CN101326220B - 增强的离子传导膜 - Google Patents

增强的离子传导膜 Download PDF

Info

Publication number
CN101326220B
CN101326220B CN2006800464419A CN200680046441A CN101326220B CN 101326220 B CN101326220 B CN 101326220B CN 2006800464419 A CN2006800464419 A CN 2006800464419A CN 200680046441 A CN200680046441 A CN 200680046441A CN 101326220 B CN101326220 B CN 101326220B
Authority
CN
China
Prior art keywords
ionomer
layer
ion
substrate
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800464419A
Other languages
English (en)
Chinese (zh)
Other versions
CN101326220A (zh
Inventor
伊利斯·哈吉罗姆哈恩
斯科特·L·斯利斯科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN101326220A publication Critical patent/CN101326220A/zh
Application granted granted Critical
Publication of CN101326220B publication Critical patent/CN101326220B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/00091—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching by evaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0013—Casting processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0016—Coagulation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/14—Dynamic membranes
    • B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
    • B01D69/1411—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes containing dispersed material in a continuous matrix
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275—Heterogeneous membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1048—Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1053—Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/1062—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the physical properties of the porous support, e.g. its porosity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/60—Co-casting; Co-extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/14—Membrane materials having negatively charged functional groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/26—Electrical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/42—Ion-exchange membranes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0094—Composites in the form of layered products, e.g. coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/24996—With internal element bridging layers, nonplanar interface between layers, or intermediate layer of commingled adjacent foam layers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)
  • Conductive Materials (AREA)
CN2006800464419A 2005-12-07 2006-11-27 增强的离子传导膜 Expired - Fee Related CN101326220B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/295,764 2005-12-07
US11/295,764 US20070128425A1 (en) 2005-12-07 2005-12-07 Reinforced ion-conductive membranes
PCT/US2006/045481 WO2007067385A1 (en) 2005-12-07 2006-11-27 Reinforced ion-conductive membranes

Publications (2)

Publication Number Publication Date
CN101326220A CN101326220A (zh) 2008-12-17
CN101326220B true CN101326220B (zh) 2013-03-27

Family

ID=38119121

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800464419A Expired - Fee Related CN101326220B (zh) 2005-12-07 2006-11-27 增强的离子传导膜

Country Status (5)

Country Link
US (2) US20070128425A1 (enExample)
EP (1) EP1957567B1 (enExample)
JP (1) JP5129152B2 (enExample)
CN (1) CN101326220B (enExample)
WO (1) WO2007067385A1 (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7842214B2 (en) 2007-03-28 2010-11-30 3M Innovative Properties Company Process for forming microporous membranes
JP5324070B2 (ja) * 2007-08-27 2013-10-23 スリーエム イノベイティブ プロパティズ カンパニー 高分子ゲル構造体及びその製造方法
KR101000214B1 (ko) * 2008-05-28 2010-12-10 주식회사 엘지화학 이온전도성 수지 파이버, 이온전도성 복합막, 막-전극 접합체 및 연료전지
WO2011149732A2 (en) * 2010-05-25 2011-12-01 3M Innovative Properties Company Reinforced electrolyte membrane
US10505197B2 (en) 2011-03-11 2019-12-10 Audi Ag Unitized electrode assembly with high equivalent weight ionomer
US8709199B2 (en) * 2011-09-13 2014-04-29 GM Global Technology Operations LLC Method of preparing a water vapor transfer membrane
KR101617253B1 (ko) * 2011-11-04 2016-05-02 도요타 지도샤（주） 연료 전지용 막·전극 접합체
GB201212229D0 (en) * 2012-07-10 2012-08-22 Johnson Matthey Plc Ion-conducting membrance
JP6165878B2 (ja) 2012-12-21 2017-07-19 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ 電解質膜、分散体、および分散方法
EP2956979B1 (en) 2012-12-21 2019-02-20 Toyota Jidosha Kabushiki Kaisha Proton exchange material and method therefor
JP6185079B2 (ja) 2012-12-21 2017-08-23 アウディ アクチェンゲゼルシャフトＡｕｄｉ Ａｇ 電解質材料の製造方法
US20140261981A1 (en) * 2013-03-15 2014-09-18 GM Global Technology Operations LLC Cathode composite structure and methods thereof for improved fuel cell performance under high humidity
EP2842620A1 (en) * 2013-08-26 2015-03-04 Agfa-Gevaert A method for preparing a composite membrane
KR20150097024A (ko) * 2014-02-17 2015-08-26 삼성에스디아이 주식회사 고분자 전해질막, 이를 포함하는 막전극 접합체 및 연료전지
KR20160067720A (ko) * 2014-12-04 2016-06-14 주식회사 엘지화학 중합체 및 이를 포함하는 고분자 전해질막
US10407521B2 (en) * 2014-12-04 2019-09-10 Lg Chem, Ltd. Polymer and polymer electrolyte membrane comprising same
WO2016089155A1 (ko) 2014-12-04 2016-06-09 주식회사 엘지화학 고분자 전해질막
KR101991430B1 (ko) 2014-12-04 2019-06-20 주식회사 엘지화학 할로겐화 화합물, 이를 포함하는 중합체 및 이를 포함하는 고분자 전해질막
US20160248113A1 (en) * 2015-02-20 2016-08-25 The Board Of Trustees Of The Leland Stanford Junior University Semi-Interpenetrating Network Method for Dimensionally Stabilizing Highly Charged Polyelectrolyte Membranes
JP2018513912A (ja) 2015-03-16 2018-05-31 カレラ コーポレイション イオン交換膜、電気化学システムおよび方法
US10478778B2 (en) 2015-07-01 2019-11-19 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use
WO2017004492A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Pvp- and/or pvl-containing composite membranes and methods of use
CN107921370B (zh) 2015-07-01 2022-03-29 3M创新有限公司 聚合离聚物分离膜及其使用方法
WO2017075443A1 (en) 2015-10-28 2017-05-04 Calera Corporation Electrochemical, halogenation, and oxyhalogenation systems and methods
GB201609320D0 (en) * 2016-05-26 2016-07-13 Johnson Matthey Fuel Cells Ltd Membrane and process
KR102248538B1 (ko) * 2018-05-17 2021-05-04 주식회사 엘지화학 이온 교환 분리막 및 이를 포함하는 흐름전지
WO2020023057A1 (en) * 2018-07-27 2020-01-30 W. L. Gore & Associates, Inc. Integral composite membrane with a continuous ionomer phase
GB202113809D0 (en) * 2021-09-28 2021-11-10 Johnson Matthey Plc Catalyst coated proton exchange membranes for green hydrogen producing water electrolysers
CN116722167B (zh) * 2023-08-10 2024-01-26 液流储能科技有限公司 一种有机/无机氧化还原液流电池用离子传导薄膜及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
CN1675292A (zh) * 2002-08-21 2005-09-28 3M创新有限公司 制备多层质子交换膜的方法和薄膜电极组件

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4865930A (en) * 1988-10-27 1989-09-12 Hughes Aircraft Company Method for forming a gas-permeable and ion-permeable membrane
US5094895A (en) * 1989-04-28 1992-03-10 Branca Phillip A Composite, porous diaphragm
US5795668A (en) * 1994-11-10 1998-08-18 E. I. Du Pont De Nemours And Company Fuel cell incorporating a reinforced membrane
US6054230A (en) * 1994-12-07 2000-04-25 Japan Gore-Tex, Inc. Ion exchange and electrode assembly for an electrochemical cell
US5654109A (en) * 1995-06-30 1997-08-05 The Dow Chemical Company Composite fuel cell membranes
US6248469B1 (en) * 1997-08-29 2001-06-19 Foster-Miller, Inc. Composite solid polymer electrolyte membranes
US6890677B2 (en) * 1999-05-06 2005-05-10 Sandia Corporation Fuel cell and membrane
EP1268619A2 (en) * 2000-03-22 2003-01-02 Victrex Manufacturing Limited Composite ion exchange material
US7229665B2 (en) * 2001-05-22 2007-06-12 Millipore Corporation Process of forming multilayered structures
US6736971B2 (en) * 2000-08-07 2004-05-18 Cuno Incorporated Pre-metered, unsupported multilayer microporous membrane
TW587351B (en) * 2001-10-15 2004-05-11 Du Pont Fuel cell membranes
JP2004139836A (ja) * 2002-10-17 2004-05-13 Toyobo Co Ltd 複合イオン交換膜
US7649025B2 (en) * 2002-10-17 2010-01-19 Toyo Boseki Kabushiki Kaisha Composite ion-exchange membrane
US6737158B1 (en) * 2002-10-30 2004-05-18 Gore Enterprise Holdings, Inc. Porous polymeric membrane toughened composites
US6867159B2 (en) * 2002-12-04 2005-03-15 Ballard Power Systems Inc. Application of an ionomer layer to a substrate and products related thereto
US6624328B1 (en) * 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7348088B2 (en) * 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
US20040157101A1 (en) * 2003-02-11 2004-08-12 Smedley Stuart I. Fuel cell electrode assembly
JP2004259593A (ja) * 2003-02-26 2004-09-16 Mitsubishi Chemicals Corp イオン伝導体用多孔質材料及びイオン伝導体、並びに燃料電池
JP2005036055A (ja) * 2003-07-17 2005-02-10 Toyobo Co Ltd ポリベンザゾール複合体およびその製造方法
JP2005050561A (ja) * 2003-07-29 2005-02-24 Toyobo Co Ltd 複合イオン交換膜
JP2007503098A (ja) * 2003-08-19 2007-02-15 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 電気化学電池のための、非イオノマーフルオロポリマーとブレンドされたフッ素化イオノマーの膜
US7338692B2 (en) * 2003-09-12 2008-03-04 3M Innovative Properties Company Microporous PVDF films

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6277512B1 (en) * 1999-06-18 2001-08-21 3M Innovative Properties Company Polymer electrolyte membranes from mixed dispersions
CN1675292A (zh) * 2002-08-21 2005-09-28 3M创新有限公司 制备多层质子交换膜的方法和薄膜电极组件

Also Published As

Publication number Publication date
US20070128425A1 (en) 2007-06-07
EP1957567B1 (en) 2016-08-24
US20090123641A1 (en) 2009-05-14
US7906052B2 (en) 2011-03-15
WO2007067385A1 (en) 2007-06-14
EP1957567A1 (en) 2008-08-20
JP2009518206A (ja) 2009-05-07
EP1957567A4 (en) 2012-03-07
JP5129152B2 (ja) 2013-01-23
CN101326220A (zh) 2008-12-17

Similar Documents

Publication Publication Date Title
CN101326220B (zh) 增强的离子传导膜
US11380927B2 (en) Highly reinforced ionomer membranes for high selectivity and high strength
EP3185345A2 (en) Reinforced composite membranes and method for manufacturing the same
CN104247118A (zh) 聚合物电解质膜及其制造方法以及包含该聚合物电解质膜的膜电极组件
KR102140121B1 (ko) 다공성 기재를 포함하는 강화-복합 전해질막 및 이의 제조방법
CN105009341A (zh) 具有包含离聚物的隔膜的液流电池
KR101315744B1 (ko) 고체 고분자 전해질형 연료전지용 다층 강화 복합전해질 막, 그 제조방법, 그 막을 구비한 막-전극 어셈블리 및 연료전지
JP6502500B2 (ja) イオン伝導体の充填特性に優れた多孔性支持体、その製造方法及びそれを含む強化膜
JP2022142731A (ja) 高分子電解質膜およびこれを含む燃料電池
US20240429418A1 (en) Method of manufacturing an ion-conducting membrane
US10186720B2 (en) Membrane-seal assembly
US20140134506A1 (en) Proton Exchange Membrane
JP2023500598A (ja) 高分子電解質膜、それを含む膜－電極アセンブリ及び燃料電池
KR20140118914A (ko) 고분자 전해질막, 이의 제조 방법 및 이를 포함하는 막-전극 어셈블리
JP2006073235A (ja) 積層電解質膜およびその製造方法
US20190259509A1 (en) Ion exchange membrane and method of producing same, membrane electrode assembly, and redox flow battery
JP2019517111A (ja) 膜及び方法
JP2006269266A (ja) 補強材を有する複合高分子固体電解質膜
KR102811032B1 (ko) 고도로 정렬된 이온 채널을 가지는 과불소계 이오노머 멤브레인의 제조방법 및 이의 활용
US20220293989A1 (en) Highly reinforced ionomer membranes for high selectivity and high strength
KR20200056069A (ko) 다층 강화 분리막, 이의 제조방법 및 이를 포함하는 전지
JPS62254363A (ja) 燃料電池
JP6878412B2 (ja) 補強した膜シールアセンブリを作成するためのプロセスおよび燃料電池用の膜シールアセンブリ
WO2014112497A1 (ja) 複合高分子電解質膜およびその製造方法ならびに膜電極接合体、燃料電池

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130327

Termination date: 20171127

CF01 Termination of patent right due to non-payment of annual fee