CA2944762C - Flow reactor synthesis of polymers - Google Patents

Flow reactor synthesis of polymers Download PDF

Info

Publication number
CA2944762C
CA2944762C CA2944762A CA2944762A CA2944762C CA 2944762 C CA2944762 C CA 2944762C CA 2944762 A CA2944762 A CA 2944762A CA 2944762 A CA2944762 A CA 2944762A CA 2944762 C CA2944762 C CA 2944762C
Authority
CA
Canada
Prior art keywords
tubing
salt
monomer
amount
introducing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2944762A
Other languages
English (en)
French (fr)
Other versions
CA2944762A1 (en
Inventor
Patrick John Kinlen
Andrew M. Zweig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boeing Co
Original Assignee
Boeing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boeing Co filed Critical Boeing Co
Publication of CA2944762A1 publication Critical patent/CA2944762A1/en
Application granted granted Critical
Publication of CA2944762C publication Critical patent/CA2944762C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G85/00—General processes for preparing compounds provided for in this subclass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/242—Tubular reactors in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2425—Tubular reactors in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1809—Controlling processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/026—Wholly aromatic polyamines
    • C08G73/0266—Polyanilines or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/025—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/02—Polyamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B01J2219/00792—One or more tube-shaped elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B01J2219/00792—One or more tube-shaped elements
    • B01J2219/00795—Spiral-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00822—Metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00831—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00833—Plastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00837—Materials of construction comprising coatings other than catalytically active coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/0086—Dimensions of the flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00867—Microreactors placed in series, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00869—Microreactors placed in parallel, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00873—Heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00891—Feeding or evacuation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/0095—Control aspects
    • B01J2219/00952—Sensing operations
    • B01J2219/00954—Measured properties
    • B01J2219/00963—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2944762A 2015-10-13 2016-10-05 Flow reactor synthesis of polymers Active CA2944762C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/882,073 2015-10-13
US14/882,073 US9481764B1 (en) 2015-10-13 2015-10-13 Flow reactor synthesis of polymers

Publications (2)

Publication Number Publication Date
CA2944762A1 CA2944762A1 (en) 2017-04-13
CA2944762C true CA2944762C (en) 2021-08-31

Family

ID=57136683

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2944762A Active CA2944762C (en) 2015-10-13 2016-10-05 Flow reactor synthesis of polymers

Country Status (7)

