CH618714A5 - Composition based on halogen-containing synthetic resins containing tin esters as stabilisers - Google Patents
Composition based on halogen-containing synthetic resins containing tin esters as stabilisers Download PDFInfo
- Publication number
- CH618714A5 CH618714A5 CH68775A CH68775A CH618714A5 CH 618714 A5 CH618714 A5 CH 618714A5 CH 68775 A CH68775 A CH 68775A CH 68775 A CH68775 A CH 68775A CH 618714 A5 CH618714 A5 CH 618714A5
- Authority
- CH
- Switzerland
- Prior art keywords
- weight
- compound
- amount
- formula
- stabilizer
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 54
- 239000003381 stabilizer Substances 0.000 title claims description 39
- 229910052736 halogen Inorganic materials 0.000 title claims description 8
- 150000002367 halogens Chemical class 0.000 title claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims description 5
- 229920003002 synthetic resin Polymers 0.000 title 1
- 239000000057 synthetic resin Substances 0.000 title 1
- -1 vinyl halide Chemical class 0.000 claims description 48
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 14
- IRFPIPNMASANJY-UHFFFAOYSA-L dimethyltin(2+);2-(6-methylheptoxy)-2-oxoethanethiolate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](C)(C)SCC(=O)OCCCCCC(C)C IRFPIPNMASANJY-UHFFFAOYSA-L 0.000 claims description 13
- NIXLJQORAUOBAU-UHFFFAOYSA-K 6-methylheptyl 2-[methyl-bis[[2-(6-methylheptoxy)-2-oxoethyl]sulfanyl]stannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](C)(SCC(=O)OCCCCCC(C)C)SCC(=O)OCCCCCC(C)C NIXLJQORAUOBAU-UHFFFAOYSA-K 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 241000700159 Rattus Species 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000004709 Chlorinated polyethylene Substances 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 claims 1
- 238000011105 stabilization Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- DZXKSFDSPBRJPS-UHFFFAOYSA-N tin(2+);sulfide Chemical compound [S-2].[Sn+2] DZXKSFDSPBRJPS-UHFFFAOYSA-N 0.000 claims 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 46
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical class C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 41
- 239000007983 Tris buffer Substances 0.000 description 35
- IUNVCWLKOOCPIT-UHFFFAOYSA-N 6-methylheptylsulfanyl 2-hydroxyacetate Chemical compound CC(C)CCCCCSOC(=O)CO IUNVCWLKOOCPIT-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- LYRCQNDYYRPFMF-UHFFFAOYSA-N trimethyltin Chemical compound C[Sn](C)C LYRCQNDYYRPFMF-UHFFFAOYSA-N 0.000 description 10
- 229920000915 polyvinyl chloride Polymers 0.000 description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 8
- 238000001149 thermolysis Methods 0.000 description 7
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 5
