CN101048378B - N-烷氧基胺的合成方法 - Google Patents
N-烷氧基胺的合成方法 Download PDFInfo
- Publication number
- CN101048378B CN101048378B CN2005800370934A CN200580037093A CN101048378B CN 101048378 B CN101048378 B CN 101048378B CN 2005800370934 A CN2005800370934 A CN 2005800370934A CN 200580037093 A CN200580037093 A CN 200580037093A CN 101048378 B CN101048378 B CN 101048378B
- Authority
- CN
- China
- Prior art keywords
- compound
- formula
- butyl
- alkyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 0 C*(C(CC(*1O*)(N)N)CC1=*)NC Chemical compound C*(C(CC(*1O*)(N)N)CC1=*)NC 0.000 description 8
- YLHMLEZQTCCIGG-UHFFFAOYSA-N CCCCN(C(CC1(C)C)CC(C)(C)N1OCCC)c1nc(C(C)(C)N(CCCCCCNC(CC2(C)C)CC(C)(C)N2OCCC)C(CC2(C)C)CC(C)(C)N2OCCC)nc(N(CCCCCCNC(CC2(C)C)CC(C)(C)N2OCCC)C(CC2(C)C)CC(C)(C)N2OCCC)n1 Chemical compound CCCCN(C(CC1(C)C)CC(C)(C)N1OCCC)c1nc(C(C)(C)N(CCCCCCNC(CC2(C)C)CC(C)(C)N2OCCC)C(CC2(C)C)CC(C)(C)N2OCCC)nc(N(CCCCCCNC(CC2(C)C)CC(C)(C)N2OCCC)C(CC2(C)C)CC(C)(C)N2OCCC)n1 YLHMLEZQTCCIGG-UHFFFAOYSA-N 0.000 description 1
- HIROKUGRELXDPB-UHFFFAOYSA-N CCCCN(C(CC1(C)C)CC(C)(C)N1OCCC)c1nc(Cl)nc(Cl)n1 Chemical compound CCCCN(C(CC1(C)C)CC(C)(C)N1OCCC)c1nc(Cl)nc(Cl)n1 HIROKUGRELXDPB-UHFFFAOYSA-N 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N Clc1nc(Cl)nc(Cl)n1 Chemical compound Clc1nc(Cl)nc(Cl)n1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/42—One nitrogen atom
- C07D251/44—One nitrogen atom with halogen atoms attached to the two other ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/48—Two nitrogen atoms
- C07D251/50—Two nitrogen atoms with a halogen atom attached to the third ring carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Catalysts (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04105456 | 2004-11-02 | ||
| EP04105456.0 | 2004-11-02 | ||
| PCT/EP2005/055472 WO2006048389A1 (en) | 2004-11-02 | 2005-10-24 | Process for the synthesis of n-alkoxyamines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101048378A CN101048378A (zh) | 2007-10-03 |
| CN101048378B true CN101048378B (zh) | 2013-12-25 |
Family
ID=34929797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2005800370934A Expired - Lifetime CN101048378B (zh) | 2004-11-02 | 2005-10-24 | N-烷氧基胺的合成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (4) | US20090069470A1 (enExample) |
| EP (2) | EP1807395B1 (enExample) |
| JP (1) | JP4960874B2 (enExample) |
| CN (1) | CN101048378B (enExample) |
| ES (1) | ES2562403T3 (enExample) |
| PL (1) | PL1807395T3 (enExample) |
| SI (1) | SI1807395T1 (enExample) |
| TW (1) | TWI438192B (enExample) |
| WO (1) | WO2006048389A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5420179B2 (ja) * | 2008-02-29 | 2014-02-19 | 株式会社Adeka | ポリ乳酸樹脂組成物 |
| TWI492956B (zh) | 2009-12-01 | 2015-07-21 | Mitsubishi Rayon Co | 使用具有哌啶骨架的單體之聚合物的製造方法及成型體 |
| CN102464609A (zh) * | 2010-11-18 | 2012-05-23 | 南通市振兴精细化工有限公司 | 一种三丙酮胺4-羰基-2,2,6,6-四甲基哌啶氧自由基及其制造工艺 |
| KR101911115B1 (ko) | 2011-05-31 | 2018-10-23 | 미쯔비시 케미컬 주식회사 | 경화용 조성물 및 중합체 |
| WO2013095912A1 (en) * | 2011-12-19 | 2013-06-27 | Rohm And Haas Company | Improved method for the preparation of n-oxyl hindered amine inhibitors |
| WO2016057234A1 (en) * | 2014-10-10 | 2016-04-14 | Entegris, Inc. | Point of use or point of dispense filter with multiple pleat packs |
| US20190153219A1 (en) * | 2016-07-25 | 2019-05-23 | Mitsubishi Engineering-Plastics Corporation | Polycarbonate resin composition |
| KR102576757B1 (ko) * | 2016-08-29 | 2023-09-07 | 제이엔씨 주식회사 | 피페리딘 유도체, 액정 조성물, 및 액정 표시 소자 |
| CN109705023A (zh) * | 2018-10-23 | 2019-05-03 | 山东兄弟科技股份有限公司 | 一种双(1-烷氧基-2,2,6,6-四甲基哌啶-4-基)癸二酸酯的制备方法 |
| CN109825847B (zh) * | 2019-03-01 | 2020-09-01 | 宿迁联盛科技股份有限公司 | 受阻胺烷氧基化的中间体的制备方法 |
| CN113544126B (zh) | 2019-03-08 | 2024-11-08 | 巴斯夫欧洲公司 | 位阻胺稳定剂混合物 |
| CN112126060B (zh) * | 2019-06-25 | 2022-05-31 | 北京天罡助剂有限责任公司 | 一种聚合型高分子空间位阻胺及其制备方法 |
| CN113058289A (zh) * | 2021-02-19 | 2021-07-02 | 江钨世泰科钨品有限公司 | 一种钨酸钠溶液转型的萃取体系 |
| CN115724788A (zh) * | 2022-11-23 | 2023-03-03 | 宿迁盛瑞新材料有限公司 | 一种阻聚剂702的微通道合成方法 |
| CN116351412B (zh) * | 2023-01-17 | 2024-05-28 | 西安凯立新材料股份有限公司 | 一种抗氧剂44pd合成用负载型双金属催化剂及其催化方法 |
| WO2025067782A1 (en) * | 2023-09-27 | 2025-04-03 | Geneuschem Ag | Preparation of n-alkoxyamine hals from corresponding hydroxylamines |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0389419A1 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | Non-migrating 1-hydrocarbyloxy hindered amine compounds as polymer stabilizers |
| CN1257493A (zh) * | 1997-05-27 | 2000-06-21 | 西巴特殊化学品控股有限公司 | 可用作有机材料的稳定剂的含有1-烃氧基-2,2,6,6-四甲基-4-哌啶基基团的嵌段低聚物 |
| WO2003053931A1 (en) * | 2001-12-21 | 2003-07-03 | Ciba Specialty Chemicals Holding Inc. | Transition-metal-catalyzed process for the conversion of alkenes to sterically hindered substituted n-alkoxyamines |
| CN1592740A (zh) * | 2001-11-26 | 2005-03-09 | 西巴特殊化学品控股有限公司 | 由仲氨基氧化物合成胺醚的方法及其应用 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2042562B (en) | 1979-02-05 | 1983-05-11 | Sandoz Ltd | Stabilising polymers |
| US4691015A (en) | 1984-07-23 | 1987-09-01 | Ciba-Geigy Corporation | Hydroxylamines derived from hindered amines |
| US4734502A (en) | 1986-12-22 | 1988-03-29 | Ici Americas Inc. | Process for the preparation of 2,2,6,6-tetramethyl-4-oxopiperidine |
| US5204473A (en) * | 1987-09-21 | 1993-04-20 | Ciba-Geigy Corporation | O-substituted N-hydroxy hindered amine stabilizers |
| US5145893A (en) * | 1989-03-21 | 1992-09-08 | Ciba-Geigy Corporation | Non-migrating 1-hydrocarbyloxy hindered amine derivatives as polymer stabilizers |
| US5175312A (en) | 1989-08-31 | 1992-12-29 | Ciba-Geigy Corporation | 3-phenylbenzofuran-2-ones |
| IT1240690B (it) | 1990-04-30 | 1993-12-17 | Ciba Geigy Ag | Composti piperdin-triazinici atti all'impiego come stabilizzanti per materiali organici |
| TW206220B (enExample) | 1991-07-01 | 1993-05-21 | Ciba Geigy Ag | |
| US5252643A (en) | 1991-07-01 | 1993-10-12 | Ciba-Geigy Corporation | Thiomethylated benzofuran-2-ones |
| US5216156A (en) | 1992-05-05 | 1993-06-01 | Ciba-Geigy Corporation | Non-migrating 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine 1,3,5-triazine derivatives |
| NL9300801A (nl) | 1992-05-22 | 1993-12-16 | Ciba Geigy | 3-(acyloxyfenyl)benzofuran-2-on als stabilisatoren. |
| GB2267490B (en) | 1992-05-22 | 1995-08-09 | Ciba Geigy Ag | 3-(Carboxymethoxyphenyl)benzofuran-2-one stabilisers |
| TW260686B (enExample) | 1992-05-22 | 1995-10-21 | Ciba Geigy | |
| TW255902B (enExample) | 1992-09-23 | 1995-09-01 | Ciba Geigy | |
| MX9305489A (es) | 1992-09-23 | 1994-03-31 | Ciba Geigy Ag | 3-(dihidrobenzofuran-5-il)benzofuran-2-onas, estabilizadores. |
| FR2735481B1 (fr) | 1995-06-16 | 1997-08-22 | Rhone Poulenc Chimie | Nouveaux composes silicones a fonctions amines cycliques steriquement encombrees, utiles pour la stabilisation lumiere et thermique des polymeres |
| US6046304A (en) | 1995-12-04 | 2000-04-04 | Ciba Specialty Chemicals Corporation | Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials |
| TW428008B (en) * | 1997-05-27 | 2001-04-01 | Ciba Sc Holding Ag | Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethy1-4-piperidyl groups as stabilizers for organic materials |
| US5844026A (en) | 1997-06-30 | 1998-12-01 | Ciba Specialty Chemicals Corporation | N,N',N''-tris{2,4-bis Hydrocarbyloxy-2,2,6,6-tetra-methylpiperidin-4-yl)alkylamino!-s-triazin-6-yl}-3,3'-ethylenediiminodipropylamines, their isomers and bridged derivatives and polymer compositions stabilized therewith |
| US6599963B2 (en) * | 1997-06-30 | 2003-07-29 | Ciba Specialty Chemicals Corporation | Flame retardant compositions |
| SG74700A1 (en) | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
| KR100550224B1 (ko) | 1998-12-14 | 2006-02-08 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 입체장애 아민 화합물 |
| JP3816697B2 (ja) * | 1999-07-07 | 2006-08-30 | 大日精化工業株式会社 | 重合体が結合した機能剤、その製造方法、それらの使用方法及びそれらを使用した物品 |
| US6380285B1 (en) * | 2000-02-01 | 2002-04-30 | Ciba Specialty Chemicals Corporation | Bloom-resistant benzotriazole UV absorbers and compositions stabilized therewith |
| TW572896B (en) | 2000-05-26 | 2004-01-21 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| US6489482B2 (en) * | 2001-02-22 | 2002-12-03 | Council Of Scientific And Industrial Research | Process for the preparation of novel vinylic hindered amine light stabilizers |
| US6737528B2 (en) * | 2001-02-22 | 2004-05-18 | Council Of Scientific And Industrial Research | Vinylic hindered amine light stabilizers |
| US6465645B1 (en) * | 2001-04-17 | 2002-10-15 | Ciba Specialty Chemicals Corporation | Long chain hindered amines and compositions stabilized therewith |
| DE60232452D1 (de) * | 2001-08-15 | 2009-07-09 | Ciba Holding Inc | Flammwidrige zusammensetzungen |
| US7220288B2 (en) * | 2002-08-13 | 2007-05-22 | Belmay, Inc. | Protection of fragrance in a wax candle using an antioxidant |
| JP2007533867A (ja) * | 2004-04-23 | 2007-11-22 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 可染性ポリオレフィン繊維及び布 |
-
2005
- 2005-10-24 EP EP05801650.2A patent/EP1807395B1/en not_active Expired - Lifetime
- 2005-10-24 US US11/665,885 patent/US20090069470A1/en not_active Abandoned
- 2005-10-24 WO PCT/EP2005/055472 patent/WO2006048389A1/en not_active Ceased
- 2005-10-24 PL PL05801650T patent/PL1807395T3/pl unknown
- 2005-10-24 EP EP15181106.4A patent/EP2993168B1/en not_active Expired - Lifetime
- 2005-10-24 ES ES05801650.2T patent/ES2562403T3/es not_active Expired - Lifetime
- 2005-10-24 JP JP2007539568A patent/JP4960874B2/ja not_active Expired - Lifetime
- 2005-10-24 CN CN2005800370934A patent/CN101048378B/zh not_active Expired - Lifetime
- 2005-10-24 SI SI200532045T patent/SI1807395T1/sl unknown
- 2005-10-31 TW TW094138062A patent/TWI438192B/zh active
-
2010
- 2010-09-27 US US12/890,846 patent/US20110015315A1/en not_active Abandoned
-
2012
- 2012-10-15 US US13/651,497 patent/US20130041148A1/en not_active Abandoned
-
2014
- 2014-10-14 US US14/514,043 patent/US20150031879A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0389419A1 (en) * | 1989-03-21 | 1990-09-26 | Ciba-Geigy Ag | Non-migrating 1-hydrocarbyloxy hindered amine compounds as polymer stabilizers |
| CN1257493A (zh) * | 1997-05-27 | 2000-06-21 | 西巴特殊化学品控股有限公司 | 可用作有机材料的稳定剂的含有1-烃氧基-2,2,6,6-四甲基-4-哌啶基基团的嵌段低聚物 |
| CN1592740A (zh) * | 2001-11-26 | 2005-03-09 | 西巴特殊化学品控股有限公司 | 由仲氨基氧化物合成胺醚的方法及其应用 |
| WO2003053931A1 (en) * | 2001-12-21 | 2003-07-03 | Ciba Specialty Chemicals Holding Inc. | Transition-metal-catalyzed process for the conversion of alkenes to sterically hindered substituted n-alkoxyamines |
Also Published As
| Publication number | Publication date |
|---|---|
| US20150031879A1 (en) | 2015-01-29 |
| EP1807395B1 (en) | 2015-12-23 |
| CN101048378A (zh) | 2007-10-03 |
| JP4960874B2 (ja) | 2012-06-27 |
| US20090069470A1 (en) | 2009-03-12 |
| EP1807395A1 (en) | 2007-07-18 |
| JP2008519003A (ja) | 2008-06-05 |
| US20130041148A1 (en) | 2013-02-14 |
| EP2993168A1 (en) | 2016-03-09 |
| EP2993168B1 (en) | 2017-05-17 |
| PL1807395T3 (pl) | 2016-06-30 |
| SI1807395T1 (sl) | 2016-04-29 |
| WO2006048389A1 (en) | 2006-05-11 |
| US20110015315A1 (en) | 2011-01-20 |
| ES2562403T3 (es) | 2016-03-04 |
| TWI438192B (zh) | 2014-05-21 |
| TW200630339A (en) | 2006-09-01 |
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Granted publication date: 20131225 |