CN105064081B - The natural binder of a kind of paper coloring dyestuff and preparing process thereof - Google Patents
The natural binder of a kind of paper coloring dyestuff and preparing process thereof Download PDFInfo
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- CN105064081B CN105064081B CN201510576830.3A CN201510576830A CN105064081B CN 105064081 B CN105064081 B CN 105064081B CN 201510576830 A CN201510576830 A CN 201510576830A CN 105064081 B CN105064081 B CN 105064081B
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- flos sophorae
- sophorae immaturus
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- paper coloring
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Abstract
The natural binder of a kind of paper coloring dyestuff and preparing process thereof.The present invention is to solve similar prior art and have that serviceability is undesirable, cost is high, pollute environment, affecting the defects such as operator is healthy, safety in utilization is poor.Drip irrigation device: natural binder feature is made up of by weight preparation following material: the Flos Sophorae Immaturus 5~25%;One or more mixture 0.05~5% in Alumen, Borax and boric acid;One or both mixture 0.1~6% in sodium carbonate and sodium hydroxide;One or more mixture 0.05~1% in Kazon, sodium benzoate and potassium sorbate;Water is surplus.Preparing process feature is that water carries Flos Sophorae Immaturus gum components, heat and be sequentially added into one or both the mixture in one or more mixture, sodium carbonate and the sodium hydroxide in Alumen, Borax and boric acid and one or more mixture in Kazon, sodium benzoate and potassium sorbate, after material retrogradation is lowered the temperature, filter wherein moisture content.
Description
Technical field
The present invention relates to making raw material and the preparing process thereof of paper product among the people, the natural binder of a kind of paper coloring dyestuff and preparing process thereof.
Background technology
The current paper coloring dyestuff binder typically by colorant with as liquid carrier mixes and forms.In order to enable illuminating colour good filming, have the serviceability such as weatherability and wearability, binder usually contains film forming matter, solvent, auxiliary agent etc., and wherein film forming matter generally can use osseocolla, gelatin, synthetic resin etc..Owing to the natural sex material such as osseocolla and gelatin has superpower water absorption, easily make when high solids content binder retrogradation to use, and insoluble in cold water, binder can be made in cold water solvent to use, thus greatly limit its applicable elements, the most gradually eliminated by paper dyeing;And synthetic resin is in addition to cost height, also residing in and typically must be dissolved in organic solvent, the VOC discharge capacity often leading to Work places is greatly increased, and causes environmental pollution and to affect operator healthy, also add disaster hidden-trouble.Therefore, the serviceability of binder of existing paper coloring dyestuff, economy, the feature of environmental protection, safety all have much room for improvement.
Disclosed in Chinese Patent No. 200480008432.1, a kind of aqueous colorant preparations, is made up of following material: organic and/or inorganic colourant;Succinamate (fat);Polyethylene glycol alkyl ether;Styrene-the phenol condensate of alkoxylate;Organic solvent;Hydrotropes;Other is for the conventional additives of ink jet formulas;Ionized water.This aqueous colorant preparations belongs to above-mentioned synthetic resin and adds the scheme of organic solvent, there is cost height, pollution environment, affects the problems such as healthy, the use potential safety hazard of operator.
A kind of method improving sodium copper chlorophllin dyeing cotton fabric sunlight fastness disclosed in Chinese Patent No. 201110164165.9, its method processes with the natural Flos Sophorae Immaturus before dyeing after adding the natural Flos Sophorae Immaturus, dyeing in fabric, dye liquor and processes with the natural Flos Sophorae Immaturus.The fabric dyed is compared with the dyed fabric being not added with the Flos Sophorae Immaturus, and its sunlight fastness to be got well.But this method is not suitable for using printing process to colour paper.Using the Flos Sophorae Immaturus to be only limitted in textile industry application as natural dye at present, the Flos Sophorae Immaturus uses only as colored colorants.
Paper product among the people is the paper that a kind of surface ratio is rougher, and its background color is yellow or light yellow generally by printing process printing and dyeing.Its illuminating colour had both been different from the illuminating colour of smooth surface paper, was also different from the illuminating colour of yarn fabric, and its main different manifestations is different at the composition of the binder of illuminating colour.There is presently no the binder of a kind of ideal applicable illuminating colour being used in paper product background color among the people of printing and dyeing.
