CN101189318B - 可逆的热致变色组合物 - Google Patents

可逆的热致变色组合物 Download PDF

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Publication number
CN101189318B
CN101189318B CN2006800200228A CN200680020022A CN101189318B CN 101189318 B CN101189318 B CN 101189318B CN 2006800200228 A CN2006800200228 A CN 2006800200228A CN 200680020022 A CN200680020022 A CN 200680020022A CN 101189318 B CN101189318 B CN 101189318B
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CN
China
Prior art keywords
group
alkyl
tert
reversible thermochromic
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800200228A
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English (en)
Chinese (zh)
Other versions
CN101189318A (zh
Inventor
W·费希尔
A·-I·巴斯巴斯
M·德斯特罗
M·维塔利
D·拉扎里
M·罗西
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
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Publication date
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Publication of CN101189318A publication Critical patent/CN101189318A/zh
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Publication of CN101189318B publication Critical patent/CN101189318B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/95—Esters of quinone carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/24—Sulfones; Sulfoxides having sulfone or sulfoxide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/94—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of polycyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/58—[b]- or [c]-condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/40—Ortho- or ortho- and peri-condensed systems containing four condensed rings
    • C07C2603/42—Ortho- or ortho- and peri-condensed systems containing four condensed rings containing only six-membered rings
    • C07C2603/44—Naphthacenes; Hydrogenated naphthacenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1003—Carbocyclic compounds
    • C09K2211/1011—Condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)
CN2006800200228A 2005-06-10 2006-05-31 可逆的热致变色组合物 Expired - Fee Related CN101189318B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP05105099.5 2005-06-10
EP05105099 2005-06-10
EP05110655.7 2005-11-11
EP05110655 2005-11-11
PCT/EP2006/062749 WO2006131465A1 (en) 2005-06-10 2006-05-31 Reversibly thermochromic compositions

Publications (2)

Publication Number Publication Date
CN101189318A CN101189318A (zh) 2008-05-28
CN101189318B true CN101189318B (zh) 2012-06-20

Family

ID=36660155

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800200228A Expired - Fee Related CN101189318B (zh) 2005-06-10 2006-05-31 可逆的热致变色组合物

Country Status (7)

Country Link
US (1) US9039946B2 (enExample)
EP (1) EP1888705B1 (enExample)
JP (1) JP2008545864A (enExample)
CN (1) CN101189318B (enExample)
AT (1) ATE478125T1 (enExample)
DE (1) DE602006016271D1 (enExample)
WO (1) WO2006131465A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007147847A2 (en) * 2006-06-23 2007-12-27 Ciba Holding Inc. Reversibly thermochromic compositions
JP4934398B2 (ja) * 2006-10-20 2012-05-16 パイロットインキ株式会社 感温変色性組成物及びそれを用いた感温変色性繊維
US7911676B2 (en) * 2008-12-16 2011-03-22 Transitions Optical, Inc. Photochromic optical articles prepared with reversible thermochromic materials
JP5398606B2 (ja) * 2010-03-17 2014-01-29 富士フイルム株式会社 インク組成物およびインクセット、並びに画像形成方法
US20130037508A1 (en) * 2011-08-12 2013-02-14 Plastipak Packaging, Inc. Preform with insert ring, container, and method
KR102089118B1 (ko) 2012-08-23 2020-03-13 코베스트로 도이칠란드 아게 홀로그램을 갖는 시각적으로 변화가능한 윈도우를 함유하는 보안 문서 및/또는 중요 문서
DE102012018813A1 (de) * 2012-09-24 2014-03-27 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Thermochromes Material, dieses enthaltende Formkörper und deren Verwendung
ES1136780Y (es) * 2015-02-12 2015-05-19 Ciudad Jesus Merino Recipiente inteligente para alimentos y fluidos.
WO2016166592A1 (en) * 2015-04-14 2016-10-20 Savare' I.C. S.R.L. Wetness indicator compositions comprising leuco dyes
CN105017807B (zh) * 2015-07-30 2017-03-29 苏州雄鹰笔墨科技有限公司 一种可逆温敏变色染料、制备方法及其应用
US12359083B2 (en) 2018-02-05 2025-07-15 Chromatic Technologies, Inc. Ultraviolet light stable color-changing systems
US11236247B2 (en) 2018-02-05 2022-02-01 Chromatic Technologies, Inc. Ultraviolet light stable color-changing systems

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4033923A (en) * 1974-02-07 1977-07-05 Mitsui Toatsu Chemicals, Incorporated Coloring resins by mixing naphthacenequinones therewith
US5177227A (en) * 1990-01-18 1993-01-05 Ciba-Geigy Corporation Photochromic naphthacenequinones, process for their preparation and the use thereof

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE659638C (de) 1936-01-16 1938-05-10 I G Farbenindustrie Akt Ges Verfahren zur Herstellung von Orthooxycarbonsaeuren der Anthrachinonreihe
JPS5417877B2 (enExample) * 1972-07-28 1979-07-03
JPS538331B2 (enExample) * 1974-02-07 1978-03-28
SU665218A1 (ru) * 1978-01-23 1979-05-30 Предприятие П/Я Г-4371 Термохромна пленка
GB1601945A (en) 1978-04-28 1981-11-04 Ici Ltd Process for the manufacture of naphthacene derivatives
JPS61136965A (ja) * 1984-12-06 1986-06-24 京セラ株式会社 薄膜用セラミツク基板の製造方法
JPS62127322A (ja) * 1985-11-28 1987-06-09 Matsui Shikiso Kagaku Kogyosho:Kk 熱可逆変色性ポリ塩化ビニル成型品の製造法
JP2802338B2 (ja) 1988-07-29 1998-09-24 リーデル―デ・ヘーン・アクチェンゲゼルシャフト 新規の１，４−ジケトンピローロピロール染料
TW203095B (enExample) 1991-07-22 1993-04-01 Mitsui Toatsu Kagaku Co Ltd
JP3263130B2 (ja) * 1991-07-22 2002-03-04 三井化学株式会社 可逆性熱変色材料

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4033923A (en) * 1974-02-07 1977-07-05 Mitsui Toatsu Chemicals, Incorporated Coloring resins by mixing naphthacenequinones therewith
US5177227A (en) * 1990-01-18 1993-01-05 Ciba-Geigy Corporation Photochromic naphthacenequinones, process for their preparation and the use thereof

Also Published As

Publication number Publication date
DE602006016271D1 (de) 2010-09-30
WO2006131465A1 (en) 2006-12-14
CN101189318A (zh) 2008-05-28
US9039946B2 (en) 2015-05-26
EP1888705B1 (en) 2010-08-18
US20090302284A1 (en) 2009-12-10
EP1888705A1 (en) 2008-02-20
JP2008545864A (ja) 2008-12-18
ATE478125T1 (de) 2010-09-15

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Granted publication date: 20120620

Termination date: 20180531