CA2956491C - Graphene-reinforced polymer matrix composites - Google Patents

Graphene-reinforced polymer matrix composites Download PDF

Info

Publication number
CA2956491C
CA2956491C CA2956491A CA2956491A CA2956491C CA 2956491 C CA2956491 C CA 2956491C CA 2956491 A CA2956491 A CA 2956491A CA 2956491 A CA2956491 A CA 2956491A CA 2956491 C CA2956491 C CA 2956491C
Authority
CA
Canada
Prior art keywords
graphene
graphite
polyamide
polymer matrix
matrix composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2956491A
Other languages
English (en)
French (fr)
Other versions
CA2956491A1 (en
Inventor
Thomas Nosker
Jennifer Lynch
Bernard Kear
Justin HENDRIX
Gordon Chiu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rutgers State University of New Jersey
Original Assignee
Rutgers State University of New Jersey
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rutgers State University of New Jersey filed Critical Rutgers State University of New Jersey
Publication of CA2956491A1 publication Critical patent/CA2956491A1/en
Application granted granted Critical
Publication of CA2956491C publication Critical patent/CA2956491C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/19—Preparation by exfoliation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/21—After-treatment
    • C01B32/22—Intercalation
    • C01B32/225—Expansion; Exfoliation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/02—Single layer graphene
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/04—Specific amount of layers or specific thickness
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/20—Graphene characterized by its properties
    • C01B2204/32—Size or surface area
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino carboxylic acids or of polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/04—Polysulfides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CA2956491A 2014-07-30 2015-07-29 Graphene-reinforced polymer matrix composites Active CA2956491C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462030799P 2014-07-30 2014-07-30
US62/030,799 2014-07-30
PCT/US2015/042623 WO2016018995A1 (en) 2014-07-30 2015-07-29 Graphene-reinforced polymer matrix composites

Publications (2)

Publication Number Publication Date
CA2956491A1 CA2956491A1 (en) 2016-02-04
CA2956491C true CA2956491C (en) 2021-12-14

Family

ID=55218266

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2956491A Active CA2956491C (en) 2014-07-30 2015-07-29 Graphene-reinforced polymer matrix composites

Country Status (10)

Country Link
US (2) US10329391B2 (https=)
EP (1) EP3174827B1 (https=)
JP (2) JP7001472B2 (https=)
KR (1) KR102435617B1 (https=)
CN (2) CN107074552A (https=)
BR (1) BR112017002562B1 (https=)
CA (1) CA2956491C (https=)
ES (1) ES2926381T3 (https=)
MX (1) MX2017001350A (https=)
WO (1) WO2016018995A1 (https=)

