CN101193925B - 制备二烯弹性体，如聚丁二烯的方法 - Google Patents

制备二烯弹性体，如聚丁二烯的方法 Download PDF

Info

Publication number
CN101193925B
CN101193925B CN2006800208821A CN200680020882A CN101193925B CN 101193925 B CN101193925 B CN 101193925B CN 2006800208821 A CN2006800208821 A CN 2006800208821A CN 200680020882 A CN200680020882 A CN 200680020882A CN 101193925 B CN101193925 B CN 101193925B
Authority
CN
China
Prior art keywords
catalyst system
polymerization
alkylaluminum
rare earth
conjugated diene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2006800208821A
Other languages
English (en)
Chinese (zh)
Other versions
CN101193925A (zh
Inventor
C·加尼韦
J-P·拉斯戈德
F·巴伯提
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
MICHELIN RECHERCHE ET TECHNIQUE SA
Societe de Technologie Michelin SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MICHELIN RECHERCHE ET TECHNIQUE SA, Societe de Technologie Michelin SAS filed Critical MICHELIN RECHERCHE ET TECHNIQUE SA
Publication of CN101193925A publication Critical patent/CN101193925A/zh
Application granted granted Critical
Publication of CN101193925B publication Critical patent/CN101193925B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08—Isoprene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN2006800208821A 2005-06-14 2006-04-06 制备二烯弹性体，如聚丁二烯的方法 Active CN101193925B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0506040 2005-06-14
FR0506040A FR2886937B1 (fr) 2005-06-14 2005-06-14 Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
PCT/EP2006/003151 WO2006133757A1 (fr) 2005-06-14 2006-04-06 Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene.

Publications (2)

Publication Number Publication Date
CN101193925A CN101193925A (zh) 2008-06-04
CN101193925B true CN101193925B (zh) 2011-07-27

Family

ID=35788442

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800208821A Active CN101193925B (zh) 2005-06-14 2006-04-06 制备二烯弹性体，如聚丁二烯的方法

Country Status (12)

Country Link
US (1) US9040644B2 (enExample)
EP (1) EP1899389B1 (enExample)
JP (1) JP5269590B2 (enExample)
CN (1) CN101193925B (enExample)
AT (1) ATE434003T1 (enExample)
BR (1) BRPI0612083A2 (enExample)
DE (1) DE602006007354D1 (enExample)
ES (1) ES2328848T3 (enExample)
FR (1) FR2886937B1 (enExample)
PL (1) PL1899389T3 (enExample)
RU (1) RU2411251C2 (enExample)
WO (1) WO2006133757A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2939800B1 (fr) 2008-12-15 2011-06-17 Michelin Soc Tech Procede de preparation d'un elastomere dienique fonctionnalise, tel qu'un polybutadiene.
RU2442653C2 (ru) * 2010-05-04 2012-02-20 Открытое акционерное общество "Воронежский синтетический каучук" Способ получения каталитической системы для полимеризации бутадиена и способ получения цис-1,4-полибутадиена
CN101870745B (zh) * 2010-06-11 2011-11-23 茂名鲁华化工有限公司 用于合成橡胶生产的钕催化剂
KR101279977B1 (ko) 2010-10-18 2013-07-05 제일모직주식회사 공액 디엔으로부터 고무변성 방향족 비닐중합체를 연속적으로 제조하는 방법
CN102532354B (zh) * 2010-12-09 2016-07-06 中国石油化工股份有限公司 钕系均相稀土催化剂、其制备方法及其应用
FR2984890B1 (fr) 2011-12-22 2014-06-13 Michelin Soc Tech Activation de systemes catalytiques pour la polymerisation stereospecifique des dienes
RU2494116C1 (ru) * 2012-05-22 2013-09-27 Открытое акционерное общество "Нижнекамскнефтехим" Способ получения бутадиеновых каучуков
FR2992649B1 (fr) * 2012-07-02 2015-06-19 Michelin & Cie Procede de synthese en continu d'un elastomere dienique
JP6054821B2 (ja) * 2013-07-03 2016-12-27 住友ゴム工業株式会社 変性共役ジエン系重合体及びゴム組成物
FR3015979B1 (fr) 2014-01-02 2016-02-05 Michelin & Cie Procede de synthese en continu d'un polyisoprene fonctionnalise.
FR3015980B1 (fr) 2014-01-02 2016-02-05 Michelin & Cie Procede de synthese en continu d'un elastomere dienique fonctionnalise.
EP3221368A1 (en) * 2014-11-17 2017-09-27 Bridgestone Corporation Bulk polymerization of polyisoprene with preformed catalyst
CN113105573A (zh) 2015-01-28 2021-07-13 株式会社普利司通 具有改善的耐冷流性的顺式-1,4-聚二烯
US10774162B2 (en) 2015-01-28 2020-09-15 Bridgestone Corporation Aged lanthanide-based catalyst systems and their use in the preparation of cis-1,4-polydienes
KR102156108B1 (ko) * 2015-12-23 2020-09-15 주식회사 엘지화학 공액디엔계 중합체의 제조방법 및 이로부터 제조된 공액디엔계 중합체
CN108219046A (zh) * 2016-12-15 2018-06-29 中国石油天然气股份有限公司 一种稀土催化剂及其制备方法和应用
EP3720889B1 (fr) 2017-12-05 2025-08-06 Compagnie Générale des Etablissements Michelin Procede continu de preparation d'un elastomere dienique

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5945311A (ja) * 1982-09-07 1984-03-14 Japan Synthetic Rubber Co Ltd 改良されたポリブタジエンの製造方法
JPS5945337A (ja) * 1982-09-07 1984-03-14 Japan Synthetic Rubber Co Ltd 生強度の改良されたポリブタジエンゴム組成物
ES2020484A6 (es) * 1990-06-29 1991-08-01 Repsol Quimica Sa Procedimiento de preparacion de homopolimeros de dienos conjugados y de copolimeros de dienos conjugados con otros dienos o compuestos vinil aromaticos.
JPH0873515A (ja) * 1994-07-08 1996-03-19 Ube Ind Ltd 共役ジオレフィンの重合法
DE4436059A1 (de) * 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
JP4067592B2 (ja) * 1996-12-04 2008-03-26 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
US20030134999A1 (en) * 1998-07-18 2003-07-17 Heike Windisch Method for polymerizing conjugated diolefins (dienes) with rare earth catalysts in the presence of vinylaromatic solvents
US6441107B1 (en) * 1998-12-18 2002-08-27 Union Carbide Chemicals & Plastics Technology Corporation Molecular weight control of gas phase polymerized polybutadiene when using a rare earth catalyst
BR9902609B1 (pt) 1999-05-27 2010-08-10 processo para a preparação de neodecanoato de neodìmio, processo para a preparação de um sistema catalìtico homogêneo de coordenação, processo para polimerização em solução para a preparação de polibutadieno de alto teor de ligações 1,4-cis.
FR2799394A1 (fr) * 1999-10-11 2001-04-13 Michelin Soc Tech Catalyseur solide supporte utilisable pour la polymerisation de dienes conjugues, son procede de preparation et procede de polymerisation de dienes conjugues utilisant ce catalyseur
DE19951841A1 (de) * 1999-10-28 2001-05-03 Bayer Ag Katalysator auf Basis von Verbindungen der Seltenen Erdmetalle
JP4332690B2 (ja) * 1999-11-12 2009-09-16 Ｊｓｒ株式会社 ゴム組成物
US6255420B1 (en) * 1999-11-22 2001-07-03 Union Carbide Chemicals & Plastics Technology Corporation Start-up process for gas phase production of polybutadiene
DE60136856D1 (de) * 2000-11-09 2009-01-15 Michelin Soc Tech Katalytisches system und verfahren zur herstellung von elastomeren unter verwendung dieses systems
BR0115305B1 (pt) * 2000-11-13 2011-06-14 poliisopreno de sÍntese e processo de preparaÇço do mesmo.
KR100804601B1 (ko) * 2000-12-14 2008-02-20 소시에떼 드 테크놀로지 미쉐린 시스-1,4 결합 함량이 높은 폴리이소프렌의 제조방법
JP4828085B2 (ja) * 2001-02-28 2011-11-30 株式会社ブリヂストン 狭い分子量分布を示す共役ジエン重合体の連続製造方法およびそれから製造された製品
DE50211520D1 (de) * 2001-04-23 2008-02-21 Lanxess Deutschland Gmbh Modifizierte polymere mit einem hohen anteil an cis-ständigen doppelbindungen, ein verfahren zu deren herstellung sowie deren verwendung
CN1273508C (zh) * 2001-12-07 2006-09-06 米其林技术公司 丁二烯/异戊二烯共聚物的制备方法及所述共聚物
US6780948B2 (en) * 2002-03-28 2004-08-24 The Goodyear Tire & Rubber Company Synthesis of polyisoprene with neodymium catalyst
WO2003097708A1 (fr) * 2002-05-16 2003-11-27 Societe De Technologie Michelin Systeme catalytique pour preparer des polybutadienes et procede de preparation
RU2203289C1 (ru) * 2002-05-29 2003-04-27 Открытое акционерное общество "Воронежсинтезкаучук" Способ получения цис-1,4-(со)полимеров сопряженных диенов и (со)полимер, полученный этим способом
AU2003292037A1 (en) * 2002-11-18 2004-06-15 Michelin Recherche Et Technique S.A. Method for obtaining a butadiene hompolymer in the presence of mono-olefin(s) with 4 carbon atoms
KR100472649B1 (ko) * 2002-11-22 2005-03-11 금호석유화학 주식회사 조절된 저온흐름성을 갖는 고 1,4-시스 폴리부타디엔의제조방법
RU2263121C2 (ru) * 2003-01-30 2005-10-27 Открытое акционерное общество "Ефремовский завод синтетического каучука" Способ получения цис-1,4-диенового каучука
BRPI0407665A (pt) * 2003-02-21 2006-03-01 Dow Global Technology Inc catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturados
FR2858817B1 (fr) * 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
FR2892121B1 (fr) * 2005-10-19 2008-01-04 Michelin Soc Tech Procede de preparation en continu d'un systeme catalytique pour polymeriser un diene conjugue, et installation pour sa mise en oeuvre.

Also Published As

Publication number Publication date
ATE434003T1 (de) 2009-07-15
JP5269590B2 (ja) 2013-08-21
FR2886937A1 (fr) 2006-12-15
PL1899389T3 (pl) 2009-12-31
RU2008101413A (ru) 2009-07-20
RU2411251C2 (ru) 2011-02-10
CN101193925A (zh) 2008-06-04
DE602006007354D1 (de) 2009-07-30
EP1899389A1 (fr) 2008-03-19
JP2008543996A (ja) 2008-12-04
WO2006133757A1 (fr) 2006-12-21
US9040644B2 (en) 2015-05-26
FR2886937B1 (fr) 2007-08-10
EP1899389B1 (fr) 2009-06-17
ES2328848T3 (es) 2009-11-18
BRPI0612083A2 (pt) 2012-09-04
US20100041843A1 (en) 2010-02-18

Similar Documents

Publication Publication Date Title
CN101193925B (zh) 制备二烯弹性体，如聚丁二烯的方法
JP5265135B2 (ja) ポリブタジエンのようなジエンエラストマーの製造方法
JP5583343B2 (ja) 共役ジエンを重合させるのに使用する触媒系の連続製造方法および該方法を実施するための装置
EP0652239B1 (en) Process for cis-1,4-poly-butadiene production with reduced gel formation
CN105189578B (zh) 具有受控长链支化和宽分子量分布的海绵聚合物
Zheng et al. Amphiphilic silicon hydroxyl-functionalized cis-polybutadiene: synthesis, characterization, and properties
EP1637549B1 (en) Synthesis of CIS-1,4-polybutadiene
US20140350202A1 (en) Activation of catalytic systems for the stereospecific polymerization of dienes
US20180016368A1 (en) Process for continuous synthesis of a diene elastomer
CN112204058A (zh) 官能化聚丁二烯合成方法
CN104125967A (zh) 用于制备聚二烯的本体聚合方法
CN104854149B (zh) 多组分催化体系及其制备方法以及使用其聚合异戊二烯的方法
US11427653B2 (en) Continuous method for producing a diene elastomer
EP2507270A1 (en) Catalyst systems for rubber polymerizations
WO2003102041A1 (en) A two-step butadiene polymerization process for manufacturing high-cis 1,4-ploybutadiene
RU2432365C1 (ru) Способ получения катализатора (со)полимеризации бутадиена
JP2025534126A (ja) 共重合体、およびその調製方法、並びに加硫ゴムおよびその使用
RU2653851C2 (ru) Способ непрерывного синтеза функционализированного диенового эластомера
HK1135121B (en) Process for the partial hydrogenation of random vinyl arene - conjugated diene copolymers
EP2158225A1 (en) Process for the partial hydrogenation of random vinyl arene - conjugated diene copolymers

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN

Free format text: FORMER OWNER: MICHELIN TECHNIQUE S.A.

Effective date: 20121113

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20121113

Address after: French Clermont Ferrand

Patentee after: Compagnie General Des Etablissements Michelin

Patentee after: Michelin Research & Technology Co., Ltd.

Address before: French Clermont Ferrand

Patentee before: Michelin Co., Ltd.

Patentee before: Michelin Research & Technology Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20171117

Address after: French Clermont Ferrand

Patentee after: Compagnie General Des Etablissements Michelin

Address before: French Clermont Ferrand

Co-patentee before: Michelin Research & Technology Co., Ltd.

Patentee before: Compagnie General Des Etablissements Michelin