CH242605A - Process for the preparation of a new derivative of a ring-substituted aromatic oxy compound. - Google Patents

Process for the preparation of a new derivative of a ring-substituted aromatic oxy compound.

Info

Publication number
CH242605A
CH242605A CH242605DA CH242605A CH 242605 A CH242605 A CH 242605A CH 242605D A CH242605D A CH 242605DA CH 242605 A CH242605 A CH 242605A
Authority
CH
Switzerland
Prior art keywords
ring
substituted aromatic
preparation
oxy compound
new derivative
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellschaft Ciba
Original Assignee
Ciba Geigy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy filed Critical Ciba Geigy
Publication of CH242605A publication Critical patent/CH242605A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

  

      Verfahren    zur Herstellung eines neuen     -Derivats    einer kernsubstituierten       aromatischen        Ogyverbindung.       Es wurde     gefunden,    dass man zu ,einem  neuen Derivat einer kernsubstituierten aro  matischen     Oxyverbindung    gelangt, wenn man  das     Kondensationsprodukt    aus     Kokosfett-          säure-N-methylolamid        und    Phenol mit Form  aldehyd und     Diäthanolamin    kondensiert.  



  Die Kondensation wird zweckmässig     in     der Wärme, z. B. bei 60 bis 100 ,     ausgeführt.     Das neue     Erzeugnis    bildet eine ziemlich  zähe Masse, die nach dem Lösen in Eisessig  beim Verdünnen mit Wasser eine annähernd  klare, schäumende Lösung liefert. Es kann  als     Textilhilfsstoff        Anwendung    finden.  



  <I>Beispiel:</I>  Man vermischt 31,8 Teile des     Konden-          sationsproduktes    aus     Kokosfettsäure-N-me-          thylolamid    und Phenol mit 11,6 Teilen     Di-          äthanolamin,    lässt bei Raumtemperatur  9 Teile     wässrige,    36,6 %     ige    Formaldehyd  lösung innert etwa 1     Stunde        hinzufliessen     und erhitzt während     etwa    3 Stunden auf 85  bis 90 .

   Das mit Wasser gewaschene neue  Erzeugnis bildet nach dem Trocknen eine    ziemlich zähe Masse, die nach dem Lösen in       Eisessig    beim     Verdünnen    mit Wasser eine  annähernd klare, schäumende     Lösung    liefert.  Das neue Erzeugnis kann z. B. als Textil  hilfsstoff     Anwendung    finden.  



  Zur     Herstellung    des als Ausgangs  material     dienenden    Kondensationsproduktes  kann man wie folgt verfahren: Man löst 72,6  Teile     Kokosf        ettsäure    - N -     methylolamid    und  30;9 Teile Phenol in 200 Teilen Eisessig, fügt  72,6 Teile     entwässertes    Zinkchlorid hinzu  und erwärmt während 24 Stunden auf 45 bis  50 . Das mit Wasser gewaschene, von gerin  gen Mengen unverändertem Phenol durch Ab  blasen mit Wasserdampf befreite Erzeugnis,  eine weiche Masse, ist nach dem Lösen in  alkoholischer     galiumhydroxydlösung    mit  Wasser klar     verdünnbar.  



      Process for the preparation of a new derivative of a ring-substituted aromatic ogy compound. It has been found that a new derivative of a ring-substituted aromatic oxy compound is obtained if the condensation product of coconut fatty acid-N-methylolamide and phenol is condensed with formaldehyde and diethanolamine.



  The condensation is expedient in the heat, for. B. at 60 to 100 executed. The new product forms a rather viscous mass which, when dissolved in glacial acetic acid, when diluted with water produces an almost clear, foaming solution. It can be used as a textile auxiliary.



  <I> Example: </I> 31.8 parts of the condensation product of coconut fatty acid N-methylolamide and phenol are mixed with 11.6 parts of diethanolamine, and 9 parts of 36.6% aqueous solution are left at room temperature Add formaldehyde solution within about 1 hour and heat to 85 to 90 for about 3 hours.

   The new product, washed with water, forms a rather viscous mass after drying, which, when dissolved in glacial acetic acid, produces an almost clear, foaming solution when diluted with water. The new product can e.g. B. found as a textile auxiliary application.



  The following procedure can be used to prepare the condensation product used as the starting material: 72.6 parts of coconut fatty acid-N-methylolamide and 30.9 parts of phenol are dissolved in 200 parts of glacial acetic acid, 72.6 parts of dehydrated zinc chloride are added and the mixture is heated for 24 hours on 45 to 50. Washed with water and freed from small amounts of unchanged phenol by blowing off with steam, the product, a soft mass, can be thinned with water after it has been dissolved in an alcoholic solution of galium hydroxide.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines neuen Derivats einer kernsubstituierten aroma tischen Oxyverbindung, dadurch gekennzeich net, dass man das Kondensationsprodukt aus Kokosfettsäure-N-methylolamid und Phenol mit Formaldehyd und Diäthanolamin kon densiert. Das neue Erzeugnis bildet eine ziemlich zähe Masse, die nach dem Lösen in Eisessig beim Verdünnen mit Wasser eine annähernd klare, schäumende Lösung liefert. Es kann. als Tegtilhilfsstoff Anwendung finden. PATENT CLAIM: Process for the preparation of a new derivative of a ring-substituted aromatic oxy compound, characterized in that the condensation product of coconut fatty acid-N-methylolamide and phenol is condensed with formaldehyde and diethanolamine. The new product forms a rather viscous mass which, when dissolved in glacial acetic acid, when diluted with water produces an almost clear, foaming solution. It can. find application as a Tegtilhilfsstoff. UNTERANSPRUCH: Verfahren nach Patentanspruch, dadurch gekennzeichnet, dass man die Kondensation in der Wärme ausführt. SUBCLAIM: Method according to claim, characterized in that the condensation is carried out in the heat.
CH242605D 1946-05-31 1944-05-10 Process for the preparation of a new derivative of a ring-substituted aromatic oxy compound. CH242605A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH242605T 1946-05-31

Publications (1)

Publication Number Publication Date
CH242605A true CH242605A (en) 1946-05-31

Family

ID=4463049

Family Applications (1)

Application Number Title Priority Date Filing Date
CH242605D CH242605A (en) 1946-05-31 1944-05-10 Process for the preparation of a new derivative of a ring-substituted aromatic oxy compound.

Country Status (1)

Country Link
CH (1) CH242605A (en)

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