CN101755752B - Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide - Google Patents

Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide Download PDF

Info

Publication number
CN101755752B
CN101755752B CN200910214362XA CN200910214362A CN101755752B CN 101755752 B CN101755752 B CN 101755752B CN 200910214362X A CN200910214362X A CN 200910214362XA CN 200910214362 A CN200910214362 A CN 200910214362A CN 101755752 B CN101755752 B CN 101755752B
Authority
CN
China
Prior art keywords
tea saponin
preparation
pesticide
agent
pyrroles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200910214362XA
Other languages
Chinese (zh)
Other versions
CN101755752A (en
Inventor
钟国华
胡美英
郝卫宁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
South China Agricultural University
Original Assignee
South China Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by South China Agricultural University filed Critical South China Agricultural University
Priority to CN200910214362XA priority Critical patent/CN101755752B/en
Publication of CN101755752A publication Critical patent/CN101755752A/en
Application granted granted Critical
Publication of CN101755752B publication Critical patent/CN101755752B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention discloses a pesticide by mixing tea saponin with pyrrole and a pyrazole pesticide. The mixed pesticide preparation comprises the following materials in percentage by weight: 0.01-80 percent of tea saponin, 0.5-80 percent of pyrrole and pyrazole pesticide and the balance of additives and can be prepared into missible oil, wettable powder, micro-emulsion, suspending agents, suspending emulsion or aqueous emulsion. By compounding with the pyrrole and the pyrazole pesticide with the tea saponin, the invention has notable synergy and obviously enhanced insecticidal activity than a single preparation, and takes the effect of simultaneously killing a plurality of insects by one pesticide, thereby lessening the labor and material investment in the insect-preventing process and improving the production benefits while obviously reducing the cost on the premise of ensuring the pesticide action. The invention has a plurality of preparation forms, simple preparation method and higher popularization value.

Description

The insecticide that Tea Saponin and pyrroles and Insecticidal pyrazolines are mixed
Technical field
The invention belongs to the agricultural insecticide technical field, be specifically related to the insecticide that a kind of Tea Saponin and pyrroles and Insecticidal pyrazolines are mixed.
Background technology
Because long-term, a large amount of unreasonable uses of chemical pesticide, and because the intrinsic shortcoming of some medicament itself has caused insect generation " 3R " problem.Therefore, be object with the natural products, seek bioactivator, the research and development novel biopesticide enjoys attention at home and abroad, and wherein, botanical pesticide is the most noticeable one type.Being mixed of the exploitation of botanical pesticide, botanical pesticide and chemical pesticide, botanical pesticide and being mixed of microbial pesticide all are the forward position and the focus of pesticide research in the world.
Tea Saponin (Tea saponin) is the vegetable insecticide that from the tea cake after the seed of plant of theaceae such as tea seed cake, the tea-seed oil expression, extracts, and belongs to pentacyclic triterpenoid, and its pure article are colorless prismatic crystal, have hygroscopicity, and bitter is pungent, and molecular formula is C 57H 90O 26, molecular weight is 1191.31,223~224 ℃ of fusing points, and soluble in water and organic solvents such as alcohols, organic acid are insoluble to organic solvents such as ether, benzinum, benzene.
Tea Saponin is a kind of nonionic surface active agent, has that stronger exhibition is puted forth effort, emulsifying ability, dispersion force, wetting power and a foaming power, and cold-blooded animal is had high poison, and people and animals are waited the nontoxic or low toxicity of homoiothermy animal.This compound has desinsection, sterilization, kills mite and reduces capillary multiple function, has different mechanism of action with chemical pesticide.But Tea Saponin has action of contace poison and stomach poison function to damage by disease and insect, but Tea Saponin quick-acting is poor, application dosage is big, and result of use is bad separately.
Pyrroles and Insecticidal pyrazolines have unique mechanism of action, and wide spectrum, desinsection, acaricidal activity height have stomach toxicity and action of contace poison concurrently; On crop, there are medium residual activity, toxicity low, safe and efficient; Characteristics such as the systemic activity of selection are arranged, not only low to mammalian toxicity, well reach crop safety with Environmental compatibility; Do not have cross resistance with conventional pesticides, and the antagonism insect can also show very high insecticidal activity.Make pyrazoles and pyroles Insecticidal and acaricidal agent become one of most active research field of present chemical pesticide.But, the risk that the independent use cost of pyrroles and Insecticidal pyrazolines is higher and existence is developed immunity to drugs.
Do not see the technology report about Tea Saponin and pyrroles and Insecticidal pyrazolines combination operation technique scheme at present.
Summary of the invention
The objective of the invention is to make full use of the unique effect mechanism of abundant plant resources and botanical pesticide; The insecticide that provides a kind of Tea Saponin and pyrroles and Insecticidal pyrazolines to be mixed has efficient, wide spectrum, is difficult for developing immunity to drugs, superiority such as low toxicity, low cost.
The present invention provides the various formulations and the preparation method of the insecticide that said Tea Saponin and pyrroles and Insecticidal pyrazolines be mixed simultaneously.
The object of the invention is achieved through following technical proposals:
The Pesticidal combination of a kind of Tea Saponin and pyrroles and pyrazoles is provided, comprises each component of following weight percentage:
Tea Saponin: 0.01~80%
Pyrroles and Insecticidal pyrazolines: 0.5~80%
The auxiliary agent surplus.
Preferably, the said Pesticidal combination that contains Tea Saponin and pyrroles and pyrazoles comprises each component of following weight percentage:
Tea Saponin: 0.5~5.0%;
Pyrroles and Insecticidal pyrazolines: 0.5~30%;
The auxiliary agent surplus.
Said Tea Saponin can be the mixture of a kind of or arbitrary proportion of the preparation that contains Tea Saponin of the pure article of crude extract, Tea Saponin of Tea Saponin or form of ownership, if use mixture, total usage amount can not account for the maximum of preparation deal greater than Tea Saponin.
Said pyrroles and Insecticidal pyrazolines can be one or more of capillary, chlorfenapyr, fluorine worm nitrile, second sulphur worm nitrile, azoles mite ester, azoles insect amide, tebufenpyrad or acetyl worm nitrile, can be former medicine or preparation.When using mixture, total usage amount can not be greater than the maximum of pyrroles and the shared preparation deal of Insecticidal pyrazolines.
Said insecticide can be missible oil, wetting powder, microemulsion, suspending agent, suspended emulsion or aqueous emulsion, and the preparation method is the method that adopts usually during corresponding formulation is produced.
Described auxiliary agent is confirmed according to required formulation is different, and is specific as follows:
(1) when preparation missible oil, its auxiliary agent is
1) the surfactant comprise preparation by weight 5~70%; Surfactant is the polyethenoxy ether class of nonionic; Or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more; Use when multiple, total usage amount can not be greater than the maximum of surfactant comprise preparation deal;
2) solvent accounts for preparation by weight 25~80%; Solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers; In available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than solvent;
3) cosolvent accounts for preparation by weight 5~20%, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than cosolvent;
4) pH value conditioning agent accounts for preparation by weight 0.5~1%, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than pH value conditioning agent;
5) synergist accounts for preparation by weight 0.5~25%, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than synergist;
6) anti-photodissociation agent accounts for preparation by weight 0.5~15%, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than anti-photodissociation agent;
7) the stabilizer comprises preparation by weight 0.5~15%, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of stabilizer comprises preparation deal;
8) penetrating agent accounts for preparation by weight 0.5~2%, and penetrating agent is one or more in Laurocapram, JFC-2, the maleic acid di-sec-octyl sodium sulfonate, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than penetrating agent;
(2) when the preparation wetting powder, its auxiliary agent is:
1) wetting agent accounts for preparation by weight 5~35%; Wetting agent is natural products wetting agent and anionic wetting agent; Available spaonin powder, soapberry powder, silkworm excrement, bay alcohol radical sodium sulphate, neopelex, washing powder, draw back in the powder one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than wetting agent;
2) dispersant accounts for preparation by weight 5~30%; Dispersant is industrial by-products and anionic dispersing agent; In available lignosulfite, lignin and derivative sulfonate, naphthalene and alkylbenzene formaldehyde condensation products sulfonate, the alkylsulfonate one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than dispersant;
3) filler accounts for preparation by weight 20~90%, and filler is mineral type carrier or synthetic vectors, and one or more in available kaolin, diatomite, the white carbon use when multiple, and total usage amount can not account for the maximum of preparation deal greater than filler;
(3) when the preparation microemulsion, its auxiliary agent is:
1) solvent accounts for preparation by weight 10~90%, and solvent is one or more in alcohols, ketone, ester class and the aromatic hydrocarbon, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than solvent;
2) emulsifier accounts for preparation by weight 10~40%; Emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C8~C20 alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15~30) ether, phenethyl phenol polyethenoxy polyoxypropylene, NPE, APES first condensation product, xenol APEO, homemade Nongru-700 number, in No. 300 one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than emulsifier;
3) the stabilizer comprises preparation by weight 0.5~15%; Stabilizing agent is a 3-chloro-1; In 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyvinyl one glycol diglycidyl ether, the sodium sorbate one or more; Use when multiple, total usage amount can not be greater than the maximum of stabilizer comprises preparation deal;
4) antifreezing agent accounts for preparation by weight 0.5~10%, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorb sodium alkoxide, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than antifreezing agent;
(4) when the preparation suspending agent, its auxiliary agent is:
1) the surfactant comprise preparation by weight 5~70%; Surfactant is the polyethenoxy ether class of nonionic; Or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more; Use when multiple, total usage amount can not be greater than the maximum of surfactant comprise preparation deal;
2) solvent accounts for preparation by weight 25~80%; Solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers; In available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than solvent;
3) cosolvent accounts for preparation by weight 5~20%, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than cosolvent;
4) pH value conditioning agent accounts for preparation by weight 0.5~1%, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than pH value conditioning agent;
5) synergist accounts for preparation by weight 0.5~25%, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not be greater than the maximum of deal;
6) anti-photodissociation agent accounts for preparation by weight 0.5~15%, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than synergist;
7) the stabilizer comprises preparation by weight 0.5~15%, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of stabilizer comprises preparation deal;
8) thickener accounts for preparation by weight 0.1~10%, and thickener is one or more in silica, the bentonite, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than thickener;
(5) when the preparation suspended emulsion, its auxiliary agent is:
1) the surfactant comprise preparation by weight 5~70%; Surfactant is the polyethenoxy ether class of nonionic; Or the sodium alkyl sulfate of anionic or in the alkyl benzene sulfonate one or more; Use when multiple, total usage amount can not be greater than the maximum of surfactant comprise preparation deal;
2) solvent accounts for preparation by weight 25~80%; Solvent is various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers; In available benzene,toluene,xylene, naphthalane, gasoline, kerosene, machine oil, MEK, propylene glycol, butyl glycol ether, the benzinum one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than solvent;
3) cosolvent accounts for preparation by weight 5~20%, and cosolvent is one or more in methyl alcohol, isoamyl alcohol, phenol, ethyl acetate, the dimethyl sulfoxide (DMSO), uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than cosolvent;
4) pH value conditioning agent accounts for preparation by weight 0.5~1%, and pH value conditioning agent is one or more in sodium hydroxide, ammonium hydroxide, acetic acid, the hydrochloric acid, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than pH value conditioning agent;
5) synergist accounts for preparation by weight 0.5~25%, and synergist is one or more in Butacide, sulfoxide, alkyl carbonate, chlorination fat, the formaldehyde, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than synergist;
6) anti-photodissociation agent accounts for preparation by weight 0.5~15%, and anti-photodissociation agent is one or more in p-aminobenzoic acid, castor oil, the Angelica oil, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than anti-photodissociation agent;
7) the stabilizer comprises preparation by weight 0.5~15%, and stabilizing agent is one or more in epoxidized soybean oil, the epoxidized linseed, uses when multiple, and total usage amount can not be greater than the maximum of stabilizer comprises preparation deal;
8) thickener accounts for preparation by weight 0.1~10%, and thickener is one or more in silica, the bentonite, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than thickener;
(6) when the preparation aqueous emulsion, its auxiliary agent is:
1) solvent accounts for preparation by weight 10~90%, and solvent is one or more in alcohols, ketone, ester class and the aromatic hydrocarbon, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than solvent;
2) emulsifier accounts for preparation by weight 10~30%; Emulsifier is alkyl benzene sulfonate calcium salt, alkyl benzene sulphonate magnesium salts, alkyl benzene sulphonate aluminium salt, alkyl benzene sulphonate sodium salt, alkyl benzene sulphonate barium salt, C8~C20 alkylsurfuric acid sodium salt, styrene polyoxyethylene ether ammonium sulfate salt, benzylbiphenyl phenol polyethenoxy ether, phenethyl phenol polyethenoxy (N=15~30) ether, phenethyl phenol polyethenoxy polyoxypropylene, NPE, APES first condensation product, xenol APEO, homemade Nongru-700 number, in No. 300 one or more; Use when multiple, total usage amount can not account for the maximum of preparation deal greater than emulsifier;
3) the stabilizer comprises preparation by weight 0.5~15%; Stabilizing agent is a 3-chloro-1; In 2-expoxy propane, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyvinyl one glycol diglycidyl ether, the sodium sorbate one or more; Use when multiple, total usage amount can not be greater than the maximum of stabilizer comprises preparation deal;
4) antifreezing agent accounts for preparation by weight 0.5~10%, and antifreezing agent is one or more in ethylene glycol, glycerine, propane diols, polyethylene glycol, the sorb sodium alkoxide, uses when multiple, and total usage amount can not account for the maximum of preparation deal greater than antifreezing agent.
The said mixed insecticide preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines; The method that each component is mixed with into missible oil is: by proportioning Tea Saponin and pyrroles and the former medicine of Insecticidal pyrazolines are dissolved in the solvent; Other auxiliary agents such as emulsifier are joined in the former drug solns of Tea Saponin and pyrroles and Insecticidal pyrazolines; Stir, put at last and give intense mixing in the homogenizer and homogenize promptly gets.
The said mixed insecticide preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines; The method that each component is mixed with into wetting powder is: by proportioning Tea Saponin and pyrroles and the former medicine of Insecticidal pyrazolines are carried out joining in the blender behind the comminution by gas stream; In blender, add auxiliary agent respectively by proportioning, stir promptly and get.
The said mixed insecticide preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines; The method that each component is mixed with into microemulsion is: pyrroles and Insecticidal pyrazolines are dissolved in the solvent; Tea Saponin is soluble in water, emulsifier is joined in pyrroles and the Insecticidal pyrazolines solution, stir; Add cosolvent, the Tea Saponin aqueous solution then, put at last and give intense mixing in the homogenizer and homogenize promptly gets.
The said mixed insecticide preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines, the method that each component is mixed with into suspending agent is: by proportioning Tea Saponin and pyrroles and the former medicine of Insecticidal pyrazolines are added wetting dispersing agent, thickener, stabilizing agent, antifoaming agent, antifreezing agent, pH regulator agent and other auxiliary agent and deionized water one and arise from the ball mill ball milling and process suspending agent and promptly get.
The said mixed insecticide preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines; The method that each component is mixed with into suspended emulsion is: by proportioning Tea Saponin and pyrroles and the former medicine of Insecticidal pyrazolines are pulverized; Add various auxiliary agents and water except that thickener again; Get into together to mix in the high-shear emulsion machine and add thickener simultaneously and further mix,, promptly get after microscopy is qualified after sand mill grinds.
The said mixed insecticide preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines; The method that each component is mixed with into aqueous emulsion is: by ratio requirement Tea Saponin and pyrroles and the former medicine of Insecticidal pyrazolines are dissolved in the solvent; Emulsifier, cosolvent are joined in the former drug solns of Tea Saponin and pyrroles and Insecticidal pyrazolines; Stir, slowly add then in the entry, fully stirring promptly gets.
The insecticide that said Tea Saponin and pyrroles and Insecticidal pyrazolines are mixed can be applicable to prevent and treat insects such as beet armyworm or diamond-back moth, and can be applicable to double diamond-back moth, beet armyworm and the cabbage caterpillar aspect controlled.
The invention has the beneficial effects as follows:
The present invention has changed Tea Saponin technological prejudice as just wetting agent and synergist in the insecticidal preparation that is mixed; In the insecticides that provides, contain two kinds of active ingredients of Tea Saponin and pyrroles and Insecticidal pyrazolines, and these two kinds of active ingredients are biopesticide; Mechanism of action effectively combines; Especially Tea Saponin is brought into play significant synergistic effect to pyrroles and pyrazoles when self has insecticidal action, and the generation of the antagonism property of medicine has retarding action; The present composition can be used for the control of common insect in the agricultural production, for the production of agricultural, pollution-free food and nuisanceless fruits and vegetables provides safe and efficient pesticide new variety.
Insecticide of the present invention plays the double effect of controlling of a medicine to multiple insect pest, thereby reduces the manpower and materials input in the pest control process, improves productivity effect.
The present invention can prepare various formulation, and the preparation method is simple, uses pyrroles and Insecticidal pyrazolines cost higher separately; And the Tea Saponin cost is very low; Adopt these two kinds of single agent composite, under the prerequisite that guarantees drug effect, reduce cost significantly, have good application value.
Embodiment
Below in conjunction with specific embodiment the present invention is further described, can not gives unnecessary details one by one in an embodiment with the simple replacement of analog assistant, but therefore not limit scope of the present invention.Virulence test and field efficiency test are tested conventional method with reference to this area.
Said Tea Saponin is that the pure article of crude extract, Tea Saponin of Tea Saponin or the preparation that contains Tea Saponin and pyrroles and Insecticidal pyrazolines are commercial product, and wherein Tea Saponin also can adopt conventional method to extract to obtain.
Embodiment 1 preparation 3% Tea Saponin capillary microemulsion, the weight proportion of each component is:
Capillary 2.1%, Tea Saponin 0.9%, methyl alcohol 10%, cyclohexane 9%, ethyl acetate 8%, cyclohexanone 25%, farming breast 5004%, Nongru-700 8%, AEO-710%, GP3300.5%, glycerine 0.5%, the water of surplus.By proportioning capillary and Tea Saponin are dissolved in methyl alcohol, cyclohexane, the ethyl acetate, mix other composition modulation of back adding and obtain microemulsion.
Embodiment 2: prepare 5% Tea Saponin chlorfenapyr missible oil, the weight proportion of each component is:
Chlorfenapyr 3.5%; Tea Saponin 1.5%; Surfactant farming breast 500 is 10%, and Nongru-700 is 10%; Organic solvent cyclohexane 20%, ethyl acetate 10%, DMF10%, carrene 10%; Cosolvent methyl alcohol 5%; Stabilizing agent castor oil 5%; Anti-photodissociation agent epoxidized soybean oil 5%; Penetrating agent Laurocapram 10%.Each component is put into modulation kettle mixes well promptly and gets.
Embodiment 3: prepare 80.5% Tea Saponin fluorine worm nitrile wetting powder, the weight proportion of each component is:
Fluorine worm nitrile 0.5%; Tea Saponin 80%; Wetting agent bay alcohol radical sodium sulphate 3%; Dispersant lignin 2.5%; Filler diatomite 14%.By proportioning fluorine worm nitrile and the former medicine of Tea Saponin are carried out joining in the blender behind the comminution by gas stream, in blender, add auxiliary agent respectively, stir promptly and get by proportioning.
Embodiment 4: prepare 80.01% Tea Saponin second sulphur worm nitrile suspending agent, the weight proportion of each component is:
Second sulphur worm nitrile 80%; Tea Saponin 0.01%; Surfactant sodium alkyl sulfate 7.39%; Solvent propylene glycol 10%; Cosolvent dimethyl sulfoxide (DMSO) 0.5%; PH value conditioning agent acetic acid 0.5%; Synergist Butacide 0.5%; Anti-photodissociation agent castor oil 0.5%; Stabilizing agent epoxidized soybean oil 0.5%; Thickener-silica 0.1%.By proportioning second sulphur worm nitrile and the former medicine of Tea Saponin are added in the above-mentioned auxiliary agent and to arise from the ball mill ball milling with deionized water one and process suspending agent and promptly get.
Embodiment 5: prepare 10% Tea Saponin azoles mite ester suspended emulsion, the weight proportion of each component is:
Azoles mite ester 5%; Tea Saponin 5%; Surfactant Nongru-700 30%; Solvent toluene 52%; Cosolvent dimethyl sulfoxide (DMSO) 5%; PH value conditioning agent acetic acid 0.5%; Synergist Butacide 0.5%; Anti-photodissociation agent castor oil 0.5%; Stabilizing agent epoxidized soybean oil 0.5%; Thickener-silica 1%.By proportioning azoles mite ester and the former medicine of Tea Saponin are pulverized, added auxiliary agent and water except that thickener, in high-shear emulsion machine, mix the adding thickener, mix, grind, promptly get after microscopy is qualified through sand mill.
Embodiment 6: prepare 30% Tea Saponin tebufenpyrad aqueous emulsion, the weight proportion of each component is:
Tebufenpyrad 29.5%; Tea Saponin 0.5%; Solvent acetone 50%; Emulsifier NPE 10%; Stabilizing agent sodium sorbate 3%; Antifreezing agent polyethylene glycol 7%.By ratio requirement tebufenpyrad and the former medicine of Tea Saponin are dissolved in the solvent, emulsifier, cosolvent are joined in tebufenpyrad and the former drug solns of Tea Saponin, slowly add after stirring in the entry, fully stirring promptly gets.
Embodiment 7: prepare 30% Tea Saponin capillary fluorine worm nitrile aqueous emulsion, the weight proportion of each component is:
Tea Saponin 5%; Capillary 15%; Fluorine worm nitrile 10%; Solvent acetone 50%; Emulsifier NPE 10%; Stabilizing agent sodium sorbate 3%; Antifreezing agent polyethylene glycol 7%.By ratio requirement Tea Saponin, capillary and the former medicine of fluorine worm nitrile are dissolved in the solvent, emulsifier, cosolvent are joined in Tea Saponin, capillary and the former drug solns of fluorine worm nitrile, slowly add after stirring in the entry, fully stirring promptly gets.
Embodiment 8: mixed insecticide preparation of the present invention is to the indoor virulence of beet armyworm
Indoor virulence and the mixed synergies thereof of 1 ~ 7 pair of beet armyworm of mixed insecticide preparation embodiment of the present invention adopt following method to carry out: will pick up from does not have the fresh cabbage leaves of using any agricultural chemicals in the solarium; Behind running water flushing and paper towel suck dry moisture; Use diameter to process the leaf dish as the card punch of 2cm; And immersed in the soup prepare about 5 seconds, take out, dry for use naturally.The blade of handling is put into culture dish, and every ware is put 3~4 leaf dish, and every ware inserts 10 beet armyworm 3 instar larvaes, is allowed to condition at and gets food on the leaf.Every ware is 1 repetition, and every concentration is established 4 repetitions; Contrast is handled with the aqueous acetone solution with amount.Each death condition of handling of 48h investigation.Be calculated as follows lethality, Abbott formula calculation correction lethality.
Abbott formula computing formula is following:
Test method adopts the abundant method that toxicity index is calculated the Mixed Pharmacy co-toxicity of passing through that waits the nineteen sixty proposition of Sun Yun.At first record mixture with the method for routine and form mixture each single agent virulence regression equation and obtain LD 50, the toxicity index that is each single agent of criterion calculation with a kind of single agent again, the actual toxicity index of mixture and theoretical toxicity index, calculate at last its co-toxicity coefficient (co-toxicity coefficient, CTC).Its formula of reduction is following:
If confection is M, single agent of forming M is A, B, and percentage composition is P,
Criterion: if the toxicity test co-toxicity coefficient of mixture near 100 expression summation actions, obviously greater than 100 expression synergistic effects, is significantly less than 100 expression antagonisms.
Result of the test is seen table 1 and table 2, can find out that from experimental data mixed insecticide preparation of the present invention all has good indoor toxic effect, LD to beet armyworm 3 instar larvaes 50All be lower than 2.0 μ g/mL.The co-toxicity coefficient of mixed insecticide preparation of the present invention obviously greater than 100, shows stronger mixed synergies all greater than 200.
Table 1 mixed insecticide preparation of the present invention is to the indoor virulence of beet armyworm 3 instar larvaes
Table 2 mixed insecticide preparation of the present invention is to the synergy of beet armyworm
Embodiment 9: mixed insecticide preparation of the present invention is to the field control effect of diamond-back moth
The 30% Tea Saponin tebufenpyrad aqueous emulsion that embodiment 6 is prepared dilutes 2000 times to diamond-back moth spraying processing, then investigation in the 1st, 3,7,14 day and calculating preventive effect behind medicine.The result shows: 30% Tea Saponin tebufenpyrad aqueous emulsion to the diamond-back moth medication after the 1st, 3,7,14 day preventive effect be respectively 76.67%, 85.74%, 96.55%, 91.48%; Contrast the 1st, 3,7,14 days preventive effect of single 2000 times of liquid of agent 50% Tea Saponin aqua and be respectively 44.15%, 55.25%, 76.38%, 67.84%; Contrast the 1st, 3,7,14 days preventive effect of single 2000 times of liquid of agent 20% tebufenpyrad missible oil and be respectively 61.62%, 72.34%, 83.62%, 73.34%.Can find out that from above-mentioned result of the test the mixture that the present invention prepares compares with former agricultural chemicals, the control efficiency of insect is significantly strengthened, demonstrate good mixed synergies and lasting effect.Simultaneously, field investigation is the result show, present embodiment processing Tanaka cabbage caterpillar insect density contrasts the field and significantly reduces, and shows that the mixture that the present invention prepares can significantly reduce the incidence of cabbage caterpillar, plays the double effect of controlling.

Claims (3)

1. the insecticide that is mixed of Tea Saponin and pyrroles and Insecticidal pyrazolines is characterized in that said insecticide is to have the preparation that following weight percentage is formed:
Microemulsion, wherein: capillary 2.1%, Tea Saponin 0.9%, methyl alcohol 10%, cyclohexane 9%, ethyl acetate 8%, cyclohexanone 25%, farming breast 500 4%, Nongru-700 8%, AEO-7 10%, and GP330 0.5%, glycerine 0.5%, water surplus;
Missible oil, wherein: capillary 3.5%; Tea Saponin 1.5%; Farming breast 500 10%, Nongru-700 10%; Cyclohexane 20%, ethyl acetate 10%, DMF10%, carrene 10%; Methyl alcohol 5%; Castor oil 5%; Epoxidized soybean oil 5%; Laurocapram 10%;
Wetting powder, wherein: fluorine worm nitrile 0.5%; Tea Saponin 80%; Bay alcohol radical sodium sulphate 3%; Lignin 2.5%; Diatomite 14%;
Suspending agent, wherein: second sulphur worm nitrile 80%; Tea Saponin 0.01%; Sodium alkyl sulfate 7.39%; Propylene glycol 10%; Dimethyl sulfoxide (DMSO) 0.5%; Acetic acid 0.5%; Butacide 0.5%; Castor oil 0.5%; Epoxidized soybean oil 0.5%; Silica 0.1%;
Suspended emulsion, wherein: azoles mite ester 5%; Tea Saponin 5%; Nongru-700 30%; Toluene 52%; Dimethyl sulfoxide (DMSO) 5%; Acetic acid 0.5%; Butacide 0.5%; Castor oil 0.5%; Epoxidized soybean oil 0.5%; Silica 1 %;
Aqueous emulsion, wherein: tebufenpyrad 29.5%; Tea Saponin 0.5%; Acetone 50%; NPE 10%; Sodium sorbate 3%; Polyethylene glycol 7%;
Aqueous emulsion, wherein: Tea Saponin 5%; Capillary 15%; Fluorine worm nitrile 10%; Acetone 50%; NPE 10%; Sodium sorbate 3%; Polyethylene glycol 7%.
2. the application of the insecticide that is mixed of said Tea Saponin of claim 1 and pyrroles and Insecticidal pyrazolines aspect control beet armyworm or diamond-back moth.
3. the insecticide that is mixed of said Tea Saponin of claim 1 and pyrroles and Insecticidal pyrazolines is in the double application of controlling aspect beet armyworm, diamond-back moth and the cabbage caterpillar.
CN200910214362XA 2009-12-29 2009-12-29 Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide Expired - Fee Related CN101755752B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910214362XA CN101755752B (en) 2009-12-29 2009-12-29 Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910214362XA CN101755752B (en) 2009-12-29 2009-12-29 Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide

Publications (2)

Publication Number Publication Date
CN101755752A CN101755752A (en) 2010-06-30
CN101755752B true CN101755752B (en) 2012-06-27

Family

ID=42487257

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200910214362XA Expired - Fee Related CN101755752B (en) 2009-12-29 2009-12-29 Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide

Country Status (1)

Country Link
CN (1) CN101755752B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102870782A (en) * 2012-10-29 2013-01-16 南京扬子鸿利源化学品有限责任公司 Tebufenpyrad pesticide effect-enhancing water emulsion and preparation method thereof
CN104604926A (en) * 2015-01-29 2015-05-13 海南力智生物工程有限责任公司 Pesticide composition for preventing and treating noctuid and preparation method of pesticide composition
CN104886068A (en) * 2015-06-12 2015-09-09 福建省德盛生物工程有限责任公司 Low-volume spray containing tolfenpxrad
CN104886087A (en) * 2015-06-12 2015-09-09 福建省德盛生物工程有限责任公司 Low-volume spray containing emamectin benzoate and tolfenpxrad
CN104996443A (en) * 2015-06-12 2015-10-28 福建省德盛生物工程有限责任公司 Low volume spray containing diafenthiuron and tolfenpxrad
CN105475292A (en) * 2015-12-04 2016-04-13 浙江威尔达化工有限公司 Insecticidal composition containing tolfenpyrad and tea saponin and application thereof
CN111838162B (en) * 2020-05-29 2022-01-11 安徽省农业科学院植物保护与农产品质量安全研究所 Medicament composition for preventing and treating spodoptera frugiperda

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995033380A1 (en) * 1994-06-08 1995-12-14 Ciba-Geigy Ag Synergistic composition
CN1460481A (en) * 2003-06-11 2003-12-10 陕西太明药物研究开发有限公司 Medicine composition using resveratrol glucodside for curing fatty liver and its preparation method
CN1836513A (en) * 2005-03-21 2006-09-27 安徽华星化工股份有限公司 Mixed insecticide composition containing fipronil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995033380A1 (en) * 1994-06-08 1995-12-14 Ciba-Geigy Ag Synergistic composition
CN1460481A (en) * 2003-06-11 2003-12-10 陕西太明药物研究开发有限公司 Medicine composition using resveratrol glucodside for curing fatty liver and its preparation method
CN1836513A (en) * 2005-03-21 2006-09-27 安徽华星化工股份有限公司 Mixed insecticide composition containing fipronil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
夏春华 等.茶皂素在农药工业中应用研究进展.《茶叶科学》.2000,第20卷(第2期),82-88. *

Also Published As

Publication number Publication date
CN101755752A (en) 2010-06-30

Similar Documents

Publication Publication Date Title
CN101743966B (en) Mixed insecticide of tea saponin and acaricide
CN101743969B (en) Mixed insecticide of tea saponin and neonicotine insecticide
CN101755751B (en) Pesticide by mixing tea saponin with insect growth regulator
CN101743967B (en) Mixed insecticide of tea saponin and carbamate insecticide
CN101755752B (en) Pesticide by mixing tea saponin with pyrrole and pyrazole pesticide
CN101720773B (en) Insecticidal composition of tea saponin and rotenone
CN101720766B (en) Insecticidal composition of tea saponin and pleocidin
CN101926337B (en) Pesticide composite of tea saponin and
CN101755821B (en) Pesticide by mixing tea saponin with thepyrethroid pesticide
CN101743968B (en) Mixed insecticide of tea saponin and organophosphate insecticide
CN101743982B (en) Mixed insecticide of tea saponin and nereistoxin insecticide
CN102365970A (en) Synergistic pesticidal composition containing Clothianidin and emamectin benzoate, and its application
CN102365958A (en) Synergistic insecticidal composition containing rotenone and emamectin benzoate
CN101161069B (en) Insecticidal composition of Chinese azalea extract III and theasaponine
CN102113508B (en) Insecticidal/acaricidal composition contaning biphenthrin
CN102165958B (en) Pesticide composite containing bifenazate and triazophos
CN101543221A (en) Sterilizing composite compounded by mancozeb and tea saponin and application thereof
CN102805089A (en) Insect and mite killing composition containing Cyflumetofen and emamectin benzoate
CN103651363A (en) Pesticidal composition containing spiromesifen and nereistoxin
CN103355299A (en) Insecticide composition containing pyridalyl and nereistoxin
CN101543219B (en) Sterilizing composite compounded by diniconazole and tea saponin, preparation method and application thereof
CN102907454A (en) Composite pesticides for controlling rice pests
CN101228876B (en) Nicouline and fluacrypyrim blending agrochemical
CN105685045A (en) Insecticide composition containing SIOC-I-002
CN101124911B (en) Insecticide composition containing rhodojaponin III and chlopyrifos

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120627

Termination date: 20171229

CF01 Termination of patent right due to non-payment of annual fee