Country Link
US (7) US9481764B1 (https=)
EP (3) EP3170854B1 (https=)
JP (3) JP6953123B2 (https=)
KR (1) KR102666306B1 (https=)
CN (2) CN106563400A (https=)
AU (2) AU2016244187B2 (https=)
CA (1) CA2944762C (https=)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9481764B1 (en) 2015-10-13 2016-11-01 The Boeing Company Flow reactor synthesis of polymers
US10923723B1 (en) 2017-05-11 2021-02-16 Richard Carl Auchterlonie Electro-conductive polymers of halogenated para-aminophenol, and electrochemical cells employing same
JPWO2019026425A1 (ja) * 2017-07-31 2020-05-28 株式会社カネカ フロー式リアクター
WO2019113640A1 (en) * 2017-12-12 2019-06-20 Commonwealth Scientific And Industrial Research Organisation Continuous flow process for preparing conducting polymers
CN108822250A (zh) * 2018-09-03 2018-11-16 安徽联合辐化有限公司 水性高分子乳液的合成方法及设备
CN109942733A (zh) * 2018-10-26 2019-06-28 复旦大学 一种连续流动合成聚合物的方法
US12150752B2 (en) 2018-12-10 2024-11-26 Anastasia Rigas Hydrogen breath analyzer and breath test method
EP4011290A1 (en) 2018-12-10 2022-06-15 Anastasia Rigas Breath analyzer devices and breath test methods
CN111434377B (zh) * 2019-01-11 2022-07-15 中国石油化工股份有限公司 一种盘管微反应器和一种微反应器系统
US11248089B2 (en) * 2019-04-10 2022-02-15 The Boeing Company Polyanilines and methods thereof
CN113891900A (zh) 2019-05-29 2022-01-04 沙特阿拉伯石油公司 聚合物纳米粒子的流动合成
US11566165B2 (en) 2019-05-30 2023-01-31 Saudi Arabian Oil Company Polymers and nanoparticles for flooding
WO2021002108A1 (ja) * 2019-07-03 2021-01-07 富士フイルム株式会社 最適化支援装置、方法およびプログラム
EP3999236B1 (en) 2019-07-16 2023-09-06 Saudi Arabian Oil Company Multipurpose microfluidics devices for rapid on-site optical chemical analysis
CN110918021A (zh) * 2019-11-21 2020-03-27 南京先进生物材料与过程装备研究院有限公司 一种微反应装置及用其制备二甲苯甲醛树脂的方法
CN110898774A (zh) * 2019-11-27 2020-03-24 迪亚莱博（张家港）生物科技有限公司 胶乳颗粒的连续生产方法
BR112022017813A2 (pt) * 2020-03-09 2022-12-20 Kemira Oyj Sistemas e métodos de produção de ácido perfórmico
US11773715B2 (en) 2020-09-03 2023-10-03 Saudi Arabian Oil Company Injecting multiple tracer tag fluids into a wellbore
KR102376167B1 (ko) * 2020-09-04 2022-03-17 인하대학교 산학협력단 연속흐름반응공정을 이용한 전도성 고분자의 제조방법
US11987669B2 (en) 2020-10-08 2024-05-21 The Boeing Company Polyaniline compositions, articles thereof, and methods thereof
US12043762B2 (en) 2020-12-21 2024-07-23 The Boeing Company Compositions and methods thereof
US11660595B2 (en) 2021-01-04 2023-05-30 Saudi Arabian Oil Company Microfluidic chip with multiple porosity regions for reservoir modeling
US11534759B2 (en) 2021-01-22 2022-12-27 Saudi Arabian Oil Company Microfluidic chip with mixed porosities for reservoir modeling
CN113929881A (zh) * 2021-11-08 2022-01-14 上海交通大学 一种基于连续流微反应器合成共轭光电高分子的制备方法
US12253467B2 (en) 2021-12-13 2025-03-18 Saudi Arabian Oil Company Determining partition coefficients of tracer analytes
US12000278B2 (en) 2021-12-16 2024-06-04 Saudi Arabian Oil Company Determining oil and water production rates in multiple production zones from a single production well
CN115656159A (zh) * 2022-10-12 2023-01-31 国家海洋局南海环境监测中心（中国海监南海区检验鉴定中心） 一种酸可挥发性硫化物的在线流动反应非在线检测分析方法
CN121398904A (zh) * 2023-06-29 2026-01-23 赢创运营有限公司 用于通过强放热反应来合成产物的反应器、设备和方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4877587A (en) * 1984-08-24 1989-10-31 Union Carbide Chemicals And Plastics Company Inc. Fluidized bed polymerization reactors
US5324453A (en) 1992-08-07 1994-06-28 Neste Oy Electrically conducting polyaniline: method for emulsion polymerization
US5567356A (en) 1994-11-07 1996-10-22 Monsanto Company Emulsion-polymerization process and electrically-conductive polyaniline salts
ATE335037T1 (de) * 2000-04-04 2006-08-15 Panipol Oy Verfahren und apparatur zur herstellung von polyanilin
FI113053B (fi) * 2000-04-04 2004-02-27 Panipol Oy Menetelmä polyaniliinin valmistamiseksi
ES2540542T3 (es) * 2000-12-07 2015-07-10 Grupo Petrotemex, S.A. De C.V. Procedimiento de poliéster de bajo coste que usa un reactor tubular
DE10301874A1 (de) * 2003-01-17 2004-07-29 Celanese Emulsions Gmbh Verfahren und Vorrichtung zur Herstellung von Emulsionspolymerisaten
RU2007108795A (ru) * 2004-08-12 2008-09-20 Е.И.Дюпон де Немур энд Компани (US) Устройство и способ получения низкомолекулярных полимеров
US7795359B2 (en) 2005-03-04 2010-09-14 Novartis Ag Continuous process for production of polymeric materials
DE102005055866A1 (de) 2005-11-23 2007-05-24 Hte Ag The High Throughput Experimentation Company Verfahren zur Herstellung von Aryl-Aryl gekoppelter Verbindungen
DE102006061967A1 (de) * 2006-12-21 2008-06-26 Bayer Technology Services Gmbh Verfahren zur Darstellung von oligomeren Thiophenen
US7819967B2 (en) 2007-11-08 2010-10-26 Fujifilm Corporation Method of producing an organic fine particle dispersion, organic fine particle dispersion obtained by the same, and ink-jet recording ink and paint using the dispersion
FR2928646B1 (fr) * 2008-03-13 2012-04-27 Centre Nat Rech Scient Procede de preparation de polyaniline et films hautement auto-orientes obtenus.
EP2133141A1 (en) 2008-06-10 2009-12-16 Nederlandse Organisatie voor Toegepast-Natuuurwetenschappelijk Onderzoek TNO Process for carrying out multi-phase reactions
KR101211856B1 (ko) * 2008-11-21 2012-12-12 주식회사 엘지화학 고분자 입자의 제조 장치 및 제조 방법
KR101295762B1 (ko) 2009-02-17 2013-08-12 소켄 케미칼 앤드 엔지니어링 캄파니, 리미티드 복합 전기 전도성 폴리머 조성물, 이의 제조 방법, 이를 함유하는 용액, 및 이의 용도
JP5945829B2 (ja) * 2010-04-01 2016-07-05 ディーピーエックス ファイン ケミカルズ オーストリア ゲーエムベーハー ウント ツェーオー カーゲー 連続乳化重合方法
WO2012037596A1 (en) 2010-09-22 2012-03-29 Commonwealth Scientific And Industrial Research Organisation Continuous flow polymerisation process
JP2012092249A (ja) * 2010-10-28 2012-05-17 Osaka Prefecture Univ 粒子状重合体及びその製造方法
CN103408754B (zh) 2013-07-11 2015-10-28 东华大学 一种聚苯胺纳米纤维的制备方法
KR20160091362A (ko) 2013-11-27 2016-08-02 코닝 인코포레이티드 반전도성 중합체의 향상된 유동 반응기 합성
US9481764B1 (en) 2015-10-13 2016-11-01 The Boeing Company Flow reactor synthesis of polymers

Also Published As

Publication number Publication date
AU2021203395A1 (en) 2021-06-24
KR20170043456A (ko) 2017-04-21
US10584208B2 (en) 2020-03-10
EP3156122B1 (en) 2023-01-04
US9481764B1 (en) 2016-11-01
CN115178204A (zh) 2022-10-14
USRE48166E1 (en) 2020-08-18
JP7411608B2 (ja) 2024-01-11
AU2016244187A1 (en) 2017-04-27
JP2021169609A (ja) 2021-10-28
JP7627713B2 (ja) 2025-02-06
AU2021203395B2 (en) 2022-12-08
AU2016244187B2 (en) 2021-02-25
US20200157282A1 (en) 2020-05-21
JP2023071775A (ja) 2023-05-23
US20170321010A1 (en) 2017-11-09
EP3170854B1 (en) 2024-12-04
US20190062502A1 (en) 2019-02-28
US11104765B2 (en) 2021-08-31
JP6953123B2 (ja) 2021-10-27
US20210363302A1 (en) 2021-11-25
CA2944762A1 (en) 2017-04-13
EP3170854A1 (en) 2017-05-24
US10118992B2 (en) 2018-11-06
CN106563400A (zh) 2017-04-19
EP3156122A1 (en) 2017-04-19
KR102666306B1 (ko) 2024-05-14
US12104016B2 (en) 2024-10-01
US20170101508A1 (en) 2017-04-13
JP2017110181A (ja) 2017-06-22
EP4039364A1 (en) 2022-08-10
US9751983B2 (en) 2017-09-05

Similar Documents

Publication Publication Date Title
US12104016B2 (en) Flow reactor synthesis of polymers
EP1259316B1 (en) Capillary reactor distribution device and method
CN100408157C (zh) 采用微型反应器的反应方法
CA3077487C (en) POLYANILINE AND ITS PROCESSES
CN116041202A (zh) 一种连续流反应器合成2-甲氧基-4-硝基乙酰苯胺的方法
Bhaskar et al. A continuous flow microreactor as a practical tool for the synthesis of active pharmaceutical ingredients
CN110404488B (zh) 一种混沌流与嵌段流相结合的危险性离子盐制备系统
CN112500357B (zh) 一种1,1-二氨基-2,2-二硝基乙烯(fox-7)的合成方法
US10562873B1 (en) Methods of producing glycidyl nitrate
CN109776330B (zh) 一种用微通道反应器制1,2,4-丁三醇三硝酸酯的方法
CN116212761A (zh) 一种管式微流控装置及制备丙三醇三硝酸酯的方法
EP1632277A1 (en) Process and apparatus for carrying out crystallization
Guo et al. Continuous flow synthesis of N, O-dimethyl-N'-nitroisourea monitored by inline FTIR: comparing machine learning and kinetic modeling for optimization
Parida Intensification of ATRP polymer syntheses by microreaction technologies
Kubota et al. Solvent Extraction of Rare Earth Metals by Microchannel Extractor

Legal Events

Date Code Title Description
MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 8TH ANNIV.) - STANDARD

Year of fee payment: 8

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20240927

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT DETERMINED COMPLIANT

Effective date: 20240927

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20240927

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 9TH ANNIV.) - STANDARD

Year of fee payment: 9

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250926

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250926