CN101146833B - 用于烯烃聚合的催化剂组分 - Google Patents

用于烯烃聚合的催化剂组分 Download PDF

Info

Publication number
CN101146833B
CN101146833B CN2006800094178A CN200680009417A CN101146833B CN 101146833 B CN101146833 B CN 101146833B CN 2006800094178 A CN2006800094178 A CN 2006800094178A CN 200680009417 A CN200680009417 A CN 200680009417A CN 101146833 B CN101146833 B CN 101146833B
Authority
CN
China
Prior art keywords
catalyst
ratio
solid catalyst
titanium
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800094178A
Other languages
English (en)
Chinese (zh)
Other versions
CN101146833A (zh
Inventor
G·莫里尼
I·M·V·卡穆拉蒂
T·达尔奥科
D·利古奥里
G·维塔尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Basell Poliolefine Italia SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia SRL filed Critical Basell Poliolefine Italia SRL
Publication of CN101146833A publication Critical patent/CN101146833A/zh
Application granted granted Critical
Publication of CN101146833B publication Critical patent/CN101146833B/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN2006800094178A 2005-03-30 2006-03-15 用于烯烃聚合的催化剂组分 Expired - Fee Related CN101146833B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP05102483.4 2005-03-30
EP05102483 2005-03-30
US66725205P 2005-04-01 2005-04-01
US60/667,252 2005-04-01
PCT/EP2006/060738 WO2006103171A1 (en) 2005-03-30 2006-03-15 Catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
CN101146833A CN101146833A (zh) 2008-03-19
CN101146833B true CN101146833B (zh) 2010-12-08

Family

ID=36282637

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800094178A Expired - Fee Related CN101146833B (zh) 2005-03-30 2006-03-15 用于烯烃聚合的催化剂组分

Country Status (7)

Country Link
US (1) US7879959B2 (https=)
EP (1) EP1863854A1 (https=)
JP (1) JP2008534723A (https=)
KR (1) KR20070118144A (https=)
CN (1) CN101146833B (https=)
RU (1) RU2007139935A (https=)
WO (1) WO2006103171A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101163722B (zh) * 2005-03-30 2011-03-09 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分
ES2435101T3 (es) 2005-03-30 2013-12-18 Basell Poliolefine Italia S.R.L. Procedimiento de obtención de (co)polímeros cristalinos de etileno
JP2012046593A (ja) * 2010-08-25 2012-03-08 Toho Titanium Co Ltd オレフィン類重合用遷移金属含有固体触媒およびオレフィン類重合用遷移金属含有固体触媒の性能評価方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0301894A2 (en) * 1987-07-30 1989-02-01 AUSIMONT S.p.A. Catalysts for preparing saturated elastomeric olefinic copolymers and terpolymers
US6544920B1 (en) * 1995-12-21 2003-04-08 Basell Poliolefine Italia S.P.A. Components and catalysts for the polymerization of olefins

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1603724A (en) * 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
JPH06810B2 (ja) * 1983-11-14 1994-01-05 三井石油化学工業株式会社 チタン触媒成分の改質方法
DE3435389A1 (de) 1984-09-27 1986-04-03 Basf Ag, 6700 Ludwigshafen Verfahren zum herstellen einer titan enthaltenden katalysatorkomponente fuer ziegler-katalysatorsysteme
SG42868A1 (en) 1989-05-08 1997-10-17 Sumitomo Chemical Co Process for producing solid catalyst for use in polymerization of olefins
ZA907017B (en) 1989-10-18 1991-09-25 Himont Inc Polymetallic catalysts,method of preparing and polymers produced thereby
CA2037025C (en) 1990-02-27 1996-12-03 Mitsui Chemicals, Incorporated Ethylene/pentene-1 copolymer, process for the preparation of the same, and ethylene/pentene-1 copolymer composition
US5118768A (en) * 1990-05-11 1992-06-02 Shell Oil Company Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process
IT1246614B (it) * 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
IT1262934B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1262935B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1254279B (it) * 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
JPH0733816A (ja) * 1993-07-20 1995-02-03 Mitsui Petrochem Ind Ltd オレフィン重合用予備重合触媒、オレフィン重合用触媒およびオレフィンの重合方法
ES2435101T3 (es) 2005-03-30 2013-12-18 Basell Poliolefine Italia S.R.L. Procedimiento de obtención de (co)polímeros cristalinos de etileno
CN101163722B (zh) 2005-03-30 2011-03-09 巴塞尔聚烯烃意大利有限责任公司 用于烯烃聚合的催化剂组分

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0301894A2 (en) * 1987-07-30 1989-02-01 AUSIMONT S.p.A. Catalysts for preparing saturated elastomeric olefinic copolymers and terpolymers
US6544920B1 (en) * 1995-12-21 2003-04-08 Basell Poliolefine Italia S.P.A. Components and catalysts for the polymerization of olefins

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
GAROFF T ET AL.DECREASE IN ACTIVITY CAUSED BY HYDROGEN INZIEGLER-NATTA ETHENE POLYMERISATION.EUROPEAN POLYMER JOURNAL PERGAMON PRESS LONDON GB38 1.2002,121-132. *
GUPTA V K ET AL.STUDIES ON MAGNESIUM DICHLORIDE-2,2-DIMETHOXYPROPANE-TITANIUM TETRACHLORIDECATALYST SYSTEM FOR PROPYLENEPOLYMERIZATION.POLYMER ELSEVIER SCIENCE PUBLISHERS B.V,GB37 8.1996,1399-1403. *
LEE D-H ET AL.PROPYLENE POLYMERIZATION WITH MG(OET)2/BENZOYL CHLORIDE/TiCl4-TRIETHYL ALUMINUN/EXTERNAL DONOR CATALYST SYSTEMS.JOURNAL OF APPLIED POLYMER SCIENCE, JOHN WILEY AND SONS INC. NEW YORK US47 8.1993,47(8),1449-1461. *
YOUNG-TAE JEONG ET AL.Propene polymerization with Mg(OET)2-supportedTiCl4catalyst,1 Catalyst composition and behavior.MAKROMOL. CHEM.191 7.1990,191(7),1487-1496. *

Also Published As

Publication number Publication date
CN101146833A (zh) 2008-03-19
EP1863854A1 (en) 2007-12-12
WO2006103171A1 (en) 2006-10-05
US7879959B2 (en) 2011-02-01
RU2007139935A (ru) 2009-05-10
JP2008534723A (ja) 2008-08-28
KR20070118144A (ko) 2007-12-13
US20090209714A1 (en) 2009-08-20

Similar Documents

Publication Publication Date Title
KR100205525B1 (ko) 올레핀 중합 촉매 및 그를 사용하는 알파-올레핀 중합체 제조방법
US20020037979A1 (en) Mixed ziegler/metallocene catalysts for the production of bimodal polyolefins
EP1572756A1 (en) Catalyst components for the polymerization of olefins
JPH11501339A (ja) ボラベンゼン系オレフィン重合触媒
EP1112293B1 (en) Polymerization process using an improved bulky ligand metallocene-type catalyst system
JP2001505249A (ja) オレフィンの重合用成分および触媒
CN101146833B (zh) 用于烯烃聚合的催化剂组分
US7651969B2 (en) Catalyst system for producing ethylene (co) polymer with improved branch distribution
CN101151283B (zh) 制备结晶乙烯（共聚物）聚合物的方法
US6448348B1 (en) Process for polymerizing olefins with supported Ziegler-Natta catalyst systems
CN101163722B (zh) 用于烯烃聚合的催化剂组分
JP2002194019A (ja) オレフィン重合用触媒及びこれを利用した重合方法
JP2010510361A (ja) オレフィン類の重合用触媒成分
US20220389137A1 (en) Polymerization catalysts for production of polyethylene with high molecular weight
EP1330476B1 (en) Catalyst composition and process for olefin polymerization and copolymerization using supported metallocene catalyst systems
CN101326201B (zh) 用于烯烃聚合的催化剂组分
EP4306555A2 (en) Novel titanium complexes as catalysts for alpha olefin polymerization
US20030045659A1 (en) Process for polymerizing olefins with supported Ziegler-Natta catalyst systems
JPS63175005A (ja) オレフイン重合用担体形チタン成分の製造法
KR20060082165A (ko) 아릴옥시기를 포함하는 지글러-나타 촉매를 사용하는 기상중합에 의한 고투명성의 올레핀 공중합체 제조방법
BRPI0611461A2 (pt) componentes catalìticos para a polimerização de olefinas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20101208

Termination date: 20130315