CN101002573A - Compounding insecticide containing destruxin and abamectin - Google Patents
Compounding insecticide containing destruxin and abamectin Download PDFInfo
- Publication number
- CN101002573A CN101002573A CNA2006101323142A CN200610132314A CN101002573A CN 101002573 A CN101002573 A CN 101002573A CN A2006101323142 A CNA2006101323142 A CN A2006101323142A CN 200610132314 A CN200610132314 A CN 200610132314A CN 101002573 A CN101002573 A CN 101002573A
- Authority
- CN
- China
- Prior art keywords
- destruxins
- avermectin
- solvent
- assistant agent
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A composite insecticide in the form of emulsified oil or microemulsion for preventing and eliminating tobacco aleyrodids is proportionally prepared from melarrhizin, abameotin, solvent, emulsifier, and other assistants including co-solvent, synergist, or optional anti-freezing agent.
Description
Technical field
The present invention relates to a kind of biological insecticides, specifically, relate to the compounded pesticides of a kind of destruxins and Avermectin.
Background technology
Destruxins (destruxin) is the secondary metabolite of insect pathogenic fungus-green muscardine fungus (Metarhiziumanisopliae var.anisopliae), is the important virulence factor of green muscardine fungus.Destruxins has desinsection, biologically active such as antiviral and anticancer, and has the brand-new mechanism of action that is different from existing insecticide and the easy feature of degraded and noresidue, and the development and use destruxins has important economic implications.Destruxins A, B, E distribute the extensivelyst, and the destruxins that content is the highest has good control efficiency to aphid, Bemisia tabaci, diamond-back moth etc., has a good application prospect.
Avermectin (abamectin) is present widely used high-efficient broad-spectrum insecticide, is mainly used in important pests such as control diamond-back moth, Bemisia tabaci and liriomyza bryoniae, and still, insect has also been developed into a major issue to the Avermectin pesticide resistance.Adopting the agriculture chemical compounding technology or mixing application technique is to overcome or delay a drug-fast important method, and therefore, the Compositional type insecticide of exploitation Avermectin is significant.
Summary of the invention
The Compositional type insecticide that the purpose of this invention is to provide a kind of destruxins and Avermectin.
The compounded pesticides of a kind of destruxins and Avermectin is made up of host and assistant agent, and its percentage by weight is a host 0.5～5%, assistant agent 95～99.5%; Described host is the mixture of destruxins and Avermectin, and its weight ratio is: destruxins: Avermectin=1: 0.5～40.
As preferably, the preferred weight ratio of destruxins and Avermectin is: destruxins: Avermectin=1: 5～20.
As preferably, the preferred destruxins A of destruxins, destruxins B or destruxins E or its mixture.
This compounded pesticides can be made into the formulation of various needs.Missible oil formulation (EC) for example, the assistant agent of this moment is solvent, emulsifier and other assistant agent, its weight ratio is 50～99: 1～50: 0～5.Described solvent is acetone, methyl alcohol, ethyl acetate, carrene and arene etc.; Described emulsifier is nonionic, anion or nonionic and anionic compound surfactant; Described other assistant agent is meant cosolvent or synergist or its mixture.Preferred benzene,toluene,xylene of described arene or ethylbenzene.
Perhaps make micro emulsion formulation (ME), the assistant agent of this moment is solvent, emulsifier, other assistant agent and water, and its weight ratio is: solvent: emulsifier: other assistant agent: water=1～20: 5～60: 0～20: 20～90.Described solvent is arene or ester class, and described emulsifier is nonionic, anion or nonionic and anionic compound surfactant; Described other assistant agent is antifreezing agent, cosolvent or synergist.Preferred benzene,toluene,xylene of described aromatic hydrocarbon solvent or ethylbenzene, described esters solvent ethyl acetate, methyl formate or Ethyl formate.
