CA2864620A1 - Process for the production of acetic acid and dimethyl ether - Google Patents
Process for the production of acetic acid and dimethyl ether Download PDFInfo
- Publication number
- CA2864620A1 CA2864620A1 CA2864620A CA2864620A CA2864620A1 CA 2864620 A1 CA2864620 A1 CA 2864620A1 CA 2864620 A CA2864620 A CA 2864620A CA 2864620 A CA2864620 A CA 2864620A CA 2864620 A1 CA2864620 A1 CA 2864620A1
- Authority
- CA
- Canada
- Prior art keywords
- zeolite
- process according
- mol
- methyl acetate
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title claims abstract description 89
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 181
- 239000010457 zeolite Substances 0.000 claims abstract description 117
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 94
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 90
- 239000003054 catalyst Substances 0.000 claims abstract description 77
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 65
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims abstract description 57
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims abstract description 56
- -1 alkali metal cations Chemical class 0.000 claims abstract description 43
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 238000005341 cation exchange Methods 0.000 claims abstract description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 78
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 53
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 150000001340 alkali metals Chemical class 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 229910052792 caesium Inorganic materials 0.000 claims description 22
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 19
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- 230000006315 carbonylation Effects 0.000 claims description 5
- 238000005810 carbonylation reaction Methods 0.000 claims description 5
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 4
- 230000009849 deactivation Effects 0.000 description 40
- 238000006297 dehydration reaction Methods 0.000 description 25
- 230000018044 dehydration Effects 0.000 description 24
- 150000001768 cations Chemical class 0.000 description 20
- 238000006460 hydrolysis reaction Methods 0.000 description 20
- 239000007789 gas Substances 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 15
- 229910052739 hydrogen Inorganic materials 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- 230000007062 hydrolysis Effects 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
- 239000001307 helium Substances 0.000 description 5
- 229910052734 helium Inorganic materials 0.000 description 5
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 229910052701 rubidium Inorganic materials 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Inorganic materials [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 229940001007 aluminium phosphate Drugs 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 2
- 229910001603 clinoptilolite Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010931 ester hydrolysis Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001930 tungsten oxide Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- TUVYