CN101652399B - 使用包括1,3-和1,4-环己烷二甲醇的扩链剂混合物的低雾度热塑性聚氨酯 - Google Patents

使用包括1,3-和1,4-环己烷二甲醇的扩链剂混合物的低雾度热塑性聚氨酯 Download PDF

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Publication number
CN101652399B
CN101652399B CN2007800523337A CN200780052333A CN101652399B CN 101652399 B CN101652399 B CN 101652399B CN 2007800523337 A CN2007800523337 A CN 2007800523337A CN 200780052333 A CN200780052333 A CN 200780052333A CN 101652399 B CN101652399 B CN 101652399B
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thermoplastic elastomer
polyurethane thermoplastic
mixture
feeding
passage
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Expired - Fee Related
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CN2007800523337A
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Chinese (zh)
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CN101652399A (zh
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J·M·考克斯
F·小莱玛
M·F·索南沙因
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Lubrizol Advanced Materials Inc
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Lubrizol Advanced Materials Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269—Lactones
    • C08G18/4277—Caprolactone and/or substituted caprolactone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2221/00—Use of unspecified rubbers as reinforcement
    • B29K2221/003—Thermoplastic elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
CN2007800523337A 2007-03-29 2007-12-03 使用包括1,3-和1,4-环己烷二甲醇的扩链剂混合物的低雾度热塑性聚氨酯 Expired - Fee Related CN101652399B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US92064207P 2007-03-29 2007-03-29
US60/920,642 2007-03-29
PCT/US2007/024753 WO2008121133A1 (en) 2007-03-29 2007-12-03 Low haze thermoplastic polyurethane using mixture of chain extenders including 1,3-and 1,4-cyclohexanedimethanol

Publications (2)

Publication Number Publication Date
CN101652399A CN101652399A (zh) 2010-02-17
CN101652399B true CN101652399B (zh) 2013-02-20

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CN2007800523337A Expired - Fee Related CN101652399B (zh) 2007-03-29 2007-12-03 使用包括1,3-和1,4-环己烷二甲醇的扩链剂混合物的低雾度热塑性聚氨酯

Country Status (9)

Country Link
US (1) US8242228B2 (enExample)
EP (1) EP2129700B1 (enExample)
JP (1) JP5506659B2 (enExample)
KR (1) KR101447935B1 (enExample)
CN (1) CN101652399B (enExample)
BR (1) BRPI0721405B1 (enExample)
ES (1) ES2467369T3 (enExample)
TW (1) TWI443118B (enExample)
WO (1) WO2008121133A1 (enExample)

