CN101326220B - 增强的离子传导膜 - Google Patents

增强的离子传导膜 Download PDF

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Publication number
CN101326220B
CN101326220B CN2006800464419A CN200680046441A CN101326220B CN 101326220 B CN101326220 B CN 101326220B CN 2006800464419 A CN2006800464419 A CN 2006800464419A CN 200680046441 A CN200680046441 A CN 200680046441A CN 101326220 B CN101326220 B CN 101326220B
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ionomer
layer
ion
substrate
membrane
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Expired - Fee Related
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Chinese (zh)
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CN101326220A (zh
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伊利斯·哈吉罗姆哈恩
斯科特·L·斯利斯科
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/00091—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching by evaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0013—Casting processes
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0016—Coagulation
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    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
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    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
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    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
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    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
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    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/1062—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the physical properties of the porous support, e.g. its porosity or thickness
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    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
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    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2323/60—Co-casting; Co-extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2325/42—Ion-exchange membranes
    • C—CHEMISTRY; METALLURGY
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    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
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    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/24996—With internal element bridging layers, nonplanar interface between layers, or intermediate layer of commingled adjacent foam layers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)
  • Conductive Materials (AREA)
CN2006800464419A 2005-12-07 2006-11-27 增强的离子传导膜 Expired - Fee Related CN101326220B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/295,764 US20070128425A1 (en) 2005-12-07 2005-12-07 Reinforced ion-conductive membranes
US11/295,764 2005-12-07
PCT/US2006/045481 WO2007067385A1 (en) 2005-12-07 2006-11-27 Reinforced ion-conductive membranes

Publications (2)

Publication Number Publication Date
CN101326220A CN101326220A (zh) 2008-12-17
CN101326220B true CN101326220B (zh) 2013-03-27

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CN2006800464419A Expired - Fee Related CN101326220B (zh) 2005-12-07 2006-11-27 增强的离子传导膜

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US (2) US20070128425A1 (enExample)
EP (1) EP1957567B1 (enExample)
JP (1) JP5129152B2 (enExample)
CN (1) CN101326220B (enExample)
WO (1) WO2007067385A1 (enExample)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7842214B2 (en) 2007-03-28 2010-11-30 3M Innovative Properties Company Process for forming microporous membranes
JP5324070B2 (ja) * 2007-08-27 2013-10-23 スリーエム イノベイティブ プロパティズ カンパニー 高分子ゲル構造体及びその製造方法
KR101000214B1 (ko) * 2008-05-28 2010-12-10 주식회사 엘지화학 이온전도성 수지 파이버, 이온전도성 복합막, 막-전극 접합체 및 연료전지
CN103004001B (zh) * 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜
EP2684239B1 (en) 2011-03-11 2025-01-01 Audi AG Unitized electrode assembly with high equivalent weight ionomer
US8709199B2 (en) * 2011-09-13 2014-04-29 GM Global Technology Operations LLC Method of preparing a water vapor transfer membrane
CN103907231B (zh) * 2011-11-04 2016-08-24 丰田自动车株式会社 燃料电池用膜-电极接合体
GB201212229D0 (en) 2012-07-10 2012-08-22 Johnson Matthey Plc Ion-conducting membrance
JP6165878B2 (ja) 2012-12-21 2017-07-19 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ 電解質膜、分散体、および分散方法
JP2016507611A (ja) 2012-12-21 2016-03-10 トヨタ自動車株式会社 プロトン交換材料およびその製造方法
WO2014098907A1 (en) 2012-12-21 2014-06-26 Utc Power Corporation Method of fabricating an electrolyte material
US20140261981A1 (en) * 2013-03-15 2014-09-18 GM Global Technology Operations LLC Cathode composite structure and methods thereof for improved fuel cell performance under high humidity
EP2842620A1 (en) * 2013-08-26 2015-03-04 Agfa-Gevaert A method for preparing a composite membrane
KR20150097024A (ko) * 2014-02-17 2015-08-26 삼성에스디아이 주식회사 고분자 전해질막, 이를 포함하는 막전극 접합체 및 연료전지
CN107004880B (zh) 2014-12-04 2020-07-28 株式会社Lg化学 聚合物电解质膜
EP3228613B1 (en) 2014-12-04 2020-06-17 LG Chem, Ltd. Halogenated compound, polymer comprising same, and polymer electrolyte membrane comprising same
KR20160067720A (ko) 2014-12-04 2016-06-14 주식회사 엘지화학 중합체 및 이를 포함하는 고분자 전해질막
WO2016089156A2 (ko) * 2014-12-04 2016-06-09 주식회사 엘지화학 중합체 및 이를 포함하는 고분자 전해질막
US20160248113A1 (en) * 2015-02-20 2016-08-25 The Board Of Trustees Of The Leland Stanford Junior University Semi-Interpenetrating Network Method for Dimensionally Stabilizing Highly Charged Polyelectrolyte Membranes
WO2016149365A1 (en) 2015-03-16 2016-09-22 Calera Corporation Ion exchange membranes, electrochemical systems, and methods
WO2017004496A1 (en) * 2015-07-01 2017-01-05 3M Innovative Properties Company Polymeric ionomer separation membranes and methods of use
EP3316997A1 (en) 2015-07-01 2018-05-09 3M Innovative Properties Company Pvp- and/or pvl-containing composite membranes and methods of use
WO2017004495A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use
CN108290807B (zh) 2015-10-28 2021-07-16 卡勒拉公司 电化学、卤化和氧卤化的系统及方法
GB201609320D0 (en) * 2016-05-26 2016-07-13 Johnson Matthey Fuel Cells Ltd Membrane and process
KR102248538B1 (ko) 2018-05-17 2021-05-04 주식회사 엘지화학 이온 교환 분리막 및 이를 포함하는 흐름전지
US11715839B2 (en) 2018-07-27 2023-08-01 W. L. Gore & Associates, Inc. Integral composite membrane with a continuous ionomer phase
GB202015379D0 (en) * 2020-09-29 2020-11-11 Fujifilm Mfg Europe Bv Membranes
GB202113809D0 (en) * 2021-09-28 2021-11-10 Johnson Matthey Plc Catalyst coated proton exchange membranes for green hydrogen producing water electrolysers
CN116722167B (zh) * 2023-08-10 2024-01-26 液流储能科技有限公司 一种有机/无机氧化还原液流电池用离子传导薄膜及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
CN1675292A (zh) * 2002-08-21 2005-09-28 3M创新有限公司 制备多层质子交换膜的方法和薄膜电极组件

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4865930A (en) * 1988-10-27 1989-09-12 Hughes Aircraft Company Method for forming a gas-permeable and ion-permeable membrane
US5094895A (en) * 1989-04-28 1992-03-10 Branca Phillip A Composite, porous diaphragm
US5795668A (en) * 1994-11-10 1998-08-18 E. I. Du Pont De Nemours And Company Fuel cell incorporating a reinforced membrane
US6054230A (en) * 1994-12-07 2000-04-25 Japan Gore-Tex, Inc. Ion exchange and electrode assembly for an electrochemical cell
US5654109A (en) * 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
US6248469B1 (en) * 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US6890677B2 (en) * 1999-05-06 2005-05-10 Sandia Corporation Fuel cell and membrane
EP1268619A2 (en) * 2000-03-22 2003-01-02 Victrex Manufacturing Limited Composite ion exchange material
US7229665B2 (en) * 2001-05-22 2007-06-12 Millipore Corporation Process of forming multilayered structures
US6736971B2 (en) * 2000-08-07 2004-05-18 Cuno Incorporated Pre-metered, unsupported multilayer microporous membrane
JP2005507012A (ja) * 2001-10-15 2005-03-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー メタノール透過度を減少させるためにその中にポリアミンが吸収された燃料電池用固体ポリマー膜
US7649025B2 (en) * 2002-10-17 2010-01-19 Toyo Boseki Kabushiki Kaisha Composite ion-exchange membrane
JP2004139836A (ja) * 2002-10-17 2004-05-13 Toyobo Co Ltd 複合イオン交換膜
US6737158B1 (en) * 2002-10-30 2004-05-18 Gore Enterprise Holdings, Inc. Porous polymeric membrane toughened composites
CA2452041A1 (en) * 2002-12-04 2004-06-04 Ballard Power Systems Inc. Application of an ionomer layer to a substrate and products related thereto
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US20040157101A1 (en) * 2003-02-11 2004-08-12 Smedley Stuart I. Fuel cell electrode assembly
JP2004259593A (ja) * 2003-02-26 2004-09-16 Mitsubishi Chemicals Corp イオン伝導体用多孔質材料及びイオン伝導体、並びに燃料電池
JP2005036055A (ja) * 2003-07-17 2005-02-10 Toyobo Co Ltd ポリベンザゾール複合体およびその製造方法
JP2005050561A (ja) * 2003-07-29 2005-02-24 Toyobo Co Ltd 複合イオン交換膜
EP1661198A2 (en) * 2003-08-19 2006-05-31 E.I. Dupont De Nemours And Company Membranes of fluorinated ionomer blended with nonionomeric fluoropolymers for electrochemical cells
US7338692B2 (en) * 2003-09-12 2008-03-04 3M Innovative Properties Company Microporous PVDF films

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
CN1675292A (zh) * 2002-08-21 2005-09-28 3M创新有限公司 制备多层质子交换膜的方法和薄膜电极组件

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