CN100385721C - 制造膜电极装置的方法 - Google Patents

制造膜电极装置的方法 Download PDF

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Publication number
CN100385721C
CN100385721C CNB038192128A CN03819212A CN100385721C CN 100385721 C CN100385721 C CN 100385721C CN B038192128 A CNB038192128 A CN B038192128A CN 03819212 A CN03819212 A CN 03819212A CN 100385721 C CN100385721 C CN 100385721C
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China
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porous substrate
slurry
substrate
catalyst
membrane
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Expired - Lifetime
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CNB038192128A
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Chinese (zh)
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CN1675787A (zh
Inventor
甄苏珊
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Motors Liquidation Co
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General Motors Corp
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/881—Electrolytic membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/8814—Temporary supports, e.g. decal
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/8828—Coating with slurry or ink
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49002—Electrical device making
    • Y10T29/49108—Electric battery cell making
    • Y10T29/49115—Electric battery cell making including coating or impregnating

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Battery Electrode And Active Subsutance (AREA)
CNB038192128A 2002-06-13 2003-06-11 制造膜电极装置的方法 Expired - Lifetime CN100385721C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/171,295 US6933003B2 (en) 2002-06-13 2002-06-13 Method of making membrane electrode assemblies
US10/171,295 2002-06-13

Publications (2)

Publication Number Publication Date
CN1675787A CN1675787A (zh) 2005-09-28
CN100385721C true CN100385721C (zh) 2008-04-30

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CNB038192128A Expired - Lifetime CN100385721C (zh) 2002-06-13 2003-06-11 制造膜电极装置的方法

Country Status (7)

Country Link
US (1) US6933003B2 (enExample)
JP (1) JP4746317B2 (enExample)
CN (1) CN100385721C (enExample)
AU (1) AU2003237991A1 (enExample)
CA (1) CA2488908C (enExample)
DE (1) DE10392800B4 (enExample)
WO (1) WO2003107468A1 (enExample)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1341250B1 (de) * 2002-02-28 2011-05-11 Umicore AG & Co. KG Verfahren zur Herstellung von katalysatorbeschichteten Membranen und Membran-Elektrodeneinheiten für Brennstoffzellen
US6916573B2 (en) * 2002-07-24 2005-07-12 General Motors Corporation PEM fuel cell stack without gas diffusion media
EP1465277A1 (en) * 2003-03-19 2004-10-06 HONDA MOTOR CO., Ltd. Solid polymer electrolyte and protonconducting membrane
US20080020253A1 (en) * 2004-07-09 2008-01-24 Ingo Neubert Method for Producing a Membrane-Electrode Unit
US20060254286A1 (en) * 2005-05-16 2006-11-16 Johnson Lonnie G Solid state cryocooler
DE102005038612A1 (de) * 2005-08-16 2007-02-22 Basf Ag Verfahren zur Herstellung von beidseitig katalysatorbeschichteten Membranen
US7651581B2 (en) * 2005-12-20 2010-01-26 Gm Global Technology Operations, Inc. Catalyst coated diffusion media
ITMI20052508A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Processo per ottenere ccm con subgasket
US7785435B2 (en) * 2006-02-27 2010-08-31 Gm Global Technology Operations, Inc. Method of laminating a decal to a carrier film
US8168025B2 (en) * 2006-04-21 2012-05-01 Bdf Ip Holdings Ltd. Methods of making components for electrochemical cells
JP5023570B2 (ja) * 2006-06-21 2012-09-12 トヨタ自動車株式会社 補強型電解質膜および膜電極接合体の製造方法
KR100957302B1 (ko) * 2007-09-07 2010-05-12 현대자동차주식회사 연료전지용 막-전극 접합체의 제조방법
KR101164874B1 (ko) * 2008-03-13 2012-07-19 한국과학기술연구원 저온 전사법을 이용한 막전극접합체 제조방법, 이에 따라제조된 막전극접합체 및 이를 이용한 연료전지
KR101021115B1 (ko) * 2008-05-06 2011-03-14 현대자동차주식회사 엠이에이의 촉매전극층 제조방법
KR101101994B1 (ko) * 2008-06-20 2012-01-02 한국에너지기술연구원 수소이온전도성 멤브레인을 사용하는 연료전지 막전극접합체의 롤 프레스에 의한 제조 방법 및 이에 의해 제조된연료전지 막전극 접합체
CN101728542B (zh) * 2008-10-10 2012-06-20 中国科学院大连化学物理研究所 一种薄层憎水催化层的制备方法
US20110217621A1 (en) * 2008-12-23 2011-09-08 E. I. Du Pont De Nemours And Company Process to produce catalyst coated membranes for fuel cell applications
WO2011123275A1 (en) 2010-04-01 2011-10-06 Trenergi Corp. High temperature membrane electrode assembly with high power density and corresponding method of making
WO2012053303A1 (ja) * 2010-10-22 2012-04-26 日産自動車株式会社 固体高分子型燃料電池用電極触媒
KR101963921B1 (ko) * 2011-07-08 2019-03-29 아우디 아게 백금 저함량 전극
JP5776584B2 (ja) * 2012-02-23 2015-09-09 トヨタ自動車株式会社 膜電極接合体の製造装置、および、膜電極接合体の製造方法
KR101637711B1 (ko) * 2014-10-30 2016-07-07 현대자동차주식회사 연료전지의 고분자 전해질막-전극 접합체용 전극의 분리방법과 그 장치
JP6702251B2 (ja) * 2017-04-17 2020-05-27 信越化学工業株式会社 ポジ型レジストフィルム積層体及びパターン形成方法
JP2019003850A (ja) * 2017-06-16 2019-01-10 トヨタ自動車株式会社 触媒層の製造方法およびその製造装置
US12347872B2 (en) * 2019-11-06 2025-07-01 Triad National Security, Llc Ionomer membranes for fuel cells and related devices
CN111082071B (zh) * 2019-12-31 2021-03-23 武汉理工氢电科技有限公司 燃料电池的电极组件及其制备方法
DE102021214489A1 (de) 2021-12-16 2023-06-22 Robert Bosch Gesellschaft mit beschränkter Haftung Verfahren zum Herstellen einer elektrochemischen Zelle
US12338539B1 (en) 2024-07-19 2025-06-24 Ohmium International, Inc. Hybrid electrocatalyst layers for membrane-based electrochemical devices and processes for making the same

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5981097A (en) * 1996-12-23 1999-11-09 E.I. Du Pont De Nemours And Company Multiple layer membranes for fuel cells employing direct feed fuels

Family Cites Families (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US523849A (en) * 1894-07-31 carroll
CA962021A (en) 1970-05-21 1975-02-04 Robert W. Gore Porous products and process therefor
US4350608A (en) 1978-04-24 1982-09-21 Diamond Shamrock Corporation Oxygen cathode for alkali-halide electrolysis and method of making same
US4469579A (en) 1981-06-26 1984-09-04 Diamond Shamrock Corporation Solid polymer electrolytes and electrode bonded with hydrophylic fluorocopolymers
US4465533A (en) 1983-01-13 1984-08-14 Eltech Systems Limited Method for making polymer bonded electrodes
US4876115A (en) 1987-01-30 1989-10-24 United States Department Of Energy Electrode assembly for use in a solid polymer electrolyte fuel cell
US5116800A (en) 1990-12-11 1992-05-26 Allied-Signal Inc. High durability and exhuast catalyst with low hydrogen sulfide emissions
US5234777A (en) 1991-02-19 1993-08-10 The Regents Of The University Of California Membrane catalyst layer for fuel cells
US5211984A (en) 1991-02-19 1993-05-18 The Regents Of The University Of California Membrane catalyst layer for fuel cells
JPH04342923A (ja) * 1991-05-21 1992-11-30 Nec Corp けい光表示管のけい光面形成方法
JPH0613085A (ja) 1991-05-21 1994-01-21 Japan Vilene Co Ltd 燃料電池用電極触媒層の製造方法
US5230849A (en) * 1991-06-04 1993-07-27 Michael S. Hsu Electrochemical converter assembly and overlay methods of forming component structures
US5272017A (en) 1992-04-03 1993-12-21 General Motors Corporation Membrane-electrode assemblies for electrochemical cells
JP3492385B2 (ja) * 1992-07-01 2004-02-03 クロリンエンジニアズ株式会社 燃料電池用ガス拡散電極の製造方法
JPH0611612A (ja) * 1992-06-26 1994-01-21 Matsushita Electric Ind Co Ltd カラー液晶素子の製造方法
JPH0676808A (ja) 1992-06-29 1994-03-18 Japan Gore Tex Inc 電池用隔膜及び電池
US5330860A (en) * 1993-04-26 1994-07-19 E. I. Du Pont De Nemours And Company Membrane and electrode structure
US6180163B1 (en) 1993-11-22 2001-01-30 E. I. Du Pont De Nemours And Company Method of making a membrane-electrode assembly
US5470448A (en) * 1994-01-28 1995-11-28 United Technologies Corporation High performance electrolytic cell electrode/membrane structures and a process for preparing such electrode structures
JP3555196B2 (ja) * 1994-09-19 2004-08-18 トヨタ自動車株式会社 燃料電池とその製造方法
US5599614A (en) 1995-03-15 1997-02-04 W. L. Gore & Associates, Inc. Integral composite membrane
US5547551A (en) 1995-03-15 1996-08-20 W. L. Gore & Associates, Inc. Ultra-thin integral composite membrane
US6054230A (en) 1994-12-07 2000-04-25 Japan Gore-Tex, Inc. Ion exchange and electrode assembly for an electrochemical cell
JP3712768B2 (ja) 1995-01-26 2005-11-02 松下電器産業株式会社 固体高分子型燃料電池の製造法
DE19509748C2 (de) * 1995-03-17 1997-01-23 Deutsche Forsch Luft Raumfahrt Verfahren zur Herstellung eines Verbundes aus Elektrodenmaterial, Katalysatormaterial und einer Festelektrolytmembran
US5518831A (en) * 1995-07-07 1996-05-21 The Dow Chemical Company Electrocatalytic structure
DE19548421B4 (de) * 1995-12-22 2004-06-03 Celanese Ventures Gmbh Verfahren zur kontinuierlichen Herstellung von Membranelektrodeneinheiten
US5937512A (en) * 1996-01-11 1999-08-17 Micron Communications, Inc. Method of forming a circuit board
JP3262708B2 (ja) 1996-03-26 2002-03-04 日本電信電話株式会社 複合高分子電解質膜
US5945231A (en) 1996-03-26 1999-08-31 California Institute Of Technology Direct liquid-feed fuel cell with membrane electrolyte and manufacturing thereof
US5707755A (en) 1996-12-09 1998-01-13 General Motors Corporation PEM/SPE fuel cell
JP3773325B2 (ja) 1997-03-17 2006-05-10 ジャパンゴアテックス株式会社 高分子固体電解質燃料電池用ガス拡散層材料及びその接合体
US6291091B1 (en) 1997-12-24 2001-09-18 Ballard Power Systems Inc. Continuous method for manufacturing a Laminated electrolyte and electrode assembly
US6074692A (en) 1998-04-10 2000-06-13 General Motors Corporation Method of making MEA for PEM/SPE fuel cell
JP2000090944A (ja) * 1998-09-10 2000-03-31 Japan Storage Battery Co Ltd 触媒層−電解質膜接合体の製造方法およびそれを用いた固体高分子電解質型燃料電池
US6127061A (en) 1999-01-26 2000-10-03 High-Density Energy, Inc. Catalytic air cathode for air-metal batteries
JP2000299119A (ja) * 1999-04-16 2000-10-24 Japan Storage Battery Co Ltd 触媒層の製造方法
JP4639415B2 (ja) * 1999-07-02 2011-02-23 トヨタ自動車株式会社 薄膜積層装置
US6641862B1 (en) * 1999-09-24 2003-11-04 Ion Power, Inc. Preparation of fuel cell electrode assemblies
JP4734688B2 (ja) * 2000-02-01 2011-07-27 東レ株式会社 電極およびその製造方法、膜−電極複合体およびその製造方法並びにこれらを用いた電気化学装置、水電解装置、燃料電池およびこれを用いた移動体および自動車
JP2002042825A (ja) * 2000-05-18 2002-02-08 Matsushita Electric Ind Co Ltd 燃料電池用電極触媒、その製造方法および燃料電池
JP5140898B2 (ja) * 2000-07-10 2013-02-13 東レ株式会社 膜−電極接合体の製造方法
US6524736B1 (en) * 2000-10-18 2003-02-25 General Motors Corporation Methods of preparing membrane electrode assemblies
US6585846B1 (en) * 2000-11-22 2003-07-01 3M Innovative Properties Company Rotary converting apparatus and method for laminated products and packaging

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5981097A (en) * 1996-12-23 1999-11-09 E.I. Du Pont De Nemours And Company Multiple layer membranes for fuel cells employing direct feed fuels

Also Published As

Publication number Publication date
CN1675787A (zh) 2005-09-28
CA2488908C (en) 2009-10-27
WO2003107468A1 (en) 2003-12-24
JP4746317B2 (ja) 2011-08-10
US20030232714A1 (en) 2003-12-18
US6933003B2 (en) 2005-08-23
DE10392800T5 (de) 2005-05-25
DE10392800B4 (de) 2009-06-25
CA2488908A1 (en) 2003-12-24
JP2006513527A (ja) 2006-04-20
AU2003237991A1 (en) 2003-12-31

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