CN101163549B - 从第ⅷ族金属催化剂络合物混合物中回收三芳基膦的方法 - Google Patents

从第ⅷ族金属催化剂络合物混合物中回收三芳基膦的方法 Download PDF

Info

Publication number
CN101163549B
CN101163549B CN2006800132790A CN200680013279A CN101163549B CN 101163549 B CN101163549 B CN 101163549B CN 2006800132790 A CN2006800132790 A CN 2006800132790A CN 200680013279 A CN200680013279 A CN 200680013279A CN 101163549 B CN101163549 B CN 101163549B
Authority
CN
China
Prior art keywords
weight
group viii
triaryl phosphine
triarylphosphine
viii metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800132790A
Other languages
English (en)
Chinese (zh)
Other versions
CN101163549A (zh
Inventor
B·N·夏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oxea Corp
Original Assignee
OQ Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OQ Chemicals Corp filed Critical OQ Chemicals Corp
Publication of CN101163549A publication Critical patent/CN101163549A/zh
Application granted granted Critical
Publication of CN101163549B publication Critical patent/CN101163549B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5095—Separation; Purification; Stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN2006800132790A 2005-04-21 2006-03-22 从第ⅷ族金属催化剂络合物混合物中回收三芳基膦的方法 Expired - Fee Related CN101163549B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/112,402 2005-04-21
US11/112,402 US7667079B2 (en) 2005-04-21 2005-04-21 Processes for recovery of a triarylphosphine from a group VIII metal catalyst complex mixture
PCT/US2006/010413 WO2006115644A2 (en) 2005-04-21 2006-03-22 Processes for recovery of a triarylphosphine from a group viii metal catalyst complex mixture

Publications (2)

Publication Number Publication Date
CN101163549A CN101163549A (zh) 2008-04-16
CN101163549B true CN101163549B (zh) 2012-02-29

Family

ID=37187837

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800132790A Expired - Fee Related CN101163549B (zh) 2005-04-21 2006-03-22 从第ⅷ族金属催化剂络合物混合物中回收三芳基膦的方法

Country Status (10)

Country Link
US (1) US7667079B2 (enExample)
EP (1) EP1883471B1 (enExample)
JP (1) JP5216577B2 (enExample)
KR (1) KR101243618B1 (enExample)
CN (1) CN101163549B (enExample)
BR (1) BRPI0610595A2 (enExample)
MX (1) MX2007013055A (enExample)
TW (1) TWI366568B (enExample)
WO (1) WO2006115644A2 (enExample)
ZA (1) ZA200707303B (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100843424B1 (ko) * 2006-07-06 2008-07-03 삼성전기주식회사 스퍼터링 공정을 이용한 필름형 안테나 제조 방법
CN105441681B (zh) * 2014-09-26 2018-03-02 中国石油化工股份有限公司 一种从包含铑膦络合催化剂的废液中回收铑的方法
WO2017083106A1 (en) * 2015-11-10 2017-05-18 Dow Technology Investments Llc Process for producing aldehydes
CN107955038A (zh) * 2017-12-19 2018-04-24 天津渤化永利化工股份有限公司 一种丙烯羰基化中的催化剂母液综合回收利用方法及装置

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4292448A (en) * 1979-05-11 1981-09-29 Mitsubishi Chemical Industries Ltd. Process for the hydroformylation of olefins
US4503255A (en) * 1981-05-01 1985-03-05 Johnson Matthey Public Limited Company Process for recovering triarylphosphine from poisoned rhodium catalyst systems
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2912230B1 (de) * 1979-03-28 1980-10-09 Union Carbide Corp Verfahren zur Rueckgewinnung und Reaktivierung gebrauchter Rhodium- und Phosphin-enthaltender Katalysatoren aus Reaktionsprodukten der Rhodium-katalysierten Oxosynthese
NO156742C (no) * 1979-03-28 1987-11-18 Union Carbide Corp Fremgangsmaate for fremstilling av et hydroformyleringsmedium, og fremgangsmaate for fremstilling av aldehyder.
JPS5822132B2 (ja) * 1980-01-18 1983-05-06 三菱化学株式会社 オレフインのヒドロホルミル化方法
JPS584690B2 (ja) * 1979-05-11 1983-01-27 三菱化学株式会社 オレフインのヒドロホルミル化方法
JPS5645436A (en) 1979-09-21 1981-04-25 Mitsubishi Chem Ind Ltd Hydroformylation of olefin
US4528404A (en) 1983-03-16 1985-07-09 Exxon Research And Engineering Co. High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems
CA1259331A (en) * 1984-03-30 1989-09-12 Gregory J. Dembowski Process for recovery of phosphorus ligand from vaporized aldehyde
US4871879A (en) 1987-10-27 1989-10-03 Hoechst Celanese Corporation Rhodium recovery from hydroformylation reaction product
JP3758226B2 (ja) * 1996-02-13 2006-03-22 三菱化学株式会社 ルテニウム錯体の分離回収方法
JPH10291996A (ja) 1997-04-22 1998-11-04 Mitsubishi Chem Corp ロジウム錯体溶液の調製方法
JP3888008B2 (ja) * 1999-10-12 2007-02-28 三菱化学株式会社 第８族貴金属及び／又は有機ホスファイト化合物の回収方法
US6335415B1 (en) * 2001-01-30 2002-01-01 Council Of Scientific & Industrial Research Process for the preparation of a polyester
WO2004058402A2 (en) * 2002-12-23 2004-07-15 Eastman Chemical Company Process for the recovery of phosphorus and iodine containing catalyst components
WO2004065007A1 (en) 2003-01-17 2004-08-05 Sasol Technology (Proprietary) Limited Recovery of an active catalyst component from a process stream

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4292448A (en) * 1979-05-11 1981-09-29 Mitsubishi Chemical Industries Ltd. Process for the hydroformylation of olefins
US4503255A (en) * 1981-05-01 1985-03-05 Johnson Matthey Public Limited Company Process for recovering triarylphosphine from poisoned rhodium catalyst systems
US5110990A (en) * 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde

Also Published As

Publication number Publication date
WO2006115644A3 (en) 2007-03-15
KR20080023286A (ko) 2008-03-13
EP1883471B1 (en) 2018-10-10
BRPI0610595A2 (pt) 2010-07-06
WO2006115644A2 (en) 2006-11-02
US7667079B2 (en) 2010-02-23
TWI366568B (en) 2012-06-21
HK1121708A1 (en) 2009-04-30
EP1883471A2 (en) 2008-02-06
CN101163549A (zh) 2008-04-16
KR101243618B1 (ko) 2013-03-14
MX2007013055A (es) 2008-01-14
ZA200707303B (en) 2008-07-30
TW200643025A (en) 2006-12-16
JP5216577B2 (ja) 2013-06-19
JP2008536683A (ja) 2008-09-11
US20060241322A1 (en) 2006-10-26

Similar Documents

Publication Publication Date Title
JP6294374B2 (ja) 水の添加によるヒドロホルミル化におけるファウリングの緩和
US9695098B2 (en) Hydroformylation process
CN104379258B (zh) 加氢甲酰化方法
JP2021525231A (ja) ヒドロホルミル化プロセスを制御する方法
CN111278560B (zh) 从氢甲酰化方法回收铑的方法
CN109071394A (zh) 加氢甲酰化工艺
CN101163549B (zh) 从第ⅷ族金属催化剂络合物混合物中回收三芳基膦的方法
RU2719438C2 (ru) Способ получения альдегидов
BR112018016320B1 (pt) Processo para converter olefinas em álcoois, éteres ou combinações dos mesmos
HK1121708B (en) Processes for recovery of a triarylphosphine from a group viii metal catalyst complex mixture
JP2008536683A5 (enExample)
CN118317834A (zh) 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
CN114728278A (zh) 从氢甲酰化方法回收铑的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1121708

Country of ref document: HK

C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1121708

Country of ref document: HK

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120229

Termination date: 20210322