JP2006282524A - Hair-treating agent composition - Google Patents
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本発明は、毛髪処理剤用組成物に関する。更に詳しくは、毛髪脱色剤、酸化染毛剤、パーマネントウェーブ剤などに好適に使用しうる過酸化水素を含有した毛髪処理剤用組成物、並びに該毛髪処理剤用組成物を用いた毛髪脱色剤、酸化染毛剤、又はパーマネントウェーブ剤に関する。 The present invention relates to a composition for a hair treatment agent. More specifically, a composition for a hair treatment agent containing hydrogen peroxide that can be suitably used for a hair bleaching agent, an oxidative hair dye, a permanent wave agent, etc., and a hair bleaching agent using the composition for a hair treatment agent , Oxidative hair dye, or permanent wave agent.
従来より、毛髪を処理するための様々な剤型の毛髪脱色剤、染毛剤、パーマネントウェーブ剤が開発され、手軽に毛髪の変色やパーマネントウェーブを楽しめるようになってきている。これを反映し、近年では、毛髪の望む部分だけを脱色し、染毛し、又はパーマネントウェーブを行う人が増える傾向にある。 Conventionally, various types of hair bleaching agents, hair coloring agents, and permanent wave agents for treating hair have been developed, and it has become possible to easily enjoy discoloration of hair and permanent waves. Reflecting this, in recent years, there is a tendency for more people to decolorize, dye or permanent wave only the desired part of the hair.
しかし、従来の毛髪処理剤は、髪全体への塗布を前提としていることから、施術時の垂れ落ちを防止すると共に、毛髪への伸びを良好にして毛髪全体に均一に塗布できるように、適度な粘度に調整されているのが通常である。このため、従来の毛髪処理剤で望む部分のみを脱色、染色などの部分処理を施そうとすると、目的部分の毛髪を束ねた状態に保持する毛髪固定力が乏しいことから、処理剤を塗布した毛髪が目的部分周辺の毛髪に付着し、毛髪処理を望まない部分まで脱色、染毛などがされてしまうという問題があった。 However, since the conventional hair treatment agent is premised on application to the entire hair, it can be applied moderately so that it can be applied to the entire hair with good elongation to the hair while preventing dripping during treatment. Usually, the viscosity is adjusted to a proper value. For this reason, when trying to perform partial treatments such as decoloring and dyeing only the desired part with the conventional hair treatment agent, the treatment agent was applied because the hair fixing power to hold the target portion of the hair in a bundled state is poor. There is a problem that the hair adheres to the hair around the target portion, and the hair is uncolored or dyed to a portion where the hair treatment is not desired.
また、過酸化水素水と共に高級アルコールなどの油性成分を配合すると、その比重差や過酸化水素の分解などから分離や粘度低下を起こし、製剤の保存安定性に劣るといった問題もあった。 In addition, when an oily component such as higher alcohol is mixed with hydrogen peroxide solution, there is a problem that separation and viscosity decrease are caused due to a difference in specific gravity and decomposition of hydrogen peroxide, resulting in poor storage stability of the preparation.
このような問題点を解決するために、ポリアクリル酸系樹脂、ポリグリセリン脂肪酸エステル、及び酸化剤を含有した二剤式染毛剤の第２剤組成物が提案されている（特許文献１参照）。しかし、このような毛髪処理剤は、系を増粘し、製剤の保存安定性をも向上させることができたとしても、処理剤の毛髪への固定力が十分ではなく、毛髪の所望部分のみの部分処理を行うには未だ満足しうるものではなかった。 In order to solve such problems, a second agent composition of a two-component hair dye containing a polyacrylic acid resin, a polyglycerin fatty acid ester, and an oxidizing agent has been proposed (see Patent Document 1). ). However, even if such a hair treatment agent can thicken the system and improve the storage stability of the preparation, the fixing force of the treatment agent to the hair is not sufficient, and only the desired portion of the hair is used. It was not yet satisfactory to perform the partial processing.
本発明は、前記従来技術に鑑みてなされたものであって、製剤の分離や粘度低下の防止といった保存安定性に優れると共に、施術時には毛髪上からの垂れ落ちが無く、毛髪の固定力に優れ、毛髪の部分処理をも可能とする毛髪処理剤用組成物を提供することを課題とする。 The present invention has been made in view of the prior art, and has excellent storage stability such as separation of the preparation and prevention of viscosity reduction, and does not sag from the hair during treatment, and has excellent hair fixing power. Another object of the present invention is to provide a composition for a hair treatment agent that enables partial treatment of hair.
すなわち、請求項１に係る発明は、（Ａ）セチルアルコール、（Ｂ）ステアリルアルコール、（Ｃ）モノグリセリン脂肪酸エステル、及び（Ｄ）ポリオキシエチレンアルキルエーテルを含有し、その重量含有比が、Ａ：Ｂ＝１：４〜４：１であり、Ｃ：Ｄ＝１：６〜６：１である、過酸化水素を含む毛髪処理剤用組成物に関する。
請求項２に係る発明は、前記Ｄ成分が、ＨＬＢ値１０〜２５のポリオキシエチレンアルキルエーテルである請求項１記載の毛髪処理剤用組成物に関する。
請求項３に係る発明は、更に、（Ｅ）多価アルコールを含有する請求項１又は２記載の毛髪処理剤用組成物に関する。
請求項４に係る発明は、Ｅ成分が、ジプロピレングリコールである請求項３記載の毛髪処理剤用組成物に関する。
そして、請求項５に係る発明は、請求項１〜４いずれか記載の毛髪処理剤用組成物を用いた毛髪脱色剤、酸化染毛剤、又はパーマネントウェーブ剤に関する。
That is, the invention according to claim 1 contains (A) cetyl alcohol, (B) stearyl alcohol, (C) monoglycerin fatty acid ester, and (D) polyoxyethylene alkyl ether. : B = 1: 4-4: 1, C: D = 1: 6-6: 1 It is related with the composition for hair treatment agents containing hydrogen peroxide.
The invention according to claim 2 relates to the hair treatment composition according to claim 1, wherein the component D is a polyoxyethylene alkyl ether having an HLB value of 10 to 25.
The invention according to claim 3 further relates to the composition for a hair treatment agent according to claim 1 or 2, further comprising (E) a polyhydric alcohol.
The invention according to claim 4 relates to the hair treatment composition according to claim 3, wherein the E component is dipropylene glycol.
And the invention which concerns on Claim 5 is related with the hair decoloring agent, the oxidative hair dye, or the permanent wave agent using the composition for hair treatment agents in any one of Claims 1-4.
本発明の毛髪処理剤用組成物は、製剤の保存安定性に優れると共に、施術時には毛髪上からの垂れ落ちが無く、毛髪の固定力に優れ、毛髪の部分処理をも可能にすることができるという効果を奏する。 The composition for a hair treatment agent of the present invention is excellent in the storage stability of the preparation, does not sag from the hair during treatment, has excellent hair fixing power, and can also allow partial treatment of hair. There is an effect.
本発明の毛髪処理剤用組成物は、過酸化水素を含有する毛髪処理剤用組成物であって、（Ａ）セチルアルコール、（Ｂ）ステアリルアルコール、（Ｃ）モノグリセリン脂肪酸エステル、及び（Ｄ）ポリオキシエチレンアルキルエーテルを含有してなる。 The hair treatment composition of the present invention is a composition for hair treatment containing hydrogen peroxide, comprising (A) cetyl alcohol, (B) stearyl alcohol, (C) monoglycerin fatty acid ester, and (D ) It contains polyoxyethylene alkyl ether.
Ａ成分の含有量は、特に限定されないが、毛髪の部分処理に適した粘度及び毛髪固定力を付与する観点から、通常、組成物中、０．５〜２０重量％とするのが好ましく、１〜１６重量％とするのがより好ましい。 Although content of A component is not specifically limited, From a viewpoint of providing the viscosity suitable for the partial treatment of hair, and a hair fixing force, it is preferable normally to set it as 0.5 to 20 weight% in a composition. More preferably, it is set to ˜16% by weight.
Ｂ成分の含有量は、特に限定されないが、毛髪の部分処理に適した粘度及び毛髪固定力を付与する観点から、通常、組成物中、０．５〜２０重量％とするのが好ましく、１〜１６重量％とするのがより好ましい。 Although content of B component is not specifically limited, From a viewpoint of providing the viscosity suitable for the partial treatment of hair, and a hair fixing force, it is preferable normally to set it as 0.5 to 20 weight% in a composition. More preferably, it is set to ˜16% by weight.
また、Ａ成分とＢ成分の含有比は、重量比として、Ａ：Ｂ＝１：４〜４：１の範囲で調製される。これにより、本発明の毛髪処理剤用組成物に、毛髪の部分処理に適した粘度及び毛髪固定力を付与すると共に、製剤の保存安定性を著しく向上させることができる。 Moreover, the content ratio of A component and B component is prepared in the range of A: B = 1: 4-4: 1 as a weight ratio. Thereby, while providing the composition for hair treatment agents of this invention with the viscosity and hair fixing force suitable for the partial treatment of hair, the storage stability of a formulation can be improved significantly.
Ｃ成分のモノグリセリン脂肪酸エステルとしては、特に限定されなが、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリル、モノエルカ酸グリセリル等のモノグリセリン脂肪酸エステル等を例示することができ、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル等の炭素数１２〜１８のモノグリセリン脂肪酸エステルを用いるのが好ましい。 The monoglycerin fatty acid ester of component C is not particularly limited, but glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, Examples thereof include monoglycerin fatty acid esters such as glyceryl monobehenate, glyceryl monooleate, glyceryl monoerucate, and the like, such as glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, and glyceryl monostearate. Preferably 18 monoglycerin fatty acid esters are used.
Ｃ成分の含有量は、特に限定されないが、安定な乳化状態を形成する観点から、通常、組成物中、０．１〜１５重量％とするのが好ましく、０．５〜１０重量％とするのがより好ましい。 Although content of C component is not specifically limited, From a viewpoint of forming a stable emulsified state, it is usually preferable to set it as 0.1 to 15 weight% in a composition, and to 0.5 to 10 weight%. Is more preferable.