Compared with prior art, Compositional type insecticide of the present invention has following beneficial effect: (1) has synergistic effect, and composite dose co-toxicity coefficient is greater than 120.(2) help delaying pest resistance to insecticide and produce, the insect of antagonism Avermectin is effective.(3) price a little less than or be not higher than existing kind.
Embodiment
The preparation of embodiment 1:1% destruxins and abamectin emulsifiable concentrate (EC) preparation
The mass ratio of each component is: destruxins A0.1%, Avermectin 0.9%, solvent 80%, emulsifier 19%.
Compound method: first weighing solvent is dissolved in destruxins A and Avermectin in ethyl acetate and the toluene respectively in container then, adds emulsifier again, fully stirs evenly the back packing.The preparation of embodiment 2:2% destruxins and abamectin emulsifiable concentrate (EC) preparation
The mass ratio of each component is: destruxins 0.1%, Avermectin 1.9%, solvent 90%, emulsifier 8%.
Compound method: first weighing solvent takes by weighing thick destruxins and Avermectin then respectively and is dissolved in the solvent in container, adds emulsifier again, fully stirs evenly the back packing.
The green stiff avermectin micro-emulsion of embodiment 3:3% (ME)
The mass ratio of each component is: destruxins 0.1%, Avermectin 2.9%, solvent 8%, emulsifier 15%, water 74%.
Compound method: first weighing solvent is dissolved in destruxins and Avermectin in the solvent respectively in container then, adds emulsifier again, makes preparation become the solution of homogeneous transparent after fully stirring evenly, and packs then.
Embodiment 4: mixture is to the Toxicity Determination of Bemisia tabaci (Bemisia tabaci)
During Toxicity Determination, make test plant with Japan (Hibiscus rosa-sinensis L.), its potted plant seedling is educated in dependent insect cage, Bemisia tabaci adults is inserted dependent insect cage, treat after it was laid eggs one day it all to be driven out of, keep 26 ℃ temperature and 14: 10 illumination in the cage, treat that Bemisia tabaci on Japan's blade grows to 2 ages during nymph, adopt infusion process to carry out the virulence test, repeat 4 times, 4 days effect behind the investigation medicine, the calculation correction lethality, ask the regression equation of drug concentration logarithm-lethality probability value, and the comptibility test of the side of card, obtain LC then
50, calculate the co-toxicity coefficient (CTC) of relative virus force index (TI) and intermixture with reference to the abundant method of Sun Yun.Its result of the test such as table 1 when destruxins A or thick destruxins and Avermectin are mixed, have synergistic effect.
The green stiff Avermectin of table 1 is to the Toxicity Determination of Bemisia tabaci (behind the medicine 4 days)
| Handle | Virulence regression equation | R 2 | LC 50And 95% confidence interval | TI | CTC |
| Destruxins A | y＝3.8670x-1.5008 | 0.9816 | 47.98，45.51-50.59 | 100.00 | |
| Avermectin | y＝2.0096x+2.9539 | 0.9944 | 10.43，9.64-11.28 | 460.19 | |
| Destruxins A: Avermectin (1: 1) | y＝1.697x+3.013 | 0.9712 | 14.82，13.62-16.13 | 323.75 | 115.59 |
| Destruxins A: Avermectin (1: 9) | y＝1.9217x+3.1360 | 0.9961 | 9.33，8.65-10.06 | 514.19 | 121.22 |
| Destruxins A: Avermectin (1: 19) | y＝2.0570x+3.1088 | 0.9541 | 8.31，7.74-8.91 | 577.7 | 130.65 |
| Destruxins A: Avermectin (1: 29) | y＝1.9893x+3.1599 | 0.9705 | 8.41，7.83-9.04 | 570.29 | 127.25 |
| Thick destruxins | y＝2.9740x- 0.1058 | 0.9690 | 52.10，49.06-55.33 | 100.00 | |
| Thick destruxins: Avermectin (1: 1) | y＝1.8616x+ 2.8280 | 0.9659 | 14.68，13.59-15.86 | 354.87 | 118.36 |
| Thick destruxins: Avermectin (1: 9) | y＝2.0219x+3.0015 | 0.9702 | 9.74，9.04-10.48 | 535.04 | 116.40 |
| Thick destruxins: Avermectin (1: 19) | y＝1.75 14x+3.4144 | 0.9760 | 8.04，7.41-8.73 | 647.86 | 135.07 |
| Thick destruxins: Avermectin (1: 29) | y＝1.7410x+3.4126 | 0.9709 | 8.16，7.51-8.87 | 638.32 | 131.26 |
Thick destruxins is the destruxins crude extract, contains A, B, three kinds of destruxinses of E, and its ratio is A: B: E=6.5: 1.9: 1.6; R
2: determination coefficient; TI: relative virus force index; CTC: co-toxicity coefficient.CTC had the effect of subtracting effect less than 80 o'clock between the two; Greater than having synergistic effect at 120 o'clock; It in the time of between 80～120 summation action.
Claims (9)
1, the compounded pesticides of a kind of destruxins and Avermectin is characterized in that, is made up of host and assistant agent, and its percentage by weight is a host 0.5～5%, assistant agent 95～99.5%; Described host is the mixture of destruxins and Avermectin, and its weight ratio is: destruxins: Avermectin=1: 0.5～40.
2, compounded pesticides as claimed in claim 1 is characterized in that, the weight ratio of described destruxins and Avermectin is: destruxins: Avermectin=1: 5～20.
3, compounded pesticides as claimed in claim 1 or 2 is characterized in that, described destruxins is one or more the mixture among destruxins A, destruxins B, the destruxins E.
4, compounded pesticides as claimed in claim 1 or 2 is characterized in that, described assistant agent is solvent, emulsifier and other assistant agent, and its weight ratio is 50～99: 1～50: 0～5.
5, compounded pesticides as claimed in claim 4 is characterized in that, described solvent is an arene; Described emulsifier is nonionic, anion or nonionic and anionic compound surfactant; Described other assistant agent is meant cosolvent or synergist or its mixture.
6, compounded pesticides as claimed in claim 5 is characterized in that, described arene is benzene,toluene,xylene or ethylbenzene.
7, compounded pesticides as claimed in claim 1 or 2 is characterized in that, described assistant agent is solvent, emulsifier, other assistant agent and water, and its weight ratio is: solvent: emulsifier: other assistant agent: water=1～20: 5～60: 0～20: 20～90.
8, compounded pesticides as claimed in claim 7 is characterized in that, described solvent is arene or ester class, and described emulsifier is nonionic, anion or nonionic and anion compounded surfactant; Described other assistant agent is antifreezing agent, cosolvent or synergist or its mixture.
