CL2011001701A1 - Membrana polimerica semipermeable que comprende un polimero base no entrecruzado que tiene restos reactivos suspendidos, siendo modificado dicho polimero base por la formacion de una pelicula entrecruzada sobre una superficie del mismo; metodo para formar una membrana. - Google Patents

Membrana polimerica semipermeable que comprende un polimero base no entrecruzado que tiene restos reactivos suspendidos, siendo modificado dicho polimero base por la formacion de una pelicula entrecruzada sobre una superficie del mismo; metodo para formar una membrana.

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Publication number
CL2011001701A1
CL2011001701A1 CL2011001701A CL2011001701A CL2011001701A1 CL 2011001701 A1 CL2011001701 A1 CL 2011001701A1 CL 2011001701 A CL2011001701 A CL 2011001701A CL 2011001701 A CL2011001701 A CL 2011001701A CL 2011001701 A1 CL2011001701 A1 CL 2011001701A1
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CL
Chile
Prior art keywords
base polymer
film
membrane
polymer
oligomer
Prior art date
Application number
CL2011001701A
Other languages
English (en)
Inventor
Vera Ginzburg
Boris Ginzburg
Polina Perry Mordechai Lapido
Original Assignee
Ams Tech Int 2012 Ltd
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Publication date
Application filed by Ams Tech Int 2012 Ltd filed Critical Ams Tech Int 2012 Ltd
Publication of CL2011001701A1 publication Critical patent/CL2011001701A1/es

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/58Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/60Polyamines
    • B01D71/601Polyethylenimine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027Nanofiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/145Ultrafiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06Tubular membrane modules
    • B01D63/066Tubular membrane modules with a porous block having membrane coated passages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0006Organic membrane manufacture by chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0083Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0093Chemical modification
    • B01D67/00931Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0093Chemical modification
    • B01D67/00933Chemical modification by addition of a layer chemically bonded to the membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0095Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/125In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B01D69/1251In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/40Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/42Polymers of nitriles, e.g. polyacrylonitrile
    • B01D71/421Polyacrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/66Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68Polysulfones; Polyethersulfones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/30Cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/36Introduction of specific chemical groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/38Graft polymerization
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/40Details relating to membrane preparation in-situ membrane formation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/20Specific permeability or cut-off range
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/30Chemical resistance

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Transplantation (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

UNA MEMBRANA POLIMÉRICA SEMIPERMEABLE CON ALTA ESTABILIDAD EN AMBIENTES AGRESIVOS COMO MEDIOS ÁCIDOS, BÁSICOS, SOLVENTES ORGÁNICOS, ESPECIES OXIDANTES, TEMPERATURA Y PRESIÓN ELEVADAS, QUE COMPRENDE UN POLÍMERO BASE NO ENTRECRUZADO, CON RESTOS REACTIVOS SUSPENDIDOS Y QUE ES MODIFICADO POR LA FORMACIÓN DE UNA PELÍCULA ENTRECRUZADA SOBRE UNA SUPERFICIE DEL MISMO ESTA PELÍCULA ESTÁ SE FORMA POR UNA REACCIÓN DE ENTRECRUZAMIENTO DE LOS RESTOS REACTIVOS SUSPENDIDOS SOBRE DICHA SUPERFICIE CON UN OLIGÓMERO U OTRO POLÍMERO, Y EN DONDE UNA PORCIÓN DE LA PELÍCULA ENTRECRUZADA ESTÁ COVALENTEMENTE UNIDA A UNA CAPA DE NANOFILTRACIÓN, ÉSTA ÚLTIMA FORMADA A PARTIR DE (I) UN MONÓMERO COMPRENDIENDO DIAZINA O TRIAZINA DI-, TRI-, O TETRA-HALO SUSTITUIDO, UN OHGÓMERO O UN POLÍMERO; <strong>O </strong>(U) UNA AMINA MULTIFUNCIONAL CON UN PESO MOLECULAR ENTRE 400 A 750.000, SIEMPRE QUE UNO DEL MONÓMERO, OLIGÓMERO O POLÍMERO ANTES MENCIONADOS, SEA SUSTITUIDO SÓLO CON CLORO. ADICIONALMENTE, SE REIVINDICA UN MÉTODO PARA FORMAR DICHA MEMBRANA, QUE COMPRENDE LOS PASOS DE PROPORCIONAR UN POLÍMERO BASE NO ENTRECRUZADO CON RESTOS REACTIVOS SUSPENDIDOS; EFECTUAR UNA REACCIÓN DE ENTRECRUZAMIENTO ENTRE ESTOS RESTOS EN UNA SUPERFICIE DEL POLÍMERO BASE CON UN OLIGÓMERO U OTRO POLIMERO, PARA FORMAR UNA PELÍCULA ENTRECRUZADA; Y FORMAR UNA CAPA DE NANOFILTRACIÓN (NF) SOBRE UNA PORCIÓN DE LA PELÍCULA ENTRECRUZADA, EN DONDE ESTE ÚLTIMO PASO COMPRENDE ADEMÁS EL DE UNIR COVALENTEMENTE DICHA CAPA DE NANOFILTRACIÓN (NF) A UNA PORCIÓN DE LA PELÍCULA ENTRECRUZADA
CL2011001701A 2009-01-13 2011-07-13 Membrana polimerica semipermeable que comprende un polimero base no entrecruzado que tiene restos reactivos suspendidos, siendo modificado dicho polimero base por la formacion de una pelicula entrecruzada sobre una superficie del mismo; metodo para formar una membrana. CL2011001701A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US19396209P 2009-01-13 2009-01-13
US14445909P 2009-01-14 2009-01-14

Publications (1)

Publication Number Publication Date
CL2011001701A1 true CL2011001701A1 (es) 2012-03-16

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Application Number Title Priority Date Filing Date
CL2011001701A CL2011001701A1 (es) 2009-01-13 2011-07-13 Membrana polimerica semipermeable que comprende un polimero base no entrecruzado que tiene restos reactivos suspendidos, siendo modificado dicho polimero base por la formacion de una pelicula entrecruzada sobre una superficie del mismo; metodo para formar una membrana.
CL2014001427A CL2014001427A1 (es) 2009-01-13 2014-05-30 Membrana de nanofiltracion (nf) con matriz formada a partir de al menos un monomero comprendiendo diazina o triazina di- tri- o tetra halo sustituido, un oligomero o un polimero, y al menos una amina multifuncional (divisional de solicitud 1701-11)

Family Applications After (1)

Application Number Title Priority Date Filing Date
CL2014001427A CL2014001427A1 (es) 2009-01-13 2014-05-30 Membrana de nanofiltracion (nf) con matriz formada a partir de al menos un monomero comprendiendo diazina o triazina di- tri- o tetra halo sustituido, un oligomero o un polimero, y al menos una amina multifuncional (divisional de solicitud 1701-11)

Country Status (10)

Country Link
US (2) US9205383B2 (es)
EP (1) EP2387445B1 (es)
CN (2) CN105289305B (es)
AU (1) AU2016208306B2 (es)
CA (1) CA2752454C (es)
CL (2) CL2011001701A1 (es)
ES (1) ES2877072T3 (es)
IL (1) IL214042B (es)
SG (3) SG172975A1 (es)
WO (1) WO2010082194A2 (es)

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IL214042A0 (en) 2011-08-31
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US20120273421A1 (en) 2012-11-01
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US9205383B2 (en) 2015-12-08
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