尚、本発明に用い得る市販のモノグリセリン脂肪酸エステルは、例えば、モノステアリン酸グリセリルとしては、商品名：ＣＵＴＩＮＡ ＧＭＳ（ＣＯＧＮＩＳ ＣＯＲＰ製）、モノミリスチン酸グリセリルとしては、商品名：ＮＩＫＫＯＬ ＭＧＭ（日光ケミカルズ社製）、モノステアリン酸グリセリルとしては、商品名：ＣＵＴＩＮＡ ＧＭＳ（ＣＯＧＮＩＳ ＣＯＲＰ製）等を例示することができる。 The commercially available monoglycerin fatty acid ester that can be used in the present invention is, for example, trade name: CUTINA GMS (manufactured by COGNIS CORP) as glyceryl monostearate, and trade name: NIKKOL MGM (Nikko Chemicals) as glyceryl monomyristate. As the glyceryl monostearate, a trade name: CUTINA GMS (manufactured by COGNIS CORP) and the like can be exemplified.
Ｄ成分のポリオキシエチレンアルキルエーテルとしては、特に限定されず、例えば、ポリオキシエチレンブチルエーテル、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンイソステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンオクチルドデシルエーテル、ポリオキシエチレンベヘニルエーテル等を例示することができ、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンベヘニルエーテル等を用いるのが好ましい。 The polyoxyethylene alkyl ether of component D is not particularly limited. For example, polyoxyethylene butyl ether, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene isostearyl ether, polyoxyethylene Examples thereof include ethylene oleyl ether, polyoxyethylene octyldodecyl ether, polyoxyethylene behenyl ether and the like, and it is preferable to use polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether and the like.
また、系の温度安定性を向上させる観点から、Ｄ成分のＨＬＢ値は、１０〜２５の範囲を有するものが好ましく、１５〜２０の範囲のものがより好ましい。このようなＨＬＢ値を有するポリオキシエチレンアルキルエーテルとしては、例えば、ポリオキシエチレン（５．５）セチルエーテル、ポリオキシエチレン（１０）セチルエーテル、ポリオキシエチレン（２０）セチルエーテル、ポリオキシエチレン（４０）セチルエーテル、ポリオキシエチレン（２０）ステアリルエーテル、ポリオキシエチレン（２０）ベヘニルエーテル、ポリオキシエチレン（３０）ベヘニルエーテル等を例示することができる。 Further, from the viewpoint of improving the temperature stability of the system, the HLB value of the D component is preferably in the range of 10 to 25, and more preferably in the range of 15 to 20. Examples of the polyoxyethylene alkyl ether having such an HLB value include polyoxyethylene (5.5) cetyl ether, polyoxyethylene (10) cetyl ether, polyoxyethylene (20) cetyl ether, polyoxyethylene ( 40) Cetyl ether, polyoxyethylene (20) stearyl ether, polyoxyethylene (20) behenyl ether, polyoxyethylene (30) behenyl ether and the like can be exemplified.
Ｄ成分の含有量は、特に限定されないが、安定な乳化状態を形成する観点から、通常、組成物中、０．１〜１５重量％とするのが好ましく、０．５〜１０重量％とするのがより好ましい。 Although content of D component is not specifically limited, From a viewpoint of forming a stable emulsified state, it is usually preferable to set it as 0.1 to 15 weight% in a composition, and to 0.5 to 10 weight%. Is more preferable.
尚、本発明に用い得る市販のポリオキシエチレンアルキルエーテルは、例えば、ポリオキシエチレンセチルエーテルとしては、商品名：ＮＩＫＫＯＬ ＢＣ−２０ＴＸ、ＢＣ−４０ＴＸ（いずれも日光ケミカルズ社製）、ポリオキシエチレンステアリルエーテルとしては、商品名：ＮＩＫＫＯＬ ＢＳ−２０（日光ケミカルズ社製）、ポリオキシエチレンベヘニルエーテルとしては、商品名：ＮＩＫＫＯＬ ＢＢ−２０，ＢＢ−３０（いずれも日光ケミカルズ社製）等を例示することができる。 The commercially available polyoxyethylene alkyl ether that can be used in the present invention is, for example, trade names: NIKKOL BC-20TX, BC-40TX (both manufactured by Nikko Chemicals), polyoxyethylene stearyl, as polyoxyethylene cetyl ether. Examples of the ether include trade name: NIKKOL BS-20 (manufactured by Nikko Chemicals), and examples of the polyoxyethylene behenyl ether include trade names: NIKKOL BB-20, BB-30 (all manufactured by Nikko Chemicals). Can do.
また、前記Ｃ成分とＤ成分の含有比は、重量比として、Ａ：Ｂ＝１：６〜６：１の範囲で調製される。これにより、本発明の毛髪処理剤用組成物に、毛髪の部分処理に適した粘度及び毛髪固定力を付与すると共に、製剤の保存安定性を著しく向上させることができる。 Moreover, the content ratio of the said C component and D component is prepared in the range of A: B = 1: 6-6: 1 as a weight ratio. Thereby, while providing the composition for hair treatment agents of this invention with the viscosity and hair fixing force suitable for the partial treatment of hair, the storage stability of a formulation can be improved significantly.
