CN100343286C - 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法 - Google Patents

在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法 Download PDF

Info

Publication number
CN100343286C
CN100343286C CNB018158609A CN01815860A CN100343286C CN 100343286 C CN100343286 C CN 100343286C CN B018158609 A CNB018158609 A CN B018158609A CN 01815860 A CN01815860 A CN 01815860A CN 100343286 C CN100343286 C CN 100343286C
Authority
CN
China
Prior art keywords
poly
group
compound
alkyl
different
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB018158609A
Other languages
English (en)
Chinese (zh)
Other versions
CN1458937A (zh
Inventor
M·德斯塔拉克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Publication of CN1458937A publication Critical patent/CN1458937A/zh
Application granted granted Critical
Publication of CN100343286C publication Critical patent/CN100343286C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
CNB018158609A 2000-09-18 2001-09-11 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法 Expired - Fee Related CN100343286C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0011877A FR2814168B1 (fr) 2000-09-18 2000-09-18 Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure
FR00/11877 2000-09-18

Publications (2)

Publication Number Publication Date
CN1458937A CN1458937A (zh) 2003-11-26
CN100343286C true CN100343286C (zh) 2007-10-17

Family

ID=8854411

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB018158609A Expired - Fee Related CN100343286C (zh) 2000-09-18 2001-09-11 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法

Country Status (19)

Country Link
US (1) US6916884B2 (https=)
EP (1) EP1319027B1 (https=)
JP (1) JP2004509181A (https=)
KR (1) KR20030032031A (https=)
CN (1) CN100343286C (https=)
AT (1) ATE320451T1 (https=)
AU (2) AU9000901A (https=)
BR (1) BR0113941A (https=)
CA (1) CA2422593A1 (https=)
CZ (1) CZ2003751A3 (https=)
DE (1) DE60118007T2 (https=)
FR (1) FR2814168B1 (https=)
HU (1) HUP0303387A3 (https=)
MX (1) MXPA03002318A (https=)
NO (1) NO20031231L (https=)
PL (1) PL361423A1 (https=)
SK (1) SK3112003A3 (https=)
WO (1) WO2002022688A2 (https=)
ZA (1) ZA200301563B (https=)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2794463B1 (fr) 1999-06-04 2005-02-25 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
US20030158078A1 (en) * 2002-02-11 2003-08-21 Jeanne Chang Detergent composition comprising a block copolymer
FR2842814B1 (fr) 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
NL1025250C2 (nl) * 2004-01-15 2005-07-18 Univ Eindhoven Tech Multi- en bi-functionele dithiocarboxylaatverbindingen, monofunctionele alkoxycarbonyldithiocarbamaatverbinding, een werkwijze voor de bereiding van alkoxycarbonyldithiocarbamaatverbindingen evenals een werkwijze voor het door middel van radicaalpolymerisatie bereiden van multiblok-copolymeren.
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
ATE431368T1 (de) * 2006-08-17 2009-05-15 Rhodia Operations Blockcopolymere, verfahren zu deren herstellung und ihre verwendung in emulsionen
US8362190B2 (en) 2007-09-12 2013-01-29 Nissan Chemical Industries, Ltd. Method for producing hyperbranched polymer
WO2010101252A1 (ja) * 2009-03-06 2010-09-10 日産化学工業株式会社 ハイパーブランチポリマーの製造方法
US9127111B2 (en) * 2009-07-16 2015-09-08 Daikin Industries, Ltd. Process for production of fluorine-containing block copolymer
BR122022001868B1 (pt) 2015-12-10 2022-09-13 Adama Makhteshim Ltd. Composição de material agrícola, método de controle e prevenção de peste e de aperfeiçoamento do crescimento de planta, processo de preparo da composição de material agrícola e uso de um copolímero em bloco
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
EP3472212A4 (en) * 2016-06-15 2020-02-19 Rhodia Operations HIGH PERFORMANCE LATEX WITHOUT SURFACTANT FOR IMPROVED WATER RESISTANCE
WO2018049135A1 (en) * 2016-09-09 2018-03-15 Rhodia Operations Self-thickening latex for waterborne systems and related methods
AR114185A1 (es) 2018-01-23 2020-07-29 Adama Makhteshim Ltd Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol
WO2020173725A1 (en) 2019-02-28 2020-09-03 Rhodia Operations Compositions for high stabilization of emulsions
CN113557284A (zh) 2019-03-12 2021-10-26 罗地亚经营管理公司 稳定化的减摩剂乳液
FR3095447B1 (fr) 2019-04-26 2021-12-24 Michelin & Cie Bandage pour roue de véhicule transportable manuellement
CN110357992A (zh) * 2019-07-09 2019-10-22 复旦大学 一种超高分子量含氟聚合物的制备方法
FR3111636B1 (fr) 2020-06-18 2022-08-26 Michelin & Cie Composition élastomérique comprenant un composé phénolique et un composé de la famille des oses
FR3113906B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
FR3113905B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
JPWO2023210671A1 (https=) * 2022-04-26 2023-11-02

