CN101495796A - 气体耐压容器或含有具有过滤器设备的气体耐压容器的储存装置 - Google Patents
气体耐压容器或含有具有过滤器设备的气体耐压容器的储存装置 Download PDFInfo
- Publication number
- CN101495796A CN101495796A CNA200780019715XA CN200780019715A CN101495796A CN 101495796 A CN101495796 A CN 101495796A CN A200780019715X A CNA200780019715X A CN A200780019715XA CN 200780019715 A CN200780019715 A CN 200780019715A CN 101495796 A CN101495796 A CN 101495796A
- Authority
- CN
- China
- Prior art keywords
- gas
- pressure container
- gas pressure
- fuel gas
- dioctyl phthalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000003860 storage Methods 0.000 title claims abstract description 37
- 239000007789 gas Substances 0.000 claims abstract description 133
- 239000002737 fuel gas Substances 0.000 claims abstract description 81
- 239000000446 fuel Substances 0.000 claims abstract description 21
- 238000011049 filling Methods 0.000 claims abstract description 11
- 239000002594 sorbent Substances 0.000 claims description 52
- 239000012535 impurity Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 239000012621 metal-organic framework Substances 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 2
- 239000003463 adsorbent Substances 0.000 abstract description 4
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 239000000356 contaminant Substances 0.000 abstract 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 91
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 38
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 28
- SUAKHGWARZSWIH-UHFFFAOYSA-N N,N‐diethylformamide Chemical compound CCN(CC)C=O SUAKHGWARZSWIH-UHFFFAOYSA-N 0.000 description 27
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Substances OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 27
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 24
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 20
- 150000002894 organic compounds Chemical class 0.000 description 19
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- -1 alkane hydrocarbon Chemical class 0.000 description 15
- 150000002148 esters Chemical class 0.000 description 15
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 13
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 13
- 235000019253 formic acid Nutrition 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- JZKNMIIVCWHHGX-UHFFFAOYSA-N adamantane-1,2,2,3-tetracarboxylic acid Chemical compound C1C(C2)CC3CC1(C(=O)O)C(C(O)=O)(C(O)=O)C2(C(O)=O)C3 JZKNMIIVCWHHGX-UHFFFAOYSA-N 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 229910021645 metal ion Inorganic materials 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- QNVNLUSHGRBCLO-UHFFFAOYSA-N H2BDC Natural products OC(=O)C1=CC(O)=CC(C(O)=O)=C1 QNVNLUSHGRBCLO-UHFFFAOYSA-N 0.000 description 9
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- QAXZWHGWYSJAEI-UHFFFAOYSA-N n,n-dimethylformamide;ethanol Chemical compound CCO.CN(C)C=O QAXZWHGWYSJAEI-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 150000001491 aromatic compounds Chemical class 0.000 description 8
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 125000000524 functional group Chemical group 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 150000003628 tricarboxylic acids Chemical class 0.000 description 7
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 150000001991 dicarboxylic acids Chemical class 0.000 description 6
- 125000005842 heteroatom Chemical group 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Inorganic materials [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229910021575 Iron(II) bromide Inorganic materials 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 150000007824 aliphatic compounds Chemical class 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 5
- 239000012429 reaction media Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 4
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Chemical compound [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- LBHYQZOIQOEFQP-UHFFFAOYSA-N dioctyl benzene-1,2-dicarboxylate thiophene Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.S1C=CC=C1 LBHYQZOIQOEFQP-UHFFFAOYSA-N 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011592 zinc chloride Substances 0.000 description 4
- 235000005074 zinc chloride Nutrition 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- QUTGXAIWZAMYEM-UHFFFAOYSA-N 2-cyclopentyloxyethanamine Chemical compound NCCOC1CCCC1 QUTGXAIWZAMYEM-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 3
- BNXYVROGIGSJNK-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C#C Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C#C BNXYVROGIGSJNK-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920002266 Pluriol® Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- IYSNYCQLARBERC-UHFFFAOYSA-N methylsulfinylmethane;toluene Chemical compound CS(C)=O.CC1=CC=CC=C1 IYSNYCQLARBERC-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- MARQLFJLMKVMKJ-UHFFFAOYSA-N 2-methyl-4a,9-dihydropyrido[3,4-b]indol-9-ium;iodide Chemical compound [I-].C1=CC=C2C3C=CN(C)C=C3[NH2+]C2=C1 MARQLFJLMKVMKJ-UHFFFAOYSA-N 0.000 description 2
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910021091 Co(NO3)26H2O Inorganic materials 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000013206 MIL-53 Substances 0.000 description 2
- 239000013132 MOF-5 Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000013142 Zn-HKUST-1 Substances 0.000 description 2
- AXLLOYXRJRMBEW-UHFFFAOYSA-N adamantane;benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1.C1C(C2)CC3CC1CC2C3 AXLLOYXRJRMBEW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- ZZHNUBIHHLQNHX-UHFFFAOYSA-N butoxysilane Chemical class CCCCO[SiH3] ZZHNUBIHHLQNHX-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001404 mediated effect Effects 0.000 description 2
- 150000001455 metallic ions Chemical class 0.000 description 2
- WWECJGLXBSQKRF-UHFFFAOYSA-N n,n-dimethylformamide;methanol Chemical compound OC.CN(C)C=O WWECJGLXBSQKRF-UHFFFAOYSA-N 0.000 description 2
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000013384 organic framework Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 150000003463 sulfur Chemical class 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- IRFHMTUHTBSEBK-QGZVFWFLSA-N tert-butyl n-[(2s)-2-(2,5-difluorophenyl)-3-quinolin-3-ylpropyl]carbamate Chemical compound C1([C@H](CC=2C=C3C=CC=CC3=NC=2)CNC(=O)OC(C)(C)C)=CC(F)=CC=C1F IRFHMTUHTBSEBK-QGZVFWFLSA-N 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- ZTKHNPJNKUGXLL-UHFFFAOYSA-N 1,3-dibenzylimidazol-2-one Chemical compound C1=CN(CC=2C=CC=CC=2)C(=O)N1CC1=CC=CC=C1 ZTKHNPJNKUGXLL-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- UOCUWTUAHBUBNX-UHFFFAOYSA-N 2-hexoxypropanedioic acid Chemical class C(OCCCCCC)(C(=O)O)C(=O)O UOCUWTUAHBUBNX-UHFFFAOYSA-N 0.000 description 1
