CN100378160C - 无卤素阻燃聚丙烯及制备方法 - Google Patents
无卤素阻燃聚丙烯及制备方法 Download PDFInfo
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- CN100378160C CN100378160C CNB2005100409866A CN200510040986A CN100378160C CN 100378160 C CN100378160 C CN 100378160C CN B2005100409866 A CNB2005100409866 A CN B2005100409866A CN 200510040986 A CN200510040986 A CN 200510040986A CN 100378160 C CN100378160 C CN 100378160C
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- Prior art keywords
- polypropylene
- coupling agent
- nano
- ammonium polyphosphate
- magnesium hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 39
- -1 polypropylene Polymers 0.000 title claims abstract description 39
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 39
- 239000003063 flame retardant Substances 0.000 title claims abstract description 32
- 229910052736 halogen Inorganic materials 0.000 title claims description 17
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 25
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 24
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 24
- 239000007822 coupling agent Substances 0.000 claims abstract description 23
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 19
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 19
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 19
- 239000003094 microcapsule Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 3
- 239000002105 nanoparticle Substances 0.000 claims description 27
- 150000002367 halogens Chemical class 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 6
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000008188 pellet Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 abstract description 9
- 238000001125 extrusion Methods 0.000 abstract description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 5
- 238000001816 cooling Methods 0.000 abstract description 5
- 239000000779 smoke Substances 0.000 abstract description 4
- 229920000877 Melamine resin Polymers 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003053 toxin Substances 0.000 abstract 1
- 231100000765 toxin Toxicity 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000011284 combination treatment Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100409866A CN100378160C (zh) | 2005-07-12 | 2005-07-12 | 无卤素阻燃聚丙烯及制备方法 |
Applications Claiming Priority (1)
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CNB2005100409866A CN100378160C (zh) | 2005-07-12 | 2005-07-12 | 无卤素阻燃聚丙烯及制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1712444A CN1712444A (zh) | 2005-12-28 |
CN100378160C true CN100378160C (zh) | 2008-04-02 |
Family
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Family Applications (1)
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CNB2005100409866A Expired - Fee Related CN100378160C (zh) | 2005-07-12 | 2005-07-12 | 无卤素阻燃聚丙烯及制备方法 |
Country Status (1)
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CN (1) | CN100378160C (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101831095A (zh) * | 2010-04-01 | 2010-09-15 | 北京富迪创业科技有限公司 | 一种舰船用电缆护套管及制备方法 |
CN101481829B (zh) * | 2009-01-20 | 2012-06-06 | 浙江依莱特纺织有限公司 | 一种有色阻燃丙纶纤维及其制备方法和应用 |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100376628C (zh) * | 2006-04-14 | 2008-03-26 | 上海市合成树脂研究所 | 一种阻燃聚丙烯组成物 |
CN101343387B (zh) * | 2007-07-12 | 2011-09-07 | 上海化工研究院 | 一种聚烯烃用无卤耐水性膨胀型磷氮阻燃剂及其制备方法 |
CN101235175B (zh) * | 2008-01-14 | 2010-12-01 | 宁波永发新材料发展有限公司 | 一种阻燃性聚丙烯复合材料的制备方法 |
