CH631430A5 - Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester. - Google Patents

Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester. Download PDF

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Publication number
CH631430A5
CH631430A5 CH1032277A CH1032277A CH631430A5 CH 631430 A5 CH631430 A5 CH 631430A5 CH 1032277 A CH1032277 A CH 1032277A CH 1032277 A CH1032277 A CH 1032277A CH 631430 A5 CH631430 A5 CH 631430A5
Authority
CH
Switzerland
Prior art keywords
dimethyl
spp
halogen
substituted
meaning given
Prior art date
Application number
CH1032277A
Other languages
German (de)
English (en)
Inventor
Hans-Georg Heine
Willy Hartmann
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of CH631430A5 publication Critical patent/CH631430A5/de

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/31—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing rings other than six-membered aromatic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/76—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton with the aid of ketenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/693—Unsaturated compounds containing a keto groups being part of a ring containing halogen polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16—Unsaturated compounds
    • C07C61/40—Unsaturated compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C62/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C62/08—Saturated compounds containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C07C67/42—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of secondary alcohols or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/04—Systems containing only non-condensed rings with a four-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/50—Spiro compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CH1032277A 1976-08-26 1977-08-23 Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester. CH631430A5 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762638356 DE2638356A1 (de) 1976-08-26 1976-08-26 Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester

Publications (1)

Publication Number Publication Date
CH631430A5 true CH631430A5 (de) 1982-08-13

Family

ID=5986385

Family Applications (3)

Application Number Title Priority Date Filing Date
CH1032277A CH631430A5 (de) 1976-08-26 1977-08-23 Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester.
CH513581A CH631427A5 (de) 1976-08-26 1981-08-10 Verfahren zur herstellung von alpha-halogencyclobutanonen.
CH136782A CH634289A5 (de) 1976-08-26 1982-03-05 Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester.

Family Applications After (2)

Application Number Title Priority Date Filing Date
CH513581A CH631427A5 (de) 1976-08-26 1981-08-10 Verfahren zur herstellung von alpha-halogencyclobutanonen.
CH136782A CH634289A5 (de) 1976-08-26 1982-03-05 Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester.

Country Status (18)

Country Link
US (2) US4291176A (US06653308-20031125-C00199.png)
JP (1) JPS5328147A (US06653308-20031125-C00199.png)
AT (1) AT359473B (US06653308-20031125-C00199.png)
BE (1) BE858137A (US06653308-20031125-C00199.png)
BR (1) BR7705690A (US06653308-20031125-C00199.png)
CH (3) CH631430A5 (US06653308-20031125-C00199.png)
CS (1) CS193591B2 (US06653308-20031125-C00199.png)
DD (1) DD133228A5 (US06653308-20031125-C00199.png)
DE (1) DE2638356A1 (US06653308-20031125-C00199.png)
DK (1) DK377777A (US06653308-20031125-C00199.png)
ES (1) ES461872A1 (US06653308-20031125-C00199.png)
FR (4) FR2362820A1 (US06653308-20031125-C00199.png)
GB (3) GB1586989A (US06653308-20031125-C00199.png)
HU (2) HU176921B (US06653308-20031125-C00199.png)
IL (2) IL52801A (US06653308-20031125-C00199.png)
NL (1) NL7709405A (US06653308-20031125-C00199.png)
SU (1) SU688122A3 (US06653308-20031125-C00199.png)
ZA (1) ZA775146B (US06653308-20031125-C00199.png)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0113864A1 (en) * 1982-12-17 1984-07-25 Schering Corporation Cyclopropyl substituted polyenes, processes for their preparation and pharmaceutical compositions containing them