- 230000001976 improved effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920006385 Geon Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical class CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical compound CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- JLLRJAYEZDANQR-UHFFFAOYSA-N 2-cyclopentyl-2-sulfanylacetic acid Chemical compound OC(=O)C(S)C1CCCC1 JLLRJAYEZDANQR-UHFFFAOYSA-N 0.000 description 2
- QYIGFZOHYGYBLX-UHFFFAOYSA-N 2-phenyl-2-sulfanylacetic acid Chemical compound OC(=O)C(S)C1=CC=CC=C1 QYIGFZOHYGYBLX-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- REFZTFPICLNNPM-UHFFFAOYSA-N 2-sulfanyldodecanoic acid Chemical compound CCCCCCCCCCC(S)C(O)=O REFZTFPICLNNPM-UHFFFAOYSA-N 0.000 description 2
- HGIOOMCLOWLFTJ-UHFFFAOYSA-N 3-phenyl-2-sulfanylpropanoic acid Chemical compound OC(=O)C(S)CC1=CC=CC=C1 HGIOOMCLOWLFTJ-UHFFFAOYSA-N 0.000 description 2
- HLRRSFOQAFMOTJ-UHFFFAOYSA-L 6-methylheptyl 2-[[2-(6-methylheptoxy)-2-oxoethyl]sulfanyl-dioctylstannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCCCCCC)(CCCCCCCC)SCC(=O)OCCCCCC(C)C HLRRSFOQAFMOTJ-UHFFFAOYSA-L 0.000 description 2
- VNPRJHMMOKDEDZ-UHFFFAOYSA-L 6-methylheptyl 2-[dibutyl-[2-(6-methylheptoxy)-2-oxoethyl]sulfanylstannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCC)(CCCC)SCC(=O)OCCCCCC(C)C VNPRJHMMOKDEDZ-UHFFFAOYSA-L 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- SKGVGRLWZVRZDC-UHFFFAOYSA-N butyl 2-sulfanylacetate Chemical compound CCCCOC(=O)CS SKGVGRLWZVRZDC-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- HXQIZSOBKJTOLW-UHFFFAOYSA-N prop-2-enyl 2-sulfanylacetate Chemical compound SCC(=O)OCC=C HXQIZSOBKJTOLW-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229940071127 thioglycolate Drugs 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- CMCOFAYLDYIEBR-UHFFFAOYSA-L 2-[carboxymethylsulfanyl(dioctyl)stannyl]sulfanylacetic acid Chemical compound [O-]C(=O)CS.[O-]C(=O)CS.CCCCCCCC[Sn+2]CCCCCCCC CMCOFAYLDYIEBR-UHFFFAOYSA-L 0.000 description 1
- IDZOFXZSEPNDPJ-UHFFFAOYSA-K 2-methyl-3-sulfanylpropanoate methyltin(3+) Chemical compound [Sn+3]C.SCC(C)C([O-])=O.SCC(C)C([O-])=O.SCC(C)C([O-])=O IDZOFXZSEPNDPJ-UHFFFAOYSA-K 0.000 description 1
- KIEZUZFDXQJEBB-UHFFFAOYSA-K 2-methyl-4-sulfanylbutanoate methyltin(3+) Chemical compound [Sn+3]C.[O-]C(=O)C(C)CCS.[O-]C(=O)C(C)CCS.[O-]C(=O)C(C)CCS KIEZUZFDXQJEBB-UHFFFAOYSA-K 0.000 description 1
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 1
- ZRWNRAJCPNLYAK-UHFFFAOYSA-N 4-bromobenzamide Chemical compound NC(=O)C1=CC=C(Br)C=C1 ZRWNRAJCPNLYAK-UHFFFAOYSA-N 0.000 description 1
- BEFRKDFWQCSRJO-UHFFFAOYSA-K 6-methylheptyl 2-[butyl-bis[[2-(6-methylheptoxy)-2-oxoethyl]sulfanyl]stannyl]sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS[Sn](CCCC)(SCC(=O)OCCCCCC(C)C)SCC(=O)OCCCCCC(C)C BEFRKDFWQCSRJO-UHFFFAOYSA-K 0.000 description 1
- ORDRGXFSRBRQQG-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)C(C)S ORDRGXFSRBRQQG-UHFFFAOYSA-N 0.000 description 1
- KORGTBPVXBSXAP-UHFFFAOYSA-L 6-methylheptyl 3-[dimethyl-[3-(6-methylheptoxy)-3-oxopropyl]sulfanylstannyl]sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)CCS[Sn](C)(C)SCCC(=O)OCCCCCC(C)C KORGTBPVXBSXAP-UHFFFAOYSA-L 0.000 description 1
- QMZKXDNERSNNCQ-UHFFFAOYSA-N 6-methylheptyl 4-sulfanylbutanoate Chemical compound CC(C)CCCCCOC(=O)CCCS QMZKXDNERSNNCQ-UHFFFAOYSA-N 0.000 description 1
- UPUQMZPQGQLBPC-UHFFFAOYSA-K 8-methyl-2-(6-methylheptyl)-2-(6-methylheptylsulfanyl)nonanoate methyltin(3+) Chemical compound [Sn+3]C.CC(C)CCCCCSC(CCCCCC(C)C)(CCCCCC(C)C)C([O-])=O.CC(C)CCCCCSC(CCCCCC(C)C)(CCCCCC(C)C)C([O-])=O.CC(C)CCCCCSC(CCCCCC(C)C)(CCCCCC(C)C)C([O-])=O UPUQMZPQGQLBPC-UHFFFAOYSA-K 0.000 description 1
- UIKHSWLUBHYVLH-UHFFFAOYSA-K 8-methyl-2-sulfanylnonanoate octyltin(3+) Chemical compound CCCCCCCC[Sn+3].CC(C)CCCCCC(S)C([O-])=O.CC(C)CCCCCC(S)C([O-])=O.CC(C)CCCCCC(S)C([O-])=O UIKHSWLUBHYVLH-UHFFFAOYSA-K 0.000 description 1
- XHMPRTGGXOYMCK-UHFFFAOYSA-N 8-methyl-2-sulfanylnonanoic acid Chemical class CC(C)CCCCCC(S)C(O)=O XHMPRTGGXOYMCK-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- XJNRHFFRCKBEII-UHFFFAOYSA-L C(CCCCCCC(C)C)C(C(=O)[O-])S.C(CCCCCCC(C)C)C(C(=O)[O-])S.C[Sn+2]C Chemical compound C(CCCCCCC(C)C)C(C(=O)[O-])S.C(CCCCCCC(C)C)C(C(=O)[O-])S.C[Sn+2]C XJNRHFFRCKBEII-UHFFFAOYSA-L 0.000 description 1
- NWUDMXCYKQGPSL-UHFFFAOYSA-L C[Sn+2]C.[O-]C(=O)C(C)CCS.[O-]C(=O)C(C)CCS Chemical compound C[Sn+2]C.[O-]C(=O)C(C)CCS.[O-]C(=O)C(C)CCS NWUDMXCYKQGPSL-UHFFFAOYSA-L 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- OEUHFELZLBHJME-UHFFFAOYSA-K [Sn+3]C.CC(C)CCCCCC(CS)C([O-])=O.CC(C)CCCCCC(CS)C([O-])=O.CC(C)CCCCCC(CS)C([O-])=O Chemical compound [Sn+3]C.CC(C)CCCCCC(CS)C([O-])=O.CC(C)CCCCCC(CS)C([O-])=O.CC(C)CCCCCC(CS)C([O-])=O OEUHFELZLBHJME-UHFFFAOYSA-K 0.000 description 1
- KGSDETDNNVQBKU-UHFFFAOYSA-K [Sn+3]C.CCCCC(CC)CC(S)C([O-])=O.CCCCC(CC)CC(S)C([O-])=O.CCCCC(CC)CC(S)C([O-])=O Chemical compound [Sn+3]C.CCCCC(CC)CC(S)C([O-])=O.CCCCC(CC)CC(S)C([O-])=O.CCCCC(CC)CC(S)C([O-])=O KGSDETDNNVQBKU-UHFFFAOYSA-K 0.000 description 1
- NCHPANLKGNXFRX-UHFFFAOYSA-K [Sn+3]C.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O Chemical compound [Sn+3]C.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O NCHPANLKGNXFRX-UHFFFAOYSA-K 0.000 description 1
- JOIPELSUFGRPDR-UHFFFAOYSA-K [di(dodecanoyloxy)-methylstannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](C)(OC(=O)CCCCCCCCCCC)OC(=O)CCCCCCCCCCC JOIPELSUFGRPDR-UHFFFAOYSA-K 0.000 description 1
- QASXJOGGAHCHBO-UHFFFAOYSA-L [dimethyl(2-sulfanylpropanoyloxy)stannyl] 2-sulfanylpropanoate Chemical compound C[Sn+2]C.CC(S)C([O-])=O.CC(S)C([O-])=O QASXJOGGAHCHBO-UHFFFAOYSA-L 0.000 description 1
