FR2362820A1 - Procede de preparation d'esters d'acide cyclopropane-carboxylique a substituant vinylique - Google Patents

Procede de preparation d'esters d'acide cyclopropane-carboxylique a substituant vinylique

Info

Publication number
FR2362820A1
FR2362820A1 FR7725960A FR7725960A FR2362820A1 FR 2362820 A1 FR2362820 A1 FR 2362820A1 FR 7725960 A FR7725960 A FR 7725960A FR 7725960 A FR7725960 A FR 7725960A FR 2362820 A1 FR2362820 A1 FR 2362820A1
Authority
FR
France
Prior art keywords
preparation
carboxylic acid
acid esters
cyclopropane
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7725960A
Other languages
English (en)
Other versions
FR2362820B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of FR2362820A1 publication Critical patent/FR2362820A1/fr
Application granted granted Critical
Publication of FR2362820B1 publication Critical patent/FR2362820B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/31—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing rings other than six-membered aromatic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/76—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton with the aid of ketenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/693—Unsaturated compounds containing a keto groups being part of a ring containing halogen polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16—Unsaturated compounds
    • C07C61/40—Unsaturated compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C62/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C62/08—Saturated compounds containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • C07C67/42—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of secondary alcohols or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/04—Systems containing only non-condensed rings with a four-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/50—Spiro compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

L'invention concerne les esters d'acide cyclopropane-carboxylique à substituant vinyle, de formule génerale I et de leurs procédés de préparation
FR7725960A 1976-08-26 1977-08-25 Procede de preparation d'esters d'acide cyclopropane-carboxylique a substituant vinylique Granted FR2362820A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762638356 DE2638356A1 (de) 1976-08-26 1976-08-26 Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester

Publications (2)

Publication Number Publication Date
FR2362820A1 true FR2362820A1 (fr) 1978-03-24
FR2362820B1 FR2362820B1 (fr) 1983-12-30

Family

ID=5986385

Family Applications (4)

Application Number Title Priority Date Filing Date
FR7725960A Granted FR2362820A1 (fr) 1976-08-26 1977-08-25 Procede de preparation d'esters d'acide cyclopropane-carboxylique a substituant vinylique
FR7739859A Granted FR2362811A1 (fr) 1976-08-26 1977-12-30 A-halogenocyclobutanones substituees et leur procede de preparation
FR7739861A Granted FR2362817A1 (fr) 1976-08-26 1977-12-30 Acides cyclopropane-carboxyliques et leur procede de preparation
FR7739860A Granted FR2362812A1 (fr) 1976-08-26 1977-12-30 Cyclobutanones substituees et leur procede de preparation

Family Applications After (3)

Application Number Title Priority Date Filing Date
FR7739859A Granted FR2362811A1 (fr) 1976-08-26 1977-12-30 A-halogenocyclobutanones substituees et leur procede de preparation
FR7739861A Granted FR2362817A1 (fr) 1976-08-26 1977-12-30 Acides cyclopropane-carboxyliques et leur procede de preparation
FR7739860A Granted FR2362812A1 (fr) 1976-08-26 1977-12-30 Cyclobutanones substituees et leur procede de preparation

Country Status (18)