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2606635A1 (de) * 1976-02-19 1977-08-25 Bayer Ag Verfahren zur herstellung von 2,2-dimethyl-3-(2',2'-dichlorvinyl) -cyclopropan-1-carbonsaeure
FI780930A (fi) * 1977-03-31 1978-10-01 Ciba Geigy Ag Foerfarande foer framstaellning av 2-(2'2'2'-trihalogenetyl)-4-halogencyklobutan-1-oner de medelst foerfarandet framstaellda produkterna och deras anvaendning samt de foer deras framstaellning anvaenda mellanprodukterna
DE2740849A1 (de) * 1977-09-10 1979-03-22 Bayer Ag Verfahren zur herstellung von halogenvinylsubstituierten tetrahydrofuran-2-onen
EP0002207B1 (de) * 1977-11-24 1981-09-02 Ciba-Geigy Ag Dichlorvinylcyclobutanone, Verfahren zu deren Herstellung und ihre Verwendung als Zwischenprodukte für die Herstellung von Schädlingsbekämpfungsmitteln
US4235927A (en) 1978-01-20 1980-11-25 Fmc Corporation Insecticidal benzylfurylmethyl perhaloalkylvinylcyclopropanecarboxylates
IN150399B (US06653308-20031125-C00199.png) 1978-01-20 1982-09-25 Fmc Corp
US4243677A (en) 1978-01-20 1981-01-06 Fmc Corporation Insecticidal perhaloalkylvinylcyclopropanecarboxylates
US4238505A (en) 1978-01-20 1980-12-09 Fmc Corporation Insecticidal biphenylmethyl perhaloalkylvinylcyclopropanecarboxylates
BG48333A3 (en) * 1978-02-28 1991-01-15 Montedison Spa Method for preparing of 2, 2- dimethyl cyclopropane carbonic acid derivatives
US4328237A (en) 1978-02-28 1982-05-04 Montedison S.P.A. Pyrethroids
US4258202A (en) 1978-02-28 1981-03-24 Montedison S.P.A. Cyclopropanecarboxylic acids and esters
DE2842601A1 (de) * 1978-09-29 1980-04-17 Ciba Geigy Ag Verfahren zur herstellung von 2-(2',2',2'-tribromaethyl)-4-horcyclobutan-1-onen
US4341796A (en) 1979-06-25 1982-07-27 Fmc Corporation Control of acarids with biphenylmethyl perhaloalkylvinylcyclopropanecarboxylates
IT1209146B (it) * 1979-11-26 1989-07-10 Montedison Spa Piretroidi.
DE3070182D1 (en) * 1979-11-26 1985-03-28 Montedison Spa Pyrethroids and their preparation, their pesticidal composition; intermediates and their preparation
OA06730A (fr) * 1980-01-25 1982-06-30 Roussel Uclaf Dérivés 3-(buta-1',3'-diényl) substitué de l'acide cyclopropane-1-carboxylique, leur application contre les parasites des végétaux et des animaux à sang chaud, les compositions correspondantes ainsi que les compositions parfumantes les renfermant, leur pré
DE3042218A1 (de) * 1980-11-08 1982-06-09 Bayer Ag, 5090 Leverkusen 2,2-dimethylcyclobutanone, und verfahren zu ihrer herstellung
IT1135265B (it) * 1981-02-02 1986-08-20 Montedison Spa Processo per la preparazione di intermedi per piretroidi
DE3220730A1 (de) * 1982-06-02 1983-12-08 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von 2,2-dimethyl-3-aryl-cyclopropan-carbonsaeuren (carbonsaeureestern), neue zwischenprodukte hierfuer und verfahren zu deren herstellung
FR2534252A1 (fr) * 1982-10-12 1984-04-13 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique substitues en 3 par une chaine vinylique elle-meme substituee, leur procede de preparation et leur application comme pesticides
US4691052A (en) * 1983-12-12 1987-09-01 S.C. Johnson & Son, Inc. Process for the preparation of pyrethroid acids
US6677487B2 (en) 2001-08-30 2004-01-13 Pharmacia Corporation α-haloenamine reagents
US20030105279A1 (en) * 2001-08-30 2003-06-05 Pharmacia Corporation Aromatic and heteroaromatic acid halides for synthesizing polyamides
JP4724027B2 (ja) * 2006-03-23 2011-07-13 因幡電機産業株式会社 空調用縦配管の固定支持装置
CN102822143B (zh) * 2010-03-31 2015-04-22 住友化学株式会社 作为杀虫剂的拟除虫菊酯型酯
CN113248353B (zh) * 2021-07-01 2022-02-25 山东国邦药业有限公司 一种2,4-二氯-5-氟苯乙酮的制备方法

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DE1199259B (de) * 1963-04-24 1965-08-26 Hoechst Ag Verfahren zur Herstellung von 2, 2-Dimethyl-cyclobutanon bzw. dessen Alkyl- und Cyclo-alkylsubstitutionsprodukten
US3360564A (en) 1964-01-13 1967-12-26 Eastman Kodak Co 2, 2-dialkylcyclobutanone and 2, 2-dialkylcyclobutanol compounds and processes for their preparation
US3408398A (en) * 1964-03-17 1968-10-29 Eastman Kodak Co 2-cyclobuten-1-one compounds and process for their preparation
FR1414457A (fr) * 1964-11-19 1965-10-15 Eastman Kodak Co Nouveaux composés des 2, 2-dialcoyl-3-(1-alcényl) cyclobutanes, procédé pour leur préparation et leurs applications
US3390185A (en) * 1964-12-23 1968-06-25 Eastman Kodak Co Alkoxyvinylcyclobutanone compounds and process for their preparation
US3400101A (en) * 1966-04-21 1968-09-03 Eastman Kodak Co Alkoxyalkylidenecyclobutanones
GB1446304A (en) * 1972-05-25 1976-08-18 Nat Res Dev 3-substituted cyclopropane carboxylic acids and derivatives thereof
GB1437832A (en) * 1973-04-16 1976-06-03 Shell Int Research Halocyclobutanones
HU176610B (en) * 1974-09-04 1981-03-28 Shell Int Research Process for producing cyclobutanones
IN142702B (US06653308-20031125-C00199.png) * 1974-09-10 1977-08-20 Sagami Chem Res
GB1498931A (en) * 1975-02-12 1978-01-25 Sumitomo Chemical Co Tetrahalopentyl ketone derivatives processes for producing them and their conversion to beta-dihaloethenylcyclopropane derivatives
CA1051454A (en) * 1975-05-21 1979-03-27 Marinus J. Van Den Brink Process for the preparation of cyclobutanones
GB1571581A (en) * 1976-01-06 1980-07-16 Shell Int Research Process for the preparation of 2-halocyclobutanones and cyclopropane carbolic acids derived therefrom
FI780930A (fi) * 1977-03-31 1978-10-01 Ciba Geigy Ag Foerfarande foer framstaellning av 2-(2'2'2'-trihalogenetyl)-4-halogencyklobutan-1-oner de medelst foerfarandet framstaellda produkterna och deras anvaendning samt de foer deras framstaellning anvaenda mellanprodukterna
US4242278A (en) * 1977-03-31 1980-12-30 Ciba-Geigy Corporation Process for the preparation of 2-(2',2',2'-trihalogenoethyl)-4-halogenocyclobutan-1-ones

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0113864A1 (en) * 1982-12-17 1984-07-25 Schering Corporation Cyclopropyl substituted polyenes, processes for their preparation and pharmaceutical compositions containing them

Also Published As

Publication number Publication date
IL52801A (en) 1982-03-31
ZA775146B (en) 1978-07-26
IL59583A0 (en) 1980-06-30
FR2362820A1 (fr) 1978-03-24
BR7705690A (pt) 1978-06-06
DD133228A5 (de) 1978-12-20
FR2362817B1 (US06653308-20031125-C00199.png) 1983-12-30
DE2638356A1 (de) 1978-03-02
US4291176A (en) 1981-09-22
GB1586988A (en) 1981-03-25
GB1586989A (en) 1981-03-25
SU688122A3 (ru) 1979-09-25
BE858137A (fr) 1978-02-27
CH631427A5 (de) 1982-08-13
IL52801A0 (en) 1977-10-31
CH634289A5 (de) 1983-01-31
HU176921B (hu) 1981-06-28
JPS5328147A (en) 1978-03-16
AT359473B (de) 1980-11-10
ES461872A1 (es) 1978-12-01
FR2362812A1 (fr) 1978-03-24
DK377777A (da) 1978-02-27
FR2362811A1 (fr) 1978-03-24
ATA619177A (de) 1980-04-15
FR2362812B1 (US06653308-20031125-C00199.png) 1980-11-07
NL7709405A (nl) 1978-02-28
HU182666B (en) 1984-02-28
US4529813A (en) 1985-07-16
FR2362820B1 (US06653308-20031125-C00199.png) 1983-12-30
FR2362817A1 (fr) 1978-03-24
CS193591B2 (en) 1979-10-31
FR2362811B1 (US06653308-20031125-C00199.png) 1980-11-07
GB1586990A (en) 1981-03-25

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