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ES2342618T3 (es) * 2005-12-09 2010-07-09 Lubrizol Advanced Materials, Inc. Poliuretano termoplastico de baja turbidez usando prolongadores de cadena complementarios.
JP5543915B2 (ja) * 2007-05-21 2014-07-09 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド ポリウレタンポリマー
JP2011521074A (ja) * 2008-05-22 2011-07-21 ダウ グローバル テクノロジーズ エル エルエルシー シス，トランス−１，３−及び１，４−シクロヘキサンジメチルエーテル基を含む熱硬化性ポリウレタン
WO2012116164A2 (en) * 2011-02-23 2012-08-30 The University Of Akron Melt processible polyureas and polyurea-urethanes, method for the production thereof and products made therefrom
US20130331537A1 (en) * 2012-06-08 2013-12-12 Poly-Med, Inc. Polyether urethane and polyether urea based copolymers and methods related thereto
CN104955860B (zh) * 2013-02-04 2018-09-21 路博润先进材料公司 透明疏水性热塑性聚氨酯
WO2014210098A1 (en) * 2013-06-27 2014-12-31 Lubrizol Advanced Materials, Inc. Fast recovery hard thermoplastic polyurethanes
EP2952531A1 (de) * 2014-06-02 2015-12-09 Basf Se Kompakte Elastomerformteile auf Basis von Polyurethan
US10051913B2 (en) 2014-08-27 2018-08-21 Nike, Inc. Article of footwear with soil-shedding performance
GB2532837B (en) 2014-08-27 2017-10-25 Nike Innovate Cv Article of footwear with soil-shedding performance
US10463105B2 (en) 2014-08-27 2019-11-05 Nike, Inc. Articles of footwear, apparel, and sports equipment with soil-shedding properties
US10070686B2 (en) 2014-08-27 2018-09-11 Nike, Inc. Soil-shedding article of footwear, components thereof, and methods of making the article
US10314364B2 (en) 2014-08-27 2019-06-11 Nike, Inc. Soil-shedding article of footwear, and method of using the same
US10362834B2 (en) 2016-03-02 2019-07-30 Nike, Inc. Hydrogel connection
US10531705B2 (en) 2016-03-02 2020-01-14 Nike, Inc. Hydrogel tie layer
US10675609B2 (en) 2016-03-02 2020-06-09 Nike, Inc. Articles with soil-shedding performance
US10455893B2 (en) 2016-03-02 2019-10-29 Nike, Inc. Hydrogel with mesh for soil deflection
MY198291A (en) * 2016-03-31 2023-08-21 Lubrizol Advanced Mat Inc Thermoplastic Polyurethane Compositions For Solid Freeform Fabrication Of Oral Care And Medical Devices And Components
EP3475328A1 (en) * 2016-06-28 2019-05-01 Lubrizol Advanced Materials, Inc. Articles made from hydrophilic thermoplastic polyurethane compositions
CN107383325B (zh) * 2017-06-28 2020-02-07 苏州奥斯汀新材料科技有限公司 一种高透明热塑性聚氨酯弹性体的制备方法
TWI700175B (zh) 2017-08-01 2020-08-01 荷蘭商耐基創新公司 製造用於鞋類物品之外底的組件之方法
CN111225796B (zh) 2017-10-19 2022-08-23 耐克创新有限合伙公司 复合材料、制造方法、使用方法和并入复合材料的物品
CN111448234A (zh) * 2017-12-14 2020-07-24 巴斯夫欧洲公司 制备具有低玻璃化转变温度的热塑性聚氨酯的方法
CN113527625B (zh) * 2021-08-06 2022-02-22 盛鼎高新材料有限公司 聚氨酯弹性体预制物及聚氨酯弹性体的生产方法
CN113754858A (zh) * 2021-09-30 2021-12-07 宁波长阳科技股份有限公司 热塑性聚氨酯材料、热塑性聚氨酯膜及包含其的隐形车衣
CN116217882A (zh) * 2022-12-07 2023-06-06 山东一诺威聚氨酯股份有限公司 隐形车衣高强度低雾度tpu及其制备方法

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EP0781792A1 (en) * 1995-12-28 1997-07-02 Asahi Glass Company Ltd. Cross-linked polyurethane resin sheet and laminated product employing it
US6187968B1 (en) * 1996-06-28 2001-02-13 Sk Njc Co., Ltd. Process for the preparation of cyclohexanedimethanol
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KR20080094672A (ko) * 2006-02-03 2008-10-23 다우 글로벌 테크놀로지스 인크. 1,3/1,4-사이클로헥산 디메탄올계 단량체 및 중합체
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US6521164B1 (en) * 1996-02-06 2003-02-18 Parker-Hannifin Corporation Injection-moldable thermoplastic polyurethane elastomer
US6187968B1 (en) * 1996-06-28 2001-02-13 Sk Njc Co., Ltd. Process for the preparation of cyclohexanedimethanol

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TWI443118B (zh) 2014-07-01
BRPI0721405B1 (pt) 2018-07-31
ES2467369T3 (es) 2014-06-12
JP5506659B2 (ja) 2014-05-28
US8242228B2 (en) 2012-08-14
WO2008121133A1 (en) 2008-10-09
EP2129700B1 (en) 2014-05-14
KR101447935B1 (ko) 2014-10-07
EP2129700A1 (en) 2009-12-09
BRPI0721405A2 (pt) 2014-03-04
KR20100016046A (ko) 2010-02-12
CN101652399A (zh) 2010-02-17
JP2010522799A (ja) 2010-07-08
US20100113733A1 (en) 2010-05-06
TW200904845A (en) 2009-02-01

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