CN100548476C - 一种适合于浆态床用纳米催化剂及制法和应用 - Google Patents
一种适合于浆态床用纳米催化剂及制法和应用 Download PDFInfo
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- CN100548476C CN100548476C CNB2008100551225A CN200810055122A CN100548476C CN 100548476 C CN100548476 C CN 100548476C CN B2008100551225 A CNB2008100551225 A CN B2008100551225A CN 200810055122 A CN200810055122 A CN 200810055122A CN 100548476 C CN100548476 C CN 100548476C
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- nanocatalyst
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- alcoholic solvent
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- 239000002002 slurry Substances 0.000 title claims abstract description 29
- 239000011943 nanocatalyst Substances 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 230000001476 alcoholic effect Effects 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 230000003019 stabilising effect Effects 0.000 claims abstract description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 18
- 238000003786 synthesis reaction Methods 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 15
- 238000010992 reflux Methods 0.000 claims description 13
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 5
- 239000008246 gaseous mixture Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 18
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 18
- 239000002105 nanoparticle Substances 0.000 description 14
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
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- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (13)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2008100551225A CN100548476C (zh) | 2008-05-19 | 2008-05-19 | 一种适合于浆态床用纳米催化剂及制法和应用 |
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CNB2008100551225A CN100548476C (zh) | 2008-05-19 | 2008-05-19 | 一种适合于浆态床用纳米催化剂及制法和应用 |
Publications (2)
Publication Number | Publication Date |
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CN101269330A CN101269330A (zh) | 2008-09-24 |
CN100548476C true CN100548476C (zh) | 2009-10-14 |
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CNB2008100551225A Expired - Fee Related CN100548476C (zh) | 2008-05-19 | 2008-05-19 | 一种适合于浆态床用纳米催化剂及制法和应用 |
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CN (1) | CN100548476C (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103045284B (zh) * | 2011-10-13 | 2015-02-25 | 中国石油化工股份有限公司 | 一种提高液体烃选择性的费托合成方法 |
CN104607190B (zh) * | 2015-01-30 | 2018-01-16 | 武汉凯迪工程技术研究总院有限公司 | 用于费托合成的单分散过渡金属纳米催化剂及其制备方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1613560A (zh) * | 2004-09-18 | 2005-05-11 | 太原理工大学 | 浆态床用催化剂及制备方法 |
CN1974006A (zh) * | 2006-12-14 | 2007-06-06 | 太原理工大学 | 一种浆状催化剂及其制备方法 |
CN101045206A (zh) * | 2007-05-08 | 2007-10-03 | 北京大学 | 一种进行费托合成反应的方法及其专用催化剂 |
CN101134163A (zh) * | 2007-10-11 | 2008-03-05 | 北京大学 | 一种合成甲酸酯的方法及其专用催化剂 |
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2008
- 2008-05-19 CN CNB2008100551225A patent/CN100548476C/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1613560A (zh) * | 2004-09-18 | 2005-05-11 | 太原理工大学 | 浆态床用催化剂及制备方法 |
CN1974006A (zh) * | 2006-12-14 | 2007-06-06 | 太原理工大学 | 一种浆状催化剂及其制备方法 |
CN101045206A (zh) * | 2007-05-08 | 2007-10-03 | 北京大学 | 一种进行费托合成反应的方法及其专用催化剂 |
CN101134163A (zh) * | 2007-10-11 | 2008-03-05 | 北京大学 | 一种合成甲酸酯的方法及其专用催化剂 |
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CN101269330A (zh) | 2008-09-24 |
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