Summary of the invention
In order to overcome prior art to exist, serviceability is undesirable, cost is high, pollute environment, affect the defects such as operator is healthy, safety in utilization is poor, it is an object of the invention to provide the natural binder of the paper coloring dyestuff of a kind of improvement, the defect of prior art can be overcome.
The technical solution adopted for the present invention to solve the technical problems is: the natural binder of a kind of paper coloring dyestuff, it is characterized in that being made up of by weight preparation following material:
The Flos Sophorae Immaturus 5~25%
One or more mixture 0.05~5% in Alumen, Borax and boric acid
One or both mixture 0.1~6% in sodium carbonate and sodium hydroxide
One or more mixture 0.05~1% in Kazon, sodium benzoate and potassium sorbate
Water is surplus.
The Flos Sophorae Immaturus described in technique scheme, is by the Flos Sophorae Immaturus water extraction of described weight ratio, allows its gum components fully separate out, then use the extracting solution obtained.
The preferable weight ratio of the Flos Sophorae Immaturus described in technique scheme can take 12~20%.
The preferable weight ratio of one or more mixture in Alumen, Borax and boric acid described in technique scheme can take 0.1~0.5%.
The preferable weight ratio of the mixture of sodium carbonate described in technique scheme and one or both in sodium hydroxide can take 0.5~3%.
The preferable weight ratio of one or more mixture in Kazon, sodium benzoate and potassium sorbate described in technique scheme can take 0.1~0.5%.
The technique of preparation described in technique scheme, its feature can be carried out the most successively:
1. first adding water in agitated kettle, be subsequently adding the described Flos Sophorae Immaturus, stirring makes its gum components fully separate out;
The most again the Flos Sophorae Immaturus is squeezed, then collect the extracting solution of the described Flos Sophorae Immaturus;
Extracting solution is added heated and stirred in agitated kettle the most again;
4., when extracting solution is heated to 75-85 DEG C, add one or both the mixture in described sodium carbonate and sodium hydroxide, stir;
The most again with one or more mixture in Alumen, Borax and boric acid described in a small amount of hot water dissolving, it is subsequently adding in agitated kettle and stirs, carry out cross-linking reaction;
One or more mixture in the most described Kazon, sodium benzoate and potassium sorbate are added in agitated kettle and stir;
During material retrogradation in pot the most to be mixed, it is slowly stirred and is cooled to 40-50 DEG C, be subsequently poured in the strainer with filter cloth after filtering moisture, just obtain the natural binder of paper coloring dyestuff.
Beneficial effects of the present invention: one is the gum components selecting the Flos Sophorae Immaturus extraction film forming matter as binder, both there is excellent film-formation result, there is again excellent water solublity, dissolve in cold water, thus overcome osseocolla, the problem that binder retrogradation cannot use easily is made when the natural materials such as gelatin exist high solids content, also overcome synthetic resin and there is cost height, need to be dissolved in organic solvent, pollute environment, affect operator healthy, there is the problems such as disaster hidden-trouble, it it is the harmless natural film former of the green of the rougher paper of a kind of this surface ratio of paper product among the people that is applicable to print and dye;Two is the natural yellow colorant composition separated out when water carries Flos Sophorae Immaturus gum components in extracting solution, just match with the background color tone of paper product among the people, avoid technique and the cost of binder colorant to be removed composition, binder can also reduce the addition of yellow colorant when being configured to illuminating colour, so can effectively reduce the cost of manufacture of binder;Three is to add one or more mixture in the Alumen as cross-linking agent, Borax and boric acid, and add one or both the mixture in the sodium carbonate as curing agent and sodium hydroxide, there is enough intensity and elasticity, it is ensured that its serviceability such as weatherability, wearability after can making binder molding;Four is to have chosen one or more mixture in nontoxic Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination), sodium benzoate and potassium sorbate, it is ensured that the effectiveness of natural component and superperformance in binder;Five is with the illuminating colour of the present invention natural binder preparation, paper to be carried out printing, dyeing to have high permeability, preferable film property and adhesion-tight, and the wearability of paper surface can be improved, be a kind of natural, low cost, environmental protection, nontoxic, non-stimulated, use the paper coloring dyestuff binder with natural plants fragrance of safety, be particularly suitable for the rougher paper of this surface ratio of paper product among the people and carry out printing and dyeing and use.
Below in conjunction with embodiment, the invention will be further described.
Detailed description of the invention
Embodiment one
The natural binder of this paper coloring dyestuff, is characterized in that being made up of by weight preparation following material:
The Flos Sophorae Immaturus 5%
Alumen 5%
Sodium carbonate 0.1%
Kazon 0.05%
Water is surplus.
The described Flos Sophorae Immaturus, is by the Flos Sophorae Immaturus water extraction of described weight ratio, allows its gum components fully separate out, then use the extracting solution obtained.
The technique of described preparation is carried out the most successively:
1. first adding water in agitated kettle, be subsequently adding the described Flos Sophorae Immaturus, stirring makes the gum components of the Flos Sophorae Immaturus fully separate out;
The most again the Flos Sophorae Immaturus is squeezed, then collect the extracting solution of the described Flos Sophorae Immaturus;
Extracting solution is added heated and stirred in agitated kettle the most again;
4., when extracting solution is heated to 75 DEG C, add described sodium carbonate, stir;
The most again with Alumen described in a small amount of hot water dissolving, it is subsequently adding in agitated kettle and stirs, carry out cross-linking reaction;
The most described Kazon is added in agitated kettle and stir;
During material retrogradation in pot the most to be mixed, it is slowly stirred and is cooled to 40 DEG C, be subsequently poured in the strainer with filter cloth after filtering moisture, just obtain the natural binder of paper coloring dyestuff.
Embodiment two
The natural binder of this paper coloring dyestuff, is characterized in that being made up of following weight ratio component preparation:
The Flos Sophorae Immaturus 15%
Borax 2.5%
Sodium hydroxide 3%
Sodium benzoate 0.5%
Water is surplus.
The described Flos Sophorae Immaturus, is by the Flos Sophorae Immaturus water extraction of described weight ratio, allows its gum components fully separate out, then use the extracting solution obtained.
The technique of described preparation is carried out the most successively:
1. first adding water in agitated kettle, be subsequently adding the described Flos Sophorae Immaturus, stirring makes the gum components of the Flos Sophorae Immaturus fully separate out;
The most again the Flos Sophorae Immaturus is squeezed, then collect the extracting solution of the described Flos Sophorae Immaturus;
Extracting solution is added heated and stirred in agitated kettle the most again;
4., when extracting solution is heated to 80 DEG C, add described sodium hydroxide, stir;
The most again with Borax described in a small amount of hot water dissolving, it is subsequently adding in agitated kettle and stirs, carry out cross-linking reaction;
The most described sodium benzoate is added in agitated kettle and stir;
During material retrogradation in pot the most to be mixed, it is slowly stirred and is cooled to 45 DEG C, be subsequently poured in the strainer with filter cloth after filtering moisture, just obtain the natural binder of paper coloring dyestuff.
Embodiment three
The natural binder of this paper coloring dyestuff, is characterized in that being made up of following weight ratio component preparation:
The Flos Sophorae Immaturus 25%
Boric acid 0.05%
The mixture 6% of sodium carbonate and sodium hydroxide
Potassium sorbate 1%
Water is surplus.
The described Flos Sophorae Immaturus, is by the Flos Sophorae Immaturus water extraction of described weight ratio, allows its gum components fully separate out, then use the extracting solution obtained.
The technique of described preparation is carried out the most successively:
1. first adding water in agitated kettle, be subsequently adding the described Flos Sophorae Immaturus, stirring makes the gum components of the Flos Sophorae Immaturus fully separate out,
The most again the Flos Sophorae Immaturus is squeezed, then collects the extracting solution of the described Flos Sophorae Immaturus,
Extracting solution is added heated and stirred in agitated kettle the most again,
4., when extracting solution is heated to 85 DEG C, add the mixture of described sodium carbonate and sodium hydroxide, stir,
The most again with boric acid described in a small amount of hot water dissolving, it is subsequently adding in agitated kettle and stirs, carry out cross-linking reaction,
The most described potassium sorbate is added in agitated kettle and stirs,
During material retrogradation in pot the most to be mixed, it is slowly stirred and is cooled to 50 DEG C, be subsequently poured in the strainer with filter cloth after filtering moisture, just obtain the natural binder of paper coloring dyestuff.