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 1
- HSSYVKMJJLDTKZ-UHFFFAOYSA-N 3-phenylphthalic acid Chemical compound OC(=O)C1=CC=CC(C=2C=CC=CC=2)=C1C(O)=O HSSYVKMJJLDTKZ-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- JIIUWPYGXWLJRT-UHFFFAOYSA-N 4,5,9,10-tetrahydropyrene-2,7-dicarboxylic acid Chemical compound C1CC2=CC(C(=O)O)=CC3=C2C2=C1C=C(C(O)=O)C=C2CC3 JIIUWPYGXWLJRT-UHFFFAOYSA-N 0.000 description 1
- KOGDFDWINXIWHI-OWOJBTEDSA-N 4-[(e)-2-(4-aminophenyl)ethenyl]aniline Chemical compound C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1 KOGDFDWINXIWHI-OWOJBTEDSA-N 0.000 description 1
- PWFCXQJXVJZYMH-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1(=CC=CC=C1)C1CCC2=CC=CC=C12 Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1(=CC=CC=C1)C1CCC2=CC=CC=C12 PWFCXQJXVJZYMH-UHFFFAOYSA-N 0.000 description 1
- FDPCUMMFVSGZBV-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45 Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.C1=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45 FDPCUMMFVSGZBV-UHFFFAOYSA-N 0.000 description 1
- PWZCWMZJLQNYPL-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCC Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCC PWZCWMZJLQNYPL-UHFFFAOYSA-N 0.000 description 1
- XYTBSXAMSZGTNN-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCCCC Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCCCC XYTBSXAMSZGTNN-UHFFFAOYSA-N 0.000 description 1
- KRIBXUDUUOUVSK-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCCCCCCC Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCCCCCCC KRIBXUDUUOUVSK-UHFFFAOYSA-N 0.000 description 1
- RTGPEHKYFIXNRF-UHFFFAOYSA-N C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC Chemical compound C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC.CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC RTGPEHKYFIXNRF-UHFFFAOYSA-N 0.000 description 1
- WEXKTQAKJRRWBW-UHFFFAOYSA-N CCCCCCCCCCC.C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC Chemical compound CCCCCCCCCCC.C(C=1C(C(=O)OCCCCCCCC)=CC=CC1)(=O)OCCCCCCCC WEXKTQAKJRRWBW-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910002492 Ce(NO3)3·6H2O Inorganic materials 0.000 description 1
- URYAFVKLYSEINW-UHFFFAOYSA-N Chlorfenethol Chemical compound C=1C=C(Cl)C=CC=1C(O)(C)C1=CC=C(Cl)C=C1 URYAFVKLYSEINW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229910002538 Eu(NO3)3·6H2O Inorganic materials 0.000 description 1
- 239000013217 IRMOP-51 Substances 0.000 description 1
- 241001580033 Imma Species 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000013216 MIL-68 Substances 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 101100353526 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) pca-2 gene Proteins 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 101710110702 Probable chorismate pyruvate-lyase 1 Proteins 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000013236 Zn4O(BTB)2 Substances 0.000 description 1
- QFHMNFAUXJAINK-UHFFFAOYSA-N [1-(carbamoylamino)-2-methylpropyl]urea Chemical group NC(=O)NC(C(C)C)NC(N)=O QFHMNFAUXJAINK-UHFFFAOYSA-N 0.000 description 1
- 101150117319 aba2 gene Proteins 0.000 description 1
- DSRXQXXHDIAVJT-UHFFFAOYSA-N acetonitrile;n,n-dimethylformamide Chemical compound CC#N.CN(C)C=O DSRXQXXHDIAVJT-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- GIXWDMTZECRIJT-UHFFFAOYSA-N aurintricarboxylic acid Chemical compound C1=CC(=O)C(C(=O)O)=CC1=C(C=1C=C(C(O)=CC=1)C(O)=O)C1=CC=C(O)C(C(O)=O)=C1 GIXWDMTZECRIJT-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229940111759 benzophenone-2 Drugs 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical class CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- CZORBZCFAPGTNL-UHFFFAOYSA-N butane-1,1,4,4-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)CCC(C(O)=O)C(O)=O CZORBZCFAPGTNL-UHFFFAOYSA-N 0.000 description 1
- LOGBRYZYTBQBTB-UHFFFAOYSA-N butane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(C(O)=O)CC(O)=O LOGBRYZYTBQBTB-UHFFFAOYSA-N 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- STZIXLPVKZUAMV-UHFFFAOYSA-N cyclopentane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1(C(O)=O)C(O)=O STZIXLPVKZUAMV-UHFFFAOYSA-N 0.000 description 1
- LUEPYSLOLQVVCZ-UHFFFAOYSA-N decane-1,2,9,10-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)CCCCCCC(C(O)=O)CC(O)=O LUEPYSLOLQVVCZ-UHFFFAOYSA-N 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 239000012024 dehydrating agents Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000012973 diazabicyclooctane Substances 0.000 description 1
- 229910001649 dickite Inorganic materials 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- HQZAZPULUDJUDP-UHFFFAOYSA-N dodecane-1,2,11,12-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)CCCCCCCCC(C(O)=O)CC(O)=O HQZAZPULUDJUDP-UHFFFAOYSA-N 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BIQKRILZMDQPHI-UHFFFAOYSA-N heptadec-8-ene Chemical compound CCCCCCCCC=CCCCCCCC BIQKRILZMDQPHI-UHFFFAOYSA-N 0.000 description 1
- YSFZWUJOBANROZ-UHFFFAOYSA-N heptylmalonic acid Chemical compound CCCCCCCC(C(O)=O)C(O)=O YSFZWUJOBANROZ-UHFFFAOYSA-N 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- FYHFEMFNYGEMRB-UHFFFAOYSA-N hexane-1,2,5,6-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)CCC(C(O)=O)CC(O)=O FYHFEMFNYGEMRB-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Substances C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- WHRBSMVATPCWLU-UHFFFAOYSA-K iron(3+);triformate Chemical compound [Fe+3].[O-]C=O.[O-]C=O.[O-]C=O WHRBSMVATPCWLU-UHFFFAOYSA-K 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N isocitric acid Chemical compound OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Inorganic materials [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 1
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- BUTPBERGMJVRBM-UHFFFAOYSA-N methanol;methylsulfinylmethane Chemical compound OC.CS(C)=O BUTPBERGMJVRBM-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- WHQSYGRFZMUQGQ-UHFFFAOYSA-N n,n-dimethylformamide;hydrate Chemical compound O.CN(C)C=O WHQSYGRFZMUQGQ-UHFFFAOYSA-N 0.000 description 1
- PUPKPAZSFZOLOR-UHFFFAOYSA-N n,n-dimethylformamide;toluene Chemical compound CN(C)C=O.CC1=CC=CC=C1 PUPKPAZSFZOLOR-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- WDAISVDZHKFVQP-UHFFFAOYSA-N octane-1,2,7,8-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)CCCCC(C(O)=O)CC(O)=O WDAISVDZHKFVQP-UHFFFAOYSA-N 0.000 description 1
