CN100546715C - 金属氧化物催化剂和其制备方法 - Google Patents

金属氧化物催化剂和其制备方法 Download PDF

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Publication number
CN100546715C
CN100546715C CNB2005800247997A CN200580024799A CN100546715C CN 100546715 C CN100546715 C CN 100546715C CN B2005800247997 A CNB2005800247997 A CN B2005800247997A CN 200580024799 A CN200580024799 A CN 200580024799A CN 100546715 C CN100546715 C CN 100546715C
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catalyst
acid
average
water
composition
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Expired - Fee Related
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Chinese (zh)
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CN101001696A (zh
Inventor
罗伯特·施勒格尔
奥拉夫·廷佩
谢里凡比宾提Oa阿卜杜哈米德
德克·尼迈尔
斯特凡·克诺布尔
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Max Planck Association Fritz Haber Institute
NanoC Sdn Bhd
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Max Planck Association Fritz Haber Institute
NanoC Sdn Bhd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB2005800247997A 2004-07-22 2005-07-22 金属氧化物催化剂和其制备方法 Expired - Fee Related CN100546715C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04017308 2004-07-22
EP04017308.0 2004-07-22

Publications (2)

Publication Number Publication Date
CN101001696A CN101001696A (zh) 2007-07-18
CN100546715C true CN100546715C (zh) 2009-10-07

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Country Status (5)

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US (1) US20070203022A1 (enExample)
EP (1) EP1776185A1 (enExample)
JP (1) JP5160888B2 (enExample)
CN (1) CN100546715C (enExample)
WO (1) WO2006008177A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4727506B2 (ja) * 2006-06-07 2011-07-20 旭化成ケミカルズ株式会社 ブロンズ構造を有する酸化物の製造方法
KR100954045B1 (ko) * 2007-08-13 2010-04-20 주식회사 엘지화학 개선된 아크릴산 제조용 촉매의 합성방법
KR100954046B1 (ko) * 2007-08-22 2010-04-20 주식회사 엘지화학 반응성 볼밀링을 이용한 아크릴산 제조용 촉매의 제조방법
DE112009000404T5 (de) 2008-02-25 2010-12-30 Sakthivel, Ayyamperumal, Dr., Vadodara Phasen-angereicherter MoVTeNb-Mischoxidkatalysator und Verfahren zu seiner Herstellung
US20090264283A1 (en) * 2008-04-16 2009-10-22 Basf Catalysts Llc Stabilized Iridium and Ruthenium Catalysts
JP5295815B2 (ja) * 2009-02-18 2013-09-18 住友化学株式会社 メタクロレインおよびメタクリル酸の製造触媒
CN103260755A (zh) * 2010-12-17 2013-08-21 旭化成化学株式会社 催化剂的制造装置及制造方法、以及不饱和酸或不饱和腈的制造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
CN102921407B (zh) * 2012-03-26 2014-10-29 湖北恒昊科技有限公司 一种锰铈复合氧化物、制备方法及其应用
CN103285888B (zh) * 2013-04-18 2016-03-16 沈阳化工大学 一种用于丙烯一步氧化制备丙烯酸反应的催化剂及其制备方法
US20150119233A1 (en) * 2013-10-30 2015-04-30 Basf Corporation Highly dispersed metal oxide catalyst coatings
CN105582964B (zh) * 2014-11-18 2018-08-07 中触媒有限公司 一种复合金属氧化物催化剂及其制备方法和应用
CN112867560A (zh) * 2018-10-18 2021-05-28 国际壳牌研究有限公司 用于烷烃氧化脱氢和/或烯烃氧化的催化剂
CN109569577A (zh) * 2019-01-15 2019-04-05 山东玉皇化工有限公司 复合金属氧化物催化剂及其制备方法和应用
CN111468136B (zh) * 2020-05-19 2021-06-15 西南化工研究设计院有限公司 一种由丙烷氧化制丙烯酸催化剂及其制备方法
CN112156795A (zh) * 2020-10-30 2021-01-01 山东玉皇化工有限公司 一种催化剂及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1382523A (zh) * 2001-04-25 2002-12-04 罗姆和哈斯公司 改进的催化剂
EP1407819A2 (en) * 2002-10-01 2004-04-14 Rohm And Haas Company Hydrothermally synthesized Mo-V-M-Nb-X oxide catalysts for the selective oxidation of hydrocarbons
DE10254279A1 (de) * 2002-11-20 2004-06-03 Basf Ag Multimetalloxidmassen

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5049692A (en) * 1987-11-25 1991-09-17 Mitsubishi Kasei Corporation Catalytic conversion of alkanes to nitriles, and a catalyst therefor
JPH0857319A (ja) * 1994-08-24 1996-03-05 Mitsubishi Chem Corp 金属酸化物触媒の活性化方法
JPH1143314A (ja) * 1997-07-25 1999-02-16 Mitsubishi Chem Corp 複合酸化物の製造方法
DE19835247B4 (de) * 1997-08-05 2022-04-28 Asahi Kasei Kabushiki Kaisha Ammonoxidationskatalysator und Verfahren zur Herstellung von Acrylnitril oder Methacrylnitril aus Propan oder Isobutan durch Ammonoxidation
US6693059B2 (en) * 2000-02-09 2004-02-17 Rohm And Haas Company Process for preparing a catalyst and catalytic oxidation therewith
US6841699B2 (en) * 2001-04-25 2005-01-11 Rohm And Haas Company Recalcined catalyst
KR20030035896A (ko) * 2001-10-26 2003-05-09 롬 앤드 하스 캄파니 혼합 금속 산화물 촉매의 처리
US7001866B2 (en) * 2002-11-13 2006-02-21 Conocophillips Company Modification of the pore structure of metal oxide and mixed metal oxide supports for catalysts synthesis

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1382523A (zh) * 2001-04-25 2002-12-04 罗姆和哈斯公司 改进的催化剂
EP1407819A2 (en) * 2002-10-01 2004-04-14 Rohm And Haas Company Hydrothermally synthesized Mo-V-M-Nb-X oxide catalysts for the selective oxidation of hydrocarbons
DE10254279A1 (de) * 2002-11-20 2004-06-03 Basf Ag Multimetalloxidmassen

Also Published As

Publication number Publication date
WO2006008177A1 (en) 2006-01-26
CN101001696A (zh) 2007-07-18
EP1776185A1 (en) 2007-04-25
US20070203022A1 (en) 2007-08-30
JP5160888B2 (ja) 2013-03-13
JP2008506522A (ja) 2008-03-06

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