CN100355793C - 烯烃聚合载体催化剂 - Google Patents

烯烃聚合载体催化剂 Download PDF

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Publication number
CN100355793C
CN100355793C CNB200380109629XA CN200380109629A CN100355793C CN 100355793 C CN100355793 C CN 100355793C CN B200380109629X A CNB200380109629X A CN B200380109629XA CN 200380109629 A CN200380109629 A CN 200380109629A CN 100355793 C CN100355793 C CN 100355793C
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CN
China
Prior art keywords
catalyst system
supported catalyst
group
activator
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB200380109629XA
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English (en)
Chinese (zh)
Other versions
CN1747973A (zh
Inventor
G·B·雅各布森
B·S·金伯利
S·马斯特罗伊安尼
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NEOS COMMERCIAL SERVICES UK Ltd
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Innovene Europe Ltd
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Publication of CN1747973A publication Critical patent/CN1747973A/zh
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Publication of CN100355793C publication Critical patent/CN100355793C/zh
Anticipated expiration legal-status Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
CNB200380109629XA 2002-12-17 2003-12-03 烯烃聚合载体催化剂 Expired - Fee Related CN100355793C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02358031 2002-12-17
EP02358031.9 2002-12-17

Publications (2)

Publication Number Publication Date
CN1747973A CN1747973A (zh) 2006-03-15
CN100355793C true CN100355793C (zh) 2007-12-19

Family

ID=32524110

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB200380109629XA Expired - Fee Related CN100355793C (zh) 2002-12-17 2003-12-03 烯烃聚合载体催化剂

Country Status (12)

Country Link
US (2) US20060247397A1 (enExample)
EP (1) EP1578811B1 (enExample)
JP (1) JP5362168B2 (enExample)
KR (1) KR101118495B1 (enExample)
CN (1) CN100355793C (enExample)
AT (1) ATE360037T1 (enExample)
AU (1) AU2003288399A1 (enExample)
DE (1) DE60313362T2 (enExample)
ES (1) ES2285220T3 (enExample)
MY (1) MY136117A (enExample)
TW (1) TWI357907B (enExample)
WO (1) WO2004055061A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6982306B2 (en) 2003-11-26 2006-01-03 Chevron Phillips Chemical Company, L.P. Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US7094857B2 (en) 2004-03-10 2006-08-22 Chevron Phillips Chemical Company, L.P. Ethylene polymers and copolymers with high optical opacity
EP1693388A1 (en) * 2005-02-21 2006-08-23 Innovene Europe Limited Polymerisation catalysts
EP1834983A1 (en) * 2006-03-14 2007-09-19 Ineos Europe Limited Polymer films
WO2011017092A1 (en) 2009-07-28 2011-02-10 Univation Technologies, Llc Polymerization process using a supported constrained geometry catalyst
CN106632751B (zh) * 2015-10-29 2019-12-24 中国石油化工股份有限公司 一种催化剂的制备方法和制得的催化剂及其应用
CA3159350A1 (en) 2019-10-28 2021-05-06 China Petroleum & Chemical Corporation Biphenol metal complex, preparation method therefor and use thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1225101A (zh) * 1996-05-17 1999-08-04 陶氏化学公司 制备共聚物和含该共聚物的共混组合物的方法
CN1268519A (zh) * 1999-03-24 2000-10-04 索尔维聚烯烃欧洲-比利时公司 α－烯烃的聚合方法
CN1278272A (zh) * 1997-09-05 2000-12-27 英国石油化学品有限公司 聚合催化剂
CN1278833A (zh) * 1997-12-01 2001-01-03 旭化成工业株式会社 烯烃聚合催化剂和使用该催化剂来聚合烯烃的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5006500A (en) * 1988-10-27 1991-04-09 Exxon Chemical Patents Inc. Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
JP2807571B2 (ja) * 1990-04-18 1998-10-08 三井化学株式会社 オレフィン重合用固体触媒およびオレフィンの重合方法
JP2812566B2 (ja) * 1990-08-08 1998-10-22 三井化学株式会社 オレフィン重合体の製造方法
JP3197314B2 (ja) * 1992-02-24 2001-08-13 三井化学株式会社 分子量分布の広いポリオレフィンの製造方法
DE69312306T2 (de) * 1992-10-02 1997-11-13 Dow Chemical Co Aufträger homogener komplexkatalysator für olefinpolymerisation
JPH06345808A (ja) * 1993-06-14 1994-12-20 Mitsui Toatsu Chem Inc オレフィン重合用固体触媒成分の製造方法およびこれを用いたポリオレフィンの製造方法
IT1273701B (it) * 1994-07-29 1997-07-09 Enichem Elastomers Derivati metallorganici del grupo iiia e procedimento per la loro preparazione
US5527929A (en) * 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
IL129929A0 (en) * 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
AU743376B2 (en) * 1998-06-12 2002-01-24 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
ATE355308T1 (de) * 1998-07-16 2006-03-15 Univation Tech Llc Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
WO2000015672A1 (en) * 1998-09-16 2000-03-23 The Dow Chemical Company Functionalized catalyst supports and supported catalyst systems
JP2001302716A (ja) * 2000-04-25 2001-10-31 Asahi Kasei Corp オレフィン重合体の製造方法
US6908972B2 (en) * 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1225101A (zh) * 1996-05-17 1999-08-04 陶氏化学公司 制备共聚物和含该共聚物的共混组合物的方法
CN1278272A (zh) * 1997-09-05 2000-12-27 英国石油化学品有限公司 聚合催化剂
CN1278833A (zh) * 1997-12-01 2001-01-03 旭化成工业株式会社 烯烃聚合催化剂和使用该催化剂来聚合烯烃的方法
CN1268519A (zh) * 1999-03-24 2000-10-04 索尔维聚烯烃欧洲-比利时公司 α－烯烃的聚合方法

Also Published As

Publication number Publication date
KR101118495B1 (ko) 2012-03-12
TW200415150A (en) 2004-08-16
CN1747973A (zh) 2006-03-15
ES2285220T3 (es) 2007-11-16
MY136117A (en) 2008-08-29
US20090043058A1 (en) 2009-02-12
KR20050085706A (ko) 2005-08-29
WO2004055061A8 (en) 2004-09-02
DE60313362T2 (de) 2007-08-16
AU2003288399A8 (en) 2004-07-09
DE60313362D1 (de) 2007-05-31
JP5362168B2 (ja) 2013-12-11
ATE360037T1 (de) 2007-05-15
US7811956B2 (en) 2010-10-12
JP2006509868A (ja) 2006-03-23
AU2003288399A1 (en) 2004-07-09
EP1578811A1 (en) 2005-09-28
WO2004055061A1 (en) 2004-07-01
EP1578811B1 (en) 2007-04-18
US20060247397A1 (en) 2006-11-02
TWI357907B (en) 2012-02-11

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