- 239000008041 oiling agent Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- UFOIOXZLTXNHQH-UHFFFAOYSA-N oxolane-2,3,4,5-tetracarboxylic acid Chemical compound OC(=O)C1OC(C(O)=O)C(C(O)=O)C1C(O)=O UFOIOXZLTXNHQH-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- FVDOBFPYBSDRKH-UHFFFAOYSA-N perylene-3,4,9,10-tetracarboxylic acid Chemical compound C=12C3=CC=C(C(O)=O)C2=C(C(O)=O)C=CC=1C1=CC=C(C(O)=O)C2=C1C3=CC=C2C(=O)O FVDOBFPYBSDRKH-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- VLCMRTMCMQJSKM-UHFFFAOYSA-N phenyl-[4-phenyl-8-(trifluoromethyl)quinolin-3-yl]methanone Chemical compound C=1C=CC=CC=1C(=O)C1=CN=C2C(C(F)(F)F)=CC=CC2=C1C1=CC=CC=C1 VLCMRTMCMQJSKM-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/007—Use of gas-solvents or gas-sorbents in vessels for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0341—Filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0165—Applications for fluid transport or storage on the road
- F17C2270/0168—Applications for fluid transport or storage on the road by vehicles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/526—Sorbent for fluid storage, other than an alloy for hydrogen storage
Abstract
本发明涉及一种具有1m3的最小体积和规定最大填充压力的用于吸取、储存和分配燃料气体的气体耐压容器,所述燃料气体在储存条件下呈气态并可通过燃烧该燃料气体而驱动车辆,其特征在于该气体耐压容器具有过滤器,燃料气体可至少在吸取或分配过程中流过该过滤器,其中过滤器适合从料流中除去燃料气体中可能的杂质且杂质能够降低用于储存燃料气体的吸附剂对燃料气体的储存能力。本发明进一步涉及该气体耐压容器在填充另一气体耐压容器中的用途,其中所述另一气体耐压容器配制在车辆中或车辆上且包含用于储存所述燃料气体的吸附剂。
Description
本发明涉及一种气体耐压容器及其在填充另一气体耐压容器中的用途。
借助气体的机动车辆形成了汽油或柴油燃料驱动的传统车辆的替代。
然而,合适的储存容器必须具有的高压在此代表了技术问题。已知在储存容器如罐中为了储存足够量的气体而所需的压力当在罐中提供吸附剂时可降低。对于相同量的气体,该吸附剂使得能够降低容器中的所需压力。
具有这种包含吸附剂的容器的机动车辆公开于JP-A 2002/267096中。
然而,这并没有解决如何填充这种车辆的问题。
为了解决该问题,JP-A 2003/278997提出了通过与城市煤气管线直接连接而填充车辆中的容器,其中在两者之间配有压缩机。
然而,缺点是其依赖于城市煤气管线的存在。此外,加燃料需要压缩机并且这伴随着在向车辆加燃料过程中产生的噪音。此外,所用吸附剂并没有被保护以防止可能作为组分存在于城市煤气中的杂质。
因此,需要一种气体耐压容器,其例如可为加油站的一部分,与目前盛行的具有不含吸附剂的耐压容器的气体驱动的车辆相比,其允许以简单方式填充机动车辆并且保护吸附剂防止杂质。
因此,本发明的目的是提供这种容器。
该目的通过具有1m3的最小体积和规定最大填充压力的用于吸取、储存和分配燃料气体的气体耐压容器而实现,所述燃料气体在储存条件下呈气态且适合通过燃烧该燃料气体而驱动车辆,其中该气体耐压容器具有过滤器,燃料气体可至少在吸取或分配过程中流过该过滤器,其中过滤器适合从料流中除去燃料气体中可能的杂质且杂质能够降低用于储存燃料气体的吸附剂对燃料气体的储存能力。
已经发现,有利的是用于为车辆加燃料的气体耐压容器配有保护用于储存燃料气体的吸附剂的过滤器。
燃料气体可为纯气体或气体混合物且适合通过燃烧燃料气体而驱动车辆。因此,燃料气体通常包含氢气或甲烷中的至少一种。由于经济原因,不使用纯气体而是使用包含纯氢气和/或甲烷的天然源的气体。它们优选为城市煤气或天然气。非常特别优选天然气。
燃料气体在储存条件下呈气态。这意味着燃料气体在气体耐压容器内以气态物质存在。因此,直至气体耐压容器的最大填充压力,燃料气体处于气态。在直至-20℃的温度范围内也应如此。
此外,气体耐压容器具有过滤器,燃料气体可至少在吸取或分配过程中流过该过滤器,其中过滤器适合从料流中除去燃料气体中可能的杂质且杂质能够降低用于储存燃料气体的吸附剂对燃料气体的储存能力。
因此,过滤器的任务是保护所用吸附剂防止杂质,以确保其对燃料气体的足够储存能力。
这些杂质可为至少一种高级烃、氨或硫化氢或两种或更多种这些物质的混合物。二氧化碳和/或一氧化碳也可为这类杂质。此外,至少一种有气味物质同样可为杂质。这种有气味物质的实例为四氢噻吩。此外,可污染燃料气体且可以以不利方式具体影响吸附剂的许多外来气体物质也是可能的。
高级烃的实例为乙烷、丙烷、丁烷和其它更高级链烷烃以及它们的不饱和类似物。
杂质类型取决于所用燃料气体和生产或提取它们的方法。
这些杂质的不利作用在于,它们降低了吸附剂对燃料气体的储存能力。这种降低尤其可归结于在吸附剂上的可逆或不可逆吸附。然而,其不仅可在吸附剂上吸附,同样可与吸附剂发生化学反应,从而降低了对燃料气体的储存能力。
所用吸附剂可存在于本发明气体耐压容器中。另一可能性为所用吸附剂存在于车辆中或车辆上的另一气体耐压容器中。此处,过滤器可在填充另一气体耐压容器的过程中防止杂质对车辆中或车辆上的该另一气体耐压容器中的所用吸附剂对燃料气体的储存能力的损害。
最后存在的可能性是吸附剂可同时存在于本发明气体耐压容器和另一气体耐压容器中,其中这些吸附剂可相同或不同。
对本发明而言,术语“吸附剂”为了简化目的也用于在使用多种吸附剂混合物的情况。
对本发明而言,术语“过滤器”为了简化目的也用于在使用多个过滤器的情况。
燃料气体可在其吸入本发明气体耐压容器时流过过滤器。结果是,燃料气体被纯化,为了随后分配给车辆而储存。这在将吸附剂用于本发明气体耐压容器中时特别有利。这样可避免杂质对用于本发明气体耐压容器中的吸附剂的燃料气体储存能力的损害。
本发明气体耐压容器吸取燃料气体可借助现有技术已知的吸取燃料气体的方法进行。此处,可使用常规阀技术,其中存在通向气体耐压容器且有利地具有至少一个阀的进料管线。过滤器例如可代表进料管线的一部分,其中也可存在其它组件。此外,也可存在可因此包含多个过滤器或不存在过滤器的多个进料管线。
此外,将燃料气体吸取入气体耐压容器的通向气体耐压容器的进料管线也可用于分配燃料气体。此处,燃料气体又可流过过滤器。然而,同时代表排出管线的进料管线同样可具有支路,该支路使得气体可绕过过滤器。同样可存在用于吸取和/或分配且不具有过滤器的其它管线。
如果将燃料气体吸取入本发明气体耐压容器和从气体耐压容器分配燃料气体在不同位置进行,将燃料气体吸取入本发明气体耐压容器中的装置不必配有过滤器。或者,仅分配燃料气体的装置可配有过滤器,因此在分配燃料气体时,燃料气体流过过滤器。
分配装置也可包含常规阀和管线技术。它们应设定尺寸,以使填充在车辆中或车辆上的另一耐压容器的时间不超过3-5分钟。
特别是当待填充的另一气体耐压容器具有吸附剂时,燃料气体的分配装置可额外包含冷却装置(例如以具有冷却液体的至少一个进料管线和排出管线的形式)。在填充过程中释放的热可以这种方式通过吸附热量而补偿。
分配燃料气体的装置同样可额外具有产生膨胀的燃料气体的吸入管线,膨胀的燃料气体流过另一气体耐压容器从而冷却地返回本发明气体耐压容器。
类似的情况也适用于将燃料气体吸取入本发明气体耐压容器的装置。
当气体耐压容器没有吸附剂,还应该用于常规的气体填充其中存在于车辆中的气体耐压容器不具有储存燃料气体的吸附剂的车辆时,在燃料气体仅在分配燃料气体时流过过滤器的情况下的气体耐压容器特别合适。此处,如果存在不具有过滤器的分配燃料气体的装置,气体耐压容器可以双重能力使用。因此,由现有技术已知的,向气体驱动车辆中的燃料气体的常规分配是可行的,此处不必使用过滤器,因此优选绕过过滤器。如果燃料气体然后向其另一气体耐压容器具有储存燃料气体的吸附剂的车辆分配,则燃料气体可通过过滤器分配,从而保护存在于车辆中的吸附剂防止杂质。
最后,还存在的可能性为燃料气体在吸取和分配过程中均流过过滤器。如上所述,这可借助将燃料气体吸取入也用于分配燃料气体的本发明气体耐压容器中而实现。当吸取装置不同时用于分配时,这可通过均具有过滤器的吸取装置和分配装置实现。此时,因此必须存在多个分开的过滤器。
如果气体耐压容器不具有用于储存燃料气体的吸附剂,则有利的是最大填充压力为300巴(绝对)。当它们不具有储存燃料气体的吸附剂时,该值大约对应于根据用于气体驱动机动车辆的常规填充体系的最大填充压力。然而,因为当存在储存燃料气体的吸附剂以储存相同量的燃料气体时,存在于车辆中或车辆上的另一气体耐压容器中的压力可较小,本发明气体耐压容器的最大填充压力也可低于300巴(绝对)。因此,本发明气体耐压容器的最大填充压力优选为200巴(绝对)。然而,最大填充压力应该高于100巴,以确保用于向车辆中或车辆上的另一气体耐压容器分配燃料气体的足够压降。因此,用于位于车辆中或车辆上的另一气体耐压容器的最大填充压力为100巴(绝对),优选80巴(绝对),更优选50巴(绝对)。然而,这不应低于10巴(绝对)。
如果储存燃料气体的吸附剂存在于本发明气体耐压容器中,对存在于车辆中或车辆上的另一气体耐压容器所做的说明适用于该气体耐压容器。因此,用于本发明气体耐压容器的规定最大填充压力也可小于300巴(绝对)。这特别重要,因为由于较低的最大压力,气体耐压容器的构造可较廉价。因此,具有用于储存燃料气体的吸附剂的本发明气体耐压容器的最大填充压力优选为150巴(绝对)。最大填充压力优选为100巴(绝对),更优选90巴(绝对)。然而,必须尤其确保存在本发明气体耐压容器在车辆方向上的对另一气体耐压容器(车辆中或车辆上)的压降。
当存在用于储存燃料气体的吸附剂时,由于本发明气体耐压容器的所需的最大填充压力较低,有利的是在用于分配燃料气体的合适管线中借助比用于填充气体驱动车辆的常规气体耐压容器大的横截面调节体积流量,以确保使用与其中气体耐压容器处于高压范围(最大填充压力为300巴)的情况相似高的体积流量。
例如,如果本发明气体耐压容器中的压力为100巴(而不是300巴),分配燃料气体的阀为了实现对另一气体耐压容器大约相等的填充时间应具有约3倍大系数的横截面。
如上所述,本发明气体耐压容器具有用于吸取燃料气体的装置和分配燃料气体的装置,其中过滤器包含在至少一个中。此处,通常使用具有这种过滤器且额外配有合适阀的进料管线和/或排出管线。此外,可存在其它组件。尤其可提及检测燃料气体质量的传感器。该传感器可存在于过滤器的上游或其下游。此外,可提供调节仪器以在杂质含量太高时关闭现有的阀,以防用于储存燃料气体的吸附剂对燃料气体的储存能力受到不利影响。
这种传感器和调节技术对本领域熟练技术人员是已知的。
用于将燃料气体吸取入本发明气体耐压容器中的装置还可额外包括用于填充气体耐压容器且可建立所需压力的压缩机。
本领域熟练技术人员同样知道这种过滤器如何构造和所需尺寸。后者最终取决于待使用的燃料气体的质量。过滤器例如可以以可更换筒形式或为进料和/或排出管线的整合部分。杂质通常被吸附在过滤器中的合适吸附剂上而被固定。此处,合适的系统对本领域熟练技术人员也是已知的。合适的吸附剂为金属氧化物、分子筛、沸石、活性炭和下文更详细描述的多孔金属有机骨架(framework)以及它们的混合物。包含对特定杂质优化的多种不同吸附剂的组合过滤器是特别合适的。
因此,可使用包含不同吸附剂的一个或多个过滤器分离杂质。合适的话,用于从燃料气体中分离掉杂质的用于过滤器的吸附剂可在从过滤器中取出之后或不取出而再生。这例如可通过加热实现。通常可通过压力摆动吸附或温度摆动吸附或其组合而除去这类杂质。
过滤器之前通常为除去燃料气体中存在的任何水分(水)的脱水剂。
可能有利的是提供具有过滤器的多个进料管线和/或排出管线,燃料气体的吸取和/或分配使得至少一个进料管线经由过滤器用于吸取或分配而进行,同时在至少一个其它管线中的过滤器被再生。
为了确保足够的燃料气体的库存,本发明气体耐压容器的最小体积为1m3。有利的是气体耐压容器的最小体积为10m3,更优选大于100m3。
对本发明而言,术语“气体耐压容器”为了简化目的也用于其中使用多个相互连接的气体耐压容器的情况。因此,术语“气体耐压容器”也包括其中使用多个相互连接的气体耐压容器的实施方案。
如果使用多个相互连接的气体耐压容器,则上述最小体积基于单个最小体积的总和。
如果使用多个相互连接的气体耐压容器,则过滤器可存在于至少一个气体耐压容器中。过滤器同样可存在于多个气体耐压容器中。
因此,本发明气体耐压容器用于吸取、储存和分配燃料气体,该燃料气体适合通过燃烧燃料气体而驱动车辆。
因此,本发明进一步提供了本发明气体耐压容器在填充存在于车辆中或车辆上且包含用于储存燃料气体的吸附剂的另一气体耐压容器中的用途。
车辆例如可为客车或货车。存在于车辆中或车辆上的另一气体耐压容器的体积为50-500L。
过滤器同样可存在于具有另一气体耐压容器的车辆中,其中该另一气体耐压容器具有用于储存燃料气体的吸附剂。
用于储存燃料气体的吸附剂可为活性炭或多孔金属有机骨架。
在具有吸附剂的气体耐压容器中燃料气体的储存密度在25℃下对于包含甲烷的燃料气体应为至少50g/l,优选至少80g/l且对于包含氢气的燃料气体应为至少25g/l,优选至少35g/l。
有利的是活性炭呈成型体形式且比表面积为至少500m2/g(Langmuir,N2,77K)。比表面积更优选为至少750m2/g,非常特别优选至少1000m2/g。
在特别优选的实施方案中,用于储存燃料气体的吸附剂为多孔金属有机骨架。
多孔金属有机骨架包含至少一种与至少一种金属离子配位的至少二齿的有机化合物。该金属有机骨架(MOF)例如描述于US 5,648,508,EP-A-0709253,M.O′Keeffe等,J.Sol.State Chem.,152(2000),第3-20页,H.Li等,Nature 402(1999),第276页,M.Eddaoudi等,Topics inCatalysis(催化主题)9(1999),第105-111页,B.Chen等,Science 291(2001),第1021-1023页和DE-A-10111230中。
根据本发明使用的MOF包含孔,尤其是微孔或中孔。微孔定义为直径为2nm或更小的孔,中孔定义为直径为2-50nm的孔,在每种情况下,根据Pure Applied Chem.57(1985),第603-619页,尤其是第606页上所给的定义。微孔和/或中孔的存在可借助吸附测量而检测,该吸附测量根据DIN 66131和/或DIN 66134测定MOF在77K下对氮的吸附能力。
粉末形式的MOF的比表面积根据Langmuir模型(DIN 66131,66134)计算优选为大于5m2/g,更优选大于10m2/g,更优选大于50m2/g,甚至更优选大于500m2/g,甚至更优选大于1000m2/g,特别优选大于1500m2/g。
MOF成型体可具有较小的比表面积,但这些比表面积优选大于10m2/g,更优选大于50m2/g,甚至更优选大于500m2/g,尤其是大于1000m2/g。