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11479652B2 (en) 2012-10-19 2022-10-25 Rutgers, The State University Of New Jersey Covalent conjugates of graphene nanoparticles and polymer chains and composite materials formed therefrom
US12460064B2 (en) 2012-10-19 2025-11-04 Rutgers, The State University Of New Jersey In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite
BR112015008949B1 (pt) 2012-10-19 2021-11-30 Rutgers, The State University Of New Jersey Método para formação de um compósito de matriz de polímero de grafeno-reforçado
BR112015026355B1 (pt) 2013-04-18 2021-03-30 Rutgers, The State University Of New Jersey Método de esfoliação in situ para fabricar um composto de matriz polimérica reforçado por grafeno
EP3152052B1 (en) 2014-06-04 2021-08-11 Bright Lite Structures LLC Reinforced composite structure
BR112017002562B1 (pt) 2014-07-30 2022-10-25 Rutgers , The State University Of New Jersey Compostos de matriz de polímero reforçado com grafeno, peça de motor que a utiliza e método de preparação dos mesmos
US10967583B2 (en) 2015-04-03 2021-04-06 Bright Lite Structures Llc Apparatus for controllably cutting fibers and related methods
CN109874320A (zh) * 2015-08-31 2019-06-11 纯净新世界有限公司 用于复合材料的制造的增强的增材制造方法
US20170191498A1 (en) * 2015-12-30 2017-07-06 General Electric Company Graphene ultra-conductive casing wrap
US11702518B2 (en) 2016-07-22 2023-07-18 Rutgers, The State University Of New Jersey In situ bonding of carbon fibers and nanotubes to polymer matrices
US11059945B2 (en) 2016-07-22 2021-07-13 Rutgers, The State University Of New Jersey In situ bonding of carbon fibers and nanotubes to polymer matrices
CN106220774B (zh) * 2016-08-31 2019-01-22 齐齐哈尔大学 一种聚苯乙烯/石墨烯纳米复合材料的制备方法
GB2559979A (en) * 2017-02-23 2018-08-29 Graphene Composites Ltd Graphene/Aerogel composite
BE1025159B1 (fr) * 2017-04-21 2018-11-23 Safran Aero Boosters S.A. Carter composite de compresseur de turbomachine axiale
CN111148718B (zh) * 2017-07-13 2023-06-09 碳循环技术有限公司 用以生产剥离型纳米粒子的机械化学方法
TWI810162B (zh) * 2017-09-21 2023-08-01 紐澤西州立羅格斯大學 碳纖維及奈米管對聚合物基質之原位鍵結
CN108166095B (zh) * 2017-12-18 2020-05-05 浙江恒逸高新材料有限公司 一种亲水抗静电石墨烯改性聚酯切片及其制备方法
US10756334B2 (en) 2017-12-22 2020-08-25 Lyten, Inc. Structured composite materials
US11479653B2 (en) 2018-01-16 2022-10-25 Rutgers, The State University Of New Jersey Use of graphene-polymer composites to improve barrier resistance of polymers to liquid and gas permeants
CN111542953B (zh) * 2018-01-26 2024-08-23 株式会社Lg新能源 导电剂、包括该导电剂的用于形成电极的浆料、电极和使用该电极制造的锂二次电池
US12409639B2 (en) 2018-02-22 2025-09-09 Graphene Composites Limited Laminate structure and wearable article
US20190267663A1 (en) * 2018-02-23 2019-08-29 Nanotek Instruments, Inc. Method of Producing Elastomer Composite-Encapsulated Particles of Anode Active Materials for Lithium Batteries
US11721832B2 (en) * 2018-02-23 2023-08-08 Global Graphene Group, Inc. Elastomer composite-encapsulated particles of anode active materials for lithium batteries
GB2573810B (en) * 2018-05-18 2021-02-24 Graphene Composites Ltd Protective shield and shield wall
US12060473B2 (en) 2018-07-03 2024-08-13 University Of Notre Dame Du Lac Polymer/exfoliated nano-composite films with superior mechanical properties
US11136480B2 (en) * 2018-08-01 2021-10-05 The Boeing Company Thermal spray plastic coating for edge sealing and fillet sealing
US11827987B2 (en) 2018-08-02 2023-11-28 Lyten, Inc. Coherent graphene in a metal lattice
US12018383B2 (en) 2018-08-02 2024-06-25 Lyten, Inc. Coherent or pristine graphene in a polymer matrix
DE202018106258U1 (de) * 2018-10-15 2020-01-20 Rutgers, The State University Of New Jersey Nano-Graphitische Schwämme
JP7185779B2 (ja) * 2018-11-19 2022-12-07 ブライト ライト ストラクチャーズ エルエルシー ｓｐ２炭素含有材料を内部に有する樹脂層を含む熱放出性の低い高強度の部材
JP7208390B2 (ja) 2018-11-19 2023-01-18 ブライト ライト ストラクチャーズ エルエルシー 熱放出性の低い高強度の複合材
KR102140890B1 (ko) * 2019-04-22 2020-08-04 전주대학교 산학협력단 폴리에틸렌 글리콜 기능화된 산화 그래핀을 혼입한 폴리락트산 조성물, 이의 제조방법 및 이를 기반으로 한 바이오하이브리드 소재
US11807757B2 (en) 2019-05-07 2023-11-07 Rutgers, The State University Of New Jersey Economical multi-scale reinforced composites
CN114040889A (zh) * 2019-06-17 2022-02-11 堪萨斯州立大学研究基金会 石墨烯/氧化石墨烯核/壳颗粒及其制备和使用方法
FI20195949A1 (en) 2019-11-05 2021-05-06 Arctic Biomaterials Oy Conductive polymer composition
US11577665B2 (en) 2020-02-27 2023-02-14 Cpk Interior Products Urethane and graphene interior trim panel
EP3970489A1 (en) 2020-09-18 2022-03-23 CpK Interior Products Inc. Graphene-based antiviral polymer
US12398247B2 (en) 2020-10-09 2025-08-26 Rutgers, The State University Of New Jersey Conductive polymer nanocomposites enhanced with in situ formation of 2D nanoparticles for structural sensors and smart materials
GB202116664D0 (en) * 2021-11-18 2022-01-05 Senergy Innovations Ltd Conductive polymer composite 1
WO2023171753A1 (ja) * 2022-03-10 2023-09-14 帝人株式会社 熱可塑性樹脂組成物、熱可塑性樹脂フィルム、プリプレグ及び繊維強化複合材料、並びにプリプレグ及び繊維強化複合材料の製造方法
WO2023192794A1 (en) * 2022-03-30 2023-10-05 Lyten, Inc. Composite material including three-dimensional (3d) graphene
US11591457B1 (en) 2022-03-30 2023-02-28 Lyten, Inc. Composite material including three-dimensional (3D) graphene and maleated copolymers
US11813774B2 (en) 2022-03-30 2023-11-14 Lyten, Inc. Method of producing a composite material including three-dimensional (3D) graphene
US12006388B2 (en) 2022-03-30 2024-06-11 Lyten, Inc. Composite material including three-dimensional (3D) graphene
US11674031B1 (en) 2022-03-30 2023-06-13 Lyten, Inc. Container formed of a composite material including three-dimensional (3D) graphene
WO2024116567A1 (ja) * 2022-11-29 2024-06-06 Dic株式会社 熱可塑性樹脂組成物、成形品及び複合構造体の製造方法
KR102783651B1 (ko) * 2022-12-05 2025-03-19 전북대학교산학협력단 더블벨트 라미네이터 공정을 이용한 자기강화복합재 및 그 제조 방법
US11919279B1 (en) * 2023-01-20 2024-03-05 Aisin Corporation Scratch and UV resistant films
WO2025058729A1 (en) * 2023-09-13 2025-03-20 Lyten, Inc. Coherent or pristine graphene in a polymer matrix
CN119119778B (zh) * 2024-11-18 2025-02-28 苏州诚益合电力器材有限公司 一种改性氧化石墨烯及聚乙烯改性复合管材及制备方法

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2135322C (en) 1993-11-10 2001-02-06 Hiroshi Sugahara Method for producing a fiber-reinforced thermoplastic resin foamed product
JP3419093B2 (ja) 1994-08-11 2003-06-23 三菱化学株式会社 熱可塑性樹脂組成物とその製造方法、およびこの組成物よりなる電磁波シールド成形品
CA2394955C (en) 1999-12-07 2010-01-26 William Marsh Rice University Oriented nanofibers embedded in polymer matrix
US6660241B2 (en) 2000-05-01 2003-12-09 Saint-Gobain Ceramics & Plastics, Inc. Highly delaminated hexagonal boron nitride powders, process for making, and uses thereof
US6962431B1 (en) 2000-11-08 2005-11-08 Randcastle Extrusion System, Inc. Extruder mixer
JP3958137B2 (ja) 2001-08-20 2007-08-15 大塚化学ホールディングス株式会社 樹脂組成物
US20050186378A1 (en) 2004-02-23 2005-08-25 Bhatt Sanjiv M. Compositions comprising carbon nanotubes and articles formed therefrom
JP4245514B2 (ja) 2004-05-24 2009-03-25 日信工業株式会社 炭素繊維複合材料及びその製造方法、炭素繊維複合金属材料の製造方法、炭素繊維複合非金属材料の製造方法
US8048940B2 (en) 2004-07-09 2011-11-01 Vanderbilt University Reactive graphitic carbon nanofiber reinforced polymeric composites showing enhanced flexural strength
US20110223405A1 (en) 2005-11-18 2011-09-15 Northwestern University Composite polymer film with graphene nanosheets as highly effective barrier property enhancers
CA2658970C (en) 2006-06-05 2014-10-21 University Of Akron Ultrasound assisted continuous process for dispersion of nanofibers and nanotubes in polymers
CN101479330A (zh) 2006-07-05 2009-07-08 欧文斯科宁知识产权资产有限公司 含多官能层状纳米石墨的聚合物泡沫
US7745528B2 (en) 2006-10-06 2010-06-29 The Trustees Of Princeton University Functional graphene-rubber nanocomposites
JP5207351B2 (ja) 2007-03-23 2013-06-12 独立行政法人産業技術総合研究所 溶融混練物、樹脂成形物及びその製造方法
US7824651B2 (en) 2007-05-08 2010-11-02 Nanotek Instruments, Inc. Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets
EP2176163B1 (en) 2007-08-01 2017-10-25 Dow Global Technologies LLC Highly efficient process for manufacture of exfoliated graphene
WO2009029984A1 (en) 2007-09-03 2009-03-12 Newsouth Innovations Pty Limited Graphene
DE102007049439A1 (de) 2007-09-27 2009-04-02 Electrovac Ag Kunststoff-Composite-Material sowie Verfahren zu dessen Herstellung
US7906053B1 (en) 2008-02-21 2011-03-15 Northwestern University Polymer-graphite nanocomposites via solid-state shear pulverization
CN102015529B (zh) 2008-02-28 2014-04-30 巴斯夫欧洲公司 纳米石墨片和组合物
US9625062B2 (en) * 2008-04-07 2017-04-18 John M. Crain Fuel system components
WO2009143405A2 (en) * 2008-05-22 2009-11-26 The University Of North Carolina At Chapel Hill Synthesis of graphene sheets and nanoparticle composites comprising same
TW201012749A (en) 2008-08-19 2010-04-01 Univ Rice William M Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom
KR101074027B1 (ko) 2009-03-03 2011-10-17 한국과학기술연구원 그래펜 복합 나노섬유 및 그 제조 방법
WO2010107763A1 (en) 2009-03-16 2010-09-23 Aksay Ilhan A Reinforced polymeric articles
WO2010115173A1 (en) * 2009-04-03 2010-10-07 Vorbeck Materials Corp Polymer compositions containing graphene sheets and graphite
US20110133134A1 (en) * 2009-06-09 2011-06-09 Vorbeck Materials Corp. Crosslinkable and Crosslinked Compositions of Olefin Polymers and Graphene Sheets
US8652362B2 (en) * 2009-07-23 2014-02-18 Nanotek Instruments, Inc. Nano graphene-modified curing agents for thermoset resins
KR101090517B1 (ko) 2009-08-17 2011-12-08 성균관대학교산학협력단 탄소나노물질-고분자 복합체 및 이의 제조방법
US8299159B2 (en) 2009-08-17 2012-10-30 Laird Technologies, Inc. Highly thermally-conductive moldable thermoplastic composites and compositions
IT1396193B1 (it) 2009-10-07 2012-11-16 Polimeri Europa Spa Composizioni polimeriche nanocomposite termoplastiche espansibili con migliorata capacita' di isolamento termico.
IT1396918B1 (it) 2009-11-03 2012-12-20 Polimeri Europa Spa Procedimento per la preparazione di nanopiastrine grafeniche ad elevata disperdibilita' in matrici polimeriche a bassa polarita' e relative composizioni polimeriche
WO2011117325A2 (en) * 2010-03-23 2011-09-29 Solvay Sa Polymer compositions comprising semi-aromatic polyamides and graphene materials
FR2959231B1 (fr) 2010-04-22 2012-04-20 Arkema France Materiau composite thermoplastique et/ou elastomerique a base de nanotubes de carbone et de graphenes
CN101817516A (zh) 2010-05-21 2010-09-01 哈尔滨工业大学 高效率低成本机械剥离制备石墨烯或氧化石墨烯的方法
KR20120009978A (ko) 2010-07-23 2012-02-02 현대자동차주식회사 배향 조정된 탄소나노튜브를 이용한 고분자 나노복합 성형물의 제조방법
DE102010032885A1 (de) 2010-07-30 2012-02-02 Daimler Ag Befestigungseinrichtung für ein faserverstärktes Kunststoffprofil
WO2012020099A1 (en) 2010-08-11 2012-02-16 Timcal S.A. Ground expanded graphite agglomerates, methods of making, and applications of the same
WO2012029946A1 (ja) 2010-09-03 2012-03-08 積水化学工業株式会社 樹脂複合材料及び樹脂複合材料の製造方法
US8420042B2 (en) 2010-09-21 2013-04-16 High Temperature Physics, Llc Process for the production of carbon graphenes and other nanomaterials
TW201219447A (en) 2010-10-12 2012-05-16 Solvay Polymer compositions comprising poly(arylether ketone)s and graphene materials
US20130310521A1 (en) 2011-03-30 2013-11-21 Daisuke Mukohata Resin composite material and process for producing same
US8167190B1 (en) * 2011-05-06 2012-05-01 Lockheed Martin Corporation Electrically conductive polymer compositions containing metal particles and a graphene and methods for production and use thereof
JP5953014B2 (ja) 2011-07-08 2016-07-13 積水化学工業株式会社 難燃性樹脂組成物、難燃性樹脂シート及び難燃性多層シート
KR101245815B1 (ko) 2011-07-14 2013-03-21 국립대학법인 울산과학기술대학교 산학협력단 기계 화학적 방법에 의한 가장자리가 기능화된 그래파이트 및 이의 제조 방법
US20180002512A9 (en) 2011-07-21 2018-01-04 Entegris, Inc. Nanotube and finely milled carbon fiber polymer composite compositions and methods of making
US9068037B2 (en) 2011-10-18 2015-06-30 Sekisui Chemical Co., Ltd. Method for producing resin composite material, and resin composite material
WO2013146213A1 (ja) * 2012-03-27 2013-10-03 積水化学工業株式会社 樹脂複合材料
JP2013233790A (ja) 2012-04-11 2013-11-21 Sekisui Chem Co Ltd 樹脂成形体の製造方法及び樹脂成形体
EP2900473B1 (en) 2012-09-28 2020-07-01 Applied NanoStructured Solutions, LLC Composite materials formed by shear mixing of carbon nanostructures and related methods
BR112015008949B1 (pt) 2012-10-19 2021-11-30 Rutgers, The State University Of New Jersey Método para formação de um compósito de matriz de polímero de grafeno-reforçado
US10060019B2 (en) 2012-11-16 2018-08-28 The Boeing Company Thermal spray coated reinforced polymer composites
GB201304770D0 (en) 2013-03-15 2013-05-01 Provost Fellows Foundation Scholars And The Other Members Of Board Of A scalable process for producing exfoliated defect-free, non-oxidised 2-dimens ional materials in large quantities
BR112015026355B1 (pt) 2013-04-18 2021-03-30 Rutgers, The State University Of New Jersey Método de esfoliação in situ para fabricar um composto de matriz polimérica reforçado por grafeno
ES2534575B1 (es) 2013-09-24 2016-01-14 Consejo Superior De Investigaciones Científicas (Csic) Exfoliación de grafito con disolventes eutécticos profundos
BR112017002562B1 (pt) * 2014-07-30 2022-10-25 Rutgers , The State University Of New Jersey Compostos de matriz de polímero reforçado com grafeno, peça de motor que a utiliza e método de preparação dos mesmos
WO2016106312A2 (en) 2014-12-22 2016-06-30 Reliance Industries Limited Graphite exfoliation in resin
CN104945659A (zh) 2015-06-29 2015-09-30 殷明 一种新型cnt表面处理方法及其在制备聚合物/cnt纳米复合材料中的应用
US10685763B2 (en) 2016-01-19 2020-06-16 Xerox Corporation Conductive polymer composite

Also Published As

Publication number Publication date
JP7001472B2 (ja) 2022-01-19
US20170218141A1 (en) 2017-08-03
ES2926381T3 (es) 2022-10-25
KR20170039205A (ko) 2017-04-10
CA2956491A1 (en) 2016-02-04
MX2017001350A (es) 2018-01-17
EP3174827A1 (en) 2017-06-07
US20200017645A1 (en) 2020-01-16
JP2017531052A (ja) 2017-10-19
BR112017002562A2 (pt) 2018-07-03
JP7231267B2 (ja) 2023-03-01
WO2016018995A1 (en) 2016-02-04
US11225558B2 (en) 2022-01-18
EP3174827B1 (en) 2022-04-20
BR112017002562B1 (pt) 2022-10-25
JP2022025074A (ja) 2022-02-09
US10329391B2 (en) 2019-06-25
KR102435617B1 (ko) 2022-08-24
EP3174827A4 (en) 2018-03-07
CN116804117A (zh) 2023-09-26
CN107074552A (zh) 2017-08-18

Similar Documents

Publication Publication Date Title
US11225558B2 (en) Graphene-reinforced polymer matrix composites
US11174366B2 (en) In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite
CA2888865C (en) In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite
US20260035540A1 (en) In Situ Exfoliation Method to Fabricate a Graphene-Reinforced Polymer Matrix Composite
US11479652B2 (en) Covalent conjugates of graphene nanoparticles and polymer chains and composite materials formed therefrom
HK1246760A1 (en) Graphene-reinforced polymer matrix composites
HK1246760B (en) Graphene-reinforced polymer matrix composites
TWI786340B (zh) 石墨烯奈米顆粒與聚合物鏈的共價綴合物、由其所形成的複合材料以及其製造方法

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20200722

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 9TH ANNIV.) - STANDARD

Year of fee payment: 9

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20240724

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20240724

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 10TH ANNIV.) - STANDARD

Year of fee payment: 10

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250725

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250828