CN101207181A - 聚噻吩电子器件 - Google Patents
聚噻吩电子器件 Download PDFInfo
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- CN101207181A CN101207181A CNA2007101995587A CN200710199558A CN101207181A CN 101207181 A CN101207181 A CN 101207181A CN A2007101995587 A CNA2007101995587 A CN A2007101995587A CN 200710199558 A CN200710199558 A CN 200710199558A CN 101207181 A CN101207181 A CN 101207181A
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- perfluor
- butyl
- perfluoro
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- 229920000123 polythiophene Polymers 0.000 title claims description 20
- -1 3-substituted thiophene units Chemical group 0.000 claims abstract description 190
- 239000004065 semiconductor Substances 0.000 claims abstract description 64
- 229920000642 polymer Polymers 0.000 claims abstract description 34
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 17
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 17
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 14
- 239000001257 hydrogen Substances 0.000 claims abstract description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 14
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 13
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 34
- 239000010409 thin film Substances 0.000 claims description 32
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 21
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 21
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 20
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 20
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 20
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 20
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 20
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 19
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 17
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- 125000003118 aryl group Chemical group 0.000 claims description 14
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 12
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
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- 229920001940 conductive polymer Polymers 0.000 claims description 10
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 9
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 claims description 8
- 125000005005 perfluorohexyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 claims description 8
- 125000005009 perfluoropropyl group Chemical group FC(C(C(F)(F)F)(F)F)(F)* 0.000 claims description 8
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 8
- 239000002322 conducting polymer Substances 0.000 claims description 7
- 125000001072 heteroaryl group Chemical group 0.000 claims description 6
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 6
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/14—Side-groups
- C08G2261/142—Side-chains containing oxygen
- C08G2261/1424—Side-chains containing oxygen containing ether groups, including alkoxy
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
- C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/90—Applications
- C08G2261/92—TFT applications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/464—Lateral top-gate IGFETs comprising only a single gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/466—Lateral bottom-gate IGFETs comprising only a single gate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Thin Film Transistor (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Electroluminescent Light Sources (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/638,726 US7718999B2 (en) | 2006-12-14 | 2006-12-14 | Polythiophene electronic devices |
| US11/638726 | 2006-12-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101207181A true CN101207181A (zh) | 2008-06-25 |
Family
ID=39273839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101995587A Pending CN101207181A (zh) | 2006-12-14 | 2007-12-13 | 聚噻吩电子器件 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7718999B2 (https=) |
| EP (1) | EP1932865A3 (https=) |
| JP (1) | JP4874945B2 (https=) |
| CN (1) | CN101207181A (https=) |
| CA (1) | CA2613810C (https=) |
| TW (1) | TW200840104A (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007311377A (ja) * | 2006-05-16 | 2007-11-29 | Sony Corp | 薄膜トランジスタの製造方法および薄膜トランジスタならびに表示装置 |
| KR100943146B1 (ko) * | 2007-02-13 | 2010-02-18 | 주식회사 엘지화학 | 티아졸로티아졸 유도체를 이용한 유기 트랜지스터 및 이의제조방법 |
| JP2009215546A (ja) * | 2008-02-13 | 2009-09-24 | Sumitomo Chemical Co Ltd | 多環縮環化合物、多環縮環重合体及びこれらを含む有機薄膜 |
| SG10201400519VA (en) | 2009-03-18 | 2014-05-29 | Lubrizol Advanced Mat Inc | Thermoplastic polyurethane with reduced tendency to bloom |
| US8623478B2 (en) * | 2009-03-31 | 2014-01-07 | Dic Corporation | Organic semiconductor ink composition and method for forming organic semiconductor pattern using the same |
| KR101097210B1 (ko) | 2009-06-05 | 2011-12-21 | (주)아이티켐 | 티오펜일 카바졸계 화합물 및 이를 이용한 유기전기발광 소자 |
| DE102009030848A1 (de) | 2009-06-26 | 2011-02-03 | Merck Patent Gmbh | Polymere enthaltend Struktureinheiten, die Alkylalkoxygruppen aufweisen, Blends enthaltend diese Polymere sowie optoelektronische Vorrichtungen enthaltend diese Polymere und Blends |
| US20110031475A1 (en) * | 2009-08-10 | 2011-02-10 | Xerox Corporation | Semiconductor Composition |
| US8368052B2 (en) | 2009-12-23 | 2013-02-05 | Intel Corporation | Techniques for forming contacts to quantum well transistors |
| KR101238183B1 (ko) | 2010-12-31 | 2013-03-04 | 경상대학교산학협력단 | 알킬티오펜을 포함하는 교대 공중합체와 이를 이용한 유기 박막 트랜지스터 |
| WO2015078775A2 (en) * | 2013-11-28 | 2015-06-04 | Rolic Ag | Conducting and semi-conducting alignment materials |
| CN107431125B (zh) | 2015-03-16 | 2020-01-07 | 富士胶片株式会社 | 有机半导体元件及其制造方法、化合物、有机半导体组合物和有机半导体膜及其制造方法 |
| US10050203B2 (en) | 2016-05-27 | 2018-08-14 | Samsung Electronics Co., Ltd. | Polymer and electronic device and organic thin film transistor including the same |
| CN119039575B (zh) * | 2024-10-29 | 2025-02-18 | 链行走新材料科技(广州)有限公司 | 一种长醚链噻吩共聚物及其制备方法和应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61191501A (ja) * | 1985-02-19 | 1986-08-26 | Shozo Yanagida | 導電性高分子を光触媒とする水素発生法 |
| EP0203438A1 (en) | 1985-05-31 | 1986-12-03 | Corporation Allied | Solution processible forms of neutral and electrically conductive poly(substituted heterocycles) |
| JP2902727B2 (ja) | 1990-05-30 | 1999-06-07 | 株式会社日立製作所 | 荷電粒子線照射方法及び観察方法 |
| KR0131435B1 (ko) | 1994-03-28 | 1998-04-13 | 강박광 | 가공성이 있는 에스터기가 치환된 폴리 3-알킬티오펜 유도체 및 그의 제조방법 |
| KR100207568B1 (ko) * | 1994-08-27 | 1999-07-15 | 손욱 | 전도성 측쇄형 액정화합물 및 이를 사용한 배향막 |
| US6770904B2 (en) * | 2002-01-11 | 2004-08-03 | Xerox Corporation | Polythiophenes and electronic devices generated therefrom |
| US7250625B2 (en) * | 2002-01-11 | 2007-07-31 | Xerox Corporation | Polythiophenes and electronic devices generated therefrom |
| US7141644B2 (en) | 2002-01-11 | 2006-11-28 | Xerox Corporation | Polthiophenes and devices thereof |
| US7294850B2 (en) * | 2004-06-10 | 2007-11-13 | Xerox Corporation | Device with small molecular thiophene compound having divalent linkage |
| US7402681B2 (en) * | 2004-12-14 | 2008-07-22 | Xerox Corporation | Compound with indolocarbazole moieties and devices containing such compound |
| US20060124921A1 (en) * | 2004-12-14 | 2006-06-15 | Xerox Corporation | Compound with indolocarbazole moieties and devices containing such compound |
| JP4731942B2 (ja) | 2005-02-16 | 2011-07-27 | 住友化学株式会社 | ポリチオフェン |
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- 2006-12-14 US US11/638,726 patent/US7718999B2/en active Active
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- 2007-12-07 CA CA2613810A patent/CA2613810C/en not_active Expired - Fee Related
- 2007-12-13 TW TW096147637A patent/TW200840104A/zh unknown
- 2007-12-13 JP JP2007321630A patent/JP4874945B2/ja not_active Expired - Fee Related
- 2007-12-13 CN CNA2007101995587A patent/CN101207181A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP4874945B2 (ja) | 2012-02-15 |
| US20080142788A1 (en) | 2008-06-19 |
| TW200840104A (en) | 2008-10-01 |
| CA2613810C (en) | 2013-08-27 |
| EP1932865A2 (en) | 2008-06-18 |
| CA2613810A1 (en) | 2008-06-14 |
| US7718999B2 (en) | 2010-05-18 |
| EP1932865A3 (en) | 2008-07-23 |
| JP2008153667A (ja) | 2008-07-03 |
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