CH365069A - Verfahren zur Herstellung von Dialkyl-dichlorvinyl-phosphaten - Google Patents
Verfahren zur Herstellung von Dialkyl-dichlorvinyl-phosphatenInfo
- Publication number
- CH365069A CH365069A CH5574958A CH5574958A CH365069A CH 365069 A CH365069 A CH 365069A CH 5574958 A CH5574958 A CH 5574958A CH 5574958 A CH5574958 A CH 5574958A CH 365069 A CH365069 A CH 365069A
- Authority
- CH
- Switzerland
- Prior art keywords
- parts
- dialkyl
- production
- dichlorovinyl
- mixture
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 8
- MNRWIFMPVCLIDS-UHFFFAOYSA-N 2,2-dichloroethenyl dihydrogen phosphate Chemical class OP(O)(=O)OC=C(Cl)Cl MNRWIFMPVCLIDS-UHFFFAOYSA-N 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 12
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- HFFLGKNGCAIQMO-UHFFFAOYSA-N trichloroacetaldehyde Chemical compound ClC(Cl)(Cl)C=O HFFLGKNGCAIQMO-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 4
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims 2
- 229940045803 cuprous chloride Drugs 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 14
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 5
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000012230 colorless oil Substances 0.000 description 2
- 229940050176 methyl chloride Drugs 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BVZSTBILYMMKCG-UHFFFAOYSA-N 2,2-dichloroethenyl diethyl phosphate Chemical compound CCOP(=O)(OCC)OC=C(Cl)Cl BVZSTBILYMMKCG-UHFFFAOYSA-N 0.000 description 1
- OBUPKOWLJDGPFA-UHFFFAOYSA-N 2,2-dichloroethenyl dipropyl phosphate Chemical compound CCCOP(=O)(OCCC)OC=C(Cl)Cl OBUPKOWLJDGPFA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- QOPBTFMUVTXWFF-UHFFFAOYSA-N tripropyl phosphite Chemical compound CCCOP(OCCC)OCCC QOPBTFMUVTXWFF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/113—Esters of phosphoric acids with unsaturated acyclic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH5574958A CH365069A (de) | 1958-02-12 | 1958-02-12 | Verfahren zur Herstellung von Dialkyl-dichlorvinyl-phosphaten |
| ES0247163A ES247163A1 (es) | 1958-02-12 | 1959-02-11 | Procedimiento para la preparacion de fosfatos de dialkildiclorovinilo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH5574958A CH365069A (de) | 1958-02-12 | 1958-02-12 | Verfahren zur Herstellung von Dialkyl-dichlorvinyl-phosphaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH365069A true CH365069A (de) | 1962-10-31 |
Family
ID=4520081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH5574958A CH365069A (de) | 1958-02-12 | 1958-02-12 | Verfahren zur Herstellung von Dialkyl-dichlorvinyl-phosphaten |
Country Status (2)
| Country | Link |
|---|---|
| CH (1) | CH365069A (es) |
| ES (1) | ES247163A1 (es) |
-
1958
- 1958-02-12 CH CH5574958A patent/CH365069A/de unknown
-
1959
- 1959-02-11 ES ES0247163A patent/ES247163A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES247163A1 (es) | 1959-10-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE814152C (de) | everkusen I Verfahren zur Herstellung von Estern der Phosphorsaure und Thiophosphor saure | |
| US2731487A (en) | Asymmetric tertiary alkyl trithiocarbonates | |
| EP0034239A1 (de) | Verfahren zur Herstellung von Alkanphosphonsäurediarylestern und bzw Alkanphosphinsäurearylestern | |
| EP0080149B1 (de) | Verfahren zur Herstellung phosphoniger Säuren | |
| DE2643474C2 (de) | Verfahren zur Herstellung von Phosphitchloriden | |
| AT207854B (de) | Verfahren zur Herstellung von Dialkyldichlorvinylphosphaten | |
| CH365069A (de) | Verfahren zur Herstellung von Dialkyl-dichlorvinyl-phosphaten | |
| CH505152A (de) | Verfahren zur Herstellung von Phosphonsäureestern, Phosphinsäureestern bzw. Phosphinoxiden | |
| DE1083253B (de) | Verfahren zur Herstellung von Dialkyl-ª‰,ª‰-dichlorvinyl-phosphaten | |
| EP0122587B1 (de) | Verfahren zur Herstellung organischer Chlorphosphane | |
| US2668179A (en) | Linear dodecamethyltetraphosphoramide | |
| EP0144743B1 (de) | Verfahren zur Herstellung organischer Chlorphosphane | |
| CH617206A5 (en) | Process for the preparation of phosphonic and phosphinic acids. | |
| DE2238921C3 (de) | Verfahren zur Herstellung von 0,0-Dialkyl-0-(2,2-dichlorvinyl)-thionophosphorsäureestern | |
| DE1670591C3 (de) | Verfahren zur Herstellung von Halogenphenoxy-s-triazinphosphonsäureestern | |
| DE1216278B (de) | Verfahren zur Herstellung von unsymmetrischen Phosphorigsaeure-O, O-diestern | |
| AT253526B (de) | Verfahren zur Herstellung neuer Phosphorsäureester | |
| DE1768816C3 (de) | Verfahren zur Herstellung von 4-Dialkylphosphonyldioxolonen | |
| DE1815946B2 (de) | Diaethylphosphonyldioxolenon und verfahren zur herstellung von phosphonyldioxolenonen | |
| AT376224B (de) | Verfahren zur herstellung neuer o-aryl-nphosphonmethylglycinnitrile bzw. deren sauren und alkalischen salzen | |
| DE3025573A1 (de) | Substituierte cyclische methylphosphazene und verfahren zu ihrer herstellung | |
| DE1061785B (de) | Verfahren zur Herstellung von O, O-Dialkylphosphorsaeureestern und O, O-Dialkylthiophosphorsaeureestern | |
| DE1250425B (de) | Verfahren zur Herstellung von Or ganophosphorverbmdungen | |
| DE1200295B (de) | Verfahren zur Herstellung von Triarylphosphinopropionsaeurebetainen | |
| DE1111628B (de) | Verfahren zur Abtrennung eines Phosphonigsaeureesters |