Claims (8)
1. a natural binder for paper coloring dyestuff, is characterized in that being made up of by weight preparation following material:
The Flos Sophorae Immaturus 5~25%
One or more mixture 0.05~5% in Alumen, Borax and boric acid
One or both mixture 0.1~6% in sodium carbonate and sodium hydroxide
One or more mixture 0.05~1% in Kazon, sodium benzoate and potassium sorbate
Water is surplus
The described Flos Sophorae Immaturus, is by the Flos Sophorae Immaturus water extraction of described weight ratio, allows its gum components fully separate out, then use the extracting solution obtained.
2. the natural binder of the paper coloring dyestuff as described in claim 1, is characterized in that the weight ratio of the described Flos Sophorae Immaturus takes 12~20%.
3. the natural binder of the paper coloring dyestuff as described in claim 1 or 2, is characterized in that the weight ratio of one or more mixture in described Alumen, Borax and boric acid takes 0.1~0.5%.
4. the natural binder of the paper coloring dyestuff as described in claim 1 or 2, is characterized in that the weight ratio of one or both the mixture in described sodium carbonate and sodium hydroxide takes 0.5~3%.
5. the natural binder of the paper coloring dyestuff as described in claim 1 or 2, is characterized in that the weight ratio of one or more mixture in described Kazon, sodium benzoate and potassium sorbate takes 0.1~0.5%.
6. the preparing process of the natural binder of paper coloring dyestuff as described in claim 1, is characterized in that described technique is carried out the most successively:
1. first adding water in agitated kettle, be subsequently adding the described Flos Sophorae Immaturus, stirring makes its gum components fully separate out;
The most again the Flos Sophorae Immaturus is squeezed, then collect the extracting solution of the described Flos Sophorae Immaturus;
Extracting solution is added heated and stirred in agitated kettle the most again;
4., when extracting solution is heated to 75-85 DEG C, add one or both the mixture in described sodium carbonate and sodium hydroxide, stir;
The most again with one or more mixture in Alumen, Borax and boric acid described in a small amount of hot water dissolving, it is subsequently adding in agitated kettle and stirs, carry out cross-linking reaction;
One or more mixture in the most described Kazon, sodium benzoate and potassium sorbate are added in agitated kettle and stir;
During material retrogradation in pot the most to be mixed, it is slowly stirred and is cooled to 40-50 DEG C, be subsequently poured in the strainer with filter cloth after filtering moisture, just obtain the natural binder of paper coloring dyestuff.
7. the preparing process of the natural binder of paper coloring dyestuff as described in claim 6, is characterized in that 4. described step is extracting solution when being heated to 80 DEG C, adds one or both the mixture in described sodium carbonate and sodium hydroxide.
8. the preparing process of the natural binder of paper coloring dyestuff as described in claim 6 or 7, is characterized in that, when 7. described step is the material retrogradation in pot to be mixed, being slowly stirred and being cooled to 45 DEG C, be subsequently poured in the strainer with filter cloth and filter moisture.
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Citations (4)
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CN101696553A (en) * | 2009-10-30 | 2010-04-21 | 五邑大学 | Method for dying fabrics by color combination of vegetable dyes |
CN101899239A (en) * | 2009-05-25 | 2010-12-01 | 华东理工大学 | Carbon black gel ink and preparation method thereof |
CN103603212A (en) * | 2013-11-28 | 2014-02-26 | 李振新 | Method for dyeing cotton fabrics through color matching of natural vegetable dyes |
CN104804517A (en) * | 2015-03-31 | 2015-07-29 | 安徽省嘉信包装印务有限公司 | Environment-friendly offset ink |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101899239A (en) * | 2009-05-25 | 2010-12-01 | 华东理工大学 | Carbon black gel ink and preparation method thereof |
CN101696553A (en) * | 2009-10-30 | 2010-04-21 | 五邑大学 | Method for dying fabrics by color combination of vegetable dyes |
CN103603212A (en) * | 2013-11-28 | 2014-02-26 | 李振新 | Method for dyeing cotton fabrics through color matching of natural vegetable dyes |
CN104804517A (en) * | 2015-03-31 | 2015-07-29 | 安徽省嘉信包装印务有限公司 | Environment-friendly offset ink |
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