CN101223228B - 制备含氟聚合物的水性方法 - Google Patents

制备含氟聚合物的水性方法 Download PDF

Info

Publication number
CN101223228B
CN101223228B CN2006800207481A CN200680020748A CN101223228B CN 101223228 B CN101223228 B CN 101223228B CN 2006800207481 A CN2006800207481 A CN 2006800207481A CN 200680020748 A CN200680020748 A CN 200680020748A CN 101223228 B CN101223228 B CN 101223228B
Authority
CN
China
Prior art keywords
polyethylene glycol
emulsifier
polypropylene glycol
glycol
mole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2006800207481A
Other languages
English (en)
Chinese (zh)
Other versions
CN101223228A (zh
Inventor
R·阿明一萨纳伊
C·B·欧姆斯泰德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema Inc
Original Assignee
Arkema Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema Inc filed Critical Arkema Inc
Publication of CN101223228A publication Critical patent/CN101223228A/zh
Application granted granted Critical
Publication of CN101223228B publication Critical patent/CN101223228B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN2006800207481A 2005-06-10 2006-05-23 制备含氟聚合物的水性方法 Active CN101223228B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/149,797 US20060281845A1 (en) 2005-06-10 2005-06-10 Aqueous process for making fluoropolymers
US11/149,797 2005-06-10
PCT/US2006/019894 WO2006135543A2 (en) 2005-06-10 2006-05-23 Aqueous process for making fluoropolymers

Publications (2)

Publication Number Publication Date
CN101223228A CN101223228A (zh) 2008-07-16
CN101223228B true CN101223228B (zh) 2013-06-19

Family

ID=37524922

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800207481A Active CN101223228B (zh) 2005-06-10 2006-05-23 制备含氟聚合物的水性方法

Country Status (8)

Country Link
US (2) US20060281845A1 (https=)
EP (1) EP1891153B1 (https=)
JP (1) JP5112303B2 (https=)
KR (1) KR101298055B1 (https=)
CN (1) CN101223228B (https=)
AT (1) ATE535553T1 (https=)
ES (1) ES2376079T3 (https=)
WO (1) WO2006135543A2 (https=)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8338518B2 (en) * 2005-06-10 2012-12-25 Arkema Inc. Aqueous process for making a stable fluoropolymer dispersion
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
US7728087B2 (en) * 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
WO2009126504A2 (en) * 2008-04-07 2009-10-15 Arkema Inc. Polymerization of fluoropolymers using polycaprolactone
EP2284200A1 (en) 2009-07-31 2011-02-16 3M Innovative Properties Company Aqueous fluoropolymer dispersions containing a polyol comprising at least one long chain residue and method for producing them
RU2522749C2 (ru) 2009-07-31 2014-07-20 Зм Инновейтив Пропертиз Компани Соединения фторполимера, содержащие многоатомные соединения, и способы из производства
US9000069B1 (en) 2010-07-02 2015-04-07 The Sherwin-Williams Company Self-stratifying coatings
JP6201236B2 (ja) 2010-11-09 2017-09-27 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー フルオロモノマーの水性重合における核形成
CN103210003B (zh) 2010-11-09 2016-09-07 纳幕尔杜邦公司 减弱含烃表面活性剂在含氟单体含水分散体聚合反应中的调聚性能
CN103201300B (zh) 2010-11-09 2016-11-09 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
US8735520B2 (en) 2010-11-09 2014-05-27 E.I. Du Pont De Nemours And Company Vinyl fluoride polymerization and aqueous dispersion of vinyl fluoride polymer
US9676929B2 (en) 2013-11-26 2017-06-13 The Chemours Company Fc, Llc Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer
EP3145993B1 (en) 2014-05-19 2021-09-29 Arkema, Inc. High melt flow fluoropolymer composition
CN107075021B (zh) * 2014-09-17 2020-06-30 索尔维特殊聚合物意大利有限公司 偏二氟乙烯聚合物
EP3059265B1 (en) 2015-02-23 2020-10-07 3M Innovative Properties Company Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers
WO2017173258A1 (en) 2016-04-01 2017-10-05 Arkema Inc. 3-d printed fluoropolymer structures
WO2018065306A1 (en) * 2016-10-05 2018-04-12 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride and trifluoroethylene containing polymers latexes
FR3067032B1 (fr) * 2017-06-06 2021-10-01 Arkema France Elastomere de fluoropolymere thermoplastique
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
KR102120447B1 (ko) * 2017-11-22 2020-06-09 한국화학연구원 폴리에틸렌글리콜을 이용한 폴리비닐리덴 플루오라이드 나노 입자의 제조방법 및 이에 따라 제조되는 폴리비닐리덴 플루오라이드 나노 입자
JP7410045B2 (ja) * 2018-03-16 2024-01-09 アーケマ・インコーポレイテッド 高固形分、無界面活性剤フルオロポリマー
US11380935B2 (en) 2018-05-31 2022-07-05 Kureha Corporation Resin composition for nonaqueous electrolyte secondary battery, separator for nonaqueous electrolyte secondary battery using same, resin composition for electrode mixture layer, electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
KR102913501B1 (ko) 2018-11-12 2026-01-16 알케마 인코포레이티드 플루오로 중합체 분산액의 제조방법
JP2022512330A (ja) 2018-12-06 2022-02-03 アーケマ・インコーポレイテッド フッ素－熱可塑性エラストマーブレンド
EP3950827B1 (en) * 2019-03-29 2023-07-26 Kureha Corporation Vinylidene-fluoride-based polymer composition obtained using non-fluorinated surfactant and production method therefor
WO2021067660A1 (en) 2019-10-03 2021-04-08 Arkema Inc. Method to process fluorinated thermoplastic elastomers
JP2023536649A (ja) 2020-08-06 2023-08-28 アーケマ・インコーポレイテッド 加工可能なテトラフルオロエチレンコポリマー
JP7831300B2 (ja) * 2020-09-30 2026-03-17 Ａｇｃ株式会社 含フッ素重合体の製造方法、含フッ素重合体水性分散液および重合体組成物
WO2022072693A1 (en) 2020-10-01 2022-04-07 The Chemours Company Fc, Llc Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers
CN115466343B (zh) 2021-06-11 2023-10-27 中昊晨光化工研究院有限公司 一种聚醚二酸或其盐类表面活性剂及其应用
EP4438632A1 (en) 2023-03-29 2024-10-02 Arkema France Polyvinylidene fluoride for high purity water supply applications
EP4458869A1 (en) 2023-05-03 2024-11-06 Arkema, Inc. Process for the production of polyvinylidene fluoride copolymers

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1535989A (zh) * 2003-03-28 2004-10-13 ���з��ɻ�ѧ�ɷ����޹�˾ 使用硅氧烷表面活性剂聚合含卤素的单体

