CN100546715C - 金属氧化物催化剂和其制备方法 - Google Patents

金属氧化物催化剂和其制备方法 Download PDF

Info

Publication number
CN100546715C
CN100546715C CNB2005800247997A CN200580024799A CN100546715C CN 100546715 C CN100546715 C CN 100546715C CN B2005800247997 A CNB2005800247997 A CN B2005800247997A CN 200580024799 A CN200580024799 A CN 200580024799A CN 100546715 C CN100546715 C CN 100546715C
Authority
CN
China
Prior art keywords
catalyst
average
acid
water
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2005800247997A
Other languages
English (en)
Chinese (zh)
Other versions
CN101001696A (zh
Inventor
罗伯特·施勒格尔
奥拉夫·廷佩
谢里凡比宾提Oa阿卜杜哈米德
德克·尼迈尔
斯特凡·克诺布尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Max Planck Association Fritz Haber Institute
NanoC Sdn Bhd
Original Assignee
Max Planck Association Fritz Haber Institute
NanoC Sdn Bhd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Max Planck Association Fritz Haber Institute, NanoC Sdn Bhd filed Critical Max Planck Association Fritz Haber Institute
Publication of CN101001696A publication Critical patent/CN101001696A/zh
Application granted granted Critical
Publication of CN100546715C publication Critical patent/CN100546715C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/28Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32Manganese, technetium or rhenium
    • B01J23/34Manganese
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057Selenium or tellurium; Compounds thereof
    • B01J27/0576Tellurium; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB2005800247997A 2004-07-22 2005-07-22 金属氧化物催化剂和其制备方法 Expired - Fee Related CN100546715C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04017308 2004-07-22
EP04017308.0 2004-07-22

Publications (2)

Publication Number Publication Date
CN101001696A CN101001696A (zh) 2007-07-18
CN100546715C true CN100546715C (zh) 2009-10-07

Family

ID=34925867

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005800247997A Expired - Fee Related CN100546715C (zh) 2004-07-22 2005-07-22 金属氧化物催化剂和其制备方法

Country Status (5)

Country Link
US (1) US20070203022A1 (enExample)
EP (1) EP1776185A1 (enExample)
JP (1) JP5160888B2 (enExample)
CN (1) CN100546715C (enExample)
WO (1) WO2006008177A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4727506B2 (ja) * 2006-06-07 2011-07-20 旭化成ケミカルズ株式会社 ブロンズ構造を有する酸化物の製造方法
KR100954045B1 (ko) * 2007-08-13 2010-04-20 주식회사 엘지화학 개선된 아크릴산 제조용 촉매의 합성방법
KR100954046B1 (ko) * 2007-08-22 2010-04-20 주식회사 엘지화학 반응성 볼밀링을 이용한 아크릴산 제조용 촉매의 제조방법
DE112009000404T5 (de) 2008-02-25 2010-12-30 Sakthivel, Ayyamperumal, Dr., Vadodara Phasen-angereicherter MoVTeNb-Mischoxidkatalysator und Verfahren zu seiner Herstellung
US20090264283A1 (en) * 2008-04-16 2009-10-22 Basf Catalysts Llc Stabilized Iridium and Ruthenium Catalysts
JP5295815B2 (ja) * 2009-02-18 2013-09-18 住友化学株式会社 メタクロレインおよびメタクリル酸の製造触媒
CN107008510B (zh) * 2010-12-17 2019-09-10 旭化成株式会社 催化剂的制造装置及制造方法、以及不饱和酸或不饱和腈的制造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
CN102921407B (zh) * 2012-03-26 2014-10-29 湖北恒昊科技有限公司 一种锰铈复合氧化物、制备方法及其应用
CN103285888B (zh) * 2013-04-18 2016-03-16 沈阳化工大学 一种用于丙烯一步氧化制备丙烯酸反应的催化剂及其制备方法
EP3062925B1 (en) 2013-10-30 2022-07-13 BASF Corporation Catalyst coatings for pollution control
CN105582964B (zh) * 2014-11-18 2018-08-07 中触媒有限公司 一种复合金属氧化物催化剂及其制备方法和应用
US11752494B2 (en) * 2018-10-18 2023-09-12 Shell Usa, Inc. Catalyst for alkane oxidative dehydrogenation and/or alkene oxidation
CN109569577A (zh) * 2019-01-15 2019-04-05 山东玉皇化工有限公司 复合金属氧化物催化剂及其制备方法和应用
CN111468136B (zh) * 2020-05-19 2021-06-15 西南化工研究设计院有限公司 一种由丙烷氧化制丙烯酸催化剂及其制备方法
CN112156795A (zh) * 2020-10-30 2021-01-01 山东玉皇化工有限公司 一种催化剂及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1382523A (zh) * 2001-04-25 2002-12-04 罗姆和哈斯公司 改进的催化剂
EP1407819A2 (en) * 2002-10-01 2004-04-14 Rohm And Haas Company Hydrothermally synthesized Mo-V-M-Nb-X oxide catalysts for the selective oxidation of hydrocarbons
DE10254279A1 (de) * 2002-11-20 2004-06-03 Basf Ag Multimetalloxidmassen

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5049692A (en) * 1987-11-25 1991-09-17 Mitsubishi Kasei Corporation Catalytic conversion of alkanes to nitriles, and a catalyst therefor
JPH0857319A (ja) * 1994-08-24 1996-03-05 Mitsubishi Chem Corp 金属酸化物触媒の活性化方法
JPH1143314A (ja) * 1997-07-25 1999-02-16 Mitsubishi Chem Corp 複合酸化物の製造方法
ID20670A (id) * 1997-08-05 1999-02-11 Asahi Chemical Ind Katalis amoksidasi untuk digunakan dalam memproduksi akrilonitril atau metakrilonitril dari propana atau isobutana dengan amoksidasi
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
US6841699B2 (en) * 2001-04-25 2005-01-11 Rohm And Haas Company Recalcined catalyst
EP1306129A1 (en) * 2001-10-26 2003-05-02 Rohm And Haas Company Preparation of a mixed metal oxide catalyst and its use in oxidation and ammoxidation reactions
US7001866B2 (en) * 2002-11-13 2006-02-21 Conocophillips Company Modification of the pore structure of metal oxide and mixed metal oxide supports for catalysts synthesis

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1382523A (zh) * 2001-04-25 2002-12-04 罗姆和哈斯公司 改进的催化剂
EP1407819A2 (en) * 2002-10-01 2004-04-14 Rohm And Haas Company Hydrothermally synthesized Mo-V-M-Nb-X oxide catalysts for the selective oxidation of hydrocarbons
DE10254279A1 (de) * 2002-11-20 2004-06-03 Basf Ag Multimetalloxidmassen

Also Published As

Publication number Publication date
WO2006008177A1 (en) 2006-01-26
JP2008506522A (ja) 2008-03-06
JP5160888B2 (ja) 2013-03-13
EP1776185A1 (en) 2007-04-25
US20070203022A1 (en) 2007-08-30
CN101001696A (zh) 2007-07-18

Similar Documents

Publication Publication Date Title
CN100546715C (zh) 金属氧化物催化剂和其制备方法
Yang et al. Facile surface improvement method for LaCoO 3 for toluene oxidation
Li et al. Layered double hydroxide supported gold nanoclusters by glutathione-capped Au nanoclusters precursor method for highly efficient aerobic oxidation of alcohols
JP5683467B2 (ja) 幾何形状触媒成形体の製造法
Deori et al. (100) surface-exposed CeO 2 nanocubes as an efficient heterogeneous catalyst in the tandem oxidation of benzyl alcohol, para-chlorobenzyl alcohol and toluene to the corresponding aldehydes selectively
WO2009106474A2 (en) Phase-enriched movtenb mixed oxide catalyst and methods for the preparation thereof
Fonseca et al. Ceria-zirconia supported Au as highly active low temperature Water-gas shift catalysts
RU2655387C2 (ru) Способ получения каталитически активной массы в виде смеси содержащего молибден и ванадий многоэлементного оксида по меньшей мере с одним оксидом молибдена
CN109158099A (zh) (甲基)丙烯醛非均相催化气相部分氧化为(甲基)丙烯酸的方法
TW201002420A (en) Method for producing catalyst for use in production of unsaturated aldehyde and/or unsaturated carboxylic acid, and method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
JP2008501515A (ja) 多金属酸化物材料の製造方法
Senanayake et al. Interfacial Cu+ promoted surface reactivity: Carbon monoxide oxidation reaction over polycrystalline copper–titania catalysts
EP2212022A1 (en) An improved process to produce high surface area nanoparticle vanadium phosphorus oxide catalyst and product derives thereof
US7375052B2 (en) Process for producing metal oxide catalyst
Liu et al. Study on the formation process of MoO3/Fe2 (MoO4) 3 by mechanochemical synthesis and their catalytic performance in methanol to formaldehyde
US7495121B2 (en) Mo- and V-containing multimetal oxide materials
CN100423836C (zh) 制备金属氧化物催化剂的方法
JP2008000709A (ja) メタクリル酸製造用ヘテロポリ酸系触媒の製造方法
Mo et al. Selective oxidation of toluene using Ag nanoparticles self-supported on Ag2V4O11 nanobelts
JP7237268B1 (ja) 不飽和カルボン酸製造用触媒およびその製造方法、並びに不飽和カルボン酸の製造方法
JP2008284439A (ja) メタクリル酸製造用ヘテロポリ酸系触媒
Roselin et al. Hydrogen production by partial oxidation of methanol over gold supported on Fe2O3
JP4868519B2 (ja) 純粋なI相中に存在する、Mo、Vおよびアルカリ金属を含有する多重金属酸化物材料
Miah et al. Dispersion of nanosized ceria-terbia solid solutions over silica surface: Evaluation of structural characteristics and catalytic activity
CN117083123A (zh) 羧酸酯制造用催化剂、羧酸酯的制造方法和羧酸酯制造用催化剂的制造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20091007

Termination date: 20130722