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5254198A (en) * 1988-06-20 1993-10-19 Kuraray Co., Ltd. Method of bonding a metal or alloy utilizing a polymerizable thiocarboxylic acid or a derivative thereof
WO1998058974A1 (fr) * 1997-06-23 1998-12-30 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
WO1999035178A1 (fr) * 1997-12-31 1999-07-15 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithioesters
CN1228787A (zh) * 1996-07-10 1999-09-15 纳幕尔杜邦公司 具有活性特征的聚合作用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE156600C (https=)
DE2756128A1 (de) * 1977-12-16 1979-06-21 Gerhard Kappes Klappstuhl
DE2756218C2 (de) * 1977-12-16 1983-03-10 Denki Kagaku Kogyo K.K., Tokyo Verfahren zur Herstellung eines bei Raumtemperatur mit einer Aminverbindung härtbaren in Toluol löslichen, flüssigen Copolymeren
FR2442863A1 (fr) * 1978-11-07 1980-06-27 Distugil Procede de preparation de polychloroprene modifie au soufre
DD156600A5 (de) * 1981-02-25 1982-09-08 Karin Wendler Verfahren zur herstellung fluessiger polymerer mit reaktiven endgruppen
JPH0676516B2 (ja) * 1985-11-28 1994-09-28 旭化成工業株式会社 タイヤトレツド用のゴム組成物
DE3608556A1 (de) * 1986-03-14 1987-10-01 Akzo Gmbh Telechele polymere
JPS6426672A (en) * 1987-04-01 1989-01-27 Yokohama Rubber Co Ltd Ultraviolet-curing type resin composition
JPH0753846B2 (ja) * 1988-06-20 1995-06-07 株式会社クラレ 含イオウ接着剤
JP2765137B2 (ja) * 1988-12-15 1998-06-11 ジェイエスアール株式会社 紙塗被組成物用の共重合体ラテックスおよび紙塗被組成物
JPH04198303A (ja) * 1990-11-27 1992-07-17 Sanyo Chem Ind Ltd 重合開始剤および重合方法
JPH0649131A (ja) * 1992-07-30 1994-02-22 Nippon Shokubai Co Ltd 高酸価(メタ)アクリル系重合体の製造方法
FR2755969B1 (fr) * 1996-11-20 1998-12-24 Atochem Elf Sa Polymerisation en presence d'un radical libre stable et d'un iniferter
CA2309279C (en) * 1997-12-18 2009-07-14 E.I. Du Pont De Nemours And Company Polymerization process with living characteristics and polymers made therefrom
CA2315914A1 (fr) * 1997-12-31 1999-07-15 Xavier Franck Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithiocarbamates
FR2802209B1 (fr) * 1999-12-10 2002-03-01 Rhodia Chimie Sa Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5254198A (en) * 1988-06-20 1993-10-19 Kuraray Co., Ltd. Method of bonding a metal or alloy utilizing a polymerizable thiocarboxylic acid or a derivative thereof
CN1228787A (zh) * 1996-07-10 1999-09-15 纳幕尔杜邦公司 具有活性特征的聚合作用
WO1998058974A1 (fr) * 1997-06-23 1998-12-30 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
WO1999035178A1 (fr) * 1997-12-31 1999-07-15 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithioesters

Also Published As

Publication number Publication date
MXPA03002318A (es) 2003-06-24
AU9000901A (en) 2002-03-26
KR20030032031A (ko) 2003-04-23
FR2814168B1 (fr) 2006-11-17
CN1458937A (zh) 2003-11-26
EP1319027A2 (fr) 2003-06-18
HUP0303387A2 (hu) 2004-01-28
PL361423A1 (en) 2004-10-04
WO2002022688A3 (fr) 2002-06-20
US6916884B2 (en) 2005-07-12
CZ2003751A3 (cs) 2003-06-18
EP1319027B1 (fr) 2006-03-15
WO2002022688A2 (fr) 2002-03-21
US20030187165A1 (en) 2003-10-02
DE60118007T2 (de) 2006-11-02
SK3112003A3 (en) 2003-09-11
DE60118007D1 (de) 2006-05-11
HUP0303387A3 (en) 2005-03-29
ATE320451T1 (de) 2006-04-15
FR2814168A1 (fr) 2002-03-22
CA2422593A1 (fr) 2002-03-21
BR0113941A (pt) 2003-07-22
JP2004509181A (ja) 2004-03-25
NO20031231D0 (no) 2003-03-17
AU2001290009B2 (en) 2005-05-12
ZA200301563B (en) 2004-03-01
NO20031231L (no) 2003-05-19

Similar Documents

Publication Publication Date Title
CN100343286C (zh) 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法
CN1240725C (zh) 接枝聚合物的合成
CN1121426C (zh) 受控(甲基)丙烯基、乙烯基、亚乙烯基和二烯单体的自由基聚合或共聚方法,以及获得的(共)聚合物
CN1735666A (zh) 两亲型嵌段共聚物作为在低能表面上的成膜水性组合物的粘合促进剂的用途
CN1082965C (zh) 烯丙基链转移剂
CN86106575A (zh) 氟代丙烯酸单体、由其衍生的聚合物及其用于不同基底的防水性和防油性的处理
CN1280324C (zh) 由受控自由基聚合方法合成混合硅氧烷和有机共聚物的方法
CN1073998C (zh) 高温聚合方法及其产物
CN86101422A (zh) 防污组合物及其应用
CN1550507A (zh) 使用3-烯丙氧基-2-羟基-1-丙磺酸盐作为表面活性剂聚合含氟单体
CN1276958C (zh) 可常温固化的聚合物
CN1010309B (zh) 含氟化丙烯酸单元的聚合物的制备方法
CN100347202C (zh) 活性自由基聚合物的制造方法和聚合物
CN1902244A (zh) 防水和防油的氟代丙烯酸酯
CN1241577A (zh) 在一种稳定的自由基存在下乳液聚合法
CN1820030A (zh) 活性自由基聚合物的制造方法以及聚合物
CN85109012A (zh) 主要用作为阻止原油中石蜡沉积的添加剂的接枝乙烯共聚物的制备方法以及含所说原油和添加剂的组合物
JP2005503452A5 (https=)
CN1576283A (zh) 含水多段乳液聚合物组合物
CN1147823A (zh) 从丙烯腈和烯属不饱和单体制备高腈多聚物的方法
CN1257058A (zh) 连续聚合法和由此得到的产物
CN1225485C (zh) 在稳定的硝酰自由基存在下氯乙烯的聚合或共聚
CN1576280A (zh) 一种烷氧基胺及其在制备单-或多-烷氧基胺中的应用
CN1780863A (zh) 丙烯酸共聚物组合物、制备丙烯酸共聚物的方法和包括该丙烯酸共聚物的氯乙烯树脂组合物
CN1642997A (zh) 用于除去聚合物链端的二硫代基的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20071017

Termination date: 20091012