CN101485620A - Process for lightening human keratin fibres using an anhydrous composition and a particular organic amine, and device suitable therefor - Google Patents
Process for lightening human keratin fibres using an anhydrous composition and a particular organic amine, and device suitable therefor Download PDFInfo
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- CN101485620A CN101485620A CN 200810220799 CN200810220799A CN101485620A CN 101485620 A CN101485620 A CN 101485620A CN 200810220799 CN200810220799 CN 200810220799 CN 200810220799 A CN200810220799 A CN 200810220799A CN 101485620 A CN101485620 A CN 101485620A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
Abstract
The invention relates to a method for lightening human keratin fibers using at least one anhydrous composition (A) comprising at least one fatty substance and at least one surfactant, at least one composition (B) comprising at least one organic amine having a pKb less than 12, and at least one composition (C) comprising at least one or more oxidizing agents. Finally the invention relates to a multi-compartment device, wherein at least one compartment comprises at least one anhydrous composition (A), at least another compartment comprises the at least one composition (B), and at least a final compartment comprises the at least one composition (C).
Description
Technical field
The present invention relates to be used for the method for blast (lightening) human keratin fiber, this method uses the anhydrous composition (A) that comprises one or more fatty materials and one or more surfactants, comprise one or more in the time of 25 ℃ its pKb less than the compositions (B) of 12 organic amine with comprise the compositions (C) of one or more oxidants.
At last, the present invention relates to the device of many compartments, its at least one compartment comprises above-mentioned anhydrous cosmetic composition (A), and another compartment comprises compositions (B) and last compartment comprises oxidising composition (C).
Background technology
The method of lightening human keratin fibres is in most of the cases to use the Aquo-composition that comprises at least a oxidant under the alkaline pH condition.This oxidant has the melanic effect of degraded hair, and according to the difference of oxidant character, this causes effect more obvious or more not obvious ground blast fiber.Therefore, for weak relatively blast effect, oxidant is generally hydrogen peroxide.When the bigger blast effect of expectation, in the presence of hydrogen peroxide, use peroxide salt usually, for example persulfate.
An in esse difficult problem is that this kind method for lightening is to implement under alkali condition, and the most frequently used alkaline reagent is an ammonia.Particularly advantageously ammonia in these class methods.Its reason is because it can make the pH of compositions be adjusted to alkaline pH can make the oxidant degraded.Yet this reagent also can cause the expansion of keratin fiber, and its scale (scale) is opened, and this accelerating oxidation agent penetrates in the fiber, and has therefore improved reaction efficiency.
Yet this alkalizing agent is very volatile, and user can feel unpleasant because of this intensive feature (the very offensive odour of the ammonia that gives out during this method).
In addition, evaporable ammonia amount requires to use than the higher amount of institute expense to compensate this loss.This is not to not influence of user, and they are not only because this abnormal smells from the patient and still feel inconvenience, and may face the higher risk that has no patience, for example to the stimulation (twinge) of scalp.
As for the selection that replaces purely and simply all or part of ammonia with the alkalizing agent of one or more other standards, this can not obtain and the same effective composition of those compositionss based on ammonia, particularly because these alkalizing agents can not be to the blast fully of coloured fiber in the presence of oxidant.
Summary of the invention
An object of the present invention is to propose the method for lightening human keratin fibres, this method does not have the shortcoming (owing to having a large amount of ammonia) of those methods of using with existing compositions, and simultaneously aspect the homogeneity of blast and described blast, this method be retained to look younger with effect.
These targets and other target reach by the present invention, so a method that theme is a lightening human keratin fibres of the present invention, below wherein using:
(a) anhydrous composition (A), it comprises one or more fatty materials and one or more surfactants;
(b) compositions (B), it comprises one or more its pKb less than 12 organic amine;
(c) compositions (C), it comprises one or more oxidants.
The invention still further relates to the device of many compartments, in an one compartment, comprise anhydrous composition (A), in another compartment, comprise compositions (B) and in another compartment, comprise the compositions (C) that contains one or more oxidants.
Other features and advantages of the present invention will more clearly manifest by reading following description and embodiment.
Hereinafter, unless point out in addition, the limit value of numerical range is included in this scope.
The human keratin fiber of handling with the method according to this invention is hair preferably.
More particularly, with respect to the weight of described compositions, the water content of this anhydrous cosmetic composition (A) is less than 5 weight %, preferably is less than 2 weight %, more particularly is less than 1 weight %.It should be noted that water also can be the bound water form, for example the water of crystallization of salt, the perhaps minor amount of water of in preparing, using that raw material absorbed according to compositions of the present invention.
In addition, compositions of the present invention does not contain the direct dyes or the oxidation dye precursors (alkali and coupling agent) of any people's cutin protein fiber that is generally used for dyeing, perhaps, if contain, its total content is no more than 0.005 weight % of the anhydrous composition and the weight of the Aquo-composition that comprises oxidant.Especially, under this content, have only compositions to be colored, that is, on keratin fiber, can not observe Color.
Preferably, this cosmetics anhydrous composition does not contain any alkali oxide, as p-phenylenediamine (PPD), two (phenyl) alkylene diamine, para-aminophenol, O-aminophenol or heterocyclic bases and acid-addition salts thereof.It does not also preferably contain any coupling agent, for example m-diaminobenzene., m-aminophenol, a diphenol, naphthyl coupling agent or heterocycle coupling agent, and their addition salts.
At last, this cosmetics anhydrous composition does not preferably contain any nonionic or ion (cation or anion) direct dyes (separately or with mixture), for example azo, methine, carbonyl, azine, nitro, (mixing) aryl; The fragrant methane of three (mixing); Porphyrin; Phthalocyanine direct dyes or natural direct dyes.
As previously mentioned, anhydrous cosmetic composition according to the present invention contains one or more fatty materials.
Term " fatty material " is illustrated in water-fast organic compound (dissolubility preferably less than 1%, and is more preferably less than 0.1% less than 5%) under room temperature (25 ℃) atmospheric pressure (760mmHg).In addition, fatty material is dissolved in organic solvent under identical temperature and pressure condition, for example chloroform, ethanol or benzene.
According to the present invention, it is the chemical compound of liquid state or pasty state that fatty material is selected under room temperature and atmospheric pressure.
More particularly, fatty material is selected from alkane, aliphatic alcohol, fatty acid, fatty acid ester, aliphatic alcohol ester, mineral oil, vegetable oil, animal oil, artificial oil, siloxanes and wax.
What need prompting is, for purpose of the present invention, aliphatic alcohol, fatty ester and fatty acid more particularly contain at least a straight or branched, saturated or the undersaturated hydrocarbyl group that contains 6 to 30 carbon atoms, this group randomly is substituted, and is replaced by one or more oh groups (1 to 4 especially) especially.If they are undersaturated, these chemical compounds can contain one to three conjugation or unconjugated carbon-to-carbon double bond.
About alkane, those alkane that contain 6 to 30 carbon atoms are linear.The example that can mention comprises hexane and dodecane.
As operable oil in the present composition, the example that can mention comprises:
The alkyl oil of-animal origin, for example perhydro-squalene;
The alkyl oil of-plant origin, liquid fat acid glycerol three acid esters that for example contain 6 to 30 carbon atoms, for example enanthic acid or sad triglyceride, perhaps, for example Oleum Helianthi, Semen Maydis oil, soybean oil, bone marrow oil (marrow oil), Oleum Vitis viniferae, Oleum sesami, hazelnut oil, almond oil, macadimia nut oil, arara oil, Oleum Ricini, American Avocado Tree oil, suffering/capric acid triglyceride, for example, those that sell by St é arineries Dubois company or by Dynamit Nobel company with title
810, those of 812 and 818 sale, Jojoba oil and shea oil (shea butter oil);
The straight or branched hydrocarbon in-mineral or synthetic source, for example volatility or non-volatile liquid alkane and derivant thereof, vaseline, liquid petrolatum, poly decene, Parleam are (for example
Isoparaffin, for example 2-Methylpentadecane and isodecane.
-contain the straight or branched of 8 to 30 carbon atoms, saturated or unsaturated fatty alcohol, for example hexadecanol, octadecanol and their mixture (16/stearyl alcohol), octyldodecanol, 2-butyl capryl alcohol, 2-hexyldecanol, 2-undecyl pentadecanol, oleyl alcohol or inferior oleyl alcohol (linoleyl alcohol).
-partly alkyl and/or siloxy group contain fluorocarbon oil (fluoro oils), for example those that in document JP-A-2-295912, describe; The fluorocarbon oil that contains that can mention also comprises FLUTEC PC 1 trifluoromethyl-cyclopentane. and perfluor-1, the 3-dimethyl cyclohexane, its by BNFL Fluorochemicals company with title
PCI and
PC3 sells; Perfluor-1,2-dimethyl Tetramethylene.; Perfluoro alkane, for example R-4112 and Tetradecafluorohexane, its by 3M company with title PF
And PF
Sell, or bromo PFO (bromoperfluorooctyl), its by Atochem company with title
Sell; Nonafluoromethoxybutcompositions and nine fluorine ethyoxyl iso-butanes; The perfluor morpholine derivative, 4-trifluoromethyl perfluor morpholine for example, its by 3M company with title PF
Sell.
Above-mentioned one or more waxes are selected from Brazil wax, candelilla wax, esparto wax, paraffin, ceresine (ozokerites), vegetable wax, for example Fructus Canarii albi wax, Testa oryzae are cured, the pure wax (absolutewax of flowers) of hydrogenation Jojoba wax or flower, the Ribes nigrum L. HUAJING wax of selling by Bertin (France) company (essential wax ofblackcurrant blossom) for example, animal wax, for example Cera Flava or modification Cera Flava (cerabellina); Operable other wax or waxiness parent material are especially given birth to wax (marine wax) in the sea according to the present invention, for example by Sophim company with trade mark M82 product sold, and Tissuemat E or common polyolefin-wax.
This fatty acid can be saturated or unsaturated fatty acid, and contains 6 to 30 carbon atoms, and particularly contains 9 to 30 carbon atoms.They more particularly are selected from myristic acid, Palmic acid, stearic acid, mountain Yu acid, oleic acid, linoleic acid, linolenic acid and isostearic acid.
Above-mentioned ester is C saturated or unsaturated, straight or branched
1-C
26Aliphatic list or polyprotic acid and C saturated or unsaturated, straight or branched
1-C
26The ester of aliphatic list or polyhydric alcohol, the total number of carbon atoms of described ester is more than or equal to 10.
In monoesters, can mention mountain Yu acid dihydride rosin ester, the misery basic dodecane ester of mountain Yu (octyldodecylbehenate), mountain Yu acid 2-Methylpentadecane ester, cetyl lactate, C
12-C
15Alkyl lactate ester; lactic acid isooctadecane ester; the dodecyl lactate ester; the inferior oleyl alcohol ester of lactic acid; lactic acid oleyl alcohol ester; sad (different) octadecane ester; sad 2-Methylpentadecane ester; octyl octanoate; sad hexadecane ester; decyl oleate; isostearic acid 2-Methylpentadecane ester; lauric acid 2-Methylpentadecane ester; stearic iso-16 alkyl esters; sad isodecyl ester; Ceraphyl 140A; isononyl isononanoate; Palmic acid isooctadecane ester; the methyl acetyl ricinoleate ester; stearic acid tetradecane ester; different octyl pelargonate; different n-nonanoic acid 2-Octyl Nitrite; octyl palmitate; octyl pelargonate; octyl stearate; erucic acid octyl group dodecane ester (octyldodecyl erucate); the erucic acid oil alcohol ester; ethyl palmitate and isopropyl ester; Palmic acid 2-Octyl Nitrite; Palmic acid 2-octyl group ester in the last of the ten Heavenly stems; myristic acid Arrcostab, for example isopropyl myristate; the myristic acid butyl ester; myristic acid hexadecane ester; myristic acid 2-octyl group dodecane ester; myristic acid tetradecane ester or myristic acid octadecane ester; hexyl stearate; butyl stearate; isobutyl stearate; the malic acid dioctyl ester; the own ester of lactic acid; lauric acid 2-hexyl ester in the last of the ten Heavenly stems.
Still in this modification background, can use C
4-C
22Dicarboxylic acids or tricarboxylic and C
1-C
22The ester of alcohol and single, two or tricarboxylic acids and C
2-C
26Two, three, four or the ester of penta hydroxy group alcohol.
Especially can mention following: ethyl sebacate; Dermol DIPS; diisopropyl adipate; adipic acid-di-n-propyl ester; dioctyl adipate; adipic acid two isooctadecane esters; di-2-ethylhexyl maleate; the endecatylene acid glyceride; the hard ester acyl group of octyl group dodecyl stearate; single ricinoleic acid pentaerythritol ester; four different n-nonanoic acid pentaerythritol esters; four n-nonanoic acid pentaerythritol esters; four isostearic acid pentaerythritol esters; Pentaerythrityl tetraoctanoate; two sad propylene glycol esters; the didecyl acid propylene glycol ester; erucic acid tridecyl ester; citric acid three isopropyl esters; citric acid three isooctadecane esters; three glyceride lactates; tricaprylin; citric acid trioctylphosphine dodecane ester; citric acid three oil base esters; two sad propylene glycol esters; neopentyl ethylene glycol bisthioglycolate heptanoate (neopentylglycol diheptanoate); two different n-nonanoic acid diethylene glycol esters and poly-distearyl acid diethylene glycol ester.
In the above-mentioned ester of mentioning, preferred ethyl palmitate, isopropyl palmitate, Palmic acid tetradecane ester, cetyl palmitate or Palmic acid octadecane ester, Palmic acid 2-Octyl Nitrite, Palmic acid 2-octyl group ester in the last of the ten Heavenly stems, myristic acid Arrcostab, for example isopropyl myristate, butyl myristate, myristic acid hexadecane ester or myristic acid 2-octyl group dodecane ester, hexyl stearate, butyl stearate, isobutyl stearate, malic acid dioctyl ester, lauric acid hexyl ester, lauric acid 2-hexyl dodecane ester, isononyl isononanoate or the sad hexadecane ester of using.