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3037953A (en) * 1961-04-26 1962-06-05 Du Pont Concentration of aqueous colloidal dispersions of polytetrafluoroethylene
US3301807A (en) 1963-04-11 1967-01-31 Thiokol Chemical Corp Stabilized, concentrated polytetrafluoroethylene dispersions containing non-ionic surfactants
US3704272A (en) * 1970-09-15 1972-11-28 Du Pont Concentration of polytetrafluoroethylene aqueous dispersion
US3817951A (en) * 1972-11-20 1974-06-18 Pennwalt Corp Low-modulus thermoplastic ethylene-tetrafluoroethylene-hexafluoropropene terpolymers
US4342675A (en) * 1978-06-16 1982-08-03 E. I. Du Pont De Nemours And Company Process for preparing aqueous dispersion of polytetrafluoroethylene
US4569978A (en) * 1984-07-25 1986-02-11 Pennwalt Corporation Emulsion polymerization of vinylidene fluoride polymers in the presence of trichlorofluoromethane as chain transfer agent
US5349003A (en) * 1988-09-20 1994-09-20 Japan Synthetic Rubber Co., Ltd. Aqueous fluorine-containing polymer dispersion and aqueous dispersion containing fluorine-containing polymer and water-soluble resin and/or water dispersible resin
JP3307663B2 (ja) * 1990-10-30 2002-07-24 大日本インキ化学工業株式会社 ゲル化微粒子状フッ素樹脂水性分散体及びその製造方法
JP3172983B2 (ja) * 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
JP3346090B2 (ja) * 1995-03-31 2002-11-18 ダイキン工業株式会社 ポリテトラフルオロエチレン水性分散液組成物及びその用途
US5955556A (en) * 1995-11-06 1999-09-21 Alliedsignal Inc. Method of manufacturing fluoropolymers
US5859123A (en) * 1995-11-15 1999-01-12 Central Glass Company, Limited Water-based fluorine-containing emulsion
EP1359194B1 (en) * 1998-02-24 2006-10-11 Asahi Glass Company, Limited Polytetrafluoroethylene aqueous dispersion composition
JP2000128935A (ja) * 1998-08-20 2000-05-09 Asahi Glass Co Ltd フッ素系共重合体の水性分散液
US6720360B1 (en) * 2000-02-01 2004-04-13 3M Innovative Properties Company Ultra-clean fluoropolymers
US6593416B2 (en) * 2000-02-01 2003-07-15 3M Innovative Properties Company Fluoropolymers
US6794550B2 (en) * 2000-04-14 2004-09-21 3M Innovative Properties Company Method of making an aqueous dispersion of fluoropolymers
DE10018853C2 (de) 2000-04-14 2002-07-18 Dyneon Gmbh Herstellung wässriger Dispersionen von Fluorpolymeren
US6512063B2 (en) * 2000-10-04 2003-01-28 Dupont Dow Elastomers L.L.C. Process for producing fluoroelastomers
WO2002088207A1 (en) * 2001-05-02 2002-11-07 3M Innovative Properties Company Emulsifier free aqueous emulsion polymerization process for making fluoropolymers
US6956078B2 (en) * 2002-01-04 2005-10-18 E.I. Du Pont De Nemours And Company Concentrated fluoropolymer dispersions
US7361708B2 (en) * 2002-05-20 2008-04-22 Daikin Industries, Ltd. Fluorinated resin water dispersion composition and fluorinated water base coating composition
US6734264B1 (en) * 2002-12-16 2004-05-11 Atofina Chemicals, Inc. Chain transfer agent
EP1533325B1 (en) * 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
US20060135716A1 (en) * 2004-12-20 2006-06-22 Ming-Hong Hung Fluoroelastomers having low glass transition temperature

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1535989A (zh) * 2003-03-28 2004-10-13 ���з��ɻ�ѧ�ɷ����޹�˾ 使用硅氧烷表面活性剂聚合含卤素的单体

Also Published As

Publication number Publication date
EP1891153B1 (en) 2011-11-30
JP2008543988A (ja) 2008-12-04
KR101298055B1 (ko) 2013-08-20
EP1891153A4 (en) 2010-01-27
US8158734B2 (en) 2012-04-17
WO2006135543A2 (en) 2006-12-21
ES2376079T3 (es) 2012-03-08
US20060281845A1 (en) 2006-12-14
US20070270534A1 (en) 2007-11-22
JP5112303B2 (ja) 2013-01-09
WO2006135543A3 (en) 2008-01-24
ATE535553T1 (de) 2011-12-15
KR20080017467A (ko) 2008-02-26
EP1891153A2 (en) 2008-02-27
CN101223228A (zh) 2008-07-16

Similar Documents

Publication Publication Date Title
CN101223228B (zh) 制备含氟聚合物的水性方法
JP5410987B2 (ja) 安定な含フッ素ポリマー分散液を製造するための水系方法
EP2089463B1 (en) Aqueous process for making fluoropolymers
US11066501B2 (en) Method for manufacturing an aqueous latex comprising particles of a fluoropolymer
US10377843B2 (en) Method for the controlled polymerization of fluoromonomers
EP2705061B1 (en) Method for manufacturing fluoroelastomers
CN102822213B (zh) 制造偏二氟乙烯聚合物分散体的方法
US8765890B2 (en) Aqueous process for making fluoropolymers
JP2009521586A (ja) フルオロポリマー分散体及びそれを製造する方法
JP2024147795A (ja) フルオロポリマー分散液を作るためのプロセス
US6649720B2 (en) Ethane as a chain transfer agent for vinylidene fluoride polymerization

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant