CN101085752B - 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 - Google Patents
六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 Download PDFInfo
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- CN101085752B CN101085752B CN2007101278550A CN200710127855A CN101085752B CN 101085752 B CN101085752 B CN 101085752B CN 2007101278550 A CN2007101278550 A CN 2007101278550A CN 200710127855 A CN200710127855 A CN 200710127855A CN 101085752 B CN101085752 B CN 101085752B
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 38
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
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- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical group OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 claims description 16
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims description 15
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- 125000000217 alkyl group Chemical group 0.000 claims description 4
- WHVXVDDUYCELKP-UHFFFAOYSA-N butatriene Chemical compound C=C=C=C WHVXVDDUYCELKP-UHFFFAOYSA-N 0.000 claims description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 3
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- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract 1
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- 239000007788 liquid Substances 0.000 description 5
- 125000004646 sulfenyl group Chemical group S(*)* 0.000 description 5
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 5
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 4
- 229910018287 SbF 5 Inorganic materials 0.000 description 4
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 3
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
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- 238000001035 drying Methods 0.000 description 3
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
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- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 2
- DCEPGADSNJKOJK-UHFFFAOYSA-N 2,2,2-trifluoroacetyl fluoride Chemical compound FC(=O)C(F)(F)F DCEPGADSNJKOJK-UHFFFAOYSA-N 0.000 description 2
- XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 description 2
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- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
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- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
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- 229910021630 Antimony pentafluoride Inorganic materials 0.000 description 1
- SBCCOJBGDOWBIC-UHFFFAOYSA-N C(C)O.N#CO Chemical compound C(C)O.N#CO SBCCOJBGDOWBIC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
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- 101100136092 Drosophila melanogaster peng gene Proteins 0.000 description 1
- IUONGCZCCMAORT-UHFFFAOYSA-N FCC(C(=C(F)F)F)(F)F.S(O)(=O)(=O)F Chemical class FCC(C(=C(F)F)F)(F)F.S(O)(=O)(=O)F IUONGCZCCMAORT-UHFFFAOYSA-N 0.000 description 1
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical group [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
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- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 1
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- VBVBHWZYQGJZLR-UHFFFAOYSA-I antimony pentafluoride Chemical compound F[Sb](F)(F)(F)F VBVBHWZYQGJZLR-UHFFFAOYSA-I 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
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- 150000001768 cations Chemical class 0.000 description 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
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- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
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- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical group OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- GSJFXBNYJCXDGI-UHFFFAOYSA-N methyl 2-hydroxyacetate Chemical compound COC(=O)CO GSJFXBNYJCXDGI-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
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- 239000002798 polar solvent Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
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- 150000003384 small molecules Chemical class 0.000 description 1
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/16—Preparation of carboxylic acid nitriles by reaction of cyanides with lactones or compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/10—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and halogen atoms, or nitro or nitroso groups, bound to the same acyclic carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/26—Halogenosulfates, i.e. monoesters of halogenosulfuric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/28—Hexafluoropropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38052802P | 2002-05-14 | 2002-05-14 | |
| US60/380528 | 2002-05-14 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038108488A Division CN100334074C (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101085752A CN101085752A (zh) | 2007-12-12 |
| CN101085752B true CN101085752B (zh) | 2012-07-11 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101278531A Pending CN101092378A (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278550A Expired - Fee Related CN101085752B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278565A Expired - Fee Related CN101085753B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278546A Expired - Fee Related CN101085754B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CNB038108488A Expired - Fee Related CN100334074C (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101278531A Pending CN101092378A (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101278565A Expired - Fee Related CN101085753B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278546A Expired - Fee Related CN101085754B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CNB038108488A Expired - Fee Related CN100334074C (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Country Status (7)
| Country | Link |
|---|---|
| US (6) | US7276624B2 (enExample) |
| EP (1) | EP1513801B1 (enExample) |
| JP (2) | JP4472519B2 (enExample) |
| CN (5) | CN101092378A (enExample) |
| DE (1) | DE60336720D1 (enExample) |
| RU (1) | RU2004136314A (enExample) |
| WO (1) | WO2003097588A2 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7276624B2 (en) * | 2002-05-14 | 2007-10-02 | E. I. Du Pont De Nemours And Company | Fluorosulfates of hexafluoroisobutylene and its higher homologs |
| WO2006069107A2 (en) * | 2004-12-22 | 2006-06-29 | E.I. Dupont De Nemours And Company | Copolymers of perfluoro (alkyl venyl ether) for photochemical reactor, process for increasing fluorine content and production of olefinic compound by photochlorination |
| CN101090767A (zh) * | 2004-12-22 | 2007-12-19 | 纳幕尔杜邦公司 | 用于光化学反应的末端官能化全氟(烷基乙烯基醚)的官能化共聚物的反应器壁、增加烃和卤代烃的氟含量的方法和烯烃的制备 |
| CL2007003227A1 (es) * | 2006-11-09 | 2008-07-04 | Boehringer Ingelheim Int | Composicion farmaceutica que comprende un derivado de benceno sustituido con glucopiranosilo en combinacion con uno o mas agentes terapeuticos; y uso para el tratamiento de diabetes mellitus, obesidad e hiperglucemia entre otras. |
| JP5136070B2 (ja) * | 2008-01-15 | 2013-02-06 | 旭硝子株式会社 | パーフルオロアリルブロミドの製造方法 |
| JP5756752B2 (ja) * | 2008-07-03 | 2015-07-29 | セルカコール・ラボラトリーズ・インコーポレイテッドＣｅｒｃａｃｏｒ Ｌａｂｏｒａｔｏｒｉｅｓ， Ｉｎｃ． | センサ |
| WO2011122573A1 (ja) * | 2010-03-29 | 2011-10-06 | ダイキン工業株式会社 | ３－クロロ－ペンタフルオロプロペンの製造方法 |
| RU2430914C1 (ru) * | 2010-04-09 | 2011-10-10 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Перфтор[(2-фторсульфат)этилаллиловый] эфир |
| DK2588507T3 (da) * | 2010-07-01 | 2014-09-15 | Solvay Specialty Polymers It | Fremgangsmåde til behandling af sulfonylfluoridpolymerer |
| CN102225980B (zh) * | 2011-04-29 | 2012-11-21 | 内蒙古三爱富万豪氟化工有限公司 | 一种含氟醚端基结构的聚偏氟乙烯树脂及其制备方法 |
| JP5793996B2 (ja) * | 2011-06-29 | 2015-10-14 | セントラル硝子株式会社 | フルオロ硫酸芳香環エステル類の製造方法 |
| EP3383837A4 (en) * | 2015-12-02 | 2019-09-04 | 3M Innovative Properties Company | ALLYLIC, TERMINALLY UNSATURATED HYDROFLUORAMINE AND ALLYLIC, TERMINALLY UNSATURATED HYDROFLUOROETHER COMPOUNDS AND METHOD OF USE THEREOF |
| WO2017195070A1 (en) * | 2016-05-09 | 2017-11-16 | 3M Innovative Properties Company | Hydrofluoroolefins and methods of using same |
| CN107286061A (zh) * | 2017-06-09 | 2017-10-24 | 武汉理工大学 | 一种酚类化合物脱氧还原方法 |
| US12116336B2 (en) * | 2018-12-06 | 2024-10-15 | Lts Lohmann Therapie-Systeme Ag | Method for the recycling or disposal of halocarbons |
| CN114644539B (zh) * | 2022-04-01 | 2023-07-14 | 安徽农业大学 | 一种含烯烃的二氟芳氧醚的合成方法及其在农药中的用途 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1219063A (en) * | 1968-09-10 | 1971-01-13 | Allied Chem | Process for preparing fluoroisobutylenes |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2352554A (en) * | 1939-06-02 | 1944-06-27 | Redington Co F B | Stamp feeding and gluing mechanism |
| US2852554A (en) | 1956-07-12 | 1958-09-16 | Du Pont | Alpha-sulfopolyfluoromonocarboxylic acids and derivatives hydrolyzable thereto |
| US3862978A (en) * | 1967-08-24 | 1975-01-28 | Dow Chemical Co | Catalytic synthesis of organic halogen compounds from an ethylenically unsaturated compound and a halogenated organic compound |
| US3655786A (en) * | 1968-09-10 | 1972-04-11 | Allied Chem | Process for preparing fluoroisobutylenes and novel product |
| US3706723A (en) | 1970-04-29 | 1972-12-19 | Allied Chem | Copolymer of 3,3,3 - trifluoro-2-trifluoromethyl propene and vinylidene fluoride |
| US4131740A (en) | 1977-04-20 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Alkyl perfluoro-ω-fluoroformyl esters and their preparation |
| US4235804A (en) | 1978-08-08 | 1980-11-25 | E. I. Du Pont De Nemours And Company | Preparation of perfluoroallyl fluorosulfate |
| FR2433511A1 (fr) * | 1978-08-08 | 1980-03-14 | Du Pont | Fluorosulfate de perfluoroallyle et sa sultone et procedes pour leur preparation |
| US4273728A (en) * | 1979-03-14 | 1981-06-16 | E. I. Du Pont De Nemours And Company | Polyfluoroallyloxy compounds, their preparation and copolymers therefrom |
| EP0121073B1 (en) | 1983-03-07 | 1987-07-22 | Ausimont, U.S.A., Inc. | A process of rotational molding fluoropolymers |
| US4704324A (en) * | 1985-04-03 | 1987-11-03 | The Dow Chemical Company | Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups |
| CN1061663C (zh) | 1994-06-09 | 2001-02-07 | 大金工业株式会社 | 含氟聚合物 |
| US6025092A (en) | 1998-02-13 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Fluorinated ionomers and their uses |
| KR100615497B1 (ko) | 1999-03-16 | 2006-08-25 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 플라스틱 렌즈 및 장치용 저반사성 플루오로중합체 층 |
| EP1238309A1 (en) | 1999-11-17 | 2002-09-11 | E.I. Du Pont De Nemours And Company | Ultraviolet and vacuum ultraviolet transparent polymer compositions and their uses |
| IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
| US7438995B2 (en) | 2001-05-14 | 2008-10-21 | E.I. Du Pont De Nemours And Company | Use of partially fluorinated polymers in applications requiring transparency in the ultraviolet and vacuum ultraviolet |
| US6713567B2 (en) | 2001-07-13 | 2004-03-30 | E. I. Du Pont De Nemours And Company | Method for forming fluorinated ionomers |
| US6653515B2 (en) * | 2001-12-14 | 2003-11-25 | Ballard Power Systems Inc. | Synthesis of α, β, β-trifluorostyrene via in-situ formation of trifluorovinyl metal halide |
| US7276624B2 (en) * | 2002-05-14 | 2007-10-02 | E. I. Du Pont De Nemours And Company | Fluorosulfates of hexafluoroisobutylene and its higher homologs |
| US7129009B2 (en) * | 2002-05-14 | 2006-10-31 | E. I. Du Pont De Nemours And Company | Polymer-liquid compositions useful in ultraviolet and vacuum ultraviolet uses |
-
2003
- 2003-05-09 US US10/435,003 patent/US7276624B2/en not_active Expired - Lifetime
- 2003-05-14 JP JP2004505321A patent/JP4472519B2/ja not_active Expired - Fee Related
- 2003-05-14 RU RU2004136314/04A patent/RU2004136314A/ru not_active Application Discontinuation
- 2003-05-14 CN CNA2007101278531A patent/CN101092378A/zh active Pending
- 2003-05-14 DE DE60336720T patent/DE60336720D1/de not_active Expired - Lifetime
- 2003-05-14 EP EP03728891A patent/EP1513801B1/en not_active Expired - Lifetime
- 2003-05-14 CN CN2007101278550A patent/CN101085752B/zh not_active Expired - Fee Related
- 2003-05-14 CN CN2007101278565A patent/CN101085753B/zh not_active Expired - Fee Related
- 2003-05-14 WO PCT/US2003/015107 patent/WO2003097588A2/en not_active Ceased
- 2003-05-14 CN CN2007101278546A patent/CN101085754B/zh not_active Expired - Fee Related
- 2003-05-14 CN CNB038108488A patent/CN100334074C/zh not_active Expired - Fee Related
-
2007
- 2007-03-22 US US11/726,485 patent/US7579499B2/en not_active Expired - Fee Related
- 2007-03-22 US US11/726,449 patent/US7301059B2/en not_active Expired - Lifetime
- 2007-03-22 US US11/726,772 patent/US20070167589A1/en not_active Abandoned
- 2007-03-22 US US11/726,488 patent/US7531689B2/en not_active Expired - Fee Related
-
2009
- 2009-04-22 US US12/428,041 patent/US20090203865A1/en not_active Abandoned
- 2009-11-16 JP JP2009260902A patent/JP5149885B2/ja not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1219063A (en) * | 1968-09-10 | 1971-01-13 | Allied Chem | Process for preparing fluoroisobutylenes |
Also Published As
| Publication number | Publication date |
|---|---|
| DE60336720D1 (de) | 2011-05-26 |
| CN101085754B (zh) | 2013-01-23 |
| US7531689B2 (en) | 2009-05-12 |
| US20070167640A1 (en) | 2007-07-19 |
| US7301059B2 (en) | 2007-11-27 |
| CN101085752A (zh) | 2007-12-12 |
| CN101085753A (zh) | 2007-12-12 |
| CN101092378A (zh) | 2007-12-26 |
| CN101085753B (zh) | 2012-07-18 |
| RU2004136314A (ru) | 2005-05-10 |
| US20070167651A1 (en) | 2007-07-19 |
| EP1513801B1 (en) | 2011-04-13 |
| EP1513801A2 (en) | 2005-03-16 |
| CN1665779A (zh) | 2005-09-07 |
| US20070167652A1 (en) | 2007-07-19 |
| WO2003097588A2 (en) | 2003-11-27 |
| JP2010031058A (ja) | 2010-02-12 |
| US7276624B2 (en) | 2007-10-02 |
| JP4472519B2 (ja) | 2010-06-02 |
| JP2005525428A (ja) | 2005-08-25 |
| JP5149885B2 (ja) | 2013-02-20 |
| CN101085754A (zh) | 2007-12-12 |
| CN100334074C (zh) | 2007-08-29 |
| US20070167589A1 (en) | 2007-07-19 |
| WO2003097588A3 (en) | 2004-04-22 |
| US7579499B2 (en) | 2009-08-25 |
| US20040019237A1 (en) | 2004-01-29 |
| US20090203865A1 (en) | 2009-08-13 |
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Effective date of registration: 20171227 Address after: Delaware, USA Patentee after: Como Efsee Co.,Ltd. Address before: Wilmington, Delaware, USA Patentee before: E. I. du Pont de Nemours and Co. |
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