9, compounded pesticides as claimed in claim 8 is characterized in that, described aromatic hydrocarbon solvent is benzene,toluene,xylene or ethylbenzene, and described ester class is ethyl acetate, methyl formate or Ethyl formate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101323142A CN100477920C (en) | 2006-12-26 | 2006-12-26 | Compounding insecticide containing destruxin and abamectin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101323142A CN100477920C (en) | 2006-12-26 | 2006-12-26 | Compounding insecticide containing destruxin and abamectin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101002573A true CN101002573A (en) | 2007-07-25 |
| CN100477920C CN100477920C (en) | 2009-04-15 |
Family
ID=38702132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101323142A Expired - Fee Related CN100477920C (en) | 2006-12-26 | 2006-12-26 | Compounding insecticide containing destruxin and abamectin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100477920C (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101433215B (en) * | 2008-12-15 | 2011-04-27 | 华南农业大学 | Compositional main pesticide and pesticide containing destruxins of Metarhizium anisopliae and high-efficient cypermethrin |
| CN101433214B (en) * | 2008-12-15 | 2011-04-27 | 华南农业大学 | Compositional disinsection main agent containing destruxins of Metarhizium anisopliae and deltamethrin |
| CN101433216B (en) * | 2008-12-15 | 2011-04-27 | 华南农业大学 | Compositional main pesticide and pesticide containing destruxins of Metarhizium anisopliae and phoxim |
| CN101438713B (en) * | 2008-12-15 | 2011-06-22 | 华南农业大学 | Compositional disinsection main agent containing destruxins of Metarhizium anisopliae and chlopyrifos |
| CN101438715B (en) * | 2008-12-15 | 2011-06-22 | 华南农业大学 | Compositional disinsection main agent and pesticide containing destruxins of Metarhizium anisopliae and buprofezin |
| CN101438716B (en) * | 2008-12-15 | 2011-08-17 | 华南农业大学 | Compounding pesticide containing destruxins of Metarrhizium anisopliae and Paecilomyces fumosoroseus and preparation method thereof |
| CN101438714B (en) * | 2008-12-15 | 2011-08-17 | 华南农业大学 | Compounding pesticide containing Beauveria bassiana and destruxins of Metarrhizium anisopliae and preparation method thereof |
| CN101427691B (en) * | 2008-12-15 | 2011-11-16 | 华南农业大学 | Scarabaeus green muscardine fungus and green muscardine fungus native mixed insecticidal composition |
| CN103478144A (en) * | 2013-09-26 | 2014-01-01 | 卞佳林 | Avermectin and griseofulvin composite pesticidal nanoemulsion |
| CN105794859A (en) * | 2013-01-25 | 2016-07-27 | 陕西汤普森生物科技有限公司 | Insecticidal compound containing conidioblous thromboides and biological sources |
| CN106305780A (en) * | 2016-08-18 | 2017-01-11 | 广西鑫雅皇庭园林工程有限责任公司 | Pesticide for Hibiscus root-knot nematode disease |
| CN115053913A (en) * | 2022-06-30 | 2022-09-16 | 广西壮族自治区国有钦廉林场 | Compound pesticide and method for preventing and controlling underground pests |
| CN116250546A (en) * | 2022-12-28 | 2023-06-13 | 乌鲁木齐市园林绿化工程质量监督站(乌鲁木齐市林草种苗站) | Composition for controlling grassland locust insect pests |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1433693A (en) * | 2002-01-23 | 2003-08-06 | 李智生 | Abamectin and entomogenous fungi composed microbial pesticide |
-
2006
- 2006-12-26 CN CNB2006101323142A patent/CN100477920C/en not_active Expired - Fee Related
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101438714B (en) * | 2008-12-15 | 2011-08-17 | 华南农业大学 | Compounding pesticide containing Beauveria bassiana and destruxins of Metarrhizium anisopliae and preparation method thereof |
| CN101433215B (en) * | 2008-12-15 | 2011-04-27 | 华南农业大学 | Compositional main pesticide and pesticide containing destruxins of Metarhizium anisopliae and high-efficient cypermethrin |
| CN101433216B (en) * | 2008-12-15 | 2011-04-27 | 华南农业大学 | Compositional main pesticide and pesticide containing destruxins of Metarhizium anisopliae and phoxim |
| CN101438713B (en) * | 2008-12-15 | 2011-06-22 | 华南农业大学 | Compositional disinsection main agent containing destruxins of Metarhizium anisopliae and chlopyrifos |
| CN101438715B (en) * | 2008-12-15 | 2011-06-22 | 华南农业大学 | Compositional disinsection main agent and pesticide containing destruxins of Metarhizium anisopliae and buprofezin |
| CN101438716B (en) * | 2008-12-15 | 2011-08-17 | 华南农业大学 | Compounding pesticide containing destruxins of Metarrhizium anisopliae and Paecilomyces fumosoroseus and preparation method thereof |
| CN101433214B (en) * | 2008-12-15 | 2011-04-27 | 华南农业大学 | Compositional disinsection main agent containing destruxins of Metarhizium anisopliae and deltamethrin |
| CN101427691B (en) * | 2008-12-15 | 2011-11-16 | 华南农业大学 | Scarabaeus green muscardine fungus and green muscardine fungus native mixed insecticidal composition |
| CN105794859A (en) * | 2013-01-25 | 2016-07-27 | 陕西汤普森生物科技有限公司 | Insecticidal compound containing conidioblous thromboides and biological sources |
| CN105794859B (en) * | 2013-01-25 | 2018-11-20 | 陕西汤普森生物科技有限公司 | A kind of Pesticidal combination containing Conidiobolus thromboides and biogenic substances |
| CN103478144B (en) * | 2013-09-26 | 2015-09-09 | 卞佳林 | A kind of Avermectin and griseofulvin composite pesticidal nanoemulsion |
| CN103478144A (en) * | 2013-09-26 | 2014-01-01 | 卞佳林 | Avermectin and griseofulvin composite pesticidal nanoemulsion |
| CN106305780A (en) * | 2016-08-18 | 2017-01-11 | 广西鑫雅皇庭园林工程有限责任公司 | Pesticide for Hibiscus root-knot nematode disease |
| CN115053913A (en) * | 2022-06-30 | 2022-09-16 | 广西壮族自治区国有钦廉林场 | Compound pesticide and method for preventing and controlling underground pests |
| CN116250546A (en) * | 2022-12-28 | 2023-06-13 | 乌鲁木齐市园林绿化工程质量监督站(乌鲁木齐市林草种苗站) | Composition for controlling grassland locust insect pests |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100477920C (en) | 2009-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100477920C (en) | Compounding insecticide containing destruxin and abamectin | |
| CN100486440C (en) | Compounding insecticide containing destruxin and admire | |
| CN103518713B (en) | Synergist used in 5% avermectin emulsion in water | |
| CN103385251B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN101720766B (en) | Insecticidal composition of tea saponin and pleocidin | |
| CN103814909A (en) | Synergistic pesticidal composition | |
| CN101755752B (en) | Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide | |
| CN102365958A (en) | Synergistic insecticidal composition containing rotenone and emamectin benzoate | |
| CN102835397B (en) | Spinosad synergistic aqueous emulsion and preparation method thereof | |
| CN101433214B (en) | Compositional disinsection main agent containing destruxins of Metarhizium anisopliae and deltamethrin | |
| CN101233856A (en) | Emamectin-benzoate and cyhalothrin microemulsion | |
| CN101554173A (en) | Microemulsion containing diafenthiuron and high-efficiency cyhalothrin and method for preparing same | |
| CN106376567B (en) | A kind of nematicidal composition containing fluopyram and its application | |
| CN106879611A (en) | A kind of Pesticidal combination containing AVM and second azoles mite nitrile | |
| CN102210320A (en) | Sulfoxaflor-containing insecticidal composition | |
| CN101971801A (en) | Solvent composition and use thereof | |
| CN101480187A (en) | Disinsection/miticide pharmaceutical composition | |
| CN104365600B (en) | Methyl disulfide cream, its preparation method and aqueous emulsion and capsule | |
| CN103210954A (en) | Insecticide composition, insecticide and application of insecticide | |
| CN101971832A (en) | Compounded pesticidal microemulsion of chlorantraniliprole and rotenone and preparation method thereof | |
| CN102239891A (en) | Enhanced compound pesticide containing toosedarin plant source and preparation method thereof | |
| CN101642116B (en) | Pesticide composition | |
| CN105767007A (en) | Pesticide composition comprising harpin protein and biological sources | |
| CN104255751A (en) | Mite-killing composition containing etoxazole and vermectin | |
| CN101961016A (en) | Insecticidal microemulsion compounded by chlorantraniliprole and azadirachtin and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090415 Termination date: 20161226 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |