CN101006112A - 由本体聚合方法生产的高光泽橡胶改性单亚乙烯基芳族聚合物 - Google Patents
由本体聚合方法生产的高光泽橡胶改性单亚乙烯基芳族聚合物 Download PDFInfo
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- CN101006112A CN101006112A CNA2004800036845A CN200480003684A CN101006112A CN 101006112 A CN101006112 A CN 101006112A CN A2004800036845 A CNA2004800036845 A CN A2004800036845A CN 200480003684 A CN200480003684 A CN 200480003684A CN 101006112 A CN101006112 A CN 101006112A
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- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C08L25/02—Homopolymers or copolymers of hydrocarbons
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- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
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- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
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- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C08L25/02—Homopolymers or copolymers of hydrocarbons
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
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- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/02—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to polysaccharides
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
- C08L9/08—Latex
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/904—Activation of preformed polymer in absence or monomer, for subsequent polymerization thereon, e.g. trapped radicals
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
实施例 | 1* | 2 | 3 | 4 | 5 | 对比1 | 对比2 | |
90% | 10% | |||||||
方法 | A | C | B | B | B | D | D | A |
橡胶组分 | 1 | 5 | 2 | 3 | 4 | 3 | 2 | 2 |
区域1进料组合物 | ||||||||
橡胶组分类型 | 1 | 无 | 2 | 3 | 4 | 3 | 2 | 2 |
橡胶组分(wt.%) | 14 | 0 | 14.5 | 13.5 | 13.2 | 13.5 | 14.5 | 14.5 |
丙烯腈(wt%) | 16 | 20 | 15.7 | 17.0 | 17.0 | 17.0 | 15.7 | 15.7 |
乙苯(wt%) | 15 | 15 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 |
苯乙烯(wt%) | 55 | 65 | 54.65 | 54.35 | 54.55 | 54.35 | 54.65 | 54.65 |
PDMS DC50(wt%) | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 | 0.15 |
1,1-二(t-丁基过氧)环己烷(ppm) | 100 | 200 | 140 | 145 | 145 | 120 | 100 | 140 |
NDM(到区域1)(ppm) | 200 | 0 | 350 | 350 | 350 | 0 | 0 | 300 |
NDM(到区域4)(ppm) | 1200 | 460 | 0 | 0 | 0 | 1300 | 1200 | 0 |
NDM(到区域5)(ppm) | 0 | 0 | 1700 | 2000 | 1700 | 0 | 0 | 1700 |
NDM(到区域6)(ppm) | 1600 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
NDM(到区域7)(ppm) | 0 | 1520 | 0 | 500 | 500 | 750 | 900 | 0 |
%到区域5的循环 | 0 | 6 | 0 | 0 | 0 | 0 | 6 | |
%到区域5的进料(相对于区域1) | 0 | 123 | 25 | 25 | 25 | 0 | 0 | 0 |
区域5进料组合物 | ||||||||
橡胶组分类型 | 5 | 2 | 3 | 4 | ||||
橡胶组分(wt.%) | 17.5 | 14.5 | 13.5 | 13.2 | ||||
丙烯腈(wt.%) | 16 | 15.7 | 17.0 | 17.0 | ||||
苯乙烯(wt.%) | 51.5 | 15.0 | 15.0 | 15.0 | ||||
乙苯(wt.%) | 15 | 54.65 | 54.35 | 54.55 | ||||
PDMS DC50(wt.%) | 0.15 | 0.15 | 0.15 | 0.15 | ||||
到区域6的AcrawaxC(wt.%) | 0 | 0 | 0 | 0.9%. | 0.9% | 1.1% | 0 | 0 |
到区域2的再循环 | 0 | 0 | 0 | 0 | 0 | 30 | 30 | 0 |
RPM第一反应器 | 80 | 120 | 120 | 120 | 120 | 120 | 120 | 120 |
RPM第二反应器 | 60 | 60 | 80 | 80 | 90 | 75 | 80 | 100 |
RPM第三反应器 | 30 | 30 | 20 | 25 | 25 | 25 | 25 | 25 |
最终产物性能 | ||||||||
橡胶粒度(RPs)(微米) | 0.21 | 0.21 | 0.24 | 0.24 | 0.20 | 0.16 | ||
RPS Dv(微米) | 0.24 | 0.25 | 0.25 | 0.30 | 0.27 | 0.24 | 0.18 | |
RPS D(z+1) | 0.34 | 0.35 | 0.42 | 0.32 | 0.29 | 0.21 | ||
D2=(D(z+1)/Dn) | 1.61 | 1.67 | 1.75 | 1.33 | 1.45 | 1.31 | ||
组合物 | ||||||||
Acrawax C(wt.%) | 1 | 0 | 1.5 | 1 | 1.5 | 1.5 | 0 | |
丙烯腈(%) | 22 | 20.6 | 21.2 | 20.4 | 21.1 | 19.5 | 20.5 | |
聚丁二烯级分(%) | 13.8 | 15.3 | 15.5 | 14.8 | 15.1 | 14.6 | 13.5 | |
总橡胶(wt.%) | 16.2 | 19.6 | 17.6 | 16.3 | 17.1 | 18.7 | 17.3 | |
总橡胶相体积Φ(%) | 21.0 | 27.3 | 31.4 | 32.3 | 27.2 | 30.6 | 24.5 | |
橡胶相体积>0.4微米Φ+(%) | 2.5 | 7.9 | 10.7 | 14.2 | 3.8 | 1.2 | 0.2 | |
100×Φ+/Φ(%) | 12 | 29 | 34 | 44 | 14 | 4 | <1 | |
Mw(/1000)(克/摩尔) | 113 | 138 | 125 | 123 | 133 | 131 | 151 | |
Mn(/1000)(克/摩尔) | 39 | 47 | 40 | 42 | 48 | 46 | 47 | |
Mw/Mn | 2.90 | 2.94 | 3013 | 3.15 | 2.77 | 2.85 | 3.21 | |
%交联橡胶 | 93 | 94 | 95 | 95 | 99 | |||
特性光泽 | 79 | 83 | 82 | 81 | 83 | 85 | 79 | |
MFR(克/10min) | 4.5 | 3.3 | 4.8 | 4.5 | 4.8 | 4.8 | 1.9 | |
悬臂梁(J/m) | 246 | 406 | 342 | 368 | 358 | 224 | 43 | |
总能量(J) | 44 | 43 | 44 | 37 | 36 | 13 | 4 |
Claims (14)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US44555703P | 2003-02-05 | 2003-02-05 | |
US60/445,557 | 2003-02-05 | ||
PCT/US2004/000978 WO2004072172A2 (en) | 2003-02-05 | 2004-01-15 | High gloss rubber modified monovinylidene aromatic polymers produced by a mass polymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101006112A true CN101006112A (zh) | 2007-07-25 |
CN101006112B CN101006112B (zh) | 2010-05-26 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004800036845A Expired - Fee Related CN101006112B (zh) | 2003-02-05 | 2004-01-15 | 由本体聚合方法生产的高光泽橡胶改性单亚乙烯基芳族聚合物 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7115684B2 (zh) |
EP (1) | EP1618148B1 (zh) |
JP (1) | JP2007525544A (zh) |
KR (1) | KR101027307B1 (zh) |
CN (1) | CN101006112B (zh) |
AT (1) | ATE426624T1 (zh) |
CA (1) | CA2515038A1 (zh) |
DE (1) | DE602004020205D1 (zh) |
ES (1) | ES2321402T3 (zh) |
MX (1) | MXPA05008345A (zh) |
WO (1) | WO2004072172A2 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104610694A (zh) * | 2011-12-30 | 2015-05-13 | 奇美实业股份有限公司 | 苯乙烯系树脂组成物及由其制得的成型品 |
CN107075045A (zh) * | 2015-06-19 | 2017-08-18 | 株式会社Lg化学 | 改性丙烯腈‑丁二烯‑苯乙烯树脂的制备方法及所制备的改性丙烯腈‑丁二烯‑苯乙烯树脂 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20042401A1 (it) | 2004-12-16 | 2005-03-16 | Polimeri Europa Spa | Procedimento per la preparazione di co-polimeri vinilaromatici antiurto aggraffati su elastomero |
US20100113699A1 (en) * | 2006-12-29 | 2010-05-06 | Dedecker Mark N | Method of preparing rubber comprising polymeric compositions and isoprene comprising interpolymers |
WO2008097300A2 (en) * | 2007-02-08 | 2008-08-14 | Regents Of The University Of Minnesota | Ion gels and electronic devices utilizing ion gels |
ITMI20071468A1 (it) * | 2007-07-20 | 2009-01-21 | Polimeri Europa Spa | Procedimento per la preparazione di copolimeri vinilaromatici antiurto trasparenti |
IT1393666B1 (it) * | 2008-12-16 | 2012-05-08 | Polimeri Europa Spa | (co)polimero vinilaromatico rinforzato con gomma avente un ottimo bilancio di proprieta' fisico-meccaniche ed una elevata lucentezza |
EP2230260A1 (en) | 2009-03-10 | 2010-09-22 | Total Petrochemicals Research Feluy | Rubber modified monovinylaromatic polymer composition |
JP5696662B2 (ja) | 2009-06-01 | 2015-04-08 | 日立化成株式会社 | 有機エレクトロルミネセンス素子、表示素子、照明装置および表示装置 |
KR102226065B1 (ko) | 2018-03-20 | 2021-03-11 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
CN111218086A (zh) * | 2020-03-02 | 2020-06-02 | 台州市安安焊接设备有限公司 | 电焊机塑件用高耐热阻燃abs材料及其注塑工艺 |
KR20230116914A (ko) | 2020-12-07 | 2023-08-04 | 오티아이 루미오닉스 인크. | 핵 생성 억제 코팅 및 하부 금속 코팅을 사용한 전도성 증착 층의 패턴화 |
TW202330677A (zh) | 2021-12-10 | 2023-08-01 | 義大利商佛沙里斯股份有限公司 | 橡膠強化的乙烯芳香族(共)聚合物及其製備方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2646418A (en) | 1951-05-25 | 1953-07-21 | Dow Chemical Co | Process for polymerizing monovinyl aromatic compounds with rubber |
US2727884A (en) | 1953-04-13 | 1955-12-20 | Dow Chemical Co | Process of mass polymerization in vertical unmixed strata |
US4311819A (en) | 1979-07-18 | 1982-01-19 | The Dow Chemical Company | Preparation of alkenyl aromatic monomer butadiene rubber |
US4409369A (en) | 1980-03-03 | 1983-10-11 | The Dow Chemical Company | Transparent impact resin and process for the preparation thereof |
NL8202281A (nl) * | 1982-06-04 | 1984-01-02 | Dow Chemical Nederland | Met rubber versterkte polymeren van aromatische monovinylideenverbindingen en werkwijze voor de bereiding daarvan. |
US4581429A (en) | 1983-07-11 | 1986-04-08 | Commonwealth Scientific And Industrial Research Organization | Polymerization process and polymers produced thereby |
FR2730241B1 (fr) | 1995-02-07 | 1997-02-28 | Atofina | Procede de fabrication d'une composition comprenant un polymere vinylaromatique et un caoutchouc par polymerisation en presence d'un radical libre stable |
FR2730240A1 (fr) | 1995-02-07 | 1996-08-09 | Atochem Elf Sa | Stabilisation d'un polymere par un radical libre stable |
CN1150232C (zh) * | 1995-10-27 | 2004-05-19 | 东丽株式会社 | 耐冲击性树脂组合物的制造方法 |
HU220138B (hu) * | 1996-03-29 | 2001-11-28 | The Dow Chemical Co. | Szabadgyökös tömbpolimerizálási eljárás kaucsukkal módosított polimerek vinil-aromás monomerekből való előállítására |
CN1122678C (zh) * | 1997-08-13 | 2003-10-01 | 陶氏环球技术公司 | 高光泽高抗冲单亚乙烯基芳烃聚合物 |
FR2768739B1 (fr) * | 1997-09-19 | 2004-08-06 | Atochem Elf Sa | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
FR2779437B1 (fr) * | 1998-06-03 | 2004-10-15 | Atochem Elf Sa | Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation |
US6380304B1 (en) * | 1999-09-30 | 2002-04-30 | The Dow Chemical Company | Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions |
CN1164632C (zh) * | 1999-12-23 | 2004-09-01 | 陶氏环球技术公司 | 具有改进性能的单亚乙烯基芳族聚合物及其制备方法 |
DE10016651A1 (de) | 2000-04-04 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung von Polymeren |
TWI274053B (en) * | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
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- 2004-01-15 AT AT04702520T patent/ATE426624T1/de not_active IP Right Cessation
- 2004-01-15 KR KR1020057014324A patent/KR101027307B1/ko not_active IP Right Cessation
- 2004-01-15 ES ES04702520T patent/ES2321402T3/es not_active Expired - Lifetime
- 2004-01-15 US US10/541,925 patent/US7115684B2/en not_active Expired - Fee Related
- 2004-01-15 WO PCT/US2004/000978 patent/WO2004072172A2/en active Application Filing
- 2004-01-15 MX MXPA05008345A patent/MXPA05008345A/es active IP Right Grant
- 2004-01-15 CA CA002515038A patent/CA2515038A1/en not_active Abandoned
- 2004-01-15 EP EP04702520A patent/EP1618148B1/en not_active Expired - Lifetime
- 2004-01-15 DE DE602004020205T patent/DE602004020205D1/de not_active Expired - Lifetime
- 2004-01-15 JP JP2006502831A patent/JP2007525544A/ja active Pending
- 2004-01-15 CN CN2004800036845A patent/CN101006112B/zh not_active Expired - Fee Related
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104610694A (zh) * | 2011-12-30 | 2015-05-13 | 奇美实业股份有限公司 | 苯乙烯系树脂组成物及由其制得的成型品 |
CN104610694B (zh) * | 2011-12-30 | 2017-10-10 | 奇美实业股份有限公司 | 苯乙烯系树脂组成物及由其制得的成型品 |
CN107075045A (zh) * | 2015-06-19 | 2017-08-18 | 株式会社Lg化学 | 改性丙烯腈‑丁二烯‑苯乙烯树脂的制备方法及所制备的改性丙烯腈‑丁二烯‑苯乙烯树脂 |
CN107075045B (zh) * | 2015-06-19 | 2019-06-28 | 株式会社Lg化学 | 改性丙烯腈-丁二烯-苯乙烯树脂的制备方法及所制备的改性丙烯腈-丁二烯-苯乙烯树脂 |
Also Published As
Publication number | Publication date |
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WO2004072172A3 (en) | 2007-12-27 |
DE602004020205D1 (de) | 2009-05-07 |
CN101006112B (zh) | 2010-05-26 |
CA2515038A1 (en) | 2004-08-26 |
KR101027307B1 (ko) | 2011-04-06 |
US20060122331A1 (en) | 2006-06-08 |
KR20050102633A (ko) | 2005-10-26 |
JP2007525544A (ja) | 2007-09-06 |
WO2004072172A2 (en) | 2004-08-26 |
EP1618148A2 (en) | 2006-01-25 |
US7115684B2 (en) | 2006-10-03 |
EP1618148B1 (en) | 2009-03-25 |
ES2321402T3 (es) | 2009-06-05 |
MXPA05008345A (es) | 2005-11-04 |
ATE426624T1 (de) | 2009-04-15 |
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