CN101341196B - 大孔阳离子交换树脂的制备方法 - Google Patents

大孔阳离子交换树脂的制备方法 Download PDF

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Publication number
CN101341196B
CN101341196B CN2006800479217A CN200680047921A CN101341196B CN 101341196 B CN101341196 B CN 101341196B CN 2006800479217 A CN2006800479217 A CN 2006800479217A CN 200680047921 A CN200680047921 A CN 200680047921A CN 101341196 B CN101341196 B CN 101341196B
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weight
aqueous phase
monomer mixture
cation exchange
monomer
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Expired - Fee Related
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CN2006800479217A
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Chinese (zh)
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CN101341196A (zh
Inventor
杰拉尔德·K·拉斯穆森
罗伯特·T·小菲茨西蒙斯
卡纳安·塞莎德里
西蒙·K·香农
彼得·D·维克特
詹姆斯·I·亨布里
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B01J39/05—Processes using organic exchangers in the strongly acidic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B01J39/07—Processes using organic exchangers in the weakly acidic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/26—Cation exchangers for chromatographic processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • C08F220/585—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36—Amides or imides
    • C08F222/38—Amides
    • C08F222/385—Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Filtering Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
CN2006800479217A 2005-12-21 2006-12-15 大孔阳离子交换树脂的制备方法 Expired - Fee Related CN101341196B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/313,529 2005-12-21
US11/313,529 US7683100B2 (en) 2005-12-21 2005-12-21 Method of making macroporous cation exchange resins
PCT/US2006/048119 WO2007075508A2 (en) 2005-12-21 2006-12-15 Method of making macroporous cation exchange resins

Publications (2)

Publication Number Publication Date
CN101341196A CN101341196A (zh) 2009-01-07
CN101341196B true CN101341196B (zh) 2011-07-27

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Country Link
US (2) US7683100B2 (https=)
EP (1) EP1966287B1 (https=)
JP (1) JP5144535B2 (https=)
CN (1) CN101341196B (https=)
WO (1) WO2007075508A2 (https=)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7098253B2 (en) * 2004-05-20 2006-08-29 3M Innovative Properties Company Macroporous ion exchange resins
WO2006044532A1 (en) * 2004-10-15 2006-04-27 3M Innovative Properties Company Pleated multi-layer filter media and cartridge
US7683100B2 (en) * 2005-12-21 2010-03-23 3M Innovative Properties Company Method of making macroporous cation exchange resins
US7674835B2 (en) * 2005-12-21 2010-03-09 3M Innovative Properties Company Method of making macroporous anion exchange resins
US7674836B2 (en) * 2006-07-28 2010-03-09 3M Innovative Properties Company Method of making macroporous cation exchange resins
US8710111B2 (en) * 2007-11-09 2014-04-29 3M Innovative Properties Company Porous polymeric resins
US8420379B2 (en) * 2008-01-10 2013-04-16 Universal Bio Research Co., Ltd. Material for capturing microbes, device for capturing microbes, method of capturing microbes, and method of producing material for capturing microbes
CN102190753A (zh) * 2010-03-19 2011-09-21 周家付 一种大孔弱酸性阳离子交换树脂的制备方法
JP5814360B2 (ja) 2010-06-25 2015-11-17 スリーエム イノベイティブ プロパティズ カンパニー 半相互貫入ポリマー網状組織
WO2012154314A1 (en) 2011-03-31 2012-11-15 3M Innovative Properties Company Method and device for indicating moisture based on bis (glyoxime) -transition metal complexes
WO2012129735A1 (en) * 2011-04-01 2012-10-04 General Electric Company (A New York Corporation) Electrolysis device and related detergentless washing machine
CN104093754B (zh) 2011-11-21 2017-06-23 3M创新有限公司 用于储存并递送活性剂的聚合物粒子
EP2831576A1 (en) 2012-03-27 2015-02-04 3M Innovative Properties Company Bis(glyoxime)-transition metal colorimetric moisture indicators
CN103387629B (zh) * 2012-05-07 2015-09-09 江苏苏青水处理工程集团有限公司 一种双孔道大孔结构的高强度离子交换树及其脂制备方法
WO2014078512A1 (en) 2012-11-14 2014-05-22 3M Innovative Properties Company Adjustable colorimetric moisture indicators
EP2972302A4 (en) 2013-03-15 2017-04-12 3M Innovative Properties Company Post-steam sterilization moisture-indicating articles
CN103252220B (zh) * 2013-05-28 2015-08-05 西南科技大学 锆/大孔强酸性苯乙烯系树脂复合材料及其制备
EP3052556B1 (en) 2013-10-03 2021-01-20 3M Innovative Properties Company Ligand-functionalized substrates with enhanced binding capacity
US10413881B2 (en) 2013-12-18 2019-09-17 3M Innovative Properties Company Porous articles for separation
WO2016053875A1 (en) 2014-10-01 2016-04-07 3M Innovative Properties Company Medical dressings comprising fluid management articles and methods of using same
WO2016053830A1 (en) 2014-10-01 2016-04-07 3M Innovative Properties Company Articles including fibrous substrates and porous polymeric particles and methods of making same
KR102528690B1 (ko) 2015-03-06 2023-05-08 쓰리엠 이노베이티브 프로퍼티즈 캄파니 다공성 중합체 입자를 포함하는 조성물 및 접착 용품 및 기재를 코팅하는 방법
US20180057770A1 (en) 2015-03-23 2018-03-01 3M Innovative Properties Company Polymeric composite particles
US20190194250A1 (en) 2016-09-09 2019-06-27 3M Innovative Properties Company Processes for separating aggregated proteins from monomeric proteins in a biological solution
US11446613B2 (en) 2016-09-09 2022-09-20 3M Innovative Properties Company Functionalized copolymers and use thereof
CN109718869B (zh) * 2017-10-31 2022-05-27 罗门哈斯电子材料有限责任公司 离子交换树脂、纯化方法和制备离子树脂的方法
WO2019213040A1 (en) * 2018-04-30 2019-11-07 Nitto Denko Corporation Affinity polymers and methods for reducing purine levels in complex mixtures
CN114729084B (zh) 2019-11-25 2023-09-15 3M创新有限公司 含生物素的单体及由其形成的制品
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JP7477641B2 (ja) * 2020-11-10 2024-05-01 オルガノ株式会社 テトラアルキルアンモニウムイオンを含有する被処理液の精製方法および精製装置
CN112588272B (zh) * 2020-11-23 2023-01-24 扬州工业职业技术学院 一种黄酮类物质吸附剂及其制备方法
WO2024134480A1 (en) 2022-12-21 2024-06-27 3M Innovative Properties Company Heterocyclic acrylic acid derivatives as monomers for the synthesis of polymers for use in ion exchange articles

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037858A (en) * 1990-06-21 1991-08-06 Ionics, Incorporated Anion selective polymers prepared from concentrated solutions of N,N'-methylenebisacrylamide
CN1151334A (zh) * 1995-12-02 1997-06-11 中国石化齐鲁石油化工公司 大孔强酸型阳离子交换树脂催化剂的制备方法
US20030088134A1 (en) * 2001-07-26 2003-05-08 Veli-Matti Purola Fuel components and their selective manufacturing methods
US20050261384A1 (en) * 2004-05-20 2005-11-24 3M Innovative Properties Company Macroporous ion exchange resins

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2527300A (en) * 1948-03-18 1950-10-24 American Cyanamid Co Copolymers of unsaturated sulfonic acids and polyunsaturated compounds
US3058594A (en) * 1960-06-06 1962-10-16 Purolator Products Inc Pleated paper filter
CS171962B1 (https=) * 1974-02-01 1976-11-29
CS177507B1 (https=) * 1974-02-12 1977-07-29
US3929741A (en) * 1974-07-16 1975-12-30 Datascope Corp Hydrophilic acrylamido polymers
US4071508A (en) * 1975-02-11 1978-01-31 Plastomedical Sciences, Inc. Anionic hydrogels based on hydroxyalkyl acrylates and methacrylates
US4134815A (en) * 1976-05-31 1979-01-16 Ici Australia Limited Amphoteric composite resins and method of preparing same by polymerization of a two-phase dispersion of monomers
US4153661A (en) * 1977-08-25 1979-05-08 Minnesota Mining And Manufacturing Company Method of making polytetrafluoroethylene composite sheet
JPS54100489A (en) * 1978-01-26 1979-08-08 Asahi Chem Ind Co Ltd New basic crosslinked copolymer and its preparation
US4157418A (en) * 1978-02-08 1979-06-05 Minnesota Mining And Manufacturing Company Acrylic functional aminocarboxylic acids and derivatives as components of pressure sensitive adhesives
FR2482112B1 (fr) 1980-05-09 1985-06-07 Pharmindustrie Nouveaux copolymeres hydrophiles a base de n-(tris (hydroxymethyl) methyl) acrylamide, procedes pour leur preparation, gels aqueux desdits copolymeres et leur utilisation comme echangeurs d'ions
JPS57158209A (en) * 1981-03-25 1982-09-30 Kao Corp Production of bead-form highly water-absorbing polymer
US4565663A (en) * 1981-06-26 1986-01-21 Minnesota Mining And Manufacturing Company Method for making water-swellable composite sheet
US4439545A (en) 1981-11-19 1984-03-27 Societe D "Expansion Scientifique "Expansia" Acrylic copolymers of N-acryloylpolymethyleneimines or N-acryloyldialkylamides, N,N'-acryloyldiaminoalcanes and N-acryloylaminoacids (or esters) their preparation and use as cation exchangers
US4552939A (en) * 1983-12-19 1985-11-12 Exxon Research And Engineering Co. Preparation of sulfonated copolymers by suspension copolymerization
US4833198A (en) * 1985-07-22 1989-05-23 The Dow Chemical Company Suspending agent for the suspension polymerization of water-soluble monomers
US5336742A (en) * 1987-03-13 1994-08-09 Minnesota Mining And Manufacturing Company Polymeric supports
US4842739A (en) * 1987-08-20 1989-06-27 Minnesota Mining And Manufacturing Company High surface area filter cartridge
US4810381A (en) * 1987-12-28 1989-03-07 Minnesota Mining And Manufacturing Company Composite chromatographic article
US4971736A (en) * 1987-12-28 1990-11-20 Minnesota Mining And Manufacturing Company Method of preparing composite chromatographic article
US6323249B1 (en) * 1988-09-26 2001-11-27 Purolite International, Ltd. Macroporous resins having large pores but with high crush strength
US4957943A (en) * 1988-10-14 1990-09-18 Minnesota Mining And Manufacturing Company Particle-filled microporous materials
US5264125A (en) * 1989-09-08 1993-11-23 Ionics' Incorporated Process for manufacturing continuous supported ion selective membranes using non-polymerizable high boiling point solvents
US5171808A (en) * 1990-06-11 1992-12-15 American Cyanamid Company Cross-linked anionic and amphoteric polymeric microparticles
US5104729A (en) * 1990-08-20 1992-04-14 Monsanto Company Process for surface modifying a support membrane and product produced
US5993935A (en) * 1991-10-11 1999-11-30 3M Innovative Properties Company Covalently reactive particles incorporated in a continous porous matrix
JP3301628B2 (ja) 1992-03-06 2002-07-15 日立化成工業株式会社 りん酸基を有する陽イオン交換樹脂及びその製造法
US5906734A (en) * 1992-06-19 1999-05-25 Biosepra Inc. Passivated porous polymer supports and methods for the preparation and use of same
WO1994000214A1 (en) 1992-06-19 1994-01-06 Sepracor Inc. Passivated and stabilized porous supports and methods for the preparation and use of same
JPH06228216A (ja) * 1993-02-03 1994-08-16 Dainippon Ink & Chem Inc ｐＨ応答性多孔質重合体の製造方法
JPH06228215A (ja) * 1993-02-03 1994-08-16 Dainippon Ink & Chem Inc 感温性多孔質重合体の製造方法
US5468847A (en) * 1994-03-10 1995-11-21 Minnesota Mining And Manufacturing Company Method of isolating and purifying a biomacromolecule
US5561097A (en) * 1994-04-28 1996-10-01 Minnesota Mining And Manufacturing Company Method of controlling density of ligand coupled onto supports and products produced therefrom
FR2722097B1 (fr) * 1994-07-11 1997-05-16 Oreal Composition cosmetique et/ou dermatologique gelifiee, riche en solvant et contenant des particules creuses, ses application
US5906747A (en) * 1995-11-13 1999-05-25 Biosepra Inc. Separation of molecules from dilute solutions using composite chromatography media having high dynamic sorptive capacity at high flow rates
US6059975A (en) * 1997-09-02 2000-05-09 Lockheed Martin Energy Research Corporation Bifunctional anion-exchange resins with improved selectivity and exchange kinetics
DE19907023A1 (de) 1999-02-19 2000-08-24 Bayer Ag Verfahren zur Isolierung von Nucleinsäuren
US6423666B1 (en) * 1999-10-05 2002-07-23 Bio-Rad Laboratories, Inc. Large-pore chromatographic beads prepared by suspension polymerization
DE19959264A1 (de) * 1999-12-03 2001-07-12 Elipsa Gmbh Templat-geprägte Kompositmaterialien mit hoher Bindungsspezifität und Selektivität, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10009982A1 (de) 2000-03-03 2001-09-06 Qiagen Gmbh Polymere Anionenaustauscher und deren Verwendung in chromatographischen Verfahren
WO2002000337A1 (en) 2000-06-27 2002-01-03 Bia Separations D.O.O. A chromatography material and a process of manufacturing that material
DE10033583A1 (de) * 2000-07-11 2002-01-24 Bayer Ag Superparamagnetische Perlpolymerisate
JP2004517980A (ja) * 2000-09-21 2004-06-17 ローム　アンド　ハース　カンパニー 極性モノマーと多価カチオンとに関わる方法および組成物
US6783838B2 (en) 2001-04-30 2004-08-31 3M Innovative Properties Company Coated film laminate having an ionic surface
FR2824734B1 (fr) * 2001-05-16 2003-06-27 Oreal Composition pulverulente pour la decoloration des fibres keratiniques humaines
US6756462B2 (en) * 2001-07-03 2004-06-29 Rohm And Haas Company Method for preparation of anion exchange resins
US20060070950A1 (en) * 2004-10-01 2006-04-06 3M Innovative Properties Company Composite filtration article
US7674835B2 (en) 2005-12-21 2010-03-09 3M Innovative Properties Company Method of making macroporous anion exchange resins
US7683100B2 (en) 2005-12-21 2010-03-23 3M Innovative Properties Company Method of making macroporous cation exchange resins
US7674836B2 (en) * 2006-07-28 2010-03-09 3M Innovative Properties Company Method of making macroporous cation exchange resins

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037858A (en) * 1990-06-21 1991-08-06 Ionics, Incorporated Anion selective polymers prepared from concentrated solutions of N,N'-methylenebisacrylamide
CN1151334A (zh) * 1995-12-02 1997-06-11 中国石化齐鲁石油化工公司 大孔强酸型阳离子交换树脂催化剂的制备方法
US20030088134A1 (en) * 2001-07-26 2003-05-08 Veli-Matti Purola Fuel components and their selective manufacturing methods
US20050261384A1 (en) * 2004-05-20 2005-11-24 3M Innovative Properties Company Macroporous ion exchange resins
US20050261385A1 (en) * 2004-05-20 2005-11-24 3M Innovative Properties Company Macroporous ion exchange resins

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开平5-247123A 1993.09.24

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Publication number Publication date
CN101341196A (zh) 2009-01-07
EP1966287B1 (en) 2014-01-22
US8338496B2 (en) 2012-12-25
EP1966287A4 (en) 2011-09-14
WO2007075508A3 (en) 2007-08-16
US20100112664A1 (en) 2010-05-06
US20070142586A1 (en) 2007-06-21
EP1966287A2 (en) 2008-09-10
JP5144535B2 (ja) 2013-02-13
WO2007075508A2 (en) 2007-07-05
JP2009521556A (ja) 2009-06-04
US7683100B2 (en) 2010-03-23

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