本発明の毛髪処理剤用組成物は、過酸化水素が含有される。その含有量は、特に限定されないが、充分な酸化力を得る観点および毛髪の損傷や皮膚刺激を抑制する観点から、通常、組成物中、０．１〜１０重量％、好ましくは１〜６重量％である。 The composition for a hair treatment agent of the present invention contains hydrogen peroxide. The content is not particularly limited, but is usually 0.1 to 10% by weight, preferably 1 to 6% by weight in the composition from the viewpoint of obtaining sufficient oxidizing power and suppressing hair damage and skin irritation. %.
また、本発明の毛髪処理剤用組成物には、毛髪固定力を有し、塗布時の延展性を良好な粘度に調整するために、多価アルコールを含有させることができる。用いられる多価アルコールとしては、例えば、エチレングリコール、ジプロピレングリコール、プロピレングリコール、グリセリン、ジグリセリン、１，３−ブチレングリコール、１，２−ペンタンジオール等を例示することができ、ジプロピレングリコールを用いるのが好ましい。 In addition, the composition for a hair treatment agent of the present invention can contain a polyhydric alcohol in order to have a hair fixing force and adjust the spreadability at the time of application to a good viscosity. Examples of the polyhydric alcohol used include ethylene glycol, dipropylene glycol, propylene glycol, glycerin, diglycerin, 1,3-butylene glycol, 1,2-pentanediol, and the like. It is preferable to use it.
多価アルコールの含有量は、毛髪固定力を有すると共に延展性を付与する観点から、組成物中、０．５〜１５重量％とすると良く、１〜１０重量％とするのが好ましい。 The content of the polyhydric alcohol is preferably 0.5 to 15% by weight in the composition and preferably 1 to 10% by weight from the viewpoint of imparting hair fixing ability and imparting ductility.
本発明の毛髪処理剤用組成物は、施術時に容易に混合でき、液垂れが無く、目的の処理部分の毛髪を毛束として固定することができる観点から、粘度を２０，０００ｍＰａ・ｓ以上が好ましく、より好ましくは２５，０００ｍＰａ・ｓとすると良い。また、毛髪上での延展性を保持する観点から、粘度を６０，０００ｍＰａ・ｓ以下が好ましく、より好ましくは５０，０００ｍＰａ・ｓ以下である。これら観点から、毛髪処理剤用組成物の粘度は、２０，０００〜６０，０００ｍＰａ・ｓが好ましく、２５，０００〜５０，０００ｍＰａ・ｓがより好ましい。 The composition for a hair treatment agent of the present invention can be easily mixed at the time of treatment, has no dripping, and has a viscosity of 20,000 mPa · s or more from the viewpoint of fixing the hair of the target treatment portion as a hair bundle. More preferably, it may be 25,000 mPa · s. Further, from the viewpoint of maintaining the extensibility on the hair, the viscosity is preferably 60,000 mPa · s or less, more preferably 50,000 mPa · s or less. From these viewpoints, the viscosity of the composition for a hair treatment agent is preferably 20,000 to 60,000 mPa · s, and more preferably 25,000 to 50,000 mPa · s.
本発明の毛髪処理剤用組成物には、本発明の効果を損なわない範囲内であれば、上記した成分の他に通常用いられる成分、例えば、陽イオン性界面活性剤、低級アルコール、シリコーン類、香料、ｐＨ調整剤、水、アミノ酸、植物抽出液等の添加剤などを適宜、その用途、目的などに応じて配合することができる。 In the composition for hair treatment agent of the present invention, as long as the effects of the present invention are not impaired, components other than those described above, such as cationic surfactants, lower alcohols, silicones, and the like are usually used. Additives such as fragrances, pH adjusters, water, amino acids, plant extracts and the like can be appropriately blended according to their uses and purposes.
かくして得られる本発明の毛髪処理剤用組成物は、毛髪脱色剤、酸化染毛剤、パーマネントウェーブ剤などに用いることができる。毛髪脱色剤として用いる場合、毛髪処理剤用組成物をそのまま一剤式の毛髪脱色剤として用いることができ、多剤式、例えば２剤式の毛髪脱色剤に用いる場合、アルカリ剤を含有する第１剤と共に、毛髪脱色剤の第２剤として用いることができる。また、酸化染毛剤に用いる場合、アルカリ剤と酸化染料を含有する第１剤と共に、酸化染毛剤第２剤として用いることができる。 The hair treatment composition of the present invention thus obtained can be used for hair bleaching agents, oxidative hair dyes, permanent wave agents and the like. When used as a hair bleaching agent, the hair treatment composition can be used as it is as a one-component hair bleaching agent, and when used as a multi-component hair bleaching agent, for example, a two-component hair bleaching agent, Together with one agent, it can be used as a second agent for hair bleaching agent. Moreover, when using for an oxidation hair dye, it can be used as an oxidation hair dye 2nd agent with the 1st agent containing an alkaline agent and an oxidation dye.
第１剤に用いられるアルカリ剤は、一般的な毛髪脱色剤や酸化染毛剤で用いられるものであれば特に限定されず、例えば、アンモニア、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、モノイソプロパノールアミン、２−アミノ−２−メチル−１−プロパノール、炭酸アンモニウム、炭酸水素アンモニウム、炭酸ナトリウムなどが挙げられる。 The alkaline agent used in the first agent is not particularly limited as long as it is used in general hair bleaching agents and oxidative hair dyes. For example, ammonia, monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine 2-amino-2-methyl-1-propanol, ammonium carbonate, ammonium hydrogen carbonate, sodium carbonate and the like.
酸化染毛剤の第１剤には、上記したアルカリ剤の他、酸化染料が含有される。用いられる酸化染料は、一般的な酸化染毛剤で用いられるものであれば特に限定されず、フェニレンジアミン類、アミノフェノール類、ジアミノピリジン類、及びそれらの塩類等が挙げられる。具体的には、ｐ−フェニレンジアミン、トルエン−２，５−ジアミン、ｐ−アミノフェノール、ｏ−アミノフェノール、２，５−ジアミノピリジン等およびそれらの塩類などを例示することができる。また、レゾルシン、ｍ−アミノフェノール、５−アミノ−ｏ−クレゾール、カテコール等およびそれらの塩類などのカップラーも例示することができる。 The first agent of the oxidative hair dye contains an oxidative dye in addition to the alkali agent described above. The oxidation dye used is not particularly limited as long as it is used in a general oxidation hair dye, and examples thereof include phenylenediamines, aminophenols, diaminopyridines, and salts thereof. Specifically, p-phenylenediamine, toluene-2,5-diamine, p-aminophenol, o-aminophenol, 2,5-diaminopyridine and the like and salts thereof can be exemplified. Moreover, couplers, such as resorcinol, m-aminophenol, 5-amino-o-cresol, catechol etc., and those salts, can also be illustrated.
また、本発明の毛髪処理剤用組成物をパーマネントウェーブ剤に用いる場合、還元剤を含有する第１剤と共に、パーマネントウェーブ剤の第２剤として用いることができる。用いられる還元剤としては、一般的なパーマネントウェーブ剤で用いられるものであれば特に限定されず、例えば、チオグリコール酸、Ｌ−システイン、ＤＬ−システイン、Ｎ−アセチルシステイン、メルカプトエタノール、ジチオスレイトール、チオリンゴ酸、チオ乳酸、亜硫酸、亜硫酸水素、チオ硫酸およびそれらの塩類等が挙げられる。 Moreover, when using the composition for hair treatment agents of this invention for a permanent wave agent, it can be used as a 2nd agent of a permanent wave agent with the 1st agent containing a reducing agent. The reducing agent used is not particularly limited as long as it is used in a general permanent wave agent. For example, thioglycolic acid, L-cysteine, DL-cysteine, N-acetylcysteine, mercaptoethanol, dithiothreitol Thiomalic acid, thiolactic acid, sulfurous acid, hydrogen sulfite, thiosulfuric acid and salts thereof.
上記した毛髪脱色剤、酸化染毛剤、およびパーマネントウェーブ剤の第１剤には、本発明の効果を損なわない範囲内であれば、例えば、界面活性剤、高級アルコール、多価アルコール、低級アルコール、シリコーン類、酸化防止剤、香料、防腐・殺菌剤、増粘剤、植物抽出液、ｐＨ調整剤、金属イオン封鎖剤、アミノ酸、水等の添加剤などを適宜、その用途、目的などに応じて配合することができる。 The first agent of the above-described hair bleaching agent, oxidative hair dye, and permanent wave agent may be, for example, a surfactant, a higher alcohol, a polyhydric alcohol, a lower alcohol, as long as the effects of the present invention are not impaired. Additives such as silicones, antioxidants, fragrances, antiseptics / bactericides, thickeners, plant extracts, pH adjusters, sequestering agents, amino acids, water, etc., depending on their use, purpose, etc. Can be blended.
本発明の毛髪処理剤用組成物の使用方法としては、毛髪脱色剤または酸化染毛剤の第２剤として使用する場合、例えば、毛髪脱色剤または酸化染毛剤の第１剤とトレー容器内でヘラや刷毛などを用いて混合後、また、一剤式の毛髪脱色剤として使用する場合はそのままで、櫛、刷毛または手袋をした指先を用いて、脱色若しくは染色したい部位に塗布し、又は髪全体に塗布する。所定時間放置後、十分に洗浄し乾燥すれば良い。また、パーマネントウェーブ剤の第２剤として使用する場合、例えば、パーマネントウェーブ剤の第１剤を毛髪の一部又は全体に塗布し、櫛などにより伸ばして所定時間放置後、十分に水洗する。その後、第２剤を塗布し、櫛などにより伸ばして所定時間放置後、十分に水洗すると良い。 As a method for using the composition for a hair treatment agent of the present invention, when used as a second agent of a hair bleaching agent or an oxidative hair dye, for example, the first agent of a hair bleaching agent or an oxidative hair dye and the inside of a tray container Apply with a fingertip with a comb, brush or glove, and apply to the site you want to decolorize or dye, or use it as a one-part hair bleaching agent after mixing with a spatula or brush. Apply to entire hair. After leaving it for a predetermined time, it may be sufficiently washed and dried. Moreover, when using as a 2nd agent of a permanent wave agent, for example, the 1st agent of a permanent wave agent is apply | coated to a part or all of hair, it stretches with a comb etc., and after leaving for a predetermined time, it fully washes with water. Thereafter, the second agent is applied, stretched with a comb or the like, allowed to stand for a predetermined time, and then sufficiently washed with water.
次に、本発明を実施例に基づいて更に詳細に説明するが、本発明はこれら実施例にのみ限定されるものではない。 EXAMPLES Next, although this invention is demonstrated still in detail based on an Example, this invention is not limited only to these Examples.
〔実施例１〜３および比較例１〜３〕
表１に記載した組成に従い、各成分を常法により混合して毛髪処理剤用組成物を調製し、一剤式の毛髪脱色剤の態様にて下記評価試験に供した。尚、表中、ポリオキシエチレンセチルエーテルは、商品名：ＮＩＫＫＯＬ ＢＣ−４０ＴＸ（日光ケミカルズ社製）を、ポリオキシエチレンステアリルエーテルは、商品名：ＮＩＫＫＯＬ ＢＳ−２０（日光ケミカルズ社製）をそれぞれ用いた。また、表１に記載成分の量は、いずれも「重量％」である。
[Examples 1-3 and Comparative Examples 1-3]
According to the composition described in Table 1, each component was mixed by a conventional method to prepare a composition for a hair treatment agent, and subjected to the following evaluation test in the form of a one-component hair bleaching agent. In the table, for polyoxyethylene cetyl ether, trade name: NIKKOL BC-40TX (manufactured by Nikko Chemicals) is used, and for polyoxyethylene stearyl ether, trade name: NIKKOL BS-20 (manufactured by Nikko Chemicals) is used. It was. In addition, the amounts of the components described in Table 1 are all “wt%”.
（試験例１：製剤の保存安定性評価）
実施例および比較例の各試料を透明ガラス容器に充填し、５０℃で６０日間保存後、組成物の分離の有無を目視により観察した。また、組成物の粘度低下の程度をＢ型粘度計（東機産業株式会社製：ＴＶＢ−２２Ｌ）を用いて保存前後の粘度を測定し、製剤の保存安定性を下記の評価基準に従って評価した。結果を表１に記す。
(Test Example 1: Evaluation of storage stability of the preparation)
Each sample of Examples and Comparative Examples was filled in a transparent glass container and stored at 50 ° C. for 60 days, and then the presence or absence of separation of the composition was visually observed. Further, the degree of viscosity reduction of the composition was measured using a B-type viscometer (manufactured by Toki Sangyo Co., Ltd .: TVB-22L) before and after storage, and the storage stability of the preparation was evaluated according to the following evaluation criteria. . The results are shown in Table 1.
＜分離の有無の評価基準＞
○：分離が認められない。
△：僅かに分離が認められる。
×：分離が認められる。
<Evaluation criteria for the presence or absence of separation>
○: Separation is not recognized.
Δ: Slight separation is observed.
X: Separation is recognized.
＜粘度低下の評価基準＞
○：粘度低下が認められない。
△：僅かに粘度低下が認められる。
×：粘度低下が認められる。
<Evaluation criteria for viscosity reduction>
○: No decrease in viscosity is observed.
Δ: Slight decrease in viscosity is observed.
X: A viscosity fall is recognized.
（試験例２：使用性の評価）
実施例および比較例の各試料を、専門パネル１０名に実際に使用させた。すなわち、人頭毛髪の一部に塗布し、毛髪からの垂れ落ち、および塗布後の毛髪固定力を下記評価基準に従って評価した。結果を表１に記す。
(Test Example 2: Usability evaluation)
Each sample of the examples and comparative examples was actually used by 10 professional panels. That is, it apply | coated to a part of human head hair, the dripping from hair, and the hair fixing power after application | coating were evaluated according to the following evaluation criteria. The results are shown in Table 1.
＜垂れ落ちの評価基準＞
○：１０名中７名以上が垂れ落ちは認めらないと回答
△：１０名中３〜６名が垂れ落ちは認めらないと回答
×：１０名中２名以下が垂れ落ちは認めらないと回答
<Evaluation criteria for dripping>
○: 7 or more out of 10 responded that no sagging was allowed. △: 3 to 6 out of 10 responded that no sagging was accepted. ×: 2 or less of 10 were not sagging. Answer
＜毛髪固定力の評価＞
○：１０名中７名以上が固定力ありと回答
△：１０名中３〜６名が固定力ありと回答
×：１０名中２名以下が固定力ありと回答
<Evaluation of hair fixing power>
○: 7 or more out of 10 responded that they had fixing strength △: 3-6 out of 10 responded that they had fixing strength ×: 2 out of 10 responded that they had fixing strength
表１の結果から、本発明の毛髪処理剤用組成物は、製剤の保存安定性に優れ、施術時においては、毛髪からの垂れ落ちがなく、毛髪固定力にも優れることが分かる。 From the results of Table 1, it can be seen that the composition for hair treatment agent of the present invention is excellent in the storage stability of the preparation, does not sag from the hair during the treatment, and is excellent in hair fixing ability.
〔実施例４：毛髪脱色剤第２剤〕
毛髪処理剤用組成物として、下記処方の毛髪脱色剤第２剤を下記第１剤と共に常法により調製し、二剤式の毛髪脱色剤の態様とした。
（毛髪脱色剤第２剤） 重量％
過酸化水素（３５％） １６．０
セチルアルコール ５．０
ステアリルアルコール １０．０
ポリオキシエチレン（２０）セチルエーテル １．０
モノステアリン酸グリセリル ２．０
塩化ステアリルトリメチルアンモニウム ０．１
プロピレングリコール ２．０
メチルポリシロキサン ０．１
リン酸 ０．０５
精製水 残 量
合計 １００．０
[Example 4: Hair bleaching agent second agent]
As a hair treatment agent composition, a hair bleaching agent second agent having the following formulation was prepared by a conventional method together with the following first agent to obtain an embodiment of a two-component hair bleaching agent.
(Hair depigmenting agent second agent) Weight%
Hydrogen peroxide (35%) 16.0
Cetyl alcohol 5.0
Stearyl alcohol 10.0
Polyoxyethylene (20) cetyl ether 1.0
Glyceryl monostearate 2.0
Stearyltrimethylammonium chloride 0.1
Propylene glycol 2.0
Methyl polysiloxane 0.1
Phosphoric acid 0.05
Total remaining amount of purified water 100.0
（毛髪脱色剤第１剤） 重量％
セチルアルコール ５．０
オレイルアルコール ５．０
ポリオキシエチレン（２０）セチルエーテル ３．０
エデト酸二ナトリウム ０．２
Ｌ−システイン塩酸塩 ０．３
モノイソプロパノールアミン １．０
プロピレングリコール ５．０
メチルポリシロキサン ２．０
香料 ０．２
精製水 残 量
合計 １００．０
(Hair depigmenting agent 1st) Weight%
Cetyl alcohol 5.0
Oleyl alcohol 5.0
Polyoxyethylene (20) cetyl ether 3.0
Edetate disodium 0.2
L-cysteine hydrochloride 0.3
Monoisopropanolamine 1.0
Propylene glycol 5.0
Methylpolysiloxane 2.0
Fragrance 0.2
Total remaining amount of purified water 100.0
上記毛髪脱色剤第２剤を５０℃で６０日間保存しても、系の分離は認められなかった。また、上記第１剤と等量で混合し、人頭毛髪にて部分的に施術した。室温で２０分間放置したが、毛髪からの垂れ落ちはなく、塗布後の毛髪固定力に優れており、施術を施していない周辺の毛髪に触れることはなかった。その後、毛髪を洗浄すると、毛髪は黄褐色の色調に部分的にブリーチされた。 Even when the second hair bleaching agent was stored at 50 ° C. for 60 days, no separation of the system was observed. Moreover, it mixed with the said 1st agent and the same amount, and performed partially with human head hair. Although it was allowed to stand at room temperature for 20 minutes, it did not sag from the hair, had excellent hair fixing strength after application, and did not touch surrounding hair that had not been treated. Thereafter, when the hair was washed, the hair was partially bleached to a tan color.
〔実施例５：酸化染毛剤第２剤〕
毛髪処理剤用組成物として、下記処方の酸化染毛剤第２剤を下記第１剤と共に常法により調製し、二剤式の酸化染毛剤の態様とした。
（酸化染毛剤第２剤） 重量％
過酸化水素（３５％） １６．０
セチルアルコール ６．０
ステアリルアルコール ４．０
ポリオキシエチレン（２０）セチルエーテル ３．０
モノステアリン酸グリセリル ３．０
塩化ステアリルトリメチルアンモニウム ０．１
ジプロピレングリコール ２．０
メチルフェニルポリシロキサン ０．１
リン酸 ０．０５
精製水 残 量
合計 １００．０
[Example 5: Oxidative hair dye second agent]
As a hair treatment composition, an oxidative hair dye second agent having the following formulation was prepared by a conventional method together with the following first agent to obtain a two-component oxidative hair dye embodiment.
(Oxidative hair dye second agent) Weight%
Hydrogen peroxide (35%) 16.0
Cetyl alcohol 6.0
Stearyl alcohol 4.0
Polyoxyethylene (20) cetyl ether 3.0
Glyceryl monostearate 3.0
Stearyltrimethylammonium chloride 0.1
Dipropylene glycol 2.0
Methylphenyl polysiloxane 0.1
Phosphoric acid 0.05
Total remaining amount of purified water 100.0
（酸化染毛剤第１剤） 重量％
セチルアルコール ７．０
塩化セチルトリメチルアンモニウム １．０
ポリオキシエチレン（２０）セチルエーテル ４．０
エデト酸二ナトリウム ０．２
アスコルビン酸 ０．３
アンモニア １．５
ジプロピレングリコール ５．０
メチルフェニルポリシロキサン １．０
ｏ−アミノフェノール ０．３
ｍ−アミノフェノール ０．３
香料 ０．２
精製水 残 量
合計 １００．０
(Oxidative hair dye 1st agent) Weight%
Cetyl alcohol 7.0
Cetyltrimethylammonium chloride 1.0
Polyoxyethylene (20) cetyl ether 4.0
Edetate disodium 0.2
Ascorbic acid 0.3
Ammonia 1.5
Dipropylene glycol 5.0
Methylphenylpolysiloxane 1.0
o-Aminophenol 0.3
m-aminophenol 0.3
Fragrance 0.2
Total remaining amount of purified water 100.0
上記酸化染毛剤第２剤を５０℃で６０日間保存しても、系の分離は認められなかった。また、上記第１剤と等量で混合し、人頭毛髪にて部分的に施術した。室温で２０分間放置したが、毛髪からの垂れ落ちはなく、塗布後の毛髪固定力に優れており、施術を施していない周辺の毛髪に触れることはなかった。その後、毛髪を洗浄すると、毛髪は灰黄緑の色調に部分的に染色された。 Even when the second hair dye agent was stored at 50 ° C. for 60 days, no separation of the system was observed. Moreover, it mixed with the said 1st agent and the same amount, and performed partially with human head hair. Although it was allowed to stand at room temperature for 20 minutes, it did not sag from the hair, had excellent hair fixing strength after application, and did not touch surrounding hair that had not been treated. Thereafter, when the hair was washed, the hair was partially dyed in a grayish yellow green color.
本発明の毛髪処理用組成物は、例えば、毛髪脱色剤、酸化染毛剤、パーマネントウェーブ剤などに好適に用いることができる。
The hair treatment composition of the present invention can be suitably used for, for example, a hair bleaching agent, an oxidative hair dye, a permanent wave agent, and the like.
Claims (5)
（Ａ）セチルアルコール
（Ｂ）ステアリルアルコール
（Ｃ）モノグリセリン脂肪酸エステル
（Ｄ）ポリオキシエチレンアルキルエーテル A hair treatment agent containing hydrogen peroxide, containing the following A to D, the weight content ratio of which is A: B = 1: 4 to 4: 1 and C: D = 1: 6 to 6: 1 Composition.
(A) Cetyl alcohol (B) Stearyl alcohol (C) Monoglycerin fatty acid ester (D) Polyoxyethylene alkyl ether
A hair bleaching agent, an oxidative hair dye, or a permanent wave agent using the composition for a hair treatment agent according to any one of claims 1 to 4.
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| JP2005101500A JP2006282524A (en) | 2005-03-31 | 2005-03-31 | Hair-treating agent composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005101500A JP2006282524A (en) | 2005-03-31 | 2005-03-31 | Hair-treating agent composition |
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| JP2006282524A true JP2006282524A (en) | 2006-10-19 |
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| JP2007217291A (en) * | 2006-02-14 | 2007-08-30 | Kao Corp | Hair dyestuff or hair-bleaching agent composition |
| JP2008137934A (en) * | 2006-12-01 | 2008-06-19 | Milbon Co Ltd | Second hair-dyeing agent composition |
| JP2008143829A (en) * | 2006-12-08 | 2008-06-26 | Mandom Corp | Kit for hair-treating agent |
| WO2009122873A1 (en) * | 2008-03-31 | 2009-10-08 | ホーユー 株式会社 | Oxidant-containing composition |
| JP2010053101A (en) * | 2008-08-29 | 2010-03-11 | Hoyu Co Ltd | Oxidative hair dye agent composition |
| FR2940055A1 (en) * | 2008-12-19 | 2010-06-25 | Oreal | KERATIN FIBER OXIDATION DYEING COMPOSITION COMPRISING PARA-AMINOPHENOL, DIPROPYLENE GLYCOL, AND ADDITIONAL COLOURANT PRECURSOR |
| US7879113B2 (en) | 2008-12-19 | 2011-02-01 | L'oreal S.A. | Composition comprising at least one fatty substance and at least one silicate, dyeing or lightening process using it and devices or kits therefor |
| US7901464B2 (en) | 2007-12-21 | 2011-03-08 | L'oreal S.A. | Process for lightening direct dyeing or oxidation dyeing in the presence of at least one organic amine, device therefor and anhydrous composition |
| US7909887B2 (en) | 2007-12-21 | 2011-03-22 | L'oreal S.A. | Method for dyeing in the presence of at least one oxidizing agent and at least one organic amine, device for use thereof and ready-to-use composition |
| US7909888B2 (en) | 2008-12-19 | 2011-03-22 | L'oreal | Process for dyeing or lightening human keratin fibers using an anhydrous composition and a monoethanolamine/basic amino acid mixture, and suitable device therefor |
| US7914591B2 (en) | 2008-12-19 | 2011-03-29 | L'oreal S.A. | Process for the lightening dyeing of keratin materials using at least one anhydrous dyeing composition comprising at least one alkaline agent and at least one oxidizing composition |
| US7918902B2 (en) | 2008-12-19 | 2011-04-05 | L'oreal S.A. | Process for lightening or process for direct dyeing or oxidation dyeing of keratin fibers in the presence of at least one ammonium salt and device therefor |
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2005
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