Said composition also can contain just like C
6-C
30, C preferably
12-C
22The sugar ester of fatty acid and diester are as fatty ester.What need to remind is, the alkyl compound of term " sugar " expression band oxygen, and it contains a plurality of alcohol functional group, have or do not have aldehydes or ketones functional group, and it contains four carbon atom at least.Described sugar can be monosaccharide, oligosaccharide or polysaccharide.
The example of the suitable sugar that can mention comprises sucrose (sucrose) (perhaps sucrose (saccharose)), glucose, galactose, ribose, fructose, maltose, mannose, arabinose, xylose and lactose and their derivant, especially alkyl derivative, for example methyl-derivatives, for example methyl glucoside.
The sugar ester of described fatty acid can be selected from especially comprise foregoing sugar with straight or branched, saturated or undersaturated C
6-C
30, C preferably
12-C
22The ester of fatty acid or the mixture of these esters.If they are undersaturated, these chemical compounds can contain one to three conjugation or unconjugated carbon-to-carbon double bond.
Can select list, two, three, four esters and polyester and their mixture according to the ester of this modification.
These esters can be selected from, for example oleate, laurate, cetylate, myristinate, behenate, cocos nucifera oil acid esters, stearate, linoleate, linolenate, decanoin and arachidonate, perhaps their mixture, for example, the mixed ester of oleic acid-cetylate, oleic acid-stearate and Palmic acid-stearate especially.
More particularly, preferably use monoesters and diester, especially the list of sucrose, glucose or methyl glucoside or dioleate, stearate, behenate, oleic acid cetylate, linoleate, linolenate and oleic acid stearate.
The example that can mention is called for the name of being sold by Amerchol company
The product of DO, it is a kind of methyl glucoside dioleate.
As the example of the mixture of sugar and the ester of fatty acid or ester, can also mention:
-be called F160 by the name of Crodesta company sale, F140, F110, F90, the product of F70 and SL40, they represent sucrose palmitate-stearate of being formed by the diester of 73% monoesters and 27% and three esters respectively, 61% monoesters and 39% diester, sucrose palmitate-stearate that three esters and four esters form, 52% monoesters and 48% diester, sucrose palmitate-stearate that three esters and four esters form, 45% monoesters and 55% diester, sucrose palmitate-stearate that three esters and four esters form, 39% monoesters and 61% diester, sucrose palmitate-stearate and sucrose monolaurate that three esters and four esters form;
-be called Ryoto Sugar Esters product sold with name, for example be called as B370 and corresponding to the sucrose behenate of forming by two-three esters-polyester of 20% monoesters and 80%;
The name that-Goldschmidt company sells is called
Sucrose list-two Palmic acids-stearate of PSE.
Operable siloxanes is the siloxanes of volatility or non-volatile, ring-type, straight or branched in cosmetic composition of the present invention, and it is not adorned or modifies with organic group that its viscosity of 25 ℃ is 5 * 10
-6-2.5m
2/ s, and preferably 1 * 10
-5-1m
2/ s.
Spendable siloxanes can be the form of oil, wax, resin or natural gum according to the present invention.
Preferably, siloxanes is selected from polydialkysiloxane, especially polydimethylsiloxane (PDMS) and contain the polysiloxanes of the organic decoration of at least a functional group that is selected from poly-(oxygen alkene) group, amino group and alkoxy base.
In " Chemistry and Technology of Silicones " (1968) Academic Press of Walter Noll work, defined organopolysiloxane in more detail.They can be volatile or nonvolatile.
When siloxanes was volatility, they more particularly are selected from boiling point was those of 60 ℃ to 260 ℃, more preferably is selected from:
(i) have 3 to 7 and the ring-type polydialkysiloxane of 4 to 5 silicon atoms preferably.For example, they are octamethylcy-clotetrasiloxane, its especially by Union Carbide company with title Volatile
7207 sell, or by Rhodia company with
70045 V 2 sell, decamethylcyclopentaandoxane, its by UnionCarbide company with title Volatile
7158 sell or by Rhodia company with
70045 V 5 sell, and their mixture.
Also can mention the cyclocopolymer of dimethyl siloxane/methyl alkyl siloxane type with following general formula, for example by Union Carbide company with
FZ 3109 sells:
Simultaneously
The ring-type polydialkysiloxane that also can mention and the mixture of organo-silicon compound, the for example mixture of octamethylcy-clotetrasiloxane and four-trimethyl silyl tetramethylolmethane (50/50) and octamethylcy-clotetrasiloxane and oxygen-1,1 '-two (2,2,2 ', 2 ', 3,3 '-six trimethylsiloxy) mixture of neopentane;
(ii) be less than or equal to 5 * 10 25 ℃ viscosity
-6m
2The volatile straight chain polydialkysiloxane that contains 2 to 9 silicon atoms of/s.Example is, decamethyl tetrasiloxane, and it is sold with title SH 200 by Toray Silicone company especially.The siloxanes that belongs to this class also is described in Cosmetics and Toiletries, Vol.91, Jan.76, the article Todd ﹠amp that publishes in the 27-32 page or leaf; Among the Byers ＂ Volatile Silicone Fluids forCosmetics ＂.
The non-volatile polydialkysiloxane of preferred use, preferred aforesaid polydialkysiloxane glue and resin are with the polysiloxane of above-mentioned organo-functional group modification and their mixture.
These siloxanes are selected from polydialkysiloxane especially, and what wherein can mention mainly is the poly dimethyl polysiloxanes that comprises trimethyl first siloxy group end group.Described siloxanes viscosity is for example to measure according to ASTM standard 445 Appendix C in the time of 25 ℃.
In these polydialkysiloxanes, can mention following commodity without limitation:
-47 and 70047 series of selling by Rhodia company
Oil or
Oil, for example 70047 V, 500000 oil;
-sell by Rhodia company
The oil of series;
-from the oil of 200 series of Dow Coring company, for example viscosity is 60000mm
2The DC200 of/s;
-from General Electric company
Oil and from SF series (SF96, some oil SF18).
Can also mention the polydimethylsiloxane that contains dimethyl-silicon alkanol end group, be also referred to as dimethiconol (Dimethiconol) (CTFA), as oil from 48 series of Rhodia company.
In this class polydialkysiloxane, what can also mention is with title Abil by Goldschmidt company
9800 and 9801 product solds, they are poly-(C
1-C
20) dialkylsiloxane.
The used siloxane glue polydialkysiloxane in particular according to the present invention, the polydimethylsiloxane that preferably has 200000 to 1000000 high number-average molecular weight, they use individually or with the mixture in solvent.This solvent can be selected from volatile siloxane, polydimethylsiloxane (PDMS) oil, polyphenyl methyl siloxane (PPMS) oil, isoparaffin, polyisobutylene, dichloromethane, pentane, dodecane and tridecane or their mixture.
More particularly available product is a mixture according to the present invention, as:
At chain end by hydroxylated polydimethylsiloxane, or dimethiconol (CTFA)) and the mixture that forms of annular dimethyl polysiloxane (being also referred to as ring-type poly dimethyl silicone (CTFA)), for example by the product sold Q2 of Dow Corning company 1401;
The mixture that is formed by polydimethylsiloxane glue and annular siloxane is for example from the product SF 1214 Silicone Fluid of GeneralElectric company; This product is 30 glue of the SF with 500000 number-average molecular weights (corresponding to poly-diformazan silicone (dimethicone)) that are dissolved in the SF 1202 Silicone Fluid oil (corresponding to decamethylcyclopentaandoxane);
The mixture of the PDMS of two kinds of different viscosities, more particularly PDMS glue and PDMS oil are for example from the product SF 1236 of General Electric company.Product SF 1236 is that viscosity is 20m as defined above
2SE 30 glue and the viscosity of/s are 5 * 10
-6m
2The mixture of SF 96 oil of/s.This product preferably contains 15%SE 30 glue and 85%SF 96 oil.
Available organopolysiloxane resins is to contain following unitary crosslinked siloxane systems according to the present invention:
R
2SiO
2/2, R
3SiO
1/2, RSiO
3/2And SiO
4/2,
Wherein R represents to have the hydrocarbyl group of 1 to 16 carbon atom.In these products, particularly preferably being wherein, R represents C
1-C
4Those of low alkyl group (more particularly methyl).
In these resins, what can mention is those that sell with title Silicone Fluid SS 4230 and SS 4267 with title Dow Corning 593 product solds or General Electric company, and it is the polysiloxanes with dimethyl/trimethicone structure.
Can also mention the siloxy silicic acid trimethyl esters resin of selling with title X22-4914, X21-5034 and X21-5037 by Shin-Etsu company especially.
Spendable organically-modified siloxanes is a siloxanes as defined above according to the present invention, and it contains one or more organo-functional groups that connect by hydrocarbyl group in their structure.
Except the siloxanes of foregoing description, organically-modified siloxanes can be poly-diaromatic siloxane, particularly poly-diphenyl siloxane and with the functionalized polyoxyethylene alkyl aryl radical siloxane of aforementioned organo-functional group.
This polyoxyethylene alkyl aryl radical siloxane is selected from especially at 25 ℃ has 1 * 10
-5m
2/ s to 5 * 10
-2m
2The straight chain of/s viscosity and/or the poly dimethyl/methyl phenyl siloxane of side chain and poly dimethyl/diphenyl siloxane.
In these polyoxyethylene alkyl aryl radical siloxanes, the example that can mention comprises with following title and carries out product sold:
From 70 641 series of Rhodia
Oil;
From Rhodia's
The oil of 70 633 and 763 series;
Dow Coming 556 Cosmetic Grade Fluid oil from Dow Corning;
From the siloxanes of the PK series of Bayer, product P K20 for example,
From the PN of Bayer and the siloxanes of PH series, for example product P N1000 and PH1000;
From some oil of the SF series of General Electric, for example SF1023, SF1154, SF1250 and SF1265.
In described organically-modified siloxanes, the polysiloxane that can mention comprises:
-randomly contain C
6-C
24The polyethyleneoxy of alkyl and/or polypropylene oxygen base group, for example product that is called as the dimethione copolyol sold with DC1248 by DowComing company or sell by UnionCarbide company
L 722, L 7500, L 77 and L 711 oil and the (C that sells with title Q2 5200 by Dow Coming company
12) alkyl methyl copolymeric siloxane alcohol;
-replace or unsubstituted amine groups, for example by Genesee company with GP 4 Silicone Fluid and GP7100 product sold, perhaps by Dow Corning company with title Q2 8220 and Dow Corning 929 or 939 product solds.The amine groups that replaces is C especially
1-C
4Aminoalkyl;
-alkoxylate group, for example by SWS Silicones with title Silicone Copolymer F-755 product sold and by Goldschmidt company with Abil
2428,2434 and 2440 product solds.
Preferably, described fatty material is to be liquid chemical compound under 25 ℃ of temperature and atmospheric pressure.
Preferably, described fatty material is selected from liquid petrolatum, poly decene and liquid esters, or their mixture.
With respect to anhydrous composition weight, the fatty matter content in this anhydrous cosmetic composition is 10 weight % to 99 weight % advantageously, preferred 20 weight % to 90 weight %, more preferably 25 weight % to 80 weight %.
This anhydrous cosmetic composition (A) also contains one or more surfactants.
Preferably, described one or more surfactant is selected from non-ionic surface active agent and anion surfactant.
Anion surfactant more particularly is selected from the salt (particularly alkali metal salt, particularly sodium salt, ammonium salt, amine salt, amino alkoxide or alkali salt, for example magnesium salt) of following compounds:
-alkyl sulfate, alkyl ether sulfate, alkyl amido ether sulfate, alkyl aryl polyether sulfate, monoglyceride sulfate;
-alkylsulfonate, alkylamide sulfonate, alkylaryl sulfonates, alpha-alkene sulfonate, paraffin sulfonate;
-alkylphosphonic, alkyl ether phosphate;
-2-Sulfosuccinic acid alkyl ester salt, alkyl ether sulfo succinate, alkylamide sulfosuccinate, 2-Sulfosuccinic acid alkyl ester salt;
-sulfoethanoic acid. alkyl ester salt;
-acyl sarcosinates, acyl-hydroxyethyl sulfonate and N-acyl taurine salt;
-soap, wherein for example oleic acid, ricinoleic acid, palmitoleic acid or stearic acid, coconut oil or hydrogenation coconut oil of fatty acid;
-alkyl-D-galactoside glycuronate;
-acyl-lactate;
The salt of the salt of-polyoxy alkylene alkyl ether carboxylic acid's salt, polyoxy alkylene alkyl aryl ether carboxylic acid or polyoxy alkylene alkyl amido ether carboxylic acid particularly contains those of 2 to 50 ethylene oxide groups (ethylene oxidegroup).
-and their mixture.
It should be noted that alkyl and acyl group in these different chemical compounds advantageously contain 6 to 24 carbon atoms, and preferably contain 8 to 24 carbon atoms, aryl is preferably represented phenyl or benzyl group.
Non-ionic surface active agent is selected from non-ionic surface active agent single oxidation alkylene (monooxyalkylenated) or polyoxy alkylene (polyoxyalkylenated), monoglycerolifying (monoglycerolated) or multiglycerolifying (polyglycerolated) especially.This oxyalkylene units is ethylene oxide or propylene oxide unit or their combination, preferably ethylene oxide unit more particularly.
The example of the described oxidation alkylene non-ionic surface active agent that can mention comprises:
Oxidation alkylene (C
8-C
24) alkylphenol,
Saturated or undersaturated, the oxidation alkylene C of straight or branched
8-C
30Alcohol,
Saturated or undersaturated, the oxidation alkylene C of straight or branched
8-C
30Amide,
Saturated or undersaturated, the oxidation alkylene C of straight or branched
8-C
30Amine,
Saturated or undersaturated, the C of straight or branched
8-C
30The ester of acid and Polyethylene Glycol,
Saturated or undersaturated, the C of straight or branched
8-C
30The polyoxyethylene ester of acid and Sorbitol,
Saturated or undersaturated, the ethylene oxide vegetable oil,
The condensation substance of oxirane and/or expoxy propane, in particular, they are independent or as mixture.
Surfactant comprises the oxirane and/or the expoxy propane of 1 to 50 molal quantity, preferred 2 to 30 molal quantitys.Advantageously, non-ionic surface active agent does not contain any propylene oxide unit.
According to a preferred embodiment of the invention, the non-ionic surface active agent of oxidation alkylene is selected from the C of ethylene oxideization
8-C
30The C of pure and mild ethylene oxideization
8-C
30Amine.
Example as the non-ionic surface active agent of monoglycerolifying or multiglycerolifying preferably uses C monoglycerolifying or multiglycerolifying
8-C
40Alcohol.
Especially, monoglycerolifying or multiglycerolifying C
8-C
40Pure corresponding to following general formula:
RO-[CH
2-CH(CH
2OH)-O]
m-H
Wherein R represents the C of straight or branched
8-C
40Alkyl or alkenyl, preferably C
8-C
30Alkyl or alkenyl, m represents 1 to 30, preferably the number between 1 to 10.
As the example of compounds suitable for use in background of the present invention, can mention be the lauryl alcohol that contains 4mol glycerol (the INCI title: polyglyceryl-4 lauryl ether), contain 1.5mol glycerol lauryl alcohol, contain 4mol glycerol oleyl alcohol (the INCI title: polyglyceryl-4 oleyl ether), contain 2mol glycerol oleyl alcohol (the INCI title: polyglyceryl-2 oleyl ether), contain 2mol glycerol 16/octadecanol, contain 6mol glycerol 16/octadecanol, contain the oil/hexadecanol (oleocetyl alcohol) of 6mol glycerol and contain the octadecanol of 6mol glycerol.
This alcohol can be represented the mixture of alcohol, and similarly, the m value is represented statistical value, its expression, and in commodity, several species of multiglycerolifying aliphatic alcohol can be with the form coexistence of mixture.
In monoglycerolifying alcohol or multiglycerolifying alcohol, particularly preferably use the C that contains 1mol glycerol
8/ C
10Pure, as to contain 1mol glycerol C
10/ C
12The pure and mild C that contains 1.5mol glycerol
12Alcohol.
Preferably, the surfactant that exists in anhydrous composition is a non-ionic surface active agent.
If there is surfactant, the content of the surfactant in anhydrous composition is more particularly with respect to being 0.1 weight % to 50 weight % for the weight of anhydrous composition, preferably 0.5 weight % to 30 weight %.
This anhydrous cosmetic composition (A) also can contain the various auxiliary agents that are generally used in the hair dye compositions, for example anion, cation, nonionic, both sexes or amphoteric ion polymer or their mixture; Inorganic thickening agent, particularly for example clay, micaceous powder filled dose; The association thickener of organic thickening agent, particularly anion, cation, nonionic and amphiphilic polymers (associative thickeners); Antioxidant; Penetrating agent; Chelating agen; Aromatic; Dispersant; Film former; Ceramide; Antiseptic; Opacifier.
Common every kind of 0.01 weight % to the 20 weight % that accounts for the weight of compositions (A) separately of above-mentioned auxiliary agent.
According to a favourable modification of the present invention, be that anhydrous composition (A) comprises at least a silicon dioxide, preferably have hydrophobicity, for example pyrogenic silica.
When they exist, 1 weight % to 30 weight % of the weight of silica comprises anhydrous composition (A).
As mentioned above, the method according to this invention compositions for use (B) comprise one or more at 25 ℃ of its pKb less than 12 organic amine, preferably less than 10, in addition best be less than 6.It should be noted that pKb is corresponding to the function of high basicity.
In a particularly preferred embodiment of the present invention, organic amine under room temperature and the atmospheric pressure with in compositions (A) the existence one or more fatty materials at least in part can be miscible.Preferably, described one or more organic amines dissolve in described one or more fatty materials fully under 25 ℃ and atmospheric pressure (760mmHg).Preferably, described one or more fatty material and described one or more organic amine forms single-phase under 25 ℃ and atmospheric pressure.
According to first kind of modification of the present invention, organic amine contain one or two primary, secondary, tertiary amine functional group and one or more straight or branched C that has one or more oh groups
1-C
8Alkyl.
Be selected from the organic amine of alkanolamine, for example contain one to three identical or different C
1-C
4Hydroxyalkyl single, two or trialkanolamine be specially adapted to the present invention.
What can mention in this compounds is monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), N-dimethylaminoethanol amine, 2-amino-2-methyl-1-propanol, triisopropanolamine, 2-amino-2-methyl-1, ammediol, 3-amino-1,2-propylene glycol, 3-dimethylamino-1,2-propylene glycol and three (methylol amino) methane.
The organic amine that also is fit to use has following general formula:
Wherein W is for randomly with hydroxyl or C
1-C
6The C that alkyl replaces
1-C
6Alkylidene residue, R
x, R
y, R
zAnd R
tCan be identical or different, represent hydrogen atom or C
1-C
6Alkyl, C
1-C
6Hydroxyalkyl or C
1-C
6Aminoalkyl.
The example of this amine that can mention comprises 1,3-diaminopropanes, 1,3-diaminourea-2-propanol, spermine and spermidine.
According to another kind of modification of the present invention, organic amine is selected from aminoacid.
More particularly, operable aminoacid is natural or synthetic source, is L, D or racemic form, and contains at least a acid functional group that is selected from carboxylic acid, sulfonic acid, phosphonic acids and phosphoric acid functional group especially.Aminoacid can be neutrality or ionic species.
Advantageously, this aminoacid is the basic amino acid that contains other amine functional group that randomly comprises in ring or urea/ureido functional group.
This basic amino acid preferably is selected from corresponding to those of following general formula (I):
Wherein the R representative is selected from following group:
-(CH
2)
2NH
2；-(CH
2)
2NHCONH
2；
Chemical compound corresponding to general formula (I) is histidine, lysine, arginine, ornithine and citrulline.
As operable aminoacid in the present invention, especially can mention aspartic acid, glutamic acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine, cysteine, glutamine, lysine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine.
Described one or more aminoacid can with one or more solids or pasty state, the mixture of preferred powdered auxiliary agent uses.Described auxiliary agent is optional from clay, salt, anion, nonionic, cation or zwitterionic surfactant, natural or synthetic thickening agent, the starch that randomly is modified, bead, silicon dioxide, nylon, aluminium oxide, titanium dioxide, zeolite, polymethyl methacrylate (PMMA), chitosan, maltodextrin, cyclodextrin, list or disaccharide, glucose for example, sucrose, Sorbitol or fructose, zinc oxide, zirconium oxide, resin particle, for example siloxanes or silica beads, Muscovitum, borosilicate, calcium borosilicate particularly, polyethylene, cotton, polytetrafluoroethylene (PTFE), cellulose and derivant thereof, the chemical compound of superabsorbent, magnesium carbonate, calcium carbonate, seed-grain (com seeds), polydimethylsiloxane glue, polyacrylamide, porous hydroxyapatite, silk, collagen, wood flour (sawdust), Sargassum powder (wrack powder), crospolyvinylpyrrolidone, calcium alginate, active carbon, with poly-(ethylene chlorine/acrylonitrile partially) granule, particularly by Akzo Nobel company with the particular commodity name
, specifically with clauses and subclauses
Those that WE or ExpancelDE sell, and their mixture.
According to a kind of preferred variation of the present invention, organic amine is selected from basic amino acid.Particularly preferred aminoacid is arginine, lysine and histidine, perhaps their mixture.
According to another kind of modification of the present invention, organic amine is selected from the heterocyclic type organic amine.Except that the histidine of in aminoacid, having mentioned, can mention pyridine especially, piperidines, imidazoles, triazole, tetrazolium and benzimidazole.
According to another kind of modification of the present invention, organic amine is selected from amino acid dipeptide.Operable in the present invention amino acid dipeptide can be mentioned carnosine, anserine and baleine especially.
According to another kind of modification of the present invention, organic amine is selected from the chemical compound that contains guanidine functional group.As available this class amine in the present invention, except being mentioned as amino acid whose arginine, what can mention especially is sarcosine, creatinine, 1,1-dimethylguanidine, 1,1-diethyl guanidine, glycocyamine, metformin (metformin), gamatine, N-amidino groups alanine, 3-guanidine radicals propanoic acid, 4-guanidine radicals butanoic acid and 2-([amino (imino group) methyl] amino) ethane-1-sulfonic acid.
Preferably, the organic amine that exists in anhydrous composition is an alkanolamine.More preferably, this organic amine is selected from 2-amino-2-methyl-1-propanol and monoethanolamine or their mixture.Even more preferably, organic amine is a monoethanolamine.
Advantageously, the organic amine content of compositions (B) accounts for 0.1 weight % to 40 weight % of the weight of compositions (B), preferred 0.5 weight % to 20 weight %.
Compositions (B) can be moisture or anhydrous composition.Term " Aquo-composition " expression contains the compositions greater than 5 weight % water, more preferably contains the water greater than 10 weight %, more advantageously greater than the water of 20 weight %.
Preferably, compositions (B) is an Aquo-composition.
Can choose wantonly and contain organic solvent.The example of the organic solvent that can mention comprises the C of straight or branched
2-C
4Alkanol, for example ethanol and isopropyl alcohol, glycerol, polyhydric alcohol and polyol ethers, for example butoxy ethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diethylene glycol monomethyl ether and single ether, and aromatic alcohol, for example benzyl alcohol or phenyl phenol, and their mixture.
When having one or more solvents, the content of described solvent accounts for 1 weight % to 40 weight % of the weight of compositions (B), preferably 5 weight % to 30 weight % usually.
At last, this method is implemented with the compositions (C) that contains one or more oxidants.
More particularly, described one or more oxidants are selected from hydrogen peroxide, urea peroxide, alkali metal bromate or ferricyanate and peroxide salt (peroxygenated salts), for example alkali metal or alkaline-earth metal persulfate, perborate and percarbonate and peracid and precursor thereof.
This oxidant advantageously is made up of hydrogen peroxide, and particularly as aqueous solution (hydrogen peroxide aqueous solution), its titer more particularly can be 1 to 40 volume, even 5 to 40 volumes more preferably.
According to required blast degree, oxidant also can comprise the oxidant that preferably is selected from peroxide salt.
Preferably, oxidant is not selected from peroxide salt, peracid and its precursor.
This oxidising composition can be moisture or anhydrous.Term " Aquo-composition " expression contains the compositions greater than the water of 5 weight %, preferably contains the water greater than 10 weight %, more advantageously greater than the water of 20 weight %.
Preferably, compositions (C) is an Aquo-composition.
It also can contain one or more organic solvents.
The example of the organic solvent that can mention comprises the C of straight or branched
2-C
4Alkanol, for example ethanol and isopropyl alcohol, glycerol, polyhydric alcohol and polyol ethers, for example butoxy ethanol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether, diethylene glycol monomethyl ether and single ether and aromatic alcohol, for example benzyl alcohol or phenyl phenol, and their mixture.
When having described one or more solvents, described solvent accounts for 1 weight % to 40 weight % of the weight of oxidising composition (C), preferably 5 weight % to 30 weight % usually.
Oxidising composition can contain one or more acidulant.
The example of the acidulant that can mention comprises inorganic or organic acid, for example hydrochloric acid, former phosphoric acid, sulphuric acid, carboxylic acid, for example acetic acid, tartaric acid, citric acid or lactic acid, and sulfonic acid.
Usually, when oxidising composition (C) when being moisture, its pH value is less than 7.
This oxide compound (C) also can contain other composition, particularly those that are for example described in detail commonly used in the art in the context of aforementioned anhydrous cosmetic.
At last, oxidising composition is a various forms, for example, and solution, emulsion or gel.
According to first kind of modification of the present invention, will be applied on the wet or dried keratin fiber by interim compositions of mixing above-mentioned anhydrous composition (A), compositions (B) and oxidation Aquo-composition (C) acquisition in use.
In this modification, (A)/(B) weight ratio R2 of (A)+(B)/(C) weight ratio R1 of amount of composition and amount of composition is 0.1 to 10, and is preferably 0.3 to 3.
According to second kind of modification of the inventive method, rinsing in the middle of not needing, with compositions (A), (B) and (C) continuous administration in wet or dried keratin fiber.
Preferably, use compositions (A) compositions (B) compositions (C) then then, perhaps use (B) (A) (C) then then.
According to another kind of modification, do not need in the middle of rinsing, continuous administration compositions (C), then by compositions (A) and (B) acquisition mixture.
In these two kinds of modification, (A)/(B) weight ratio R2 of (A)+(B)/(C) weight ratio R1 of amount of composition and amount of composition more particularly is 0.1 to 10, and preferably 0.3 to 3.
In addition, with the modification of using mutually independently, make mixture (it is by interim blend compositions (A), (B) and (C) generation, perhaps by part or all of continuous administration generation) the static a period of time that on fiber, exists, normally 1 minute to 1 hour, and be preferably 5 minutes to 30 minutes.
Temperature in the method is usually between room temperature (15-25 ℃) is to 80 ℃, and preferably between room temperature to 60 ℃.
After treatment, human keratin fiber before being dried or drying, can be randomly with water rinse or randomly use water rinse then with the shampoo washing.
Be to be noted that if be applied to the compositions (comprise compositions (A), (B) and (C)) of hair and contain ammonia, its content (is used NH
3Expression) will preferably be less than or equal to 0.03 weight % with respect to final composition, and more particularly be less than or equal to 0.01 weight % of final composition.It shows that final composition makes by hybrid combining (A), (B) with (C); These mixture were prepared (interim preparation) or directly are applied to keratin fiber (premixing or without premixing ground continuous administration, rinsing in the middle of need not) before being applied to keratin fiber.
