various vegetable colours, formulate rational dyeing on different textiless, dye various colors.Belong to field of fabric producing technology.
Background technology
Some customs are used for the synthetic dyestuffs on the textiles, and are because of its serious environment pollution and harmful health, progressively disabled at present.Because the raw material of synthetic dyestuffs is mainly oil, in the long run, its resource is shortage day by day, do not meet the requirement of sustainable development, moreover " back to nature " has been the tendency of the day.Thus, caused the attention of people in recent years, because the existing long history of the application of natural plant fuel to traditional natural dye; Various plant fuels are applied in to be got over general especially on the textiles, vegetable colour not only has supplementary function to textile dyestuff, and main cause is that also it and ecological environment compatibility are good; Biodegradable; Environmentally safe, and nontoxic, and the vegetable colour that has is also with health role to human body.In addition, vegetable colour aboundresources, dyeing color and luster nature.
The textiles thing of vegetable colour dyeing also has unique medicinal health-care function except that dressing function, meet the modern to environmental protection and healthy pursuit.But vegetable colour dyed color kind is few, and common majority is blue, red and yellow kind; Purple, green and the black kind of having only only a few, and plant material is rare, and cost is high; Dyeability is undesirable, and this is the application of the vegetable colour of limit to a great extent.
Summary of the invention
The objective of the invention is to overcome existing staining technique weak point, a kind of color matching and colouring method of vegetable colour is provided, enriched the color category of vegetable colour dyeing, make textiles bright in colour, the color nature, tone elegance and good hand feeling are abundant.According to method provided by the present invention, vegetable colour can be allotted any needed color.
The technical scheme of prior art that the present invention solves is: a kind of method of vegetable colour dying fabrics by color combination, take following processing step:
A. the pre-treatment of textiles: with various grey fabrics carry out destarch, concise, come unstuck, above-mentioned one or more pre-treatments such as scouring of wool, carbonization and bleaching;
Textiles comprises one or more blending and woven that interweaves and the knitted fabric in cotton, fiber crops, viscose glue, silk, wool, terylene, the nylon.
B. the preparation of dye liquor:
Select suitable vegetable colour extraction scheme to carry out the extraction and the preparation of dyestuff according to different vegetable colour raw material properties; Be specially: at first with the vegetable colour raw material pulverizing, select any method in following two kinds of methods to obtain the vegetable colour dye liquor according to the character of vegetable colour then, comprising:
1. put into the comminuted plants raw material water or ethanol immersion, decoct, filter extraction then, obtain dye liquor;
2. add vegetable colour in the entry, and then add reductant and reduce in soda bath, make dye liquor.
In step b 1. in used concentration of alcohol be 0%-80%, extraction temperature is 30-90 ℃, the time is 10-60min.
In step b 2. in dye strength be 0.1-10g/L; The reductant that is added is one or more in sodium dithionate, thiourea dioxide, the thiocarbamide, and the concentration of said reductant is 1-15g/L, and caustic soda concentration is 0-10g/L; Reaction temperature is 10-90 ℃, and the reaction time is 5-30min.
In the plant material of step b in 1. is Yellow series vegetable colour and red series vegetable dyestuff; Described Yellow series vegetable colour comprises one or more combinations in rheum officinale, turmeric, the coptis, cape jasmine, the sophora flower, and described red series vegetable dyestuff comprises one or more combinations in madder, bush, the safflower; The vegetable colour of said step b in 2. is the blue series vegetable dyestuff through soaking fermentation; This vegetable colour comprises one or more combinations of indigo plant, woaded blue, acanthaceous indigo; Adding quick lime fully stirs deposition and makes vegetable colour, and this technology has been the routine techniques of knowing for people.
C. vegetable colour color matching and dyeing: at least two kind of plant dyestuff dye liquors that will obtain as stated above mix according to the ratio of appointment and obtain mixed liquor, join mixed liquor in the textiles, add reductant again.And add sodium chloride or sodium sulphate, and be that the pH value of 30-100 ℃ of inner control mixed liquor is 2-9 at dyeing temperature, dyeing time is 40min-90min; Soap at last, wash and dry, accomplish dyeing course.
The reductant that in step c, adds is one or more in sodium dithionate, thiourea dioxide, the thiocarbamide, and its concentration is greater than 0g/L, less than 5g/L; Sodium chloride or sodium sulfate concentration are greater than 0g/L, less than 100g/L.
The vegetable colour that arrives involved in the present invention belongs to different types.Some belongs to reducing dye, and some belongs to directly or ACID DYES.Dissimilar vegetable colours, dyeing is different.The disclosed dyeing of the present invention is taken into account the dyeability of all kinds of dyestuffs, make the dyestuff that is combined together can both be preferably on dyeing on textiles.Thereby remedied the deficiency of existing staining technique, enriched the color category of vegetable colour dyeing, enlarged the scope of application of vegetable colour.
The specific embodiment
Following the present invention will combine embodiment to further describe:
Embodiment one: the color matching dyeing scheme of cyan
Textile material: through 100% Light of Mulberry Silk Fabrics of destarch, the pre-treatment of coming unstuck; Dyestuff: the coptis, the natural plants after the purification is indigo.
(1) extraction of coptis dye liquor: the 100g coptis is pulverized the back in distilled water, soak 24h; Filter 23 is inferior repeatedly after decocting 1h, obtains the coptis dye liquor of 1L at last.
(2) in 1L coptis dye liquor, add the indigo 10g of natural plants that waits technology to extract by fermentation, caustic soda 4g/L, sodium dithionate 6g/L; Behind 60 ℃ of reduction 10min, add the 100g Light of Mulberry Silk Fabrics; Add sodium chloride 40g/L again, regulating the pH value is 7, on 60 ℃, dyes 40min; The cold water flush oxidation is dried.
Embodiment two: filemot color matching dyeing scheme
Textile material: through destarch, concise and the bleaching pre-treatment 100% COTTON FABRIC; Dyestuff: bush, the coptis.
(1) the bush dye liquor extracts: the 50g bush is pulverized the back in distilled water, soak 24h; Filter 23 is inferior repeatedly after decocting 1h, obtains 1L bush dye liquor at last.
(2) extraction of coptis dye liquor: the 100g coptis is pulverized the back in distilled water, soak 24; Filter 23 is inferior repeatedly after decocting 1h, obtains 1L coptis dye liquor at last.
(3) 1L bush dye liquor is mixed the back with 1L coptis dye liquor and add the 100g COTTON FABRIC, add sodium chloride 40g/L again, regulating the pH value is 7, on 90 ℃, dyes 60min, and cold water flush is dried.
Embodiment three: indigo color matching dyeing scheme
Textile material: through 100% Light of Mulberry Silk Fabrics of destarch, the pre-treatment of coming unstuck; Dyestuff: bush, the natural plants after the purification is indigo
(1) the bush dye liquor extracts: the 50g bush is pulverized the back in distilled water, soak 24h; Filter 23 is inferior repeatedly after decocting 1h, obtains 1L bush dye liquor at last.
(2) in 1L bush dye liquor, add the indigo 10g of natural plants that waits technology to extract by fermentation, caustic soda 4g/L, sodium dithionate 6g/L; Behind 60 ℃ of reduction 10min, add the 100g Light of Mulberry Silk Fabrics; Add sodium chloride 40g/L again, regulating the pH value is 7, on 60 ℃, dyes 40min; The cold water flush oxidation is dried.
Embodiment four: khaki color matching dyeing scheme
Textile material: through 100% viscose fabric of destarch and concise pre-treatment; Dyestuff: madder, turmeric.
(1) dye liquor extracts: 100g madder and 50g turmeric are pulverized the back soak 24h in concentration 30% ethanolic solution, filter 23 is inferior repeatedly after decocting 1h, obtains the dye liquor of 1L at last.
(2) add the 100g viscose fabric in the dye liquor, add sodium chloride 40g/L again, regulating the pH value is 5, on 90 ℃, dyes 60min, and cold water flush is dried.
The above only is preferred embodiment of the present invention, is not technical scheme of the present invention is done any pro forma restriction.Every foundation technical spirit of the present invention all still belongs in the scope of technical scheme of the present invention any simple modification, equivalent variations and modification that above embodiment did.

Claims (5)

1. the method for a vegetable colour dying fabrics by color combination is characterized in that: comprise following processing step:
A. the pre-treatment of textiles: with various grey fabrics carry out destarch, concise, come unstuck, scouring of wool, carbonization and above-mentioned one or more pre-treatments of bleaching;
B. the preparation of dye liquor: plant material is pulverized, selected any method in following two kinds of methods to obtain the vegetable colour dye liquor, comprising according to the character of plant material:
1. put into the comminuted plants raw material water or ethanol immersion, decoct, filter extraction then, obtain dye liquor;
2. add vegetable colour in the entry, and then add reductant and reduce in soda bath, make dye liquor;
C. vegetable colour is matched colors and dyeing: at least two kind of plant dyestuff dye liquors are mixed obtaining mixed liquor according to the ratio of appointment, join mixed liquor in the textiles, add reductant again; And add sodium chloride or sodium sulphate, and be that the pH value of 30-100 ℃ of inner control mixed liquor is 2-9 at dyeing temperature, dyeing time is 40min-90min; Soap at last, wash and dry, accomplish dyeing course.
2. method according to claim 1 is characterized in that: the 1. middle concentration of alcohol that adds of described step b is 0%-80%, and extraction temperature is 30-90 ℃, and the time is 10-60min; In step b 2. in dye strength be 0.1-10g/L; The reductant that is added comprises: one or more of sodium dithionate, thiourea dioxide, thiocarbamide, and described reductant concentration is 1-15g/L, caustic soda concentration is 0-10g/L; Reaction temperature is 10-90 ℃, and the reaction time is 5-30min.
3. method according to claim 2; It is characterized in that: in the plant material of said step b in 1. is Yellow series vegetable colour and red series vegetable dyestuff; Described Yellow series vegetable colour comprises one or more combinations in rheum officinale, turmeric, the coptis, cape jasmine, the sophora flower, and described red series vegetable dyestuff comprises one or more combinations in madder, bush, the safflower; The vegetable colour of said step b in 2. is the blue series vegetable dyestuff through soaking fermentation, and this plant material comprises one or more combinations of indigo plant, woaded blue, acanthaceous indigo, adds quick lime and fully stirs deposition and make vegetable colour.
4. method according to claim 3 is characterized in that: the reductant that in step c, adds is one or more of sodium dithionate, thiourea dioxide, thiocarbamide, and its concentration is greater than 0g/L, less than 5g/L; Sodium chloride or sodium sulfate concentration are greater than 0g/L, less than 100g/L.
5. method according to claim 4 is characterized in that: described textiles comprises one or more blending and woven that interweaves and the knitted fabric in cotton, fiber crops, viscose glue, silk, wool, terylene, the nylon.
CN2009101935481A 2009-10-30 2009-10-30 Method for dying fabrics by color combination of vegetable dyes Expired - Fee Related CN101696553B (en)

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