- JPLYYEIOHUCWPI-UHFFFAOYSA-L [dimethyl-(2-methyl-3-sulfanylpropanoyl)oxystannyl] 2-methyl-3-sulfanylpropanoate Chemical compound C[Sn+2]C.SCC(C)C([O-])=O.SCC(C)C([O-])=O JPLYYEIOHUCWPI-UHFFFAOYSA-L 0.000 description 1
- OXDSRJYUPSCKIX-UHFFFAOYSA-L [dimethyl-[2-(sulfanylmethyl)decanoyloxy]stannyl] 2-(sulfanylmethyl)decanoate Chemical compound C[Sn+2]C.CCCCCCCCC(CS)C([O-])=O.CCCCCCCCC(CS)C([O-])=O OXDSRJYUPSCKIX-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- DHQYDHVETSVMKQ-UHFFFAOYSA-N cyclohexyl 2-sulfanylacetate Chemical compound SCC(=O)OC1CCCCC1 DHQYDHVETSVMKQ-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- LMDIIDPLWVGXKM-UHFFFAOYSA-N decyl 2-sulfanylacetate Chemical compound CCCCCCCCCCOC(=O)CS LMDIIDPLWVGXKM-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- VSGRKLWYHXHXHB-UHFFFAOYSA-L dimethyltin(2+) 2-sulfanylicosanoate Chemical compound C[Sn+2]C.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCCCCCC(S)C([O-])=O VSGRKLWYHXHXHB-UHFFFAOYSA-L 0.000 description 1
- JZGNZEAUQWKDJQ-UHFFFAOYSA-L dimethyltin(2+) 8-methyl-2-(2-sulfanylethyl)nonanoate Chemical compound C[Sn+2]C.CC(C)CCCCCC(C([O-])=O)CCS.CC(C)CCCCCC(C([O-])=O)CCS JZGNZEAUQWKDJQ-UHFFFAOYSA-L 0.000 description 1
- HKPPFWSHODSGMF-UHFFFAOYSA-L dimethyltin(2+);2-sulfanyldecanoate Chemical compound C[Sn+2]C.CCCCCCCCC(S)C([O-])=O.CCCCCCCCC(S)C([O-])=O HKPPFWSHODSGMF-UHFFFAOYSA-L 0.000 description 1
- CNNQJJSZAQNWLY-UHFFFAOYSA-L dimethyltin(2+);8-methyl-2-(6-methylheptyl)-2-sulfanylnonanoate Chemical compound C[Sn+2]C.CC(C)CCCCCC(S)(C([O-])=O)CCCCCC(C)C.CC(C)CCCCCC(S)(C([O-])=O)CCCCCC(C)C CNNQJJSZAQNWLY-UHFFFAOYSA-L 0.000 description 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical class CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- TVMDUMQNXXNGMG-UHFFFAOYSA-N dodecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCOC(=O)CS TVMDUMQNXXNGMG-UHFFFAOYSA-N 0.000 description 1
- PVBRSNZAOAJRKO-UHFFFAOYSA-N ethyl 2-sulfanylacetate Chemical compound CCOC(=O)CS PVBRSNZAOAJRKO-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- KIYINYIPIIMUOV-UHFFFAOYSA-N hexyl 3-sulfanylpropanoate Chemical compound CCCCCCOC(=O)CCS KIYINYIPIIMUOV-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- MKIJJIMOAABWGF-UHFFFAOYSA-N methyl 2-sulfanylacetate Chemical compound COC(=O)CS MKIJJIMOAABWGF-UHFFFAOYSA-N 0.000 description 1
- PDDHALCPJOVHSY-UHFFFAOYSA-K methyltin(3+) 2-sulfanylbutanoate Chemical compound [Sn+3]C.CCC(S)C([O-])=O.CCC(S)C([O-])=O.CCC(S)C([O-])=O PDDHALCPJOVHSY-UHFFFAOYSA-K 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- JQTFPHLEQLLQOT-UHFFFAOYSA-N octadecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CS JQTFPHLEQLLQOT-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 231100000212 subchronic toxicity study Toxicity 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US435264A US3887519A (en) | 1971-09-02 | 1974-01-21 | Dimethyltin ester stabilizers for vinyl-halide polymers |
| US459372A US3925309A (en) | 1971-09-02 | 1974-04-09 | Dimethyltin esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH618714A5 true CH618714A5 (en) | 1980-08-15 |
Family
ID=27030489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH68775A CH618714A5 (en) | 1974-01-21 | 1975-01-21 | Composition based on halogen-containing synthetic resins containing tin esters as stabilisers |
Country Status (15)
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5193946A (ja) * | 1975-02-18 | 1976-08-18 | Harogenganjujushisoseibutsu | |
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
| DE14747246T1 (de) * | 2013-08-08 | 2016-09-29 | Galata Chemicals Llc | Wärmestabilisator für halogenhaltige Polymere |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE788299A (fr) * | 1971-09-02 | 1973-03-01 | Cincinnati Milacron Chem | Esters de dimethyl-etain |
-
1974
- 1974-12-12 AU AU76335/74A patent/AU469786B2/en not_active Expired
-
1975
- 1975-01-11 DE DE19752501007 patent/DE2501007A1/de not_active Withdrawn
- 1975-01-13 GB GB132275A patent/GB1470016A/en not_active Expired
- 1975-01-14 AT AT24275*#A patent/AT334640B/de not_active IP Right Cessation
- 1975-01-14 IN IN81/CAL/1975A patent/IN142634B/en unknown
- 1975-01-17 BR BR370/75A patent/BR7500370A/pt unknown
- 1975-01-20 CA CA218,244A patent/CA1026546A/en not_active Expired
- 1975-01-20 JP JP50008612A patent/JPS5131258B2/ja not_active Expired
- 1975-01-20 AR AR257356A patent/AR202497A1/es active
- 1975-01-20 PH PH16730A patent/PH11018A/en unknown
- 1975-01-20 FI FI750124A patent/FI66631C/fi not_active IP Right Cessation
- 1975-01-20 NL NL757500640A patent/NL154768B/xx not_active IP Right Cessation
- 1975-01-20 IT IT19413/75A patent/IT1054196B/it active
- 1975-01-21 CH CH68775A patent/CH618714A5/de not_active IP Right Cessation
- 1975-01-21 FR FR7501737A patent/FR2258417B2/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2258417B2 (enrdf_load_stackoverflow) | 1979-10-12 |
| FI66631B (fi) | 1984-07-31 |
| DE2501007B2 (enrdf_load_stackoverflow) | 1979-06-13 |
| DE2501007A1 (de) | 1975-07-31 |
| BR7500370A (pt) | 1975-11-04 |
| PH11018A (en) | 1977-10-25 |
| AT334640B (de) | 1976-01-25 |
| AU469786B2 (en) | 1976-02-26 |
| IN142634B (enrdf_load_stackoverflow) | 1977-08-06 |
| IT1054196B (it) | 1981-11-10 |
| AR202497A1 (es) | 1975-06-13 |
| GB1470016A (en) | 1977-04-14 |
| ATA24275A (de) | 1976-05-15 |
| AU7633574A (en) | 1976-02-26 |
| JPS50103550A (enrdf_load_stackoverflow) | 1975-08-15 |
| JPS5131258B2 (enrdf_load_stackoverflow) | 1976-09-06 |
| CA1026546A (en) | 1978-02-21 |
| NL154768B (nl) | 1977-10-17 |
| FI750124A7 (enrdf_load_stackoverflow) | 1975-07-22 |
| FI66631C (fi) | 1984-11-12 |
| FR2258417A2 (enrdf_load_stackoverflow) | 1975-08-18 |
| NL7500640A (nl) | 1975-07-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |