CA2899149C - Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas - Google Patents

Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas Download PDF

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Publication number
CA2899149C
CA2899149C CA2899149A CA2899149A CA2899149C CA 2899149 C CA2899149 C CA 2899149C CA 2899149 A CA2899149 A CA 2899149A CA 2899149 A CA2899149 A CA 2899149A CA 2899149 C CA2899149 C CA 2899149C
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catalyst
layer
oxidation
scr
ammonia
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French (fr)
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CA2899149A1 (en
Inventor
Francesco Castellino
Viggo Lucassen Hansen
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Topsoe AS
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Haldor Topsoe AS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6482—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9463—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick
    • B01D53/9468—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on one brick in different layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/902—Multilayered catalyst
    • B01D2255/9022—Two layers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Exhaust Gas After Treatment (AREA)
CA2899149A 2013-02-14 2014-02-03 Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas Active CA2899149C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA201300091 2013-02-14
DKPA201300091 2013-02-14
PCT/EP2014/052043 WO2014124830A1 (en) 2013-02-14 2014-02-03 Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas

Publications (2)

Publication Number Publication Date
CA2899149A1 CA2899149A1 (en) 2014-08-21
CA2899149C true CA2899149C (en) 2020-03-24

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CA2899149A Active CA2899149C (en) 2013-02-14 2014-02-03 Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas

Country Status (11)

Country Link
US (2) US20150375207A1 (enExample)
EP (1) EP2956232B1 (enExample)
JP (1) JP6215361B2 (enExample)
KR (1) KR102186734B1 (enExample)
CN (1) CN104936679B (enExample)
BR (1) BR112015019557B1 (enExample)
CA (1) CA2899149C (enExample)
CL (1) CL2015002212A1 (enExample)
RU (1) RU2657082C2 (enExample)
WO (1) WO2014124830A1 (enExample)
ZA (1) ZA201505399B (enExample)

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CN107427771B (zh) * 2015-03-20 2021-07-02 托普索公司 催化的陶瓷烛式过滤器和清洁尾气或废气的方法
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DK180289B1 (en) * 2016-10-03 2020-10-07 Haldor Topsoe As Monolithic honeycomb oxidation catalyst and process for its preparation
CA3036953A1 (en) 2016-10-07 2018-04-12 Haldor Topsoe A/S A process for low temperature gas cleaning with ozone and a catalytic bag filter for use in the process
US10857504B2 (en) * 2017-03-31 2020-12-08 Toyota Motor Engineering & Manufacturing North America, Inc. Two-stage catalyst for removal of NOx from exhaust gas stream
ES2882548T3 (es) * 2017-04-26 2021-12-02 Haldor Topsoe As Método y sistema para la eliminación de materia particulada y compuestos nocivos de gas de combustión usando un filtro cerámico con un catalizador de SCR
EP3708253B1 (en) * 2017-06-09 2026-02-25 BASF Mobile Emissions Catalysts LLC Exhaust gas treatment systems
EP3533511A1 (en) * 2018-02-28 2019-09-04 Xpuris GmbH An exhaust gas treatment method and system arranged for treating exhaust gases collected from at least one foundry process
CN108993544B (zh) * 2018-08-03 2020-12-25 生态环境部华南环境科学研究所 一种去除低温高硫尾气中NOx和VOCs的催化剂及其制备和应用
EP3730210A1 (en) * 2019-04-26 2020-10-28 Umicore Ag & Co. Kg Catalyst ceramic candle filter for combined particulate removal and the selective catalytic reduction (scr) of nitrogen-oxides
WO2020043662A1 (en) * 2018-08-28 2020-03-05 Umicore Ag & Co. Kg Catalyst for use in the selective catalytic reduction (scr) of nitrogen oxides
KR102155628B1 (ko) * 2019-05-14 2020-09-14 이덕기 반도체 제조공정의 질소산화물 및 입자성 물질 제거장치
KR20220069934A (ko) 2019-09-27 2022-05-27 존슨 매세이 카탈리스츠 (저머니) 게엠베하 고정형 방출원 배기 가스에서 CO 및 NOx 둘 모두를 처리하기 위한 다기능 촉매 물품
KR20220070013A (ko) 2019-09-30 2022-05-27 바스프 코포레이션 탄화수소의 산화 및 NOx의 선택적 접촉 환원을 위한 다작용성 촉매
US11378278B2 (en) * 2019-12-11 2022-07-05 Umicore Ag & Co. Kg System and process for efficient SCR at high NO2 to NOx ratios
CN111482071B (zh) * 2020-04-14 2022-09-27 中钢集团天澄环保科技股份有限公司 一种烧结烟气多污染物协同净化及余热利用系统及工艺
CN115734815A (zh) 2020-06-11 2023-03-03 托普索公司 炭黑废气的催化氧化
KR102457079B1 (ko) * 2020-11-30 2022-10-21 한국에너지기술연구원 복합유해물질 동시 제거 시스템
KR102527339B1 (ko) 2021-01-06 2023-04-28 울산과학기술원 일산화탄소 탈수소효소 및 포름산 탈수소효소를 이용한 개미산의 제조 방법
KR102682231B1 (ko) 2021-02-17 2024-07-08 주식회사 엔바이온 질소화합물이 함유된 휘발성유기화합물 폐가스 처리 장치
CN113713608A (zh) * 2021-08-26 2021-11-30 复旦大学 一种用于CO和NOx同时去除的催化剂联用方法
CN113856693A (zh) * 2021-09-29 2021-12-31 北京工业大学 一种用于催化氧化CO的MoSnCo催化剂及其制备方法
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CN107427771B (zh) * 2015-03-20 2021-07-02 托普索公司 催化的陶瓷烛式过滤器和清洁尾气或废气的方法

Also Published As

Publication number Publication date
RU2015138782A (ru) 2017-03-20
KR20150116865A (ko) 2015-10-16
US10493436B2 (en) 2019-12-03
KR102186734B1 (ko) 2020-12-07
EP2956232A1 (en) 2015-12-23
BR112015019557A2 (pt) 2017-07-18
CN104936679B (zh) 2017-08-18
JP2016509956A (ja) 2016-04-04
EP2956232B1 (en) 2017-04-05
JP6215361B2 (ja) 2017-10-18
ZA201505399B (en) 2017-11-29
WO2014124830A1 (en) 2014-08-21
CL2015002212A1 (es) 2016-01-29
BR112015019557B1 (pt) 2021-06-29
US20180250661A1 (en) 2018-09-06
RU2657082C2 (ru) 2018-06-08
CN104936679A (zh) 2015-09-23
CA2899149A1 (en) 2014-08-21
US20150375207A1 (en) 2015-12-31

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