CN100473633C - 氟代烯烃的制备方法 - Google Patents

氟代烯烃的制备方法 Download PDF

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Publication number
CN100473633C
CN100473633C CNB028232666A CN02823266A CN100473633C CN 100473633 C CN100473633 C CN 100473633C CN B028232666 A CNB028232666 A CN B028232666A CN 02823266 A CN02823266 A CN 02823266A CN 100473633 C CN100473633 C CN 100473633C
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China
Prior art keywords
crown
phase transfer
hydrogen
transfer catalyst
fluorine
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Expired - Fee Related
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CNB028232666A
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English (en)
Chinese (zh)
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CN1589248A (zh
Inventor
N·K·哈里达森
I·R·尚克兰德
D·E·布拉德利
A·J·波斯
T·R·德明
D·纳尔瓦杰克
M·范德普伊
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Honeywell International Inc
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Honeywell International Inc
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Publication of CN1589248A publication Critical patent/CN1589248A/zh
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/013Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/04Preparation of halogenated hydrocarbons by addition of halogens to unsaturated halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/25Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB028232666A 2001-09-25 2002-09-25 氟代烯烃的制备方法 Expired - Fee Related CN100473633C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/962,974 US6548719B1 (en) 2001-09-25 2001-09-25 Process for producing fluoroolefins
US09/962,974 2001-09-25

Publications (2)

Publication Number Publication Date
CN1589248A CN1589248A (zh) 2005-03-02
CN100473633C true CN100473633C (zh) 2009-04-01

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CNB028232666A Expired - Fee Related CN100473633C (zh) 2001-09-25 2002-09-25 氟代烯烃的制备方法

Country Status (7)

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US (1) US6548719B1 (enExample)
EP (1) EP1430011B1 (enExample)
JP (2) JP5093972B2 (enExample)
KR (1) KR100883425B1 (enExample)
CN (1) CN100473633C (enExample)
ES (1) ES2504140T3 (enExample)
WO (1) WO2003027051A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE48889E1 (en) 2014-08-14 2022-01-11 The Chemours Company Fc, Llc Dehydrofluorination of 245FA to 1234ZE

Families Citing this family (107)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6548719B1 (en) * 2001-09-25 2003-04-15 Honeywell International Process for producing fluoroolefins
US7279451B2 (en) * 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US7230146B2 (en) * 2003-10-27 2007-06-12 Honeywell International Inc. Process for producing fluoropropenes
US20040089839A1 (en) * 2002-10-25 2004-05-13 Honeywell International, Inc. Fluorinated alkene refrigerant compositions
US8033120B2 (en) * 2002-10-25 2011-10-11 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
US7880040B2 (en) * 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US9255046B2 (en) * 2003-07-25 2016-02-09 Honeywell International Inc. Manufacturing process for HFO-1234ze
US7592494B2 (en) * 2003-07-25 2009-09-22 Honeywell International Inc. Process for the manufacture of 1,3,3,3-tetrafluoropropene
US8530708B2 (en) * 2003-07-25 2013-09-10 Honeywell International Inc. Processes for selective dehydrohalogenation of halogenated alkanes
US9499729B2 (en) * 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
US9308199B2 (en) * 2004-04-29 2016-04-12 Honeywell International Inc. Medicament formulations
US7655610B2 (en) * 2004-04-29 2010-02-02 Honeywell International Inc. Blowing agent compositions comprising fluorinated olefins and carbon dioxide
CN1926778A (zh) * 2004-02-27 2007-03-07 日本电气株式会社 Cdma接收装置和方法
US7951982B2 (en) * 2004-04-29 2011-05-31 Honeywell International Inc. Method for producing fluorinated organic compounds
JP4864879B2 (ja) * 2004-04-29 2012-02-01 ハネウェル・インターナショナル・インコーポレーテッド 1,3,3,3−テトラフルオロプロペンの合成方法
CA2564991C (en) * 2004-04-29 2013-03-19 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene
US7659434B2 (en) 2004-04-29 2010-02-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US8084653B2 (en) 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
US7674939B2 (en) * 2004-04-29 2010-03-09 Honeywell International Inc. Method for producing fluorinated organic compounds
CA2564897C (en) * 2004-04-29 2012-11-27 Honeywell International Inc. Processes for synthesis of 1,3,3,3-tetrafluoropropene
US9102579B2 (en) 2004-04-29 2015-08-11 Honeywell International Inc. Method for producing fluorinated organic compounds
US9024092B2 (en) * 2006-01-03 2015-05-05 Honeywell International Inc. Method for producing fluorinated organic compounds
US8383867B2 (en) 2004-04-29 2013-02-26 Honeywell International Inc. Method for producing fluorinated organic compounds
US20060058428A1 (en) * 2004-09-16 2006-03-16 Honeywell International Inc. Fluorinated compounds having epoxy and vinyl ether functional groups
US20060122301A1 (en) * 2004-12-08 2006-06-08 Honeywell International Inc. Fluorinated divinyl ethers
US8574451B2 (en) * 2005-06-24 2013-11-05 Honeywell International Inc. Trans-chloro-3,3,3-trifluoropropene for use in chiller applications
WO2007019358A2 (en) * 2005-08-05 2007-02-15 E. I. Du Pont De Nemours And Company Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 1,1,3,3,3-pentafluoropropene
US7423188B2 (en) 2005-11-01 2008-09-09 E. I. Du Pont De Nemours And Company Azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
US7902410B2 (en) * 2005-11-03 2011-03-08 Honeywell International Inc. Process for the manufacture of fluorinated alkanes
WO2007056149A1 (en) * 2005-11-03 2007-05-18 Honeywell International Inc. Method for producing fluorinated organic compounds
US8766020B2 (en) * 2008-07-31 2014-07-01 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
US7560602B2 (en) * 2005-11-03 2009-07-14 Honeywell International Inc. Process for manufacture of fluorinated olefins
ES2400732T3 (es) * 2005-11-03 2013-04-11 Honeywell International Inc. Método para la producción de compuestos orgánicos fluorados
EP3336074B1 (en) 2006-01-03 2025-07-09 Honeywell International Inc. Method for producing fluorinated organic compounds
ES2392591T3 (es) * 2006-03-31 2012-12-12 E.I. Du Pont De Nemours And Company Coproducción de hidrofluoroolefinas
EP2046704A2 (en) * 2006-06-27 2009-04-15 E.I. Du Pont De Nemours And Company Tetrafluoropropene production processes
US7485760B2 (en) * 2006-08-24 2009-02-03 Honeywell International Inc. Integrated HFC trans-1234ze manufacture process
US8067650B2 (en) * 2006-08-24 2011-11-29 Honeywell International Inc. Process for the production of HFO trans-1234ze from HFC-245fa
EP2066604B1 (en) 2006-09-05 2015-06-03 E. I. du Pont de Nemours and Company Dehydrofluorination process to manufacture hydrofluoroolefins
KR101394583B1 (ko) 2006-10-03 2014-05-12 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 탄소수 3-6의 (하이드로)플루오로알켄의 생성을 위한 탈수소할로겐화 방법
GB0806422D0 (en) * 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
US8013194B2 (en) 2008-03-14 2011-09-06 Honeywell International Inc. Process for the manufacture of fluorinated olefins
GB0625214D0 (en) * 2006-12-19 2007-01-24 Ineos Fluor Holdings Ltd Process
US7803890B2 (en) * 2006-12-20 2010-09-28 Honeywell International Inc. Fluorocopolymers
US8063149B2 (en) * 2006-12-20 2011-11-22 Honeywell International Inc. Fluorocopolymers blends
JP5380882B2 (ja) * 2007-04-17 2014-01-08 セントラル硝子株式会社 3,3,3−トリフルオロプロピンの製造方法
US7700815B2 (en) * 2007-09-28 2010-04-20 Honeywell International Inc Method for producing fluorinated organic compounds
US9079818B2 (en) * 2007-10-15 2015-07-14 Honeywell International Inc. Process for synthesis of fluorinated olefins
US8710282B2 (en) 2008-03-14 2014-04-29 Honeywell International Inc. Integrated process for the manufacture of fluorinated olefins
GB0806389D0 (en) 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
GB0806419D0 (en) * 2008-04-09 2008-05-14 Ineos Fluor Holdings Ltd Process
CN102015956B (zh) 2008-05-07 2014-06-11 纳幕尔杜邦公司 包含1,1,1,2,3-五氟丙烷或2,3,3,3-四氟丙烯的组合物
GB0808836D0 (en) 2008-05-15 2008-06-18 Ineos Fluor Ltd Process
FR2935701B1 (fr) * 2008-09-11 2012-07-27 Arkema France Procede de preparation de composes fluores olefiniques
FR2935703B1 (fr) 2008-09-11 2010-09-03 Arkema France Procede de preparation de composes fluores.
RU2011130904A (ru) 2008-12-25 2013-01-27 Асахи Гласс Компани, Лимитед Способы получения 1,1-дихлор-2,3,3,3-тетрафторпропена и 2,3,3,3-тетрафторпропена
US8552227B2 (en) * 2009-01-05 2013-10-08 E I Du Pont De Nemours And Company Preparation of hydrofluoroolefins by dehydrofluorination
FR2940968B1 (fr) 2009-01-13 2012-12-14 Arkema France Procede de preparation de composes fluores olefiniques
JP5598333B2 (ja) * 2009-01-19 2014-10-01 旭硝子株式会社 1,1−ジクロロ−2,2,3,3,3−ペンタフルオロプロパンの製造方法
WO2010129844A1 (en) 2009-05-08 2010-11-11 E. I. Du Pont De Nemours And Company Processes for reducing the amount of monofluoroacetate in hydrofluoroolefin production
FR2946338B1 (fr) 2009-06-04 2012-12-28 Arkema France Procede de preparation de composes fluores olefiniques
FR2948360B1 (fr) 2009-07-23 2011-08-05 Arkema France Procede de preparation de composes fluores olefiniques
US8129574B2 (en) 2009-08-31 2012-03-06 Honeywell International Inc. Hydrogenation process for fluorocarbons
DK2474517T3 (en) * 2009-08-31 2017-09-18 Sumitomo Chemical Co PROCEDURE FOR MANUFACTURING THE TRICHLOR-1 PROP
JP2013504658A (ja) 2009-09-09 2013-02-07 ハネウェル・インターナショナル・インコーポレーテッド モノクロロトリフルオロプロペン化合物及び組成物並びにそれを用いる方法
US7829748B1 (en) 2009-09-21 2010-11-09 Honeywell International Inc. Process for the manufacture of 1,3,3,3-tetrafluoropropene
WO2011102538A2 (en) * 2010-02-19 2011-08-25 Daikin Industries, Ltd. Process for producing 2-chloro-3,3,3-trifluoropropene
US8927791B2 (en) * 2010-04-29 2015-01-06 Honeywell International Inc. Method for producing tetrafluoropropenes
US8901360B2 (en) 2010-05-21 2014-12-02 Honeywell International Inc. Process for cis 1,1,1,4,4,4-hexafluoro-2-butene
TW201204686A (en) * 2010-06-23 2012-02-01 Asahi Glass Co Ltd Process for preparation of 1,1-dichloro-2,2,3,3,3-penta- fluoropropane
