CN101495226B - 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法 - Google Patents

用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法 Download PDF

Info

Publication number
CN101495226B
CN101495226B CN2007800282877A CN200780028287A CN101495226B CN 101495226 B CN101495226 B CN 101495226B CN 2007800282877 A CN2007800282877 A CN 2007800282877A CN 200780028287 A CN200780028287 A CN 200780028287A CN 101495226 B CN101495226 B CN 101495226B
Authority
CN
China
Prior art keywords
catalyst
weight
hydrogen
oxide
low temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007800282877A
Other languages
English (en)
Chinese (zh)
Other versions
CN101495226A (zh
Inventor
S·哈特彻
M·黑塞
M·赫尔茨勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN101495226A publication Critical patent/CN101495226A/zh
Application granted granted Critical
Publication of CN101495226B publication Critical patent/CN101495226B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668—Removal of carbon monoxide or carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
CN2007800282877A 2006-07-26 2007-07-19 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法 Expired - Fee Related CN101495226B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06117843.0 2006-07-26
EP06117843 2006-07-26
PCT/EP2007/057450 WO2008012255A2 (de) 2006-07-26 2007-07-19 Katalysator für die tieftemperaturkonvertierung und verfahren zur tieftemperaturkonvertierung von kohlenmonoxid und wasser zu kohlendioxid und wasserstoff

Publications (2)

Publication Number Publication Date
CN101495226A CN101495226A (zh) 2009-07-29
CN101495226B true CN101495226B (zh) 2012-06-20

Family

ID=38634636

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800282877A Expired - Fee Related CN101495226B (zh) 2006-07-26 2007-07-19 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法

Country Status (7)

Country Link
US (1) US9343767B2 (enExample)
EP (1) EP2049249B1 (enExample)
JP (1) JP5281572B2 (enExample)
CN (1) CN101495226B (enExample)
CA (1) CA2658453C (enExample)
DK (1) DK2049249T3 (enExample)
WO (1) WO2008012255A2 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5477561B2 (ja) * 2009-09-09 2014-04-23 戸田工業株式会社 炭化水素を分解する多孔質触媒体及びその製造方法、炭化水素から水素を含む混合改質ガスを製造する方法、並びに燃料電池システム
JP5886833B2 (ja) * 2010-04-21 2016-03-16 エスケー イノベーション カンパニー リミテッド ナノメートルサイズの銅系触媒、その製造方法、及びそれを用いたカルボン酸の直接水素化によるアルコール製造方法
GB201015605D0 (en) 2010-09-17 2010-10-27 Magnesium Elektron Ltd Inorganic oxides for co2 capture from exhaust systems
JP5871312B2 (ja) * 2011-01-17 2016-03-01 国立研究開発法人産業技術総合研究所 微粒子凝集体の製造方法、水蒸気改質触媒、水蒸気改質触媒の製造方法及び、水素製造方法
CN103466546B (zh) * 2013-09-06 2015-04-15 清华大学 一种将双功能吸附剂应用于吸附增强式水蒸气重整和水气变换反应的中温变压吸附方法
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
US10807866B2 (en) 2015-10-29 2020-10-20 Johnson Matthey Public Limited Company Water-gas shift catalyst
CN105833876B (zh) * 2016-04-15 2019-03-26 西安向阳航天材料股份有限公司 一种高活性铜锌铝低温变换催化剂及其制备方法
EP3254760A1 (en) * 2016-06-07 2017-12-13 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process to synthesize a catalyst performing water-gas shift reaction at a high temperature
CN109621967B (zh) * 2018-12-26 2022-03-11 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
CN114824320A (zh) * 2022-03-07 2022-07-29 国网综合能源服务集团有限公司 一种具有铜包覆氧化锌界面的铜基催化剂的制备方法及其低温催化水煤气变换反应的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5272017A (en) * 1992-04-03 1993-12-21 General Motors Corporation Membrane-electrode assemblies for electrochemical cells
DE69933184T2 (de) * 1998-11-16 2007-08-30 Fushun Research Institute of Petroleum and Petrochemicals, Sinopec, Fushun Kupferhaltiger Katalysator, dessen Verfahren zur Herstellung und seine Verwendung
US20020061277A1 (en) * 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
US6693057B1 (en) * 2002-03-22 2004-02-17 Sud-Chemie Inc. Water gas shift catalyst
CA2675742A1 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Noble metal-free nickel catalyst formulations for hydrogen generation
US7081144B2 (en) * 2003-04-04 2006-07-25 Texaco Inc. Autothermal reforming in a fuel processor utilizing non-pyrophoric shift catalyst

Also Published As

Publication number Publication date
US9343767B2 (en) 2016-05-17
EP2049249B1 (de) 2012-05-23
WO2008012255A2 (de) 2008-01-31
DK2049249T3 (da) 2012-09-10
CN101495226A (zh) 2009-07-29
US20100012895A1 (en) 2010-01-21
WO2008012255A3 (de) 2008-04-17
JP2009544464A (ja) 2009-12-17
JP5281572B2 (ja) 2013-09-04
EP2049249A2 (de) 2009-04-22
CA2658453A1 (en) 2008-01-31
CA2658453C (en) 2014-03-04

Similar Documents

Publication Publication Date Title
CN101495226B (zh) 用于低温转化的催化剂和将一氧化碳和水低温转化为二氧化碳和氢的方法
Li et al. Low-temperature water-gas shift reaction over Cu-and Ni-loaded cerium oxide catalysts
Luengnaruemitchai et al. Selective catalytic oxidation of CO in the presence of H2 over gold catalyst
TWI433723B (zh) Catalyst precursors and catalysts using them
Takeishi et al. Steam reforming of dimethyl ether
JP2004525047A (ja) 非発火性の水−気体転化反応用触媒
US20060216227A1 (en) Catalysts for hydrogen production
US20100015023A1 (en) Catalyst for carbon monoxide conversion and method of carbon monoxide modification with the same
JP3759406B2 (ja) メタノール改質触媒、メタノール改質装置及びメタノール改質方法
Silva et al. Low-temperature methanol steam reforming kinetics over a novel CuZrDyAl catalyst
Moon Hydrogen production by catalytic reforming of gaseous hydrocarbons (methane & LPG)
US6677068B2 (en) Catalyst for selective oxidation of carbon monoxide present in hydrogen-containing gases, and elimination of carbon monoxide and solid polymer electrolyte fuel cell system which make use of the catalyst
US7384986B2 (en) Process for the selective methanation of carbonmonoxide (CO) contained in a hydrogen-rich reformate gas
Kolb et al. Water-gas shift reaction in micro-channels—Results from catalyst screening and optimisation
KR102023267B1 (ko) 알칼리금속 또는 알칼리토금속이 조촉매로 첨가된 수성 가스 전이 반응용 코발트계 촉매의 제조방법
Güldür et al. Selective carbon monoxide oxidation over Ag-based composite oxides
JP2012061398A (ja) 水素製造用触媒、その触媒の製造方法およびその触媒を用いた水素の製造方法
CN106492810A (zh) 用于二甲醚水蒸气重整制氢的锌改性铜基催化剂及制备方法
WO2002016260A1 (en) Hydrogen purification apparatus
Lortie Reverse water gas shift reaction over supported Cu-Ni nanoparticle catalysts
JP2012061399A (ja) 水素製造用触媒、その触媒の製造方法およびその触媒を用いた水素の製造方法
Liu et al. Characterization and performance of a ZnO–ZnCr2O4/CeO2–ZrO2 monolithic catalyst for methanol auto-thermal reforming process
JP2008272614A (ja) Ｃｏ除去触媒、燃料改質装置、燃料電池システム及びｃｏ除去方法
JP2005034682A (ja) Ｃｏ変成触媒およびその製造方法
Kapran et al. Decomposition and partial oxidation of methanol over metal oxide Cu–Zn–Ce-based monoliths

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120620

Termination date: 20170719