CN100586993C - 具有降低的热导率的苯乙烯聚合物颗粒泡沫材料 - Google Patents
具有降低的热导率的苯乙烯聚合物颗粒泡沫材料 Download PDFInfo
- Publication number
- CN100586993C CN100586993C CN200580020105A CN200580020105A CN100586993C CN 100586993 C CN100586993 C CN 100586993C CN 200580020105 A CN200580020105 A CN 200580020105A CN 200580020105 A CN200580020105 A CN 200580020105A CN 100586993 C CN100586993 C CN 100586993C
- Authority
- CN
- China
- Prior art keywords
- styrene
- weight
- expandable
- polymers
- styrene polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 229920000642 polymer Polymers 0.000 title claims abstract description 57
- 239000002245 particle Substances 0.000 title claims abstract description 28
- 239000006260 foam Substances 0.000 title abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 12
- 239000010439 graphite Substances 0.000 claims description 12
- 239000004794 expanded polystyrene Substances 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 5
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- -1 hydroxyl macrogol ester Chemical compound 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 238000003466 welding Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 6
- 206010000269 abscess Diseases 0.000 claims 2
- 229920002367 Polyisobutene Polymers 0.000 claims 1
- 150000008065 acid anhydrides Chemical class 0.000 claims 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical class C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 claims 1
- 238000007598 dipping method Methods 0.000 claims 1
- 229950007687 macrogol ester Drugs 0.000 claims 1
- 150000003440 styrenes Chemical class 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000004604 Blowing Agent Substances 0.000 description 18
- 239000004793 Polystyrene Substances 0.000 description 15
- 229920002223 polystyrene Polymers 0.000 description 15
- 239000002736 nonionic surfactant Substances 0.000 description 9
- 239000003063 flame retardant Substances 0.000 description 6
- 239000011324 bead Substances 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920006327 polystyrene foam Polymers 0.000 description 4
- ABVVEAHYODGCLZ-UHFFFAOYSA-N tridecan-1-amine Chemical compound CCCCCCCCCCCCCN ABVVEAHYODGCLZ-UHFFFAOYSA-N 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000010557 suspension polymerization reaction Methods 0.000 description 3
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 229920006248 expandable polystyrene Polymers 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229920005652 polyisobutylene succinic anhydride Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- AUTSLLHNWAZVLE-UHFFFAOYSA-N 1,1,2,2,3-pentabromo-3-chlorocyclohexane Chemical compound ClC1(Br)CCCC(Br)(Br)C1(Br)Br AUTSLLHNWAZVLE-UHFFFAOYSA-N 0.000 description 1
- VCNJVIWFSMCZPE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-prop-2-enoxybenzene Chemical compound BrC1=C(Br)C(Br)=C(OCC=C)C(Br)=C1Br VCNJVIWFSMCZPE-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229920013747 hydroxypolyethylene Polymers 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910001872 inorganic gas Inorganic materials 0.000 description 1
- 239000004620 low density foam Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920006249 styrenic copolymer Polymers 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004028768.6 | 2004-06-16 | ||
| DE102004028768A DE102004028768A1 (de) | 2004-06-16 | 2004-06-16 | Styrolpolymer-Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1968997A CN1968997A (zh) | 2007-05-23 |
| CN100586993C true CN100586993C (zh) | 2010-02-03 |
Family
ID=34970800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200580020105A Expired - Fee Related CN100586993C (zh) | 2004-06-16 | 2005-06-09 | 具有降低的热导率的苯乙烯聚合物颗粒泡沫材料 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8173714B2 (enExample) |
| EP (1) | EP1758951B1 (enExample) |
| JP (1) | JP5208501B2 (enExample) |
| KR (1) | KR101256271B1 (enExample) |
| CN (1) | CN100586993C (enExample) |
| AT (1) | ATE468369T1 (enExample) |
| BR (1) | BRPI0512006A (enExample) |
| DE (2) | DE102004028768A1 (enExample) |
| ES (1) | ES2344211T3 (enExample) |
| MX (1) | MXPA06014440A (enExample) |
| PL (1) | PL1758951T3 (enExample) |
| WO (1) | WO2005123816A1 (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20071003A1 (it) * | 2007-05-18 | 2008-11-19 | Polimeri Europa Spa | Compositi a base di polimeri vinilaromatici aventi migliorate proprieta' di isolamento termico e procedimento per la loro preparazione |
| JP5220428B2 (ja) * | 2008-02-01 | 2013-06-26 | 株式会社フジミインコーポレーテッド | 研磨用組成物を用いた研磨方法 |
| WO2009133167A1 (de) * | 2008-05-02 | 2009-11-05 | Basf Se | Ps-schaumstoffe mit geringem metallgehalt |
| DE202008012675U1 (de) * | 2008-09-24 | 2009-01-02 | SCHWENK DÄMMTECHNIK GMBH & Co KG | Dämmelement und Verwendung eines Dämmelementes |
| WO2010066454A2 (en) * | 2008-12-12 | 2010-06-17 | Jackon Gmbh | Process for the preparation of an expandable polymer composition in the form of beads |
| EP2356173B1 (en) * | 2008-12-12 | 2018-06-13 | Jackon GmbH | Process for the preparation of an expandable polymer composition in the form of beads |
| IT1393962B1 (it) | 2009-05-05 | 2012-05-17 | Polimeri Europa Spa | Articoli espansi con ottima resistenza allo irraggiamento solare e ottime proprieta' termoisolanti e meccaniche |
| CN103261298B (zh) * | 2010-10-18 | 2014-07-16 | 道达尔研究技术弗吕公司 | 能膨胀的乙烯基芳族聚合物 |
| CN103298867B (zh) * | 2010-12-30 | 2015-01-07 | 第一毛织株式会社 | 泡沫聚苯乙烯基珠粒及其制造方法 |
| JP5885294B2 (ja) * | 2011-11-30 | 2016-03-15 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板 |
| EP2794673A1 (de) * | 2011-12-21 | 2014-10-29 | Basf Se | Verfahren zur herstellung von expandierbaren, partikelförmige additive enthaltenden styrolpolymeren |
| JP6216506B2 (ja) * | 2012-12-14 | 2017-10-18 | 株式会社カネカ | 発泡性スチレン系樹脂粒子とその製造方法、スチレン系樹脂発泡成形体 |
| JP6185607B2 (ja) * | 2013-02-26 | 2017-08-23 | ダウ グローバル テクノロジーズ エルエルシー | 熱可塑性ポリマー発泡体の管断熱材 |
| WO2015101621A1 (en) | 2013-12-30 | 2015-07-09 | Averis As | Process for the preparation of solid particulate vinyl aromatic polymer compositions |
| EP2918388A1 (en) | 2014-03-10 | 2015-09-16 | Sulzer Chemtech AG | A process to recycle expandable plastic materials and an expandable or expanded plastic material obtainable thereby |
| CN104292680B (zh) * | 2014-09-15 | 2017-02-15 | 刘崴崴 | 一种聚苯乙烯泡沫保温材料及其制备方法 |
| MA41344B1 (fr) | 2015-01-14 | 2019-01-31 | Synthos Sa | Combinaison de silice et de graphite et son utilisation pour réduire la conductivité thermique d'une mousse de polymère aromatique vinylique |
| CA2973630A1 (en) | 2015-01-14 | 2016-07-21 | Synthos S.A. | Geopolymer composite and expandable vinyl aromatic polymer granulate and expanded vinyl aromatic polymer foam comprising the same |
| MA41342A (fr) | 2015-01-14 | 2017-11-21 | Synthos Sa | Procédé pour la production de granulés de polymère vinylique aromatique expansible ayant une conductivité thermique réduite |
| JP6735281B2 (ja) | 2015-01-14 | 2020-08-05 | シントス エス．アー．Ｓｙｎｔｈｏｓ Ｓ．Ａ． | ペロブスカイト構造を有する鉱物のビニル芳香族ポリマーフォームでの使用 |
| CN105860305A (zh) * | 2015-01-23 | 2016-08-17 | 江苏业达鑫化工有限公司 | 一种功能性石墨母粒的制备方法及其应用 |
| CN104844954A (zh) * | 2015-04-24 | 2015-08-19 | 天津市天德橡塑机械有限公司 | 一种低导热聚苯乙烯保温材料 |
| CA2998094C (en) | 2015-09-09 | 2022-12-13 | Kaneka Corporation | Expandable styrene resin particles, pre-expanded particles of styrene resin, styrene resin foam molded body, and method for producing expandable resin particles |
| CN105566670B (zh) * | 2015-12-18 | 2018-05-18 | 武汉轻工大学 | 基于废聚苯乙烯材料制备梯度阻燃可发泡聚苯乙烯珠粒的水相悬浮造粒法及其产品 |
| AU2017300726B2 (en) | 2016-07-20 | 2021-12-02 | Synthos S.A. | Use of geopolymeric additive in combination with non-brominated flame retardant in polymer foams |
| BR112019000605A2 (pt) | 2016-07-20 | 2019-04-30 | Synthos S.A. | geopolímero modificado e compósito de geopolímero modificado e processo para a produção dos mesmos |
| WO2018015490A1 (en) | 2016-07-20 | 2018-01-25 | Synthos S.A. | Process for the production of geopolymer or geopolymer composite |
| CN106749791B (zh) * | 2016-12-07 | 2018-10-23 | 河海大学 | 一种低密度聚苯乙烯微球及其制备方法 |
| FR3080850B1 (fr) | 2018-05-04 | 2022-08-12 | Saint Gobain Isover | Materiau d’isolation thermique |
| CN112079610B (zh) * | 2019-06-14 | 2022-09-09 | 上海圣奎塑业有限公司 | 一种发泡保温板的制作工艺 |
| CN113248771A (zh) * | 2021-06-22 | 2021-08-13 | 富思特新材料科技发展股份有限公司 | 一种用于保温板的可发泡聚苯乙烯及其制备方法和应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0372343B1 (en) | 1988-11-25 | 2000-01-19 | The Dow Chemical Company | Polystyrene foam containing carbon black |
| FR2649983B1 (fr) * | 1989-07-19 | 1993-01-08 | Norsolor Sa | Procede de preparation de perles de polymere expansibles et materiaux en derivant |
| JP2832467B2 (ja) * | 1989-11-22 | 1998-12-09 | 鐘淵化学工業株式会社 | 発泡性熱可塑性重合体粒子の製造方法 |
| DE9305431U1 (de) | 1993-04-13 | 1994-08-11 | AlgoStat GmbH & Co. KG, 29227 Celle | Formkörper aus Polystyrol-Hartschaum |
| EP0902804A1 (de) | 1996-05-28 | 1999-03-24 | Basf Aktiengesellschaft | Russpartikel enthaltende expandierbare styrolpolymerisate |
| DE59702327D1 (de) * | 1997-05-14 | 2000-10-12 | Basf Ag | Graphitpartikel enthaltende expandierbare styrolpolymerisate |
| ES2151270T3 (es) | 1997-05-14 | 2000-12-16 | Basf Ag | Procedimiento para la obtencion de polimeros de estireno expandibles que contienen particulas de grafito. |
| US6230713B1 (en) | 1998-01-29 | 2001-05-15 | Margaret R. Dalesandro | Determining a treatment plan for patients undergoing thrombotic event by monitoring P-selectin |
| JP2002521543A (ja) * | 1998-07-27 | 2002-07-16 | ビーエーエスエフ アクチェンゲゼルシャフト | グラファイト粒子を含む発泡性スチレン重合体の製造法 |
| AT406477B (de) | 1999-01-25 | 2000-05-25 | Sunpor Kunststoff Gmbh | Teilchenförmige, expandierbare styrolpolymerisate und verfahren zu ihrer herstellung |
| KR20010112557A (ko) * | 2000-06-09 | 2001-12-20 | 방대신 | 검색사이트의 복권제공 시스템 및 방법 |
| DE10101432A1 (de) * | 2001-01-13 | 2002-07-18 | Basf Ag | Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate |
| JP4316305B2 (ja) * | 2003-06-13 | 2009-08-19 | 株式会社ジェイエスピー | 黒鉛粉を含有するスチレン系樹脂発泡体の製造方法 |
| DE10358786A1 (de) * | 2003-12-12 | 2005-07-14 | Basf Ag | Partikelschaumformteile aus expandierbaren, Füllstoff enthaltenden Polymergranulaten |
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2004
- 2004-06-16 DE DE102004028768A patent/DE102004028768A1/de not_active Withdrawn
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2005
- 2005-06-09 MX MXPA06014440A patent/MXPA06014440A/es active IP Right Grant
- 2005-06-09 US US11/629,776 patent/US8173714B2/en not_active Expired - Fee Related
- 2005-06-09 EP EP05753572A patent/EP1758951B1/de not_active Revoked
- 2005-06-09 WO PCT/EP2005/006200 patent/WO2005123816A1/de not_active Ceased
- 2005-06-09 JP JP2007515833A patent/JP5208501B2/ja not_active Expired - Fee Related
- 2005-06-09 KR KR1020077000975A patent/KR101256271B1/ko not_active Expired - Fee Related
- 2005-06-09 PL PL05753572T patent/PL1758951T3/pl unknown
- 2005-06-09 AT AT05753572T patent/ATE468369T1/de active
- 2005-06-09 ES ES05753572T patent/ES2344211T3/es not_active Expired - Lifetime
- 2005-06-09 CN CN200580020105A patent/CN100586993C/zh not_active Expired - Fee Related
- 2005-06-09 DE DE502005009601T patent/DE502005009601D1/de not_active Expired - Lifetime
- 2005-06-09 BR BRPI0512006-3A patent/BRPI0512006A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1758951B1 (de) | 2010-05-19 |
| DE502005009601D1 (de) | 2010-07-01 |
| US8173714B2 (en) | 2012-05-08 |
| DE102004028768A1 (de) | 2005-12-29 |
| JP5208501B2 (ja) | 2013-06-12 |
| CN1968997A (zh) | 2007-05-23 |
| ES2344211T3 (es) | 2010-08-20 |
| JP2008502750A (ja) | 2008-01-31 |
| KR101256271B1 (ko) | 2013-04-18 |
| EP1758951A1 (de) | 2007-03-07 |
| PL1758951T3 (pl) | 2010-10-29 |
| WO2005123816A1 (de) | 2005-12-29 |
| US20070142488A1 (en) | 2007-06-21 |
| ATE468369T1 (de) | 2010-06-15 |
| BRPI0512006A (pt) | 2008-02-06 |
| KR20070034587A (ko) | 2007-03-28 |
| MXPA06014440A (es) | 2007-03-21 |
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