But, compositions (A), (B) and (C) preferably do not contain ammonia.
At last, the present invention relates to multi-compartment device, it comprises anhydrous cosmetic composition (A) in first compartment, with in second compartment, be included in the previously described Aquo-composition (C) that contains one or more oxidants, with in the 3rd compartment, comprise and contain the compositions (B) less than one or more organic amines of 12 that these compositionss have obtained describing in preamble at 25 ℃ of its pKb.
The specific embodiment
Following embodiment is used to illustrate the present invention, and is nonrestrictive in essence.
Embodiment
Prepare following compositions:
Anhydrous composition (A); (amount is represented with gram)
| Ethylene oxideization (4 EO) Arlacel-20 | 21.67 |
| Hydrophobic pyrogenic silica | 11 |
| Liquid petrolatum | An amount of 100 |
Compositions (B), it comprises the 40g monoethanolamine, adds water to 100g.
During use, following substances is mixed together:
The anhydrous composition of-9 weight portions (A)
The compositions of-1 weight portion (B)
The oxidizing aqueous compositions of-10 weight portions, it comprises hydrogen peroxide and about 80% water of 6%pH2.3.
The pH of gained mixture is about 10, and it is applied to the natural Chestnut hair of a tuft (depth of shade is 5).
At room temperature (about 25 ℃) kept 30 minutes.
After this retention time, this tuft hair of rinsing is then with the multiple vitamin shampoo washing of Elseve.
For relatively, prepare following compositions (amount is in g%) based on ammonia;
| Oleyl alcohol with 2mol glycerol multiglycerolifying | 4 |
| Oleyl alcohol with 4mol glycerol multiglycerolifying | 5.69AM |
| Oleic acid | 3 |
| The oleyl amine (from the Ethomeen 012 of Akzo) that contains 2mol oxirane | 7 |
| Diethylamino propyl group lauryl aminosuccinamic acid sodium | 3.0AM |
| (55% active substance) | |
| Oleyl alcohol | 5 |
| Oleic acid diethyl amide | 12 |
| Ethanol | 7 |
| Propylene glycol | 3.5 |
| Dipropylene glycol | 0.5 |
| Propylene glycol monomethyl ether | 9 |
| Ammonium acetate | 0.8 |
| 20% ammonia | 10 |
| Demineralized water is an amount of | 100g |
AM: the amount of representing with active material
During use, Comparative composition is mixed weight by weight with hydrogen peroxide that comprises 6% pH2.3 and the oxidizing aqueous compositions that comprises about 80% water.
So the pH of the mixture that obtains is about 10, then it is applied to the natural Chestnut hair of a tuft (depth of shade is 5).
At room temperature kept 30 minutes.
After this retention time, with this tuft hair rinse, subsequently with the multiple vitamin shampoo washing of Elseve.
According to compositions of the present invention, at first can not send any odour nuisance, this is different from the Comparative composition of sending the strong ammonia stink.
Following table shows, the compositions that does not contain ammonia according to the present invention obtains and the suitable brightening effect of blast result based on the Comparative composition of ammonia.
Claims (18)
1. the method for lightening human keratin fibres, below wherein using:
(a) anhydrous composition (A), it comprises one or more fatty materials and one or more surfactants;
(b) compositions (B), it comprises one or more its pKb less than 12 organic amine;
(c) compositions (C), it comprises one or more oxidants.
2. the method that requires according to aforesaid right is characterized in that described one or more fatty materials are selected from alkane, aliphatic alcohol, fatty acid, fatty acid ester, aliphatic alcohol ester, mineral oil, vegetable oil, animal oil, artificial oil, siloxanes and wax.
3. require each method according to aforesaid right, it is characterized in that described one or more fatty materials are selected from liquid petrolatum, poly decene and liquid esters or their mixture.
4. require each method according to aforesaid right, it is characterized in that the weight with respect to anhydrous composition (A), the content of fatty material is 10 weight % to 99 weight %.
5. require each method according to aforesaid right, it is characterized in that anhydrous composition (A) comprises at least a non-ionic surface active agent, this non-ionic surface active agent more particularly is selected from non-ionic surface active agent single oxidation alkylene or polyoxy alkylene, monoglycerolifying or multiglycerolifying.
6. the method that requires according to aforesaid right is characterized in that the weight with respect to anhydrous composition (A), and the content of surfactant is 0.1 weight % to 50 weight %.
7. require each method according to aforesaid right, it is characterized in that organic amine be at least in part can be miscible in described one or more fatty materials.
8. require each method according to aforesaid right, it is characterized in that organic amine comprise one or two primary, the second month in a season or tertiary amine functional group and one or more C that has the straight or branched of one or more oh groups
1-C
8Alkyl.
9. according to the method for aforesaid right requirement, it is characterized in that organic amine is:
Alkanolamine, it is selected from list, two and trialkanolamine, comprises one to three identical or different C
1-C
4Hydroxyalkyl group,
Chemical compound with following general formula:
Wherein W is the C that randomly replaces with hydroxyl
1-C
6Alkylidene residue; Rx, Ry, Rz and Rt can be identical or different, represent hydrogen atom or C
1-C
6Alkyl, C
1-C
6Hydroxyalkyl or C
1-C
6Aminoalkyl groups.
10. according to claim 12 and 13 each methods, it is characterized in that organic amine is an alkanolamine, it preferably is selected from 2-amino-2-methyl-1-propanol and monoethanolamine or their mixture.
11. require each method according to aforesaid right, it is characterized in that organic amine is selected from the basic amino acid with following general formula (I):
Wherein R represents to be selected from following group:
12., it is characterized in that organic amine is selected from arginine, histidine and lysine, or their mixture according to claim 15 and 16 each methods.
13. require each method according to aforesaid right, it is characterized in that weight with respect to compositions (B), the content of organic amine is 0.1 weight % to 40 weight %, preferably 0.5 weight % to 20 weight %.
14. require each method according to aforesaid right, it is characterized in that and to be applied to keratin fiber by interim blend compositions (A), (B) and the compositions that (C) obtains in use.
15. according to each method of claim 1 to 13, rinsing in the middle of not needing it is characterized in that, with compositions (A), (B) and (C), compositions (A) (B) (C) then then preferably, perhaps compositions (B) then (A) then (C) continuous administration in keratin fiber.
16. according to each method of claim 1 to 13, rinsing in the middle of not needing it is characterized in that, with compositions (C) then by compositions (A) and (B) mixture of acquisition be applied to keratin fiber continuously.
17. require each method according to aforesaid right, it is characterized in that (A)+(B)/(C) weight ratio R1 of amount of composition and (A)/(B) weight ratio R2 of amount of composition are 0.1-10.
