KR101447935B1 - 1,3­및 1,4­시클로헥산디메탄올을 포함하는 사슬 연장제의 혼합물을 이용한 저 헤이즈 열가소성 폴리우레탄 - Google Patents

1,3­및 1,4­시클로헥산디메탄올을 포함하는 사슬 연장제의 혼합물을 이용한 저 헤이즈 열가소성 폴리우레탄 Download PDF

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KR101447935B1
KR101447935B1 KR1020097022665A KR20097022665A KR101447935B1 KR 101447935 B1 KR101447935 B1 KR 101447935B1 KR 1020097022665 A KR1020097022665 A KR 1020097022665A KR 20097022665 A KR20097022665 A KR 20097022665A KR 101447935 B1 KR101447935 B1 KR 101447935B1
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cyclohexanedimethanol
mixture
thermoplastic polyurethane
polyurethane elastomer
weight
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KR20100016046A (ko
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존 마크 콕스
프란시스코 주니어 레마
마크 에프. 손넨쉬인
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루브리졸 어드밴스드 머티어리얼스, 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269—Lactones
    • C08G18/4277—Caprolactone and/or substituted caprolactone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2221/00—Use of unspecified rubbers as reinforcement
    • B29K2221/003—Thermoplastic elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
KR1020097022665A 2007-03-29 2007-12-03 1,3­및 1,4­시클로헥산디메탄올을 포함하는 사슬 연장제의 혼합물을 이용한 저 헤이즈 열가소성 폴리우레탄 Active KR101447935B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US92064207P 2007-03-29 2007-03-29
US60/920,642 2007-03-29
PCT/US2007/024753 WO2008121133A1 (en) 2007-03-29 2007-12-03 Low haze thermoplastic polyurethane using mixture of chain extenders including 1,3-and 1,4-cyclohexanedimethanol

Publications (2)

Publication Number Publication Date
KR20100016046A KR20100016046A (ko) 2010-02-12
KR101447935B1 true KR101447935B1 (ko) 2014-10-07

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KR1020097022665A Active KR101447935B1 (ko) 2007-03-29 2007-12-03 1,3­및 1,4­시클로헥산디메탄올을 포함하는 사슬 연장제의 혼합물을 이용한 저 헤이즈 열가소성 폴리우레탄

Country Status (9)

Country Link
US (1) US8242228B2 (enExample)
EP (1) EP2129700B1 (enExample)
JP (1) JP5506659B2 (enExample)
KR (1) KR101447935B1 (enExample)
CN (1) CN101652399B (enExample)
BR (1) BRPI0721405B1 (enExample)
ES (1) ES2467369T3 (enExample)
TW (1) TWI443118B (enExample)
WO (1) WO2008121133A1 (enExample)

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ATE466895T1 (de) * 2005-12-09 2010-05-15 Lubrizol Advanced Mat Inc Thermoplastisches polyurethan mit niedriger opazität unter verwendung von co- kettenverlängerern
KR101466071B1 (ko) * 2007-05-21 2014-11-27 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 폴리우레탄 중합체
EP2291425A1 (en) * 2008-05-22 2011-03-09 Dow Global Technologies Inc. Thermoset polyurethanes comprising cis, trans-1, 3- and 1, 4-cyclohexanedimethylether groups
US9957346B2 (en) * 2011-02-23 2018-05-01 The University Of Akron Melt processible polyureas and polyurea-urethanes, method for the production thereof and products made therefrom
EP2858689A4 (en) * 2012-06-08 2017-06-14 Poly-Med Inc. Polyether urethane and polyether urea based copolymers and methods related thereto
AU2014212059B2 (en) * 2013-02-04 2017-02-16 Lubrizol Advanced Materials, Inc. Clear hydrophobic TPU
ES2635348T3 (es) * 2013-06-27 2017-10-03 Lubrizol Advanced Materials, Inc. Poliuretanos termoplásticos duros de recuperación rápida
EP2952531A1 (de) * 2014-06-02 2015-12-09 Basf Se Kompakte Elastomerformteile auf Basis von Polyurethan
US10314364B2 (en) 2014-08-27 2019-06-11 Nike, Inc. Soil-shedding article of footwear, and method of using the same
EP3169175B1 (en) 2014-08-27 2020-06-17 NIKE Innovate C.V. Articles of footwear, apparel, and sports equipment with water absorbtion properties
US10070686B2 (en) 2014-08-27 2018-09-11 Nike, Inc. Soil-shedding article of footwear, components thereof, and methods of making the article
US10051913B2 (en) 2014-08-27 2018-08-21 Nike, Inc. Article of footwear with soil-shedding performance
TWI706737B (zh) 2014-08-27 2020-10-11 荷蘭商耐基創新公司 具污垢脫落性能之鞋類製品
US10362834B2 (en) 2016-03-02 2019-07-30 Nike, Inc. Hydrogel connection
US10675609B2 (en) 2016-03-02 2020-06-09 Nike, Inc. Articles with soil-shedding performance
US10531705B2 (en) 2016-03-02 2020-01-14 Nike, Inc. Hydrogel tie layer
US10455893B2 (en) 2016-03-02 2019-10-29 Nike, Inc. Hydrogel with mesh for soil deflection
HUE056292T2 (hu) * 2016-03-31 2022-02-28 Lubrizol Advanced Mat Inc Hõre lágyuló poliuretán kompozíciók, szájápolási és orvosi eszközök és komponensek szilárd, szabad formájú gyártásához
MY209023A (en) * 2016-06-28 2025-06-17 Lubrizol Advanced Mat Inc Articles made from hydrophilic thermoplastic polyurethane compositions
CN107383325B (zh) * 2017-06-28 2020-02-07 苏州奥斯汀新材料科技有限公司 一种高透明热塑性聚氨酯弹性体的制备方法
TWI700175B (zh) 2017-08-01 2020-08-01 荷蘭商耐基創新公司 製造用於鞋類物品之外底的組件之方法
US10919257B2 (en) 2017-10-19 2021-02-16 Nike, Inc. Composite materials, methods of making, methods of use, and articles incorporating the composite materials
BR112020009775A2 (pt) 2017-12-14 2020-11-03 Basf Se método de preparação de poliuretano termoplástico, poliuretano termoplástico, uso, método de produção de partículas, partículas, espuma e uso das partículas
CN113527625B (zh) * 2021-08-06 2022-02-22 盛鼎高新材料有限公司 聚氨酯弹性体预制物及聚氨酯弹性体的生产方法
CN113754858A (zh) * 2021-09-30 2021-12-07 宁波长阳科技股份有限公司 热塑性聚氨酯材料、热塑性聚氨酯膜及包含其的隐形车衣
CN116217882A (zh) * 2022-12-07 2023-06-06 山东一诺威聚氨酯股份有限公司 隐形车衣高强度低雾度tpu及其制备方法
FR3165550A1 (fr) * 2024-08-13 2026-02-20 Arkema France Crampons de chaussure