CN101323774B (zh) * | 2008-07-28 | 2012-07-18 | 公安部四川消防研究所 | 建筑用膨胀型防火胶条 |
CN101358000B (zh) * | 2008-09-24 | 2011-04-13 | 贵州省复合改性聚合物材料工程技术研究中心 | 聚烯烃用磷系无卤复合阻燃剂及其制备方法和阻燃聚烯烃 |
CN101684196B (zh) * | 2008-09-26 | 2011-06-22 | 南京理工大学 | 协同阻燃尼龙6的制备方法 |
KR20110048339A (ko) * | 2009-11-02 | 2011-05-11 | 엘에스전선 주식회사 | 고난연 비할로겐계 유색 열수축 튜브 |
CN104119604A (zh) * | 2014-06-17 | 2014-10-29 | 沈太英 | 一种用于电力系统的无卤聚丙烯电缆材料及其制造方法 |
CN104871888B (zh) * | 2015-04-23 | 2018-06-05 | 安徽海义源进出口有限公司 | 一种杀虫农用网及其制备方法 |
CN104804304B (zh) * | 2015-04-24 | 2018-02-23 | 中国科学院合肥物质科学研究院 | 无卤阻燃聚丙烯复合材料及其制备方法 |
CN106280208A (zh) * | 2016-08-04 | 2017-01-04 | 浙江畅通科技有限公司 | 一种铅酸蓄电池抗老化塑壳制备方法 |
CN106189049A (zh) * | 2016-08-04 | 2016-12-07 | 浙江畅通科技有限公司 | 一种铅酸蓄电池阻燃塑壳材料 |
CN106589590A (zh) * | 2016-12-06 | 2017-04-26 | 佛山市高明区生产力促进中心 | 一种阻燃聚丙烯 |
CN107322748B (zh) * | 2017-07-11 | 2019-11-15 | 英杰惠能(北京)能源新技术有限公司 | 阻燃低voc刨花板及其制备方法 |
CN108841043B (zh) * | 2018-07-13 | 2020-04-21 | 广州广化塑料管道有限公司 | 聚氯乙烯材料用纳米化包覆改性复合阻燃剂及其制备方法 |
CN110105658B (zh) * | 2019-04-04 | 2021-08-20 | 台州市黄岩聚丰机车有限公司 | 无卤阻燃聚丙烯电动自行车外饰件原材料 |
CN110903544A (zh) * | 2019-10-30 | 2020-03-24 | 许继集团有限公司 | 一种储能用锂离子电池阻燃材料及其制备方法和应用 |
CN110964232B (zh) * | 2019-12-03 | 2021-07-16 | 苏州诺博恩新材料科技有限公司 | 一种高效环保多层结构的微胶囊阻燃剂及其制备方法 |
CN111875888B (zh) * | 2020-08-12 | 2022-09-02 | 深圳市固源塑胶制品有限公司 | 一种聚丙烯复合材料及其制备方法、成型体 |
CN112376123A (zh) * | 2020-11-04 | 2021-02-19 | 湖南中泰特种装备有限责任公司 | 一种微胶囊化聚磷酸铵阻燃超高分子量聚乙烯纤维及其制备方法 |
CN112457570A (zh) * | 2020-11-13 | 2021-03-09 | 江苏集萃先进高分子材料研究所有限公司 | 长玻纤增强聚丙烯复合材料用无卤环保阻燃母粒制备方法 |
CN115197566A (zh) * | 2022-07-05 | 2022-10-18 | 湖北合聚新材料有限公司 | 微胶囊化聚磷酸铵改性pa6材料及其制备方法、高压连接器 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1480253A (zh) * | 2003-04-10 | 2004-03-10 | 上海化工研究院 | 微胶囊包覆聚磷酸铵的制备方法 |
KR20040100120A (ko) * | 2003-05-21 | 2004-12-02 | 봉 경 김 | 단열, 내화 샌드위치 패널 및 이의 제조방법 |
CN1556136A (zh) * | 2003-12-30 | 2004-12-22 | 上海化工研究院 | 一种无卤膨胀型聚烯烃难燃剂及其制备方法 |
-
2005
- 2005-07-12 CN CNB2005100409866A patent/CN100378160C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1480253A (zh) * | 2003-04-10 | 2004-03-10 | 上海化工研究院 | 微胶囊包覆聚磷酸铵的制备方法 |
KR20040100120A (ko) * | 2003-05-21 | 2004-12-02 | 봉 경 김 | 단열, 내화 샌드위치 패널 및 이의 제조방법 |
CN1556136A (zh) * | 2003-12-30 | 2004-12-22 | 上海化工研究院 | 一种无卤膨胀型聚烯烃难燃剂及其制备方法 |
Non-Patent Citations (2)
Title |
---|
聚磷酸铵的研究进展. 章元春,杨荣杰.无机盐工业,第36卷第4期. 2004 * |
阻燃剂微胶囊技术的研究. 胡勇东,徐光卫.聚氨酯工业,第17卷第4期. 2002 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101481829B (zh) * | 2009-01-20 | 2012-06-06 | 浙江依莱特纺织有限公司 | 一种有色阻燃丙纶纤维及其制备方法和应用 |
CN101831095A (zh) * | 2010-04-01 | 2010-09-15 | 北京富迪创业科技有限公司 | 一种舰船用电缆护套管及制备方法 |
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Publication number | Publication date |
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CN1712444A (zh) | 2005-12-28 |
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EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Nanjing Jinshan Automobile Engineering Plastic Co., Ltd. Assignor: Nanjing University of Aeronautics and Astronautics Contract fulfillment period: 2008.12.29 to 2013.12.28 contract change Contract record no.: 2009320000129 Denomination of invention: Non-halogen fire-retardant polypropylene and production thereof Granted publication date: 20080402 License type: Exclusive license Record date: 2009.2.20 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.12.29 TO 2013.12.28; CHANGE OF CONTRACT Name of requester: NANJING JINSHAN CAR ENGINEERING PLASTIC CO.,LTD. Effective date: 20090220 |
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