在根据本发明使用的骨架中的金属组分优选选自Ia、IIa、IIIa、IVa-VIIIa和Ib-VIb族。特别优选Mg、Ca、Sr、Ba、Sc、Y、Ti、Zr、Hf、V、Nb、Ta、Cr、Mo、W、Mn、Re、Fe、Ru、Os、Co、Rh、Ir、Ni、Pd、Pt、Cu、Ag、Au、Zn、Cd、Hg、Al、Ga、In、Tl、Si、Ge、Sn、Pb、As、Sb和Bi。更优选Zn、Cu、Mg、Al、Ga、In、Sc、Y、Lu、Ti、Zr、V、Fe、Ni和Co。特别优选Cu、Zn、Al、Fe和Co。对于这些元素的离子,可特别提及Mg2+、Ca2+、Sr2+、Ba2+、Sc3+、Y3+、Ti4+、Zr4+、Hf4+、V4+、V3+、V2+、Nb3+、Ta3+、Cr3+、Mo3+、W3+、Mn3+、Mn2+、Re3+、Re2+、Fe3+、Fe2+、Ru3+、Ru2+、Os3+、Os2+、Co3+、Co2+、Rh2+、Rh+、Ir2+、Ir+、Nr2+、Ni+、Pd2+、Pd+、Pt2+、Pt+、Cu2+、Cu+、Ag+、Au+、Zn2+、Cd2+、Hg2+、Al3+、Ga3+、In3+、Tl3+、Si4+、Si2+、Ge4+、Ge2+、Sn4+、Sn2+、Pb4+、Pb2+、As5+、As3+、As+、Sb5+、Sb3+、Sb+、Bi5+、Bi3+和Bi+。
术语“至少双齿有机化合物”是指包含至少一个能够与给定的金属离子形成至少两个,优选两个配位键和/或与两个或更多个,优选两个金属原子中的每个形成配位键的官能团的有机化合物。
作为可经由其形成所述配位键的官能团,可例如特别提及如下官能团:-CO2H、-CS2H、-NO2、-B(OH)2、-SO3H、-Si(OH)3、-Ge(OH)3、-Sn(OH)3、-Si(SH)4、-Ge(SH)4、-Sn(SH)3、-PO3H、-AsO3H、-AsO4H、-P(SH)3、-As(SH)3、-CH(RSH)2、-C(RSH)3-CH(RNH2)2-C(RNH2)3、-CH(ROH)2、-C(ROH)3、-CH(RCN)2、-C(RCN)3,其中R例如优选为具有1、2、3、4或5个碳原子的亚烷基,如亚甲基、亚乙基、亚正丙基、亚异丙基、亚正丁基、亚异丁基、亚叔丁基或亚正戊基,或包含1或2个芳环,例如2个C6环的芳基,合适的话其可以是稠合的且在每种情况下可独立地被至少一个取代基取代和/或可相互独立地包含至少一个杂原子如N、O和/或S。在同样优选的实施方案中,其中不存在上述基团R的官能团也是可行的。这类基团尤其为-CH(SH)2、-C(SH)3、-CH(NH2)2、-C(NH2)3、-CH(OH)2、-C(OH)3、-CH(CN)2或-C(CN)3。
至少两个官能团原则上可为任何合适的有机化合物,只要确保其中存在这些官能团的有机化合物能够形成配位键以及产生骨架。
包含至少两个官能团的有机化合物优选源自饱和或不饱和脂族化合物或芳族化合物或脂族和芳族化合物两者。
脂族化合物或脂族和芳族化合物两者的脂族部分可为线性和/或支化和/或环状,每个化合物也可有多个环。更优选,脂族化合物或脂族和芳族化合物两者的脂族部分包含1-15,更优选1-14,更优选1-13,更优选1-12,更优选1-11,特别优选1-10个碳原子,例如1、2、3、4、5、6、7、8、9或10个碳原子。此处,特别优选甲烷、金刚烷、乙炔、乙烯或丁二烯。
芳族化合物或芳族和脂族化合物两者的芳族部分可具有一个或多个环,例如2、3、4或5个环,其中环可相互分开和/或至少两个环可以稠合形式存在。芳族化合物或芳族和脂族化合物两者的芳族部分特别优选具有1、2或3个环,特别优选1或2个环。此外,所述化合物的各环可独立地包含至少一个杂原子如N、O、S、B、P、Si、Al,优选N、O和/或S。芳族化合物或芳族和脂族化合物两者的芳族部分更优选包含1或2个C6环,其分开或以稠合形式存在。可特别提及苯、萘和/或联苯和/或联吡啶和/或吡啶基作为芳族化合物。
至少双齿有机化合物特别优选源自二羧酸、三羧酸或四羧酸或其硫类似物。硫类似物为官能团-C(=O)SH及其互变异构体和C(=S)SH,其可用于代替一个或多个羧酸基团。
对本发明而言,术语“源自”是指至少双齿有机化合物可以部分脱质子或完全脱质子形式存在于骨架中。此外,此外双齿有机化合物可包含其它取代基如-OH、-NH2、-OCH3、-CH3、NH(CH3)、-N(CH3)2、-CN和卤素。
对本发明而言,二羧酸的实例例如可提及草酸、琥珀酸、酒石酸、1,4-丁烷二甲酸、4-氧代吡喃-2,6-二甲酸、1,6-己烷二甲酸、癸烷二甲酸、1,8-十七烷二甲酸、1,9-十七烷二甲酸、十七烷二甲酸、乙炔二甲酸、1,2-苯二甲酸、2,3-吡啶二甲酸、吡啶-2,3-二甲酸、1,3-丁二烯-1,4-二甲酸、1,4-苯二甲酸、对苯二甲酸、咪唑-2,4-二甲酸、2-甲基喹啉-3,4-二甲酸、喹啉-2,4-二甲酸、喹喔啉-2,3-二甲酸、6-氯喹喔啉-2,3-二甲酸、4,4′-二氨基苯基甲烷-3,3′-二甲酸、喹啉-3,4-二甲酸、7-氯-4-羟基喹啉-2,8-二甲酸、二酰亚胺羧酸(diimidecarboxylic acid)、吡啶-2,6-二甲酸、2-甲基咪唑-4,5-二甲酸、噻吩-3,4-二甲酸、2-异丙基咪唑-4,5-二甲酸、四氢吡喃-4,4-二甲酸、二萘嵌苯-3,9-二甲酸、二萘嵌苯二甲酸、Pluriol E 200-二甲酸、3,6-二氧杂辛烷二甲酸、3,5-环己二烯-1,2-二甲酸、辛烷二甲酸、戊烷-3,3-甲酸、4,4′-二氨基-1,1′-联苯基-3,3′-二甲酸、4,4′-二氨基联苯基-3,3′-二甲酸、联苯氨-3,3′-二甲酸、1,4-二(苯基氨基)苯-2,5-二甲酸、1,1′-联萘基-5,5′-二甲酸、7-氯-8-甲基喹啉-2,3-二甲酸、1-苯氨基蒽醌-2,4′-二甲酸、聚四氢呋喃250-二甲酸、1,4-二(羧甲基)哌嗪-2,3-二甲酸、7-氯喹啉-3,8-二甲酸、1-(4-羧基)苯基-3-(4-氯)苯基吡唑啉-4,5-二甲酸、1,4,5,6,7,7-六氯-5-降冰片烯-2,3-二甲酸、苯基茚满二甲酸、1,3-二苄基-2-氧代咪唑烷-4,5-二甲酸、1,4-环己烷二甲酸、萘-1,8-二甲酸、2,-苯甲酰基苯-1,3-二甲酸、1,3-二苄基-2-氧代咪唑烷-4,5-顺式-二甲酸、2,2′-二喹啉-4,4′-二甲酸、吡啶-3,4-二甲酸、3,6,9-三氧杂十一烷二甲酸、O-羟基-二苯甲酮二甲酸、Pluriol E 300-二甲酸、Pluriol E 400-二甲酸、PluriolE 600-二甲酸、吡唑-3,4-二甲酸、2,3-吡嗪二甲酸、5,6-二甲基-2,3-吡嗪二甲酸、4,4′-二氨基(二苯基醚)二酰亚胺二甲酸、4,4′-二氨基二苯基甲烷二酰亚胺二甲酸、4,4′-二氨基(二苯基砜)二酰亚胺二甲酸、2,6-萘二甲酸、1,3-金刚烷二甲酸、1,8-萘二甲酸、2,3-萘二甲酸、8-甲氧基-2,3-萘二甲酸、8-硝基-2,3-萘甲酸、8-磺基-2,3-萘二甲酸、蒽-2,3-二甲酸、2′,3′-二苯基-对三联苯基-4,4″-二甲酸、(二苯基醚)-4,4′-二甲酸、咪唑-4,5-二甲酸、4(1H)-氧硫代苯并吡喃(oxothiochromene)-2,8-二甲酸、5-叔丁基-1,3-苯二甲酸、7,8-喹啉二甲酸、4,5-咪唑二甲酸、4-环己烯-1,2-二甲酸、三十六烷二甲酸、十四烷二甲酸、1,7-庚烷二甲酸、5-羟基-1,3-苯二甲酸、吡嗪-2,3-二甲酸、呋喃-2,5-二甲酸、1-壬烯-6,9-二甲酸、二十烯二甲酸、4,4′-二羟基二苯基甲烷-3,3′-二甲酸、1-氨基-4-甲基-9,10-二氧代-9,10-二氢蒽-2,3-二甲酸、2,5-吡啶二甲酸、环己烯-2,3-二甲酸、2,9-二氯荧红环-4,11-二甲酸、7-氯-3-甲基喹啉-6,8-二甲酸、2,4-二氯二苯甲酮-2′,5′-二甲酸、1,3-苯二甲酸、2,6-吡啶二甲酸、1-甲基吡咯-3,4-二甲酸、1-苄基-1H-吡咯-3,4-二甲酸、蒽醌-1,5-二甲酸、3,5-吡唑二甲酸、2-硝基苯-1,4-二甲酸、庚烷-1,7-二甲酸、环丁烷-1,1-二甲酸、1,14-十四烷二甲酸、5,6-脱氢降冰片烷-2,3-二甲酸或5-乙基-2,3-吡啶二甲酸,
三羧酸,例如:
2-羟基-1,2,3-丙烷三甲酸、7-氯-2,3,8-喹啉三甲酸、1,2,4-苯三甲酸、1,2,4-丁烷三甲酸、2-膦酰基-1,2,4-丁烷三甲酸、1,3,5-苯三甲酸、1-羟基-1,2,3-丙烷三甲酸、4,5-二氢-4,5-二氧代-1H-吡咯并[2,3-F]喹啉-2,7,9-三甲酸、5-乙酰基-3-氨基-6-甲基苯-1,2,4-三甲酸、3-氨基-5-苯甲酰基-6-甲基苯-1,2,4-三甲酸、1,2,3-丙烷三甲酸或金精三甲酸,
或四羧酸,例如:
(苝并[1,12-BCD]噻吩1,1-二氧化物)-3,4,9,10-四甲酸、二萘嵌苯(perylene)四甲酸如二萘嵌苯-3,4,9,10-四甲酸或(二萘嵌苯-1,12-砜)-3,4,9,10-四甲酸,丁烷四甲酸如1,2,3,4-丁烷四甲酸或内-1,2,3,4-丁烷四甲酸、癸烷-2,4,6,8-四甲酸、1,4,7,10,13,16-六氧杂环十八烷-2,3,11,12-四甲酸、1,2,4,5-苯四甲酸、1,2,11,12-十二烷四甲酸、1,2,5,6-己烷四甲酸、1,2,7,8-辛烷四甲酸、1,4,5,8-萘四甲酸、1,2,9,10-癸烷四甲酸、二苯甲酮四甲酸、3,3′-4,4′-二苯甲酮四甲酸、四氢呋喃四甲酸或环戊烷四甲酸如环戊烷-1,2,3,4-四甲酸。
非常特别优选未取代或至少单取代的芳族二羧酸、三羧酸或四羧酸,其具有1、2、3、4个或更多个环,其中各环可包含至少一个杂原子,两个或更多个环可包含相同或不同的杂原子。例如优选单环二羧酸、单环三羧酸、单环四羧酸、双环二羧酸、双环三羧酸、双环四羧酸、三环二羧酸、三环三羧酸、三环四羧酸、四环二羧酸、四环三羧酸和/或四环四羧酸。合适的杂原子例如为N、O、S、B、P、Si、Al,优选杂原子为N、S和/或O。此处,合适的取代基尤其为-OH、硝基、氨基和烷基或烷氧基。
特别优选至少双齿有机化合物为乙炔二甲酸(ADC)、苯二甲酸、萘二甲酸、联苯二甲酸如4,4′-联苯基二甲酸(BPDC)、联吡啶二甲酸如2,2′-联吡啶二甲酸如2,2′-联吡啶-5,5′-二甲酸、苯三甲酸如1,2,3-苯三甲酸或1,3,5-苯三甲酸(BTC)、金刚烷四甲酸(ATC)、金刚烷二苯甲酸盐(ADB)、苯三苯甲酸盐(BTB)、甲烷四苯甲酸盐(MTB)、金刚烷四苯甲酸盐或二羟基对苯二甲酸如2,5-二羟基对苯二甲酸(DHBDC)。
非常特别优选使用间苯二甲酸、对苯二甲酸、2,5-二羟基对苯二甲酸、1,2,3-苯三甲酸、1,3,5-苯三甲酸或2,2′-联吡啶-5,5′-二甲酸。
除了这些至少双齿有机化合物之外,MOF还可包含一个或多个单齿配体。
适合制备MOF的溶剂尤其为乙醇、二甲基甲酰胺、甲苯、甲醇、氯苯、二乙基甲酰胺、二甲亚砜、水、过氧化氢、甲胺、氢氧化钠水溶液、N-甲基吡咯烷酮醚、乙腈、苄基氯、三乙胺、乙二醇及其混合物。用于制备MOF的其它金属离子、至少双齿有机化合物和溶剂尤其描述于US-A 5,648,508或DE-A 10111230中。
MOF的孔径可通过选择合适的配体和/或至少双齿有机化合物而控制。通常的情况是有机化合物越大,孔径越大。基于晶体材料的孔径优选为0.2-30nm,特别优选0.3-3nm。
然而,其孔径分布可变化的较大孔也可出现在MOF成型体中。然而,优选超过50%的总的孔体积,尤其是超过75%的总的孔体积由孔径至多1000nm的孔组成。然而,优选大部分孔体积由具有两个直径范围的孔组成。因此,优选超过25%的总的孔体积,尤其是超过50%的总的孔体积由直径位于100-800nm范围的孔组成,以及超过15%的总的孔体积,尤其是超过25%的总的孔体积由直径为至多10nm的孔组成。孔分布可借助水银孔隙度法测定。
MOF-n | 成份摩尔比M+L | 溶剂 | α | β | γ | a | b | c | 空间群 |
MOF-0 | Zn(NO3)2·6H2OH3(BTC) | 乙醇 | 90 | 90 | 120 | 16.711 | 16.711 | 14.189 | P6(3)/Mcm |
MOF-2 | Zn(NO3)2·6H2O(0.246mmol)H2(BDC)0.241mmol) | DMF甲苯 | 90 | 102.8 | 90 | 6.718 | 15.49 | 12.43 | P2(1)/n |
MOF-3 | Zn(NO3)2·6H2O(1.89mmol)H2(BDC)(1.93mmol) | DMFMeOH | 99.72 | 111.11 | 108.4 | 9.726 | 9.911 | 10.45 | P-1 |
MOF-4 | Zn(NO3)2·6H2O(1.00mmol)H3(BTC)(0.5mmol) | 乙醇 | 90 | 90 | 90 | 14.728 | 14.728 | 14.728 | P2(1)3 |
MOF-5 | Zn(NO3)2·6H2O(2.22mmol)H2(BDC)(2.17mmol) | DMF氯苯 | 90 | 90 | 90 | 25.669 | 25.669 | 25.669 | Fm-3m |
MOF-38 | Zn(NO3)2·6H2O(0.27mmol)H3(BTC)(0.15mmol) | DMF氯苯 | 90 | 90 | 90 | 20.657 | 20.657 | 17.84 | I4cm |
MOF-31Zn(ADC)2 | Zn(NO3)2·6H2O0.4mmolH2(ADC)0.8mmol | 乙醇 | 90 | 90 | 90 | 10.821 | 10.821 | 10.821 | Pn(-3)m |
MOF-12Zn2(ATc) | Zn(NO3)2·6H2O0.3mmolH4(ATC)0.15mmol | 乙醇 | 90 | 90 | 90 | 15.745 | 16.907 | 18.167 | Pbca |
MOF-20ZnNDC | Zn(NO3)2·6H2O0.37mmolH2NDC0.36mmol | DMF氯苯 | 90 | 92.13 | 90 | 8.13 | 16.444 | 12.807 | P2(1)/c |
MOF-37 | Zn(NO3)2·6H2O0.2mmolH2NDC0.2mmol | DEF氯苯 | 72.38 | 83.16 | 84.33 | 9.952 | 11.576 | 15.556 | P-1 |
MOF-8Tb2(ADC) | Tb(NO3)3·5H2O0.10mmolH2ADC0.20mmol | DMSOMeOH | 90 | 115.7 | 90 | 19.83 | 9.822 | 19.183 | C2/c |
MOF-9Tb2(ADC) | Tb(NO3)3·5H2O0.08mmolH2ADB0.12mmol | DMSO | 90 | 102.09 | 90 | 27.056 | 16.795 | 28.139 | C2/c |
MOF-6 | Tb(NO3)3·5H2O0.30mmolH2(BDC)0.30mmol | DMFMeOH | 90 | 91.28 | 90 | 17.599 | 19.996 | 10.545 | P21/c |
MOF-7 | Tb(NO3)3·5H2O0.15mmolH2(BDC)0.15mmol | H2O | 102.3 | 91.12 | 101.5 | 6.142 | 10.069 | 10.096 | P-1 |
MOF-69A | Zn(NO3)2·6H2O0.083mmol4,4‘BPDC0.041mmol | DEFH2O2MeNH2 | 90 | 111.6 | 90 | 23.12 | 20.92 | 12 | C2/c |
MOF-69B | Zn(NO3)2·6H2O0.083mmol2,6-NCD0.041mmol | DEFH2O2MeNH2 | 90 | 95.3 | 90 | 20.17 | 18.55 | 12.16 | C2/c |
MOF-11Cu2(ATC) | Cu(NO3)2·2.5H2O0.47mmolH2ATC0.22mmol | H2O | 90 | 93.86 | 90 | 12.987 | 11.22 | 11.336 | C2/c |
MOF-11Cu2(ATC)脱水 | 90 | 90 | 90 | 8.4671 | 8.4671 | 14.44 | P42/mmc | ||
MOF-14Cu3(BTB) | Cu(NO3)2·2.5H2O0.28mmolH3BTB0.052mmol | H2ODMFEtOH | 90 | 90 | 90 | 26.946 | 26.946 | 26.946 | Im-3 |
MOF-32Cd(ATC) | Cd(NO3)2·4H2O0.24mmolH4ATC0.10mmol | H2ONaOH | 90 | 90 | 90 | 13.468 | 13.468 | 13.468 | P(-4)3m |
MOF-33Zn2(ATB) | ZnCl20.15mmolH4ATB0.02mmol | H2ODMFEtOH | 90 | 90 | 90 | 19.561 | 15.255 | 23.404 | Imma |
MOF-34Ni(ATC) | Ni(NO3)2·6H2O0.24mmolH4ATC0.10mmol | H2ONaOH | 90 | 90 | 90 | 10.066 | 11.163 | 19.201 | P212121 |
MOF-36Zn2(MTB) | Zn(NO3)2·4H2O0.20mmolH4MTB0.04mmol | H2ODMF | 90 | 90 | 90 | 15.745 | 16.907 | 18.167 | Pbca |
MOF-39Zn3O(HBTB) | Zn(NO3)24H2O0.27mmolH3BTB0.07mmol | H2ODMFEtOH | 90 | 90 | 90 | 17.158 | 21.591 | 25.308 | Pnma |
NO305 | FeCl2·4H2O5.03mmol甲酸86.90mmol | DMF | 90 | 90 | 120 | 8.2692 | 8.2692 | 63.566 | R-3c |
NO306A | FeCl2·4H2O5.03mmol甲酸86.90mmol | DEF | 90 | 90 | 90 | 9.9364 | 18.374 | 18.374 | Pbcn |
NO29类似于MOF-0 | Mn(Ac)2·4H2O0.46mmolH3BTC0.69mmol | DMF | 120 | 90 | 90 | 14.16 | 33.521 | 33.521 | P-1 |
BPR48A2 | Zn(NO3)26H2O0.012mmolH2BDC0.012mmol | DMSO甲苯 | 90 | 90 | 90 | 14.5 | 17.04 | 18.02 | Pbca |
BPR69B1 | Cd(NO3)24H2O0.0212mmolH2BDC0.0428mmol | DMSO | 90 | 98.76 | 90 | 14.16 | 15.72 | 17.66 | Cc |
BPR92A2 | Co(NO3)2·6H2O0.018mmolH2BDC0.018mmol | NMP | 106.3 | 107.63 | 107.2 | 7.5308 | 10.942 | 11.025 | P1 |
BPR95C5 | Cd(NO3)24H2O0.012mmolH2BDC0.36mmol | NMP | 90 | 112.8 | 90 | 14.460 | 11.085 | 15.829 | P2(1)/n |
Cu C6H4O6 | Cu(NO3)2·2.5H2O0.370mmolH2BDC(OH)20.37mmol | DMF氯苯 | 90 | 105.29 | 90 | 15.259 | 14.816 | 14.13 | P2(1)/c |
Cu-硫 | Cu(NO3)2·2.5H2O0.084mmol噻吩二甲酸0.085mmol | DEF | 90 | 113.6 | 90 | 15.4747 | 14.514 | 14.032 | P2(1)/c |
CIBDC1 | Cu(NO3)2·2.5H2O0.084mmolH2(BDCCl2)0.085mmol | DMF | 90 | 105.6 | 90 | 14.911 | 15.622 | 18.413 | C2/c |
MOF-101 | Cu(NO3)2·2.5H2O0.084mmolBrBDC0.085mmol | DMF | 90 | 90 | 90 | 21.607 | 20.607 | 20.073 | Fm3m |
Zn3(BTC)2 | ZnCl20.033mmolH3BTC0.033mmol | DMFEtOH加入的碱 | 90 | 90 | 90 | 26.572 | 26.572 | 26.572 | Fm-3m |
MOF-j | Co(CH3CO2)2·4H2O(1.65mmol)H3(BZC)(0.95mmol) | H2O | 90 | 112.0 | 90 | 17.482 | 12.963 | 6.559 | C2 |
MOF-n | Zn(NO3)2·6H2OH3(BTC) | 乙醇 | 90 | 90 | 120 | 16.711 | 16.711 | 14.189 | P6(3)/mcm |
PbBDC | Pb(NO3)2(0.181mmol)H2(BDC)(0.181mmol) | DMF乙醇 | 90 | 102.7 | 90 | 8.3639 | 17.991 | 9.9617 | P2(1)/n |
Zn六(Znhex) | Zn(NO3)2·6H2O(0.171mmol)H3BTB(0.114mmol) | DMF对二甲苯乙醇 | 90 | 90 | 120 | 37.1165 | 37.117 | 30.019 | P3(1)c |
AS16 | FeBr20.927mmolH2(BDC)0.927mmol | DMF无水 | 90 | 90.13 | 90 | 7.2595 | 8.7894 | 19.484 | P2(1)c | ||
AS27-2 | FeBr20.927mmolH3(BDC)0.464mmol | DMF无水 | 90 | 90 | 90 | 26.735 | 26.735 | 26.735 | Fm3m | ||
AS32 | FeCl31.23mmolH2(BDC)1.23mmol | DMF无水乙醇 | 90 | 90 | 120 | 12.535 | 12.535 | 18.479 | P6(2)c | ||
AS54-3 | FeBr20.927BPDC0.927mmol | DMF无水丙醇 | 90 | 109.98 | 90 | 12.019 | 15.286 | 14.399 | C2 | ||
AS61-4 | FeBr20.927mmolm-BDC0.927mmol | 无水吡啶 | 90 | 90 | 120 | 13.017 | 13.017 | 14.896 | P6(2)c | ||
AS68-7 | FeBr20.927mmolm-BDC1.204mmol | DMF无水吡啶 | 90 | 90 | 90 | 18.3407 | 10.036 | 18.039 | Pca21 | ||
Zn(ADC) | Zn(NO3)2·6H2O0.37mmolH2(ADC)0.36mmol | DMF氯苯 | 90 | 99.85 | 90 | 16.764 | 9.349 | 9.635 | C2/c | ||
MOF-12Zn2(ATC) | Zn(NO3)2·6H2O0.30mmolH4(ATC)0.15mmol | 乙醇 | 90 | 90 | 90 | 15.745 | 16.907 | 18.167 | Pbca |
MOF-20ZnNDC | Zn(NO3)2·6H2O0.37mmolH2NDC0.36mmol | DMF氯苯 | 90 | 92.13 | 90 | 8.13 | 16.444 | 12.807 | P2(1)/c |
MOF-37 | Zn(NO3)2·6H2O0.20mmolH2NDC0.20mmol | DEF氯苯 | 72.38 | 83.16 | 84.33 | 9.952 | 11.576 | 15.556 | P-1 |
Zn(NDC)(DMSO) | Zn(NO3)2·6H2OH2NDC | DMSO | 68.08 | 75.33 | 88.31 | 8.631 | 10.207 | 13.114 | P-1 |
Zn(NDC) | Zn(NO3)2·6H2OH2NDC | 90 | 99.2 | 90 | 19.289 | 17.628 | 15.052 | C2/c | |
Zn(HPDC) | Zn(NO3)2·4H2O0.23mmolH2(HPDC)0.05mmol | DMFH2O | 107.9 | 105.06 | 94.4 | 8.326 | 12.085 | 13.767 | P-1 |
Co(HPDC) | Co(NO3)2·6H2O0.21mmolH2(HPDC)0.06mmol | DMFH2O/乙醇 | 90 | 97.69 | 90 | 29.677 | 9.63 | 7.981 | C2/c |
Zn3(PDC)2.5 | Zn(NO3)2·4H2O0.17mmolH2(HPDC)0.05mmol | DMF/ClBzH20/TEA | 79.34 | 80.8 | 85.83 | 8.564 | 14.046 | 26.428 | P-1 |
Cd2(TPDC)2 | Cd(NO3)2·4H2O0.06mmolH2(HPDC)0.06mmol | 甲醇/CHPH2O | 70.59 | 72.75 | 87.14 | 10.102 | 14.412 | 14.964 | P-1 |
Tb(PDC)1.5 | Tb(NO3)3·5H2O0.21mmolH2(PDC)0.034mmol | DMFH2O/乙醇 | 109.8 | 103.61 | 100.14 | 9.829 | 12.11 | 14.628 | P-1 |
ZnDBP | Zn(NO3)2·6H2O0.05mmol二苄基磷酸根0.10mmol | MeOH | 90 | 93.67 | 90 | 9.254 | 10.762 | 27.93 | P2/n |
Zn3(BPDC) | ZnBr20.021mmol4,4′BPDC0.005mmol | DMF | 90 | 102.76 | 90 | 11.49 | 14.79 | 19.18 | P21/n |
CdBDC | Cd(NO3)2·4H2O0.100mmolH2(BDC)0.401mmol | DMFNa2SiO3(含水) | 90 | 95.85 | 90 | 11.2 | 11.11 | 16.71 | P21/n |
Cd-mBDC | Cd(NO3)2·4H2O0.009mmolH2(mBDC)0.018mmol | DMFMeNH2 | 90 | 101.1 | 90 | 13.69 | 18.25 | 14.91 | C2/c |
Zn4OBNDC | Zn(NO3)2·6H2O0.041mmolBNDC | DEFMeNH2H2O2 | 90 | 90 | 90 | 22.35 | 26.05 | 59.56 | Fmmm |
Eu(TCA) | Eu(NO3)3·6H2O0.14mmolTCA0.026mmol | DMF氯苯 | 90 | 90 | 90 | 23.325 | 23.325 | 23.325 | Pm-3n |
Tb(TCA) | Tb(NO3)3·6H2O0.069mmolTCA0.026mmol | DMF氯苯 | 90 | 90 | 90 | 23.272 | 23.272 | 23.372 | Pm-3n |
甲酸盐 | Ce(NO3)3·6H2O0.138mmol甲酸0.43mmol | H2O乙醇 | 90 | 90 | 120 | 10.668 | 10.667 | 4.107 | R-3m |
FeCl2·4H2O5.03mmol甲酸86.90mmol | DMF | 90 | 90 | 120 | 8.2692 | 8.2692 | 63.566 | R-3c |
FeCl2·4H2O5.03mmol甲酸86.90mmol | DEF | 90 | 90 | 90 | 9.9364 | 18.374 | 18.374 | Pbcn | |
FeCl2·4H2O5.03mmol甲酸86.90mmol | DEF | 90 | 90 | 90 | 8.335 | 8.335 | 13.34 | P-31c | |
NO330 | FeCl2·4H2O0.50mmol甲酸8.69mmol | 甲酰胺 | 90 | 90 | 90 | 8.7749 | 11.655 | 8.3297 | Pnna |
NO332 | FeCl2·4H2O0.50mmol甲酸8.69mmol | DIP | 90 | 90 | 90 | 10.0313 | 18.808 | 18.355 | Pbcn |
NO333 | FeCl2·4H2O0.50mmol甲酸8.69mmol | DBF | 90 | 90 | 90 | 45.2754 | 23.861 | 12.441 | Cmcm |
NO335 | FeCl2·4H2O0.50mmol甲酸8.69mmol | CHF | 90 | 91.372 | 90 | 11.5964 | 10.187 | 14.945 | P21/n |
NO336 | FeCl2·4H2O0.50mmol甲酸8.69mmol | MFA | 90 | 90 | 90 | 11.7945 | 48.843 | 8.4136 | Pbcm |
NO13 | Mn(Ac)2·4H2O0.46mmol苯甲酸0.92mmol联吡啶0.46mmol | 乙醇 | 90 | 90 | 90 | 18.66 | 11.762 | 9.418 | Pbcn |
NO29MOF-0 | Mn(Ac)2·4H2O0.46mmolH3BTC0.69mmol | DMF | 120 | 90 | 90 | 14.16 | 33.521 | 33.521 | P-1 |
Mn(hfac)2(O2CC6H5) | Mn(Ac)2·4H2O0.46mmolHfac0.92mmol联吡啶0.46mmol | 乙醚 | 90 | 95.32 | 90 | 9.572 | 17.162 | 14.041 | C2/c |
BPR43G2 | Zn(NO3)2·6H2O0.0288mmolH2BDC0.0072mmol | DMFCH3CN | 90 | 91.37 | 90 | 17.96 | 6.38 | 7.19 | C2/c |
BPR48A2 | Zn(NO3)26H2O0.012mmolH2BDC0.012mmol | DMSO甲苯 | 90 | 90 | 90 | 14.5 | 17.04 | 18.02 | Pbca |
BPR49B1 | Zn(NO3)26H2O0.024mmolH2BDC0.048mmol | DMSO甲醇 | 90 | 91.172 | 90 | 33.181 | 9.824 | 17.884 | C2/c |
BPR56E1 | Zn(NO3)26H2O0.012mmolH2BDC0.024mmol | DMSO正丙醇 | 90 | 90.096 | 90 | 14.5873 | 14.153 | 17.183 | P2(1)/n |
BPR68D10 | Zn(NO3)26H2O0.0016mmolH3BTC0.0064mmol | DMSO苯 | 90 | 95.316 | 90 | 10.0627 | 10.17 | 16.413 | P2(1)/c |
BPR69B1 | Cd(NO3)24H2O0.0212mmolH2BDC0.0428mmol | DMSO | 90 | 98.76 | 90 | 14.16 | 15.72 | 17.66 | Cc |
BPR73E4 | Cd(NO3)24H2O0.006mmolH2BDC0.003mmol | DMSO甲苯 | 90 | 92.324 | 90 | 8.7231 | 7.0568 | 18.438 | P2(1)/n |
BPR76D5 | Zn(NO3)26H2O0.0009mmolH2BzPDC0.0036mmol | DMSO | 90 | 104.17 | 90 | 14.4191 | 6.2599 | 7.0611 | Pc |
BPR80B5 | Cd(NO3)2·4H2O0.018mmolH2BDC0.036mmol | DMF | 90 | 115.11 | 90 | 28.049 | 9.184 | 17.837 | C2/c |
BPR80H5 | Cd(NO3)24H2O0.027mmolH2BDC0.027mmol | DMF | 90 | 119.06 | 90 | 11.4746 | 6.2151 | 17.268 | P2/c |
BPR82C6 | Cd(NO3)24H2O0.0068mmolH2BDC0.202mmol | DMF | 90 | 90 | 90 | 9.7721 | 21.142 | 27.77 | Fdd2 |
BPR86C3 | Co(NO3)26H2O0.0025mmolH2BDC0.075mmol | DMF | 90 | 90 | 90 | 18.3449 | 10.031 | 17.983 | Pca2(1) |
BPR86H6 | Cd(NO3)2·6H2O0.010mmolH2BDC0.010mmol | DMF | 80.98 | 89.69 | 83.412 | 9.8752 | 10.263 | 15.362 | P-1 |
Co(NO3)26H2O | NMP | 106.3 | 107.63 | 107.2 | 7.5308 | 10.942 | 11.025 | P1 | |
BPR95A2 | Zn(NO3)26H2O0.012mmolH2BDC0.012mmol | NMP | 90 | 102.9 | 90 | 7.4502 | 13.767 | 12.713 | P2(1)/c |
CuC6F4O4 | Cu(NO3)2·2.5H2O0.370mmolH2BDC(OH)20.37mmol | DMF氯苯 | 90 | 98.834 | 90 | 10.9675 | 24.43 | 22.553 | P2(1)/n |
甲酸铁 | FeCl2·4H2O0.370mmol甲酸0.37mmol | DMF | 90 | 91.543 | 90 | 11.495 | 9.963 | 14.48 | P2(1)/n |
甲酸镁 | Mg(NO3)2·6H2O0.370mmol甲酸0.37mmol | DMF | 90 | 91.359 | 90 | 11.383 | 9.932 | 14.656 | P2(1)/n |
MgC6H4O6 | Mg(NO3)2·6H2O0.370mmolH2BDC(OH)20.37mmol | DMF | 90 | 96.624 | 90 | 17.245 | 9.943 | 9.273 | C2/c |
ZnC2H4BDCMOF-38 | ZnCl20.44mmolCBBDC0.261mmol | DMF | 90 | 94.714 | 90 | 7.3386 | 16.834 | 12.52 | P2(1)/n |
MOF-49 | ZnCl20.44mmolm-BDC0.261mmol | DMFCH3CN | 90 | 93.459 | 90 | 13.509 | 11.984 | 27.039 | P2/c |
MOF-26 | Cu(NO3)2·5H2O0.084mmolDCPE0.085mmol | DMF | 90 | 95.607 | 90 | 20.8797 | 16.017 | 26.176 | P2(1)/n |
MOF-112 | Cu(NO3)2·2.5H2O0.084mmolo-Br-m-BDC0.085mmol | DMF乙醇 | 90 | 107.49 | 90 | 29.3241 | 21.297 | 18.069 | C2/c |
MOF-109 | Cu(NO3)2·2.5H2O0.084mmolKDB0.085mmol | DMF | 90 | 111.98 | 90 | 23.8801 | 16.834 | 18.389 | P2(1)/c |
MOF-111 | Cu(NO3)2·2.5H2O0.084mmolo-BrBDC0.085mmol | DMF乙醇 | 90 | 102.16 | 90 | 10.6767 | 18.781 | 21.052 | C2/c |
MOF-110 | Cu(NO3)2·2.5H2O0.084mmol噻吩二甲酸0.085mmol | DMF | 90 | 90 | 120 | 20.0652 | 20.065 | 20.747 | R-3/m |
MOF-107 | Cu(NO3)2·2.5H2O0.084mmol噻吩二甲酸0.085mmol | DEF | 104.8 | 97.075 | 95.206 | 11.032 | 18.067 | 18.452 | P-1 |
MOF-108 | Cu(NO3)2·2.5H2O0.084mmol噻吩二甲酸0.085mmol | DBF/甲醇 | 90 | 113.63 | 90 | 15.4747 | 14.514 | 14.032 | C2/c |
MOF-102 | Cu(NO3)2·2.5H2O0.084mmolH2(BDCCl2)0.085mmol | DMF | 91.63 | 106.24 | 112.01 | 9.3845 | 10.794 | 10.831 | P-1 |
CIbdc1 | Cu(NO3)2·2.5H2O0.084mmolH2(BDCCl2)0.085mmol | DEF | 90 | 105.56 | 90 | 14.911 | 15.622 | 18.413 | P-1 |
Cu(NMOP) | Cu(NO3)2·2.5H2O0.084mmolNBDC0.085mmol | DMF | 90 | 102.37 | 90 | 14.9238 | 18.727 | 15.529 | P2(1)/m |
Tb(BTC) | Tb(NO3)3·5H2O0.033mmolH3BTC0.033mmol | DMF | 90 | 106.02 | 90 | 18.6986 | 11.368 | 19.721 |
Zn3(BTC)2 | ZnCl20.033mmolH3BTC0.033mmol | DMF乙醇 | 90 | 90 | 90 | 26.572 | 26.572 | 26.572 | Fm-3m |
Zn4O(NDC) | Zn(NO3)2·4H2O0.066mmol14NDC0.066mmol | DMF乙醇 | 90 | 90 | 90 | 41.5594 | 18.818 | 17.574 | aba2 |
CdTDC | Cd(NO3)2·4H2O0.014mmol噻吩0.040mmolDABCO0.020mmol | DMFH2O | 90 | 90 | 90 | 12.173 | 10.485 | 7.33 | Pmma |
IRMOF-2 | Zn(NO3)2·4H2O0.160mmolo-Br-BDC0.60mmol | DEF | 90 | 90 | 90 | 25.772 | 25.772 | 25.772 | Fm-3m |
IRMOF-3 | Zn(NO3)2·4H2O0.20mmolH2N-BDC0.60mmol | DEF乙醇 | 90 | 90 | 90 | 25.747 | 25.747 | 25.747 | Fm-3m |
IRMOF-4 | Zn(NO3)2·4H2O0.11mmol[C3H7O]2-BDC0.48mmol | DEF | 90 | 90 | 90 | 25.849 | 25.849 | 25.849 | Fm-3m |
IRMOF-5 | Zn(NO3)2·4H2O0.13mmol[C5H11O]2-BDC0.50mmol | DEF | 90 | 90 | 90 | 12.882 | 12.882 | 12.882 | Pm-3m |
IRMOF-6 | Zn(NO3)2·4H2O0.20mmol[C2H4]-BDC0.60mmol | DEF | 90 | 90 | 90 | 25.842 | 25.842 | 25.842 | Fm-3m |
IRMOF-7 | Zn(NO3)2·4H2O0.07mmol1,4NDC0.20mmol | DEF | 90 | 90 | 90 | 12.914 | 12.914 | 12.914 | Pm-3m |
IRMOF-8 | Zn(NO3)2·4H2O0.55mmol2,6NDC0.42mmol | DEF | 90 | 90 | 90 | 30.092 | 30.092 | 30.092 | Fm-3m |
IRMOF-9 | Zn(NO3)2·4H2O0.05mmolBPDC0.42mmol | DEF | 90 | 90 | 90 | 17.147 | 23.322 | 25.255 | Pnnm |
IRMOF-10 | Zn(NO3)2·4H2O0.02mmolBPDC0.012mmol | DEF | 90 | 90 | 90 | 34.281 | 34.281 | 34.281 | Fm-3m |
IRMOF-11 | Zn(NO3)2·4H2O0.05mmolHPDC0.20mmol | DEF | 90 | 90 | 90 | 24.822 | 24.822 | 56.734 | R-3m |
IRMOF-12 | Zn(NO3)2·4H2O0.017mmolHPDC0.12mmol | DEF | 90 | 90 | 90 | 34.281 | 34.281 | 34.281 | Fm-3m |
IRMOF-13 | Zn(NO3)2·4H2O0.048mmolPDC0.31mmol | DEF | 90 | 90 | 90 | 24.822 | 24.822 | 56.734 | R-3m |
IRMOF-14 | Zn(NO3)2·4H2O0.17mmolPDC0.12mmol | DEF | 90 | 90 | 90 | 34.381 | 34.381 | 34.381 | Fm-3m |
IRMOF-15 | Zn(NO3)2·4H2O0.063mmolTPDC0.025mmol | DEF | 90 | 90 | 90 | 21.459 | 21.459 | 21.459 | Im-3m |
IRMOF-16 | Zn(NO3)2·4H2O0.0126mmolTPDC0.05mmol | DEFNMP | 90 | 90 | 90 | 21.49 | 21.49 | 21.49 | Pm-3m |
ADC 乙炔二甲酸
NDC 萘二甲酸
BDC 苯二甲酸
ATC 金刚烷四甲酸
BTC 苯三甲酸
BTB 苯三苯甲酸
MTB 甲烷四苯甲酸
ATB 金刚烷四苯甲酸
ADB 金刚烷二苯甲酸
其它金属有机骨架为MOF-2至4、MOF-9、MOF-31至36、MOF-39、MOF-69至80、MOF 103至106、MOF-122、MOF-125、MOF-150、MOF-177、MOF-178、MOF-235、MOF-236、MOF-500、MOF-501、MOF-502、MOF-505、IRMOF-1、IRMOF-61、IRMOP-13、IRMOP-51、MIL-17、MIL-45、MIL-47、MIL-53、MIL-59、MIL-60、MIL-61、MIL-63、MIL-68、MIL-79、MIL-80、MIL-83、MIL-85、CPL-1至2、SZL-1,其描述于文献中。
特别优选如下多孔金属有机骨架,其中Zn、Al或Cu以金属离子存在且至少双齿有机化合物为对苯二甲酸、间苯二甲酸、2,6-萘二甲酸或1,3,5-苯三甲酸。
除了例如描述于US 5,648,508中的制备MOF的常规方法外,它们也可通过电化学路线制备。就此而言,参考DE-A 10355087和WO-A 2005/049892。
通过该路线制备的MOF在化学物质,尤其是气体的吸附和解吸方面具有特别良好的性能。它们以此区别于以常规方式制备的那些,即使它们由相同的有机成分和金属离子成分制成,因此应认为是新的骨架。对本发明而言,特别优选电化学制备的MOF。
因此,电化学制备涉及晶体多孔金属有机骨架,其包含至少一种与至少一种金属离子配位的至少双齿有机化合物且在包含至少一种双齿有机化合物的反应介质中通过在包含相应金属的至少一个阳极氧化产生至少一种金属离子而得到。
术语“电化学制备”涉及一种其中形成至少一种反应产物伴随着电荷迁移或出现电势的方法。
就电化学制备而使用的术语“至少一种金属离子”涉及其中至少一种金属离子或至少一种第一金属的离子或至少一种不同于第一金属的第二金属的至少一种离子通过阳极氧化提供的实施方案。
因此,电化学制备包括其中至少一种金属的至少一种离子通过阳极氧化提供和至少一种金属的至少一种离子经由金属盐提供的实施方案,其中金属盐中的至少一种金属和借助阳极氧化提供金属离子的至少一种金属可相同或不同。因此,关于电化学制备的MOF,本发明例如包括其中反应介质包含一种或多种不同的金属盐以及包含在盐中的金属离子额外由包含该金属的至少一个阳极的阳极氧化而提供的实施方案。反应介质同样可包含至少一种金属的一种或多种不同的盐且不同于这些金属的至少一种金属可借助在反应介质中阳极氧化而提供为金属离子。
在本发明的优选实施方案中,就电化学制备而言,至少一种金属离子通过包含所述至少一种金属的至少一个阳极的阳极氧化而提供,而没有其它金属由金属盐提供。
对本发明而言,就电化学制备MOF使用的术语“金属”包括可通过涉及阳极氧化的电化学路线而提供在反应介质中且可与至少一种至少双齿的有机化合物形成至少一种多孔金属有机骨架的元素周期表的所有元素。
不考虑制备方法,MOF以粉末形式或以聚集体得到。其可直接单独或与其它吸附剂或其它材料一起在本发明方法中用作吸附剂。优选以松散材料,尤其是以固定床使用。此外,MOF可转化为成型体。此处的优选方法为挤出或压片。在成型体的生产中,可向MOF中加入其它材料如粘合剂、润滑剂或其它添加剂。同样可接受的是以成型体或分开形式的成型体生产MOF和其它吸附剂如活性炭的混合物,因此其以成型体混合物使用。
这些MOF成型体的可能的几何形状基本不受限制。实例尤其为粒料如环状粒料、丸、球、细粒、挤出物如棒、蜂窝、栅格或空心体。
为生产这些成型体,原则上所有合适的方法是可行的。特别优选如下程序:
-将骨架单独或与至少一种粘合剂和/或至少一种糊剂和/或至少一种模版化合物捏合得到混合物;借助至少一种合适的方法如挤出使所得混合物成型;任选洗涤和/或干燥和/或煅烧挤出物;任选整理处理。
-将骨架施加至至少一种多孔或无孔载体材料上。然后通过上述方法进一步加工所得材料以生产成型体。
-将骨架施加至至少一种多孔或无孔基材上。
-发泡成多孔聚合物如聚氨酯。
捏合和成型可通过任何合适的方法进行,该方法例如描述于Ullmann’sder Technischen Chemie 4,第4版,第2卷,第313页及随后各页(1972)中,其相关内容此处通过参考完全引入本专利申请中。
捏合和/或成型例如可优选借助活塞压机、滚压机在至少一种粘合剂材料存在或不存在下配混、造粒、压片、挤出、共挤出、发泡、纺丝、涂敷、成粒,优选喷雾成粒,喷雾,喷雾干燥或两者或更多种这些方法的组合而进行。
非常特别优选生产粒料、挤出物和/或片。
捏合和/或成型可在升高温度下,例如在室温至300℃和/或在超计大气压,例如在大气压力至数百巴下和/或在保护气氛中,例如在至少一种稀有气体、氮气或其两种或更多种的混合物存在下进行。
在另一实施方案中,捏合和/或成型在加入至少一种粘合剂下进行,该粘合剂原则上可为确保组合物被捏合或成型的粘度的任何化学化合物,该粘度对捏合和/或成型是所希望的。因此,对本发明而言,粘合剂可为增加粘度或降低粘度的化合物。
优选粘合剂例如为氧化铝或包含氧化铝的粘合剂,其例如描述于WO 94/29408中,例如描述于EP 0 592 050 A1中的二氧化硅,例如描述于WO 94/13584中的二氧化硅和氧化铝的混合物,例如描述于JP 03-037156A中的粘土矿物,例如蒙脱土、高岭土、膨润土、多水高岭土(hallosite)、地开石、珍珠陶土和富硅高岭石,例如描述于EP 0 102 544 B1中的烷氧基硅烷,如四烷氧基硅烷如四甲氧基硅烷、四乙氧基硅烷、四丙氧基硅烷、四丁氧基硅烷,或例如三烷氧基硅烷,例如三甲氧基硅烷、三乙氧基硅烷、三丙氧基硅烷、三丁氧基硅烷,烷氧基钛酸酯,例如四烷氧基钛酸酯如四甲氧基钛酸酯、四乙氧基钛酸酯、四丙氧基钛酸酯、三丁氧基钛酸酯,或例如三烷氧基钛酸酯如三甲氧基钛酸酯、三乙氧基钛酸酯、三丙氧基钛酸酯、三丁氧基钛酸酯,烷氧基锆酸酯,例如四氧基锆酸酯如四甲氧基锆酸酯、四乙氧基锆酸酯、四丙氧基锆酸酯、四丁氧基锆酸酯,或例如三烷氧基锆酸酯如三甲氧基锆酸酯、三乙氧基锆酸酯、三丙氧基锆酸酯、三丁氧基锆酸酯、硅溶胶,两性物质和/或石墨。特别优选石墨。
作为增加粘度的化合物,合适的话除了上述化合物之外,例如可使用有机化合物和/或亲水聚合物如纤维素或纤维素衍生物如甲基纤维素和/或聚丙烯酸酯和/或聚甲基丙烯酸酯和/或聚乙烯醇和/或聚乙烯基吡咯烷酮和/或聚异丁烯和/或聚四氢呋喃。
作为糊剂,可尤其优选使用水或至少一种醇如具有1-4个碳原子的一元醇,例如甲醇、乙醇、正丙醇、异丙醇、1-丁醇、2-丁醇、2-甲基-1-丙醇或2-甲基-2-丙醇或者水和至少一种所述醇的混合物,或多元醇如二醇,优选水溶混性多元醇,其单独或以与水和/或至少一种所述一元醇的混合物的形式使用。
可用于捏合和/或成型的其它添加剂尤其为胺或胺衍生物如四烷基铵化合物或氨基醇和包含碳酸根的化合物如碳酸钙。这类其它添加剂例如描述于EP 0 389 041 A1、EP 0 200 260 A1或WO 95/19222中。
添加剂如模版化合物、粘合剂、糊剂、增加粘度的物质在成型和捏合中的加入顺序原则上并不关键。
在另一优选实施方案中,使所得成型体在捏合和/或成型之后经受至少一个干燥步骤,该干燥步骤通常在25-300℃,优选50-300℃,特别优选100-300℃的温度下进行。同样可在减压或保护气体气氛下或通过喷雾干燥进行。
在特别优选的实施方案中,在所述干燥加工中从成型体中至少部分除去作为添加剂加入的至少一种化合物。
Claims (11)
1.一种具有1m3的最小体积和规定最大填充压力的用于吸取、储存和分配燃料气体的气体耐压容器,所述燃料气体在储存条件下呈气态且适合通过燃烧该燃料气体而驱动车辆,其中该气体耐压容器具有过滤器,燃料气体可至少在吸取或分配过程中流过该过滤器,其中过滤器适合从料流中除去燃料气体中可能的杂质且杂质能够降低用于储存燃料气体的吸附剂对燃料气体的储存能力。
2.根据权利要求1的气体耐压容器,其中所述燃料气体包含氢气或甲烷中的至少一种。
3.根据权利要求1或2的气体耐压容器,其中所述杂质为至少一种高级烃、氨、有气味物质或硫化氢或两种或更多种这些物质的混合物。
4.根据权利要求1-3中任一项的气体耐压容器,其中该容器不包含吸附剂。
5.根据权利要求4的气体耐压容器,其中最大填充压力为300巴(绝对)。
6.根据权利要求4或5的气体耐压容器,其中使所述燃料气体在分配过程中流过所述过滤器。
7.根据权利要求1-3中任一项的气体耐压容器,其中该容器包含吸附剂。
8.根据权利要求7的气体耐压容器,其中所述最大填充压力为150巴(绝对)。
9.根据权利要求7或8的气体耐压容器,其中使所述燃料气体在吸取过程中流过所述过滤器。
10.根据权利要求1-9中任一项的气体耐压容器,其中用于储存所述燃料气体的吸附剂为活性炭或多孔金属有机骨架。
11.根据权利要求1-10中任一项的气体耐压容器在填充存在于车辆中或车辆上且包含用于储存所述燃料气体的吸附剂的另一气体耐压容器中的用途。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006020852A DE102006020852A1 (de) | 2006-05-04 | 2006-05-04 | Gasdruckbehälter für gasbetriebene Kraftfahrzeuge |
DE102006020852.8 | 2006-05-04 | ||
PCT/EP2007/054092 WO2007128701A1 (de) | 2006-05-04 | 2007-04-26 | Gasdruckbehälter oder speicherungsmittel enhaltende gasdruckbehälter mit filter |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101495796A true CN101495796A (zh) | 2009-07-29 |
CN101495796B CN101495796B (zh) | 2012-11-21 |
Family
ID=38477252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200780019715XA Expired - Fee Related CN101495796B (zh) | 2006-05-04 | 2007-04-26 | 气体耐压容器或含有具有过滤器设备的气体耐压容器的储存装置 |
Country Status (10)
Country | Link |
---|---|
US (1) | US8057584B2 (zh) |
EP (1) | EP2016328A1 (zh) |
JP (1) | JP4971429B2 (zh) |
KR (1) | KR101501997B1 (zh) |
CN (1) | CN101495796B (zh) |
BR (1) | BRPI0711285A2 (zh) |
CA (1) | CA2651964C (zh) |
DE (1) | DE102006020852A1 (zh) |
MX (1) | MX2008013969A (zh) |
WO (1) | WO2007128701A1 (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014057416A1 (en) * | 2012-10-09 | 2014-04-17 | Basf Se | Method of charging a sorption store with a gas |
US9243754B2 (en) | 2012-10-09 | 2016-01-26 | Basf Se | Method of charging a sorption store with a gas |
CN111790209A (zh) * | 2020-07-23 | 2020-10-20 | 张宗洲 | 一种汽车空调滤网及其夹层制备方法 |
WO2024013492A1 (en) * | 2022-07-12 | 2024-01-18 | Swellfix Uk Limited | Hydrogen sulfide scavenging compositions |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2440123B (en) * | 2006-07-19 | 2010-12-22 | Pptek Ltd | Fuel cleaning for gas fired engines |
DE102006045920A1 (de) * | 2006-09-28 | 2008-04-03 | Robert Bosch Gmbh | Fluidspeicher |
CN101680600A (zh) * | 2007-04-05 | 2010-03-24 | 巴斯夫欧洲公司 | 包含含有有机金属骨架材料和pcm装置的混合物的气体压力容器 |
WO2008129051A2 (de) * | 2007-04-24 | 2008-10-30 | Basf Se | Metallorganische gerüstmaterialien mit hexagonal-trigonaler struktur basierend auf aluminium, eisen oder chrom, sowie einer dicarbonsäure |
WO2008142059A1 (de) * | 2007-05-21 | 2008-11-27 | Basf Se | Aluminium-aminocarboxylate als poröse metallorganische gerüstmaterialien |
US8372305B2 (en) * | 2007-05-24 | 2013-02-12 | Basf Se | Chemical-mechanical polishing composition comprising metal-organic framework materials |
WO2009007267A1 (en) * | 2007-07-10 | 2009-01-15 | Basf Se | Process for the separation of unbranched hydrocarbons from their branched isomers |
RU2487156C2 (ru) * | 2007-09-11 | 2013-07-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Композиции и полученные из них изделия |
CN101925392A (zh) * | 2008-01-24 | 2010-12-22 | 巴斯夫欧洲公司 | 作为干燥剂的多孔金属有机骨架材料 |
JP2011520592A (ja) * | 2008-04-22 | 2011-07-21 | ユニヴェルシテ ドゥ モンス | ガス吸着剤 |
WO2011123795A1 (en) | 2010-04-02 | 2011-10-06 | Battelle Memorial Institute | Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, and gas separation assemblies |
WO2012131483A1 (en) * | 2011-03-31 | 2012-10-04 | Council Of Scientific & Industrial Research | Activated carbon-metal organic framework composite materials with enhanced gas adsorption capacity and process for the preparation thereof |
US9925516B2 (en) * | 2014-12-02 | 2018-03-27 | Numat Technologies, Inc. | Formation of high surface area metal-organic frameworks |
US9190114B1 (en) | 2015-02-09 | 2015-11-17 | Western Digital Technologies, Inc. | Disk drive filter including fluorinated and non-fluorinated nanopourous organic framework materials |
JP6941762B2 (ja) * | 2016-04-27 | 2021-09-29 | パナソニックIpマネジメント株式会社 | 多孔性配位高分子、ならびにそれを用いた水素分子貯蔵方法、水素貯蔵装置、水素分子分離方法、および水素純化装置 |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1821549A (en) * | 1927-01-15 | 1931-09-01 | E K Medical Gas Lab Inc | Apparatus for dehydrating and purifying gases |
DE1011169B (de) * | 1953-08-26 | 1957-06-27 | Walther Koeniger Dr Ing | Vorrichtung zur Anzeige bestimmter Temperaturkombinationen zweier Medien |
US4343770A (en) * | 1977-12-19 | 1982-08-10 | Billings Energy Corporation | Self-regenerating system of removing oxygen and water impurities from hydrogen gas |
JPS5838238Y2 (ja) * | 1980-12-25 | 1983-08-29 | 日本コイン株式会社 | 溶解アセチレン容器の逆火防止器 |
US4600525A (en) * | 1982-07-21 | 1986-07-15 | Baker Nathaniel R | Hydrogen sorbent flow aid composition and containment thereof |
DE3231498A1 (de) | 1982-08-25 | 1984-03-01 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von harten, bruchfesten katalysatoren aus zeolith-pulver |
US4522159A (en) | 1983-04-13 | 1985-06-11 | Michigan Consolidated Gas Co. | Gaseous hydrocarbon fuel storage system and power plant for vehicles and associated refueling apparatus |
IT1187661B (it) | 1985-04-23 | 1987-12-23 | Enichem Sintesi | Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica |
GB8906726D0 (en) | 1989-03-23 | 1989-05-10 | Shell Int Research | Titania extrudates |
JPH0337156A (ja) | 1989-07-03 | 1991-02-18 | Sumitomo Metal Mining Co Ltd | ゼオライト成型焼成体及びその製造方法 |
CA2107876A1 (en) | 1992-10-08 | 1994-04-09 | Aan Hendrik Klazinga | Process for extruding crystalline aluminosilicates |
ATE207036T1 (de) | 1992-12-16 | 2001-11-15 | Chevron Usa Inc | Herstellung von aluminosilikatzeolithen |
US5378671A (en) | 1993-06-03 | 1995-01-03 | Mobil Oil Corp. | Method for preparing catalysts comprising zeolites |
DE69512204T2 (de) | 1994-01-12 | 2000-05-11 | Du Pont | Sol-gel poröses mikroverbundderivat von perfluoriertem ionenaustauschpolymer und metalloxyd |
US5601437A (en) | 1994-10-17 | 1997-02-11 | Methode Electronics, Inc. | Clockspring with centering display device |
US5648508A (en) | 1995-11-22 | 1997-07-15 | Nalco Chemical Company | Crystalline metal-organic microporous materials |
JPH09227571A (ja) * | 1996-02-28 | 1997-09-02 | Osaka Gas Co Ltd | ガス貯蔵性金属錯体とその製造方法及びガス貯蔵装置並びにガス貯蔵装置を装備した自動車 |
EP1025444B1 (en) | 1997-10-21 | 2005-03-02 | Cancer Research Technology Limited | Determination of cellular growth abnormality |
US5980599A (en) * | 1998-03-27 | 1999-11-09 | Uop Llc | In-tank purifier with bypass for filling |
CN1089903C (zh) | 1998-08-28 | 2002-08-28 | 中国科学院空间科学与应用研究中心 | 获取海洋雷达高度计中频仿真信号的方法和设备 |
US6293110B1 (en) * | 1999-12-17 | 2001-09-25 | Energy Conversion Devices, Inc. | Hydrogen cooled hydride storage unit |
JP2001322801A (ja) * | 2000-03-08 | 2001-11-20 | Denso Corp | 水素貯蔵装置 |
JP2002054798A (ja) * | 2000-08-11 | 2002-02-20 | Honda Motor Co Ltd | 水素吸蔵合金式水素貯蔵タンクに水素ガスを充填する装置及び方法 |
JP4705251B2 (ja) * | 2001-01-26 | 2011-06-22 | 本田技研工業株式会社 | Mhタンク |
JP2002221298A (ja) * | 2001-01-26 | 2002-08-09 | Honda Motor Co Ltd | 水素貯蔵装置 |
GB0103762D0 (en) * | 2001-02-15 | 2001-04-04 | Air Prod & Chem | A gas purification unit |
DE10111230A1 (de) | 2001-03-08 | 2002-09-19 | Basf Ag | Metallorganische Gerüstmaterialien und Verfahren zu deren Herstellung |
JP4646422B2 (ja) | 2001-03-08 | 2011-03-09 | 大阪瓦斯株式会社 | 天然ガス、メタン自動車用燃料の吸着式貯蔵方法 |
US6932945B2 (en) * | 2001-06-19 | 2005-08-23 | Air Products And Chemicals, Inc. | Adsorbent based gas delivery system with integrated purifier |
US6929679B2 (en) * | 2002-02-01 | 2005-08-16 | Basf Aktiengesellschaft | Method of storing, uptaking, releasing of gases by novel framework materials |
JP2003278997A (ja) | 2002-03-26 | 2003-10-02 | Nippon Steel Corp | ガス貯蔵装置 |
JP2003342260A (ja) * | 2002-05-23 | 2003-12-03 | Osaka Gas Co Ltd | 三次元型金属錯体、吸着材および分離材 |
EP1513612A2 (en) * | 2002-06-19 | 2005-03-16 | University Of Iowa Research Foundation | Gas storage materials and devices |
US7309380B2 (en) * | 2003-06-30 | 2007-12-18 | Basf Aktiengesellschaft | Gas storage system |
US6907740B2 (en) * | 2003-07-23 | 2005-06-21 | Advanced Technology Materials, Inc. | Gas charging system for fill of gas storage and dispensing vessels |
DE10355087A1 (de) | 2003-11-24 | 2005-06-09 | Basf Ag | Verfahren zur elektrochemischen Herstellung eines kristallinen porösen metallorganischen Gerüstmaterials |
US7124790B2 (en) | 2004-06-28 | 2006-10-24 | General Electric Company | System and method for storing and discharging hydrogen |
US7160359B2 (en) * | 2004-07-02 | 2007-01-09 | Air Products And Chemicals, Inc. | Built in purifier for reactive gases |
JP2006083898A (ja) * | 2004-09-14 | 2006-03-30 | Honda Motor Co Ltd | 水素貯蔵タンク |
JP5010807B2 (ja) * | 2005-02-08 | 2012-08-29 | 本田技研工業株式会社 | 水素吸着材の活性化方法 |
EP1874459B1 (en) * | 2005-04-07 | 2015-10-14 | The Regents of The University of Michigan | High gas adsorption in a microporous metal-organic framework with open-metal sites |
US7517396B2 (en) * | 2006-02-06 | 2009-04-14 | Gm Global Technology Operations, Inc. | Apparatus for optimal adsorption and desorption of gases utilizing highly porous gas storage materials |
-
2006
- 2006-05-04 DE DE102006020852A patent/DE102006020852A1/de not_active Withdrawn
-
2007
- 2007-04-26 CA CA2651964A patent/CA2651964C/en not_active Expired - Fee Related
- 2007-04-26 US US12/299,330 patent/US8057584B2/en not_active Expired - Fee Related
- 2007-04-26 BR BRPI0711285-8A patent/BRPI0711285A2/pt not_active IP Right Cessation
- 2007-04-26 CN CN200780019715XA patent/CN101495796B/zh not_active Expired - Fee Related
- 2007-04-26 MX MX2008013969A patent/MX2008013969A/es active IP Right Grant
- 2007-04-26 EP EP07728547A patent/EP2016328A1/de not_active Withdrawn
- 2007-04-26 WO PCT/EP2007/054092 patent/WO2007128701A1/de active Application Filing
- 2007-04-26 JP JP2009508316A patent/JP4971429B2/ja not_active Expired - Fee Related
- 2007-04-26 KR KR1020087029491A patent/KR101501997B1/ko not_active IP Right Cessation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014057416A1 (en) * | 2012-10-09 | 2014-04-17 | Basf Se | Method of charging a sorption store with a gas |
US9243754B2 (en) | 2012-10-09 | 2016-01-26 | Basf Se | Method of charging a sorption store with a gas |
CN111790209A (zh) * | 2020-07-23 | 2020-10-20 | 张宗洲 | 一种汽车空调滤网及其夹层制备方法 |
WO2024013492A1 (en) * | 2022-07-12 | 2024-01-18 | Swellfix Uk Limited | Hydrogen sulfide scavenging compositions |
Also Published As
Publication number | Publication date |
---|---|
CN101495796B (zh) | 2012-11-21 |
JP4971429B2 (ja) | 2012-07-11 |
EP2016328A1 (de) | 2009-01-21 |
KR20090048390A (ko) | 2009-05-13 |
US20090133576A1 (en) | 2009-05-28 |
BRPI0711285A2 (pt) | 2012-04-10 |
DE102006020852A1 (de) | 2007-11-15 |
MX2008013969A (es) | 2009-02-10 |
KR101501997B1 (ko) | 2015-03-12 |
CA2651964C (en) | 2014-12-09 |
US8057584B2 (en) | 2011-11-15 |
JP2009535586A (ja) | 2009-10-01 |
CA2651964A1 (en) | 2007-11-15 |
WO2007128701A1 (de) | 2007-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101495796B (zh) | 气体耐压容器或含有具有过滤器设备的气体耐压容器的储存装置 | |
CN102361678A (zh) | 使用用胺浸渍的金属有机骨架分离酸性气体的方法 | |
US7534303B2 (en) | Liquid absorption by metal-organic frameworks | |
US20150090344A1 (en) | Gas filtering in adsorbed gas systems | |
CN101925392A (zh) | 作为干燥剂的多孔金属有机骨架材料 | |
US20080190289A1 (en) | Gas Odorous Substance Separation | |
US10422480B2 (en) | Storage vessel comprising a one-piece shaped body of a porous solid | |
CN101379068A (zh) | 制备多孔有机骨架材料的方法 | |
EP2230288B1 (de) | Metallorganische gerüstmaterialien in kälte/wärmemaschinen | |
EP3093550A1 (en) | Storage vessel comprising at least one shaped body of a porous solid | |
CN101437601A (zh) | 含金属-有机骨架材料的封闭可逆呼吸装置 | |
EP2985075A1 (en) | Shaped body made of a porous material | |
WO2016075100A1 (en) | Storage vessel comprising layers of a shaped body of a porous solid separated by a seal | |
WO2016075129A1 (en) | Storage vessel comprising at least one shaped body of a porous solid with spacers | |
KR20160060727A (ko) | 금속-유기 골격 물질을 형성하는 성분의 회수 방법 | |
WO2015048492A1 (en) | Pressure release device for adsorbed gas systems | |
WO2015048489A1 (en) | Process for improving efficiencies of gas systems using a compressor |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: BOSCH GMBH ROBERT |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20110804 Address after: Ludwigshafen, Germany Applicant after: BASF SE Address before: Ludwigshafen, Germany Applicant before: BASF SE Co-applicant before: Bosch GmbH Robert |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121121 Termination date: 20170426 |