EP2586762B1 (en) * 2010-06-23 2019-08-07 AGC Inc. Production method for 1,1-dichloro-2,3,3,3-tetra-fluoropropene and 2,3,3,3-tetrafluoropropene
US8436217B2 (en) 2011-04-25 2013-05-07 Honeywell International Inc. Integrated process to co-produce 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene
CN102887812A (zh) * 2011-07-20 2013-01-23 中化蓝天集团有限公司 1,1,3,3,3-五氟丙烯的合成方法
JPWO2013015201A1 (ja) * 2011-07-22 2015-02-23 旭硝子株式会社 熱サイクル用作動媒体および熱サイクルシステム
JP5712894B2 (ja) * 2011-10-14 2015-05-07 セントラル硝子株式会社 (z)−1−クロロ−3,3,3−トリフルオロプロペンの製造方法
US8889924B2 (en) 2012-02-14 2014-11-18 Honeywell International Inc. Process for the production of 1,3,3,3-tetrafluoropropene
US8829254B2 (en) 2012-02-14 2014-09-09 Honeywell International Inc. Process for making 1,3,3,3-tetrafluoropropene
JP6107466B2 (ja) 2012-06-28 2017-04-05 セントラル硝子株式会社 トランス−1,3,3,3−テトラフルオロプロペンの精製方法
JP6107467B2 (ja) 2012-06-29 2017-04-05 セントラル硝子株式会社 1−クロロ−3,3,3−トリフルオロプロペンの製造方法
JP6183370B2 (ja) * 2012-09-21 2017-08-23 セントラル硝子株式会社 1,2−ジクロロ−3,3,3−トリフルオロプロペンの製造方法
EP2922809A1 (en) * 2012-09-28 2015-09-30 E. I. du Pont de Nemours and Company Dehydrochlorination of chlorinated reactants to produce 1,1,1,4,4,4-hexafluoro-2-butyne
US9532567B2 (en) * 2012-11-29 2017-01-03 Honeywell International Inc. Synthesis and use of trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymers
CN103880590B (zh) 2012-12-19 2016-10-05 中化蓝天集团有限公司 一种制备1,3,3,3-四氟丙烯的工艺
US8791309B2 (en) * 2012-12-21 2014-07-29 Honeywell International Inc. Synthesis of 3,3,3-trifluoropropyne
US9289758B2 (en) 2013-01-22 2016-03-22 Axiall Ohio, Inc. Processes for producing chlorinated hydrocarbons and methods for recovering polyvalent antimony catalysts therefrom
US8889930B2 (en) 2013-01-22 2014-11-18 Axiall Ohio, Inc. Process for producing chlorinated hydrocarbons
US9216932B2 (en) * 2013-05-20 2015-12-22 Honeywell International Inc. Dehalogenation of trans-1-chloro-3,3,3-trifluoropropene
US9139497B2 (en) 2013-10-23 2015-09-22 Axiall Ohio, Inc. Process for producing chlorinated hydrocarbons in the presence of a polyvalent bismuth compound
KR20230031374A (ko) * 2014-02-07 2023-03-07 더 케무어스 컴퍼니 에프씨, 엘엘씨 Z-1,1,1,4,4,4-헥사플루오로-2-부텐의 생산을 위한 통합 공정
JP6582569B2 (ja) * 2014-07-28 2019-10-02 セントラル硝子株式会社 2−クロロ−1,3,3,3−テトラフルオロプロペンの製造方法
CN104177219B (zh) * 2014-08-01 2018-02-13 巨化集团技术中心 一种制备1,3,3,3‑四氟丙烯的方法
US9790150B2 (en) 2014-08-12 2017-10-17 The Chemours Company Fc, Llc Processes for producing branched fluoroalkyl olefins
US10093601B2 (en) 2015-06-29 2018-10-09 The Boeing Company Fire retardant compounds
CN113968769A (zh) * 2015-09-11 2022-01-25 科慕埃弗西有限公司 氢氯氟烃的脱卤化氢
EP3395789B1 (en) * 2015-12-25 2020-11-18 AGC Inc. Manufacturing method of 1-chloro-2,3,3,3-tetrafluoropropene
CN105837397A (zh) * 2016-04-19 2016-08-10 四川西艾氟科技有限公司 一种全氟烷基乙烯的合成方法
CN106892794B (zh) * 2016-12-28 2019-10-15 西安近代化学研究所 一种制备反式-1,3,3,3-四氟丙烯的方法
GB201701099D0 (en) * 2017-01-23 2017-03-08 Mexichem Fluor Sa De Cv Process
US10611709B2 (en) * 2017-09-11 2020-04-07 The Chemours Company Fc, Llc Liquid phase process for preparing (E)-1,1,1,4,4,4-hexafluorobut-2-ene
FR3076553B1 (fr) 2018-01-08 2020-07-31 Arkema France Procede de purification du 1,1,1,2,3-pentafluoropropane et utilisation de celui-ci pour l'obtention de 2,3,3,3-tetrafluoropropene de haute purete.
JP6974221B2 (ja) * 2018-03-14 2021-12-01 株式会社クレハ アルケンの製造方法
FR3077072B1 (fr) 2019-01-22 2021-08-06 Arkema France Procédé de purification du 1,1,1,2,3-pentafluoropropane et utilisation de celui-ci pour l’obtention de 2,3,3,3-tétrafluoropropène de haute pureté
CN113527040B (zh) * 2020-04-22 2023-09-01 浙江省化工研究院有限公司 一种卤代丙烯的制备方法
WO2023171325A1 (ja) * 2022-03-09 2023-09-14 株式会社クレハ アルケンの製造方法
WO2023171326A1 (ja) * 2022-03-09 2023-09-14 株式会社クレハ アルケンの製造方法
WO2025160051A2 (en) * 2024-01-22 2025-07-31 The Chemours Company Fc, Llc Catalytic process for preparation of hydrofluoro(ether)olefins
WO2025160052A1 (en) * 2024-01-22 2025-07-31 The Chemours Company Fc, Llc Integrated process to make 1,1,1,2,2,5,5,6,6,6-decafluoro-3-hexene

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3664966A (en) * 1970-02-09 1972-05-23 Continental Oil Co Dehydrohalogenation catalyst
US5696310A (en) * 1996-04-12 1997-12-09 Jackson; Andrew Purification of 1,1,1,3,3-pentafluoropropane

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2889379A (en) 1957-02-06 1959-06-02 Dow Chemical Co Preparation of 3, 3, 3-trifluoropropene
US4465786A (en) 1982-09-27 1984-08-14 General Electric Company Catalyst composition for the preparation of 3,3,3-trifluoropropene
US4798818A (en) 1987-11-27 1989-01-17 Dow Corning Corporation Catalyst composition and process for its preparation
ATE172953T1 (de) 1993-07-29 1998-11-15 Allied Signal Inc Verfahren zur herstellung von 1,1,1,3,3 pentafluorpropan
US5446217A (en) 1994-05-16 1995-08-29 Alliedsignal Inc. Processes for the preparation of fluorinated olefins and hydrofluorocarbons using fluorinated olefin
JPH08169850A (ja) * 1994-12-16 1996-07-02 Daikin Ind Ltd 1,1,1,2,3,3−ヘキサフルオロプロパンの製造方法
JP3778298B2 (ja) * 1995-01-13 2006-05-24 ダイキン工業株式会社 ヘキサフルオロプロペンの製造方法
US5710352A (en) 1996-09-19 1998-01-20 Alliedsignal Inc. Vapor phase process for making 1,1,1,3,3-pentafluoropropane and 1-chloro-3,3,3-trifluoropropene
US6023004A (en) 1996-11-12 2000-02-08 Alliedsignal, Inc. Liquid phase catalytic fluorination of hydrochlorocarbon and hydrochlorofluorocarbon
US5969198A (en) 1997-06-27 1999-10-19 Alliedsignal Inc. Process for the preparation of 1,1,1,3,3-pentafluoropropane
JP4120043B2 (ja) * 1998-04-01 2008-07-16 日本ゼオン株式会社 フッ素化不飽和炭化水素の製造方法
US6124510A (en) 1998-07-21 2000-09-26 Elf Atochem North America, Inc. 1234ze preparation
US6380446B1 (en) * 2000-08-17 2002-04-30 Dupont Dow Elastomers, L.L.C. Process for dehydrohalogenation of halogenated compounds
US6548719B1 (en) * 2001-09-25 2003-04-15 Honeywell International Process for producing fluoroolefins

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3664966A (en) * 1970-02-09 1972-05-23 Continental Oil Co Dehydrohalogenation catalyst
US5696310A (en) * 1996-04-12 1997-12-09 Jackson; Andrew Purification of 1,1,1,3,3-pentafluoropropane

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE48889E1 (en) 2014-08-14 2022-01-11 The Chemours Company Fc, Llc Dehydrofluorination of 245FA to 1234ZE
USRE49896E1 (en) 2014-08-14 2024-04-02 The Chemours Company Fc, Llc Dehydrofluorination of 245FA to 1234ZE

Also Published As

Publication number Publication date
US6548719B1 (en) 2003-04-15
CN1589248A (zh) 2005-03-02
EP1430011B1 (en) 2014-07-23
JP5093972B2 (ja) 2012-12-12
US20030060670A1 (en) 2003-03-27
ES2504140T3 (es) 2014-10-08
WO2003027051A1 (en) 2003-04-03
JP2012233001A (ja) 2012-11-29
EP1430011A1 (en) 2004-06-23
JP2005504097A (ja) 2005-02-10
KR20040044993A (ko) 2004-05-31
KR100883425B1 (ko) 2009-02-12

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