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JPH09235343A (ja) * 1995-12-28 1997-09-09 Saint Gobain Vitrage 架橋されたポリウレタン系樹脂シートおよびそれを用いた積層体
US6521164B1 (en) * 1996-02-06 2003-02-18 Parker-Hannifin Corporation Injection-moldable thermoplastic polyurethane elastomer
WO2004069892A1 (en) 2003-02-03 2004-08-19 Ppg Industries Ohio Inc. Solvent borne 2k coating compositions

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US6252121B1 (en) * 1999-07-27 2001-06-26 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
EP1353970A1 (en) * 2000-12-19 2003-10-22 Dow Global Technologies Inc. Thermoplastic polyurethane containing structural units of ethylene oxide polyol or ethylene oxide capped propylene oxide polyol
ATE466895T1 (de) * 2005-12-09 2010-05-15 Lubrizol Advanced Mat Inc Thermoplastisches polyurethan mit niedriger opazität unter verwendung von co- kettenverlängerern
CA2637699A1 (en) * 2006-02-03 2007-08-16 Dow Global Technologies Inc. 1,3/1,4-cyclohexane dimethanol based monomers and polymers
CN101443374B (zh) * 2006-05-18 2011-11-09 陶氏环球技术有限责任公司 得自环己烷二甲醇的聚氨酯-脲聚合物
JP2009537668A (ja) * 2006-05-18 2009-10-29 ダウ グローバル テクノロジーズ インコーポレイティド 強化された耐加水分解性を備えるポリウレタンエラストマー

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Publication number Priority date Publication date Assignee Title
JPH09235343A (ja) * 1995-12-28 1997-09-09 Saint Gobain Vitrage 架橋されたポリウレタン系樹脂シートおよびそれを用いた積層体
US6521164B1 (en) * 1996-02-06 2003-02-18 Parker-Hannifin Corporation Injection-moldable thermoplastic polyurethane elastomer
WO2004069892A1 (en) 2003-02-03 2004-08-19 Ppg Industries Ohio Inc. Solvent borne 2k coating compositions

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Publication number Publication date
JP2010522799A (ja) 2010-07-08
US20100113733A1 (en) 2010-05-06
US8242228B2 (en) 2012-08-14
EP2129700A1 (en) 2009-12-09
BRPI0721405A2 (pt) 2014-03-04
ES2467369T3 (es) 2014-06-12
CN101652399A (zh) 2010-02-17
JP5506659B2 (ja) 2014-05-28
TW200904845A (en) 2009-02-01
TWI443118B (zh) 2014-07-01
KR20100016046A (ko) 2010-02-12
CN101652399B (zh) 2013-02-20
BRPI0721405B1 (pt) 2018-07-31
EP2129700B1 (en) 2014-05-14
WO2008121133A1 (en) 2008-10-09

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