18. the device of many compartments, it comprises each the anhydrous composition (A) according to claim 1-6 in first compartment, in another compartment, comprise as each defined compositions B of claim 7-13 and in the 3rd compartment, comprise the Aquo-composition that contains one or more oxidants.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0760274 | 2007-12-21 | ||
| FR0760274A FR2925311B1 (en) | 2007-12-21 | 2007-12-21 | PROCESS FOR LIGHTENING HUMAN KERATINOUS FIBERS USING ANHYDROUS COMPOSITION AND A PARTICULAR ORGANIC AMINE AND APPROPRIATE DEVICE |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310408689.7A Division CN103550078A (en) | 2007-12-21 | 2008-12-19 | Process for lightening human keratin fibres using an anhydrous composition and a particular organic amine, and device suitable therefore |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101485620A true CN101485620A (en) | 2009-07-22 |
Family
ID=39684444
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200810220799 Pending CN101485620A (en) | 2007-12-21 | 2008-12-19 | Process for lightening human keratin fibres using an anhydrous composition and a particular organic amine, and device suitable therefor |
| CN201310408689.7A Pending CN103550078A (en) | 2007-12-21 | 2008-12-19 | Process for lightening human keratin fibres using an anhydrous composition and a particular organic amine, and device suitable therefore |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310408689.7A Pending CN103550078A (en) | 2007-12-21 | 2008-12-19 | Process for lightening human keratin fibres using an anhydrous composition and a particular organic amine, and device suitable therefore |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9005594B2 (en) |
| EP (1) | EP2072035B1 (en) |
| CN (2) | CN101485620A (en) |
| BR (1) | BRPI0806180B8 (en) |
| ES (1) | ES2525587T3 (en) |
| FR (1) | FR2925311B1 (en) |
| MX (1) | MX2008016521A (en) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2925307B1 (en) | 2007-12-21 | 2009-12-18 | Oreal | METHOD FOR DIRECT LIGHTENING OR OXIDATION COLORING IN THE PRESENCE OF A PARTICULAR ORGANIC AMINE AND DEVICE |
| FR2925323B1 (en) | 2007-12-21 | 2009-12-18 | Oreal | COLORING PROCESS IN THE PRESENCE OF AN OXIDIZING AGENT AND A PARTICULAR ORGANIC AMINE AND DEVICE |
| FR2925311B1 (en) | 2007-12-21 | 2009-12-18 | Oreal | PROCESS FOR LIGHTENING HUMAN KERATINOUS FIBERS USING ANHYDROUS COMPOSITION AND A PARTICULAR ORGANIC AMINE AND APPROPRIATE DEVICE |
| FR2940092B1 (en) | 2008-12-19 | 2011-02-18 | Oreal | KERATIN FIBER OXIDATION DYE COMPOSITION COMPRISING AN AMIDE OR ESTER FATTY BODY |
| FR2940067B1 (en) | 2008-12-19 | 2011-02-25 | Oreal | OXIDIZING COMPOSITION FOR THE TREATMENT OF KERATIN FIBERS COMPRISING A CATIONIC POLYMER, A FATTY AMIDE AND AN OXYGEN AGENT |
| EP2198831B1 (en) | 2008-12-19 | 2017-05-10 | L'Oréal | Method for lightening, lightening direct dyeing or oxidation dyeing carried out in the presence of an organic amine and a mineral base; suitable kit |
| EP2198833B1 (en) | 2008-12-19 | 2017-07-26 | L'Oréal | Method of coloring or lightening of human keratinic fibers with an anhydrous composition and an inorganic base and kit |
| FR2940055B1 (en) | 2008-12-19 | 2015-03-27 | Oreal | KERATIN FIBER OXIDATION DYEING COMPOSITION COMPRISING PARA-AMINOPHENOL, DIPROPYLENE GLYCOL, AND ADDITIONAL COLOURANT PRECURSOR |
| FR2940108B1 (en) * | 2008-12-19 | 2011-04-29 | Oreal | METHOD FOR LIGHTENING KERATINIC MATERIALS USING ANHYDROUS COMPOSITION COMPRISING AN ALKALI AGENT AND AN OXIDIZING COMPOSITION |
| FR2940090B1 (en) | 2008-12-19 | 2011-02-25 | Oreal | OXIDIZING COMPOSITION FOR THE TREATMENT OF KERATIN FIBERS COMPRISING OIL, FATTY ALCOHOL AND OXYALKYLENE FATTY ALCOHOL |
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| FR2940078B1 (en) | 2008-12-19 | 2011-05-13 | Oreal | COMPOSITION COMPRISING A FATTY BODY AND A CATIONIC POLYMER, A METHOD FOR COLORING THE SAME AND DEVICES |
| FR2940077B1 (en) | 2008-12-19 | 2012-07-20 | Oreal | METHOD FOR LIGHTENING COLORING KERATINIC MATERIALS USING A COLORING ANHYDROUS COMPOSITION COMPRISING AN ALKALI AGENT AND AN OXIDIZING COMPOSITION |
| FR2940102B1 (en) | 2008-12-19 | 2016-03-11 | Oreal | KERATIN FIBER OXIDATION DYEING COMPOSITION COMPRISING A FATTY BODY, A THICKENER AND AN OXIDATION COLORING PRECURSOR |
| FR2940106B1 (en) | 2008-12-19 | 2013-04-12 | Oreal | COMPOSITION COMPRISING A FATTY BODY AND A SILICATE, COLORING PROCESS USING THE SAME AND DEVICES |
| FR2940100B1 (en) | 2008-12-19 | 2011-02-18 | Oreal | KERATIN FIBER OXIDATION DYE COMPOSITION COMPRISING A FATTY BODY AND N, N BIS (BETA-HYDROXYETHYL) -PARAPHENYLENE DIAMINE |
| FR2940105B1 (en) | 2008-12-19 | 2011-04-08 | Oreal | COMPOSITION COMPRISING A PARTICULAR OXYETHYLENE FIBER AND SURFACTANT, METHOD FOR COLORING THE SAME AND DEVICES THEREFOR |
| BRPI0910081A2 (en) | 2008-12-19 | 2012-03-13 | L'oreal | HUMAN KERATIN FIBER CLARING PROCESS, HUMAN KERATIN FIBER COLORING PROCESS AND DEVICES WITH VARIOUS COMPARTMENTS |
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- 2007-12-21 FR FR0760274A patent/FR2925311B1/en active Active
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2008
- 2008-12-19 BR BRPI0806180A patent/BRPI0806180B8/en active IP Right Grant
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- 2008-12-19 US US12/339,781 patent/US9005594B2/en active Active
- 2008-12-19 CN CN 200810220799 patent/CN101485620A/en active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0806180A2 (en) | 2010-01-19 |
| FR2925311A1 (en) | 2009-06-26 |
| ES2525587T3 (en) | 2014-12-26 |
| CN103550078A (en) | 2014-02-05 |
| EP2072035B1 (en) | 2014-09-17 |
| FR2925311B1 (en) | 2009-12-18 |
| MX2008016521A (en) | 2009-06-22 |
| EP2072035A1 (en) | 2009-06-24 |
| BRPI0806180B8 (en) | 2017-05-30 |
| BRPI0806180B1 (en) | 2016-10-25 |
| US9005594B2 (en) | 2015-04-14 |
| US20090162309A1 (en) | 2009-06-25 |
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