Country Link
US (2) US4291176A (fr)
JP (1) JPS5328147A (fr)
AT (1) AT359473B (fr)
BE (1) BE858137A (fr)
BR (1) BR7705690A (fr)
CH (3) CH631430A5 (fr)
CS (1) CS193591B2 (fr)
DD (1) DD133228A5 (fr)
DE (1) DE2638356A1 (fr)
DK (1) DK377777A (fr)
ES (1) ES461872A1 (fr)
FR (4) FR2362820A1 (fr)
GB (3) GB1586989A (fr)
HU (2) HU182666B (fr)
IL (2) IL52801A (fr)
NL (1) NL7709405A (fr)
SU (1) SU688122A3 (fr)
ZA (1) ZA775146B (fr)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2606635A1 (de) * 1976-02-19 1977-08-25 Bayer Ag Verfahren zur herstellung von 2,2-dimethyl-3-(2',2'-dichlorvinyl) -cyclopropan-1-carbonsaeure
DE2813337A1 (de) * 1977-03-31 1978-10-05 Ciba Geigy Ag Verfahren zur herstellung von 2-(2', 2',2'-trihalogenaethyl)-4-halogencyclobutan1-onen
DE2740849A1 (de) * 1977-09-10 1979-03-22 Bayer Ag Verfahren zur herstellung von halogenvinylsubstituierten tetrahydrofuran-2-onen
EP0002207B1 (fr) * 1977-11-24 1981-09-02 Ciba-Geigy Ag Dichlorovinylcyclobutanones, leur procédé de préparation et leur utilisation comme intermédiaires dans la préparation de pesticides
IN150399B (fr) 1978-01-20 1982-09-25 Fmc Corp
US4238505A (en) 1978-01-20 1980-12-09 Fmc Corporation Insecticidal biphenylmethyl perhaloalkylvinylcyclopropanecarboxylates
US4235927A (en) 1978-01-20 1980-11-25 Fmc Corporation Insecticidal benzylfurylmethyl perhaloalkylvinylcyclopropanecarboxylates
US4243677A (en) 1978-01-20 1981-01-06 Fmc Corporation Insecticidal perhaloalkylvinylcyclopropanecarboxylates
US4258202A (en) 1978-02-28 1981-03-24 Montedison S.P.A. Cyclopropanecarboxylic acids and esters
BG48921A3 (en) * 1978-02-28 1991-06-14 Montedison Spa Method for destroying of insects
US4328237A (en) 1978-02-28 1982-05-04 Montedison S.P.A. Pyrethroids
DE2842601A1 (de) * 1978-09-29 1980-04-17 Ciba Geigy Ag Verfahren zur herstellung von 2-(2',2',2'-tribromaethyl)-4-horcyclobutan-1-onen
US4341796A (en) 1979-06-25 1982-07-27 Fmc Corporation Control of acarids with biphenylmethyl perhaloalkylvinylcyclopropanecarboxylates
IT1209146B (it) * 1979-11-26 1989-07-10 Montedison Spa Piretroidi.
EP0031041B1 (fr) * 1979-11-26 1985-02-13 Montedison S.p.A. Dérivés pyréthroides et leur préparation, leur composition pesticide; intermédiaires et leur préparation
OA06730A (fr) * 1980-01-25 1982-06-30 Roussel Uclaf Dérivés 3-(buta-1',3'-diényl) substitué de l'acide cyclopropane-1-carboxylique, leur application contre les parasites des végétaux et des animaux à sang chaud, les compositions correspondantes ainsi que les compositions parfumantes les renfermant, leur pré
DE3042218A1 (de) * 1980-11-08 1982-06-09 Bayer Ag, 5090 Leverkusen 2,2-dimethylcyclobutanone, und verfahren zu ihrer herstellung
IT1135265B (it) * 1981-02-02 1986-08-20 Montedison Spa Processo per la preparazione di intermedi per piretroidi
DE3220730A1 (de) * 1982-06-02 1983-12-08 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von 2,2-dimethyl-3-aryl-cyclopropan-carbonsaeuren (carbonsaeureestern), neue zwischenprodukte hierfuer und verfahren zu deren herstellung
FR2534252A1 (fr) * 1982-10-12 1984-04-13 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique substitues en 3 par une chaine vinylique elle-meme substituee, leur procede de preparation et leur application comme pesticides
US4431669A (en) * 1982-12-17 1984-02-14 Schering Corporation Cyclopropyl substituted polyenes
US4691052A (en) * 1983-12-12 1987-09-01 S.C. Johnson & Son, Inc. Process for the preparation of pyrethroid acids
US6677487B2 (en) 2001-08-30 2004-01-13 Pharmacia Corporation α-haloenamine reagents
US20030105279A1 (en) * 2001-08-30 2003-06-05 Pharmacia Corporation Aromatic and heteroaromatic acid halides for synthesizing polyamides
JP4724027B2 (ja) * 2006-03-23 2011-07-13 因幡電機産業株式会社 空調用縦配管の固定支持装置
CN102822143B (zh) * 2010-03-31 2015-04-22 住友化学株式会社 作为杀虫剂的拟除虫菊酯型酯
CN113248353B (zh) * 2021-07-01 2022-02-25 山东国邦药业有限公司 一种2,4-二氯-5-氟苯乙酮的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2225407A1 (fr) * 1973-04-16 1974-11-08 Shell Int Research
DE2539048A1 (de) * 1974-09-04 1976-03-25 Shell Int Research Verfahren zur herstellung von derivaten des cyclobutans
NL7601063A (nl) * 1975-02-12 1976-08-16 Sumitomo Chemical Co Werkwijze voor het bereiden van (beta)-dihalogeen- ethenylcyclopropaanderivaten.
FR2385672A1 (fr) * 1977-03-31 1978-10-27 Ciba Geigy Ag Procede de preparation d'halogeno-cyclobutanones

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1199259B (de) * 1963-04-24 1965-08-26 Hoechst Ag Verfahren zur Herstellung von 2, 2-Dimethyl-cyclobutanon bzw. dessen Alkyl- und Cyclo-alkylsubstitutionsprodukten
US3360564A (en) 1964-01-13 1967-12-26 Eastman Kodak Co 2, 2-dialkylcyclobutanone and 2, 2-dialkylcyclobutanol compounds and processes for their preparation
US3408398A (en) * 1964-03-17 1968-10-29 Eastman Kodak Co 2-cyclobuten-1-one compounds and process for their preparation
FR1414457A (fr) * 1964-11-19 1965-10-15 Eastman Kodak Co Nouveaux composés des 2, 2-dialcoyl-3-(1-alcényl) cyclobutanes, procédé pour leur préparation et leurs applications
US3390185A (en) * 1964-12-23 1968-06-25 Eastman Kodak Co Alkoxyvinylcyclobutanone compounds and process for their preparation
US3400101A (en) * 1966-04-21 1968-09-03 Eastman Kodak Co Alkoxyalkylidenecyclobutanones
GB1446304A (en) * 1972-05-25 1976-08-18 Nat Res Dev 3-substituted cyclopropane carboxylic acids and derivatives thereof
IN142702B (fr) * 1974-09-10 1977-08-20 Sagami Chem Res
CA1051454A (fr) * 1975-05-21 1979-03-27 Marinus J. Van Den Brink Methode de preparation de cyclobutanones
GB1571581A (en) * 1976-01-06 1980-07-16 Shell Int Research Process for the preparation of 2-halocyclobutanones and cyclopropane carbolic acids derived therefrom
US4242278A (en) * 1977-03-31 1980-12-30 Ciba-Geigy Corporation Process for the preparation of 2-(2',2',2'-trihalogenoethyl)-4-halogenocyclobutan-1-ones

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2225407A1 (fr) * 1973-04-16 1974-11-08 Shell Int Research
DE2539048A1 (de) * 1974-09-04 1976-03-25 Shell Int Research Verfahren zur herstellung von derivaten des cyclobutans
FR2299302A1 (fr) * 1974-09-04 1976-08-27 Shell Int Research Procede pour la preparation de cyclobutanones et de cyclobutenones et composes nouveaux obtenus
NL7601063A (nl) * 1975-02-12 1976-08-16 Sumitomo Chemical Co Werkwijze voor het bereiden van (beta)-dihalogeen- ethenylcyclopropaanderivaten.
FR2300755A1 (fr) * 1975-02-12 1976-09-10 Sumitomo Chemical Co Procede de preparation de derives de beta-dihalogenoethenylcyclopropane
FR2385672A1 (fr) * 1977-03-31 1978-10-27 Ciba Geigy Ag Procede de preparation d'halogeno-cyclobutanones

Also Published As

Publication number Publication date
ZA775146B (en) 1978-07-26
DD133228A5 (de) 1978-12-20
HU182666B (en) 1984-02-28
IL52801A (en) 1982-03-31
NL7709405A (nl) 1978-02-28
GB1586990A (en) 1981-03-25
BR7705690A (pt) 1978-06-06
ATA619177A (de) 1980-04-15
FR2362811A1 (fr) 1978-03-24
GB1586988A (en) 1981-03-25
CH634289A5 (de) 1983-01-31
IL59583A0 (en) 1980-06-30
IL52801A0 (en) 1977-10-31
FR2362812B1 (fr) 1980-11-07
FR2362817B1 (fr) 1983-12-30
ES461872A1 (es) 1978-12-01
US4529813A (en) 1985-07-16
US4291176A (en) 1981-09-22
CH631430A5 (de) 1982-08-13
JPS5328147A (en) 1978-03-16
CH631427A5 (de) 1982-08-13
DK377777A (da) 1978-02-27
SU688122A3 (ru) 1979-09-25
FR2362820B1 (fr) 1983-12-30
GB1586989A (en) 1981-03-25
AT359473B (de) 1980-11-10
FR2362817A1 (fr) 1978-03-24
CS193591B2 (en) 1979-10-31
HU176921B (hu) 1981-06-28
FR2362811B1 (fr) 1980-11-07
DE2638356A1 (de) 1978-03-02
BE858137A (fr) 1978-02-27
FR2362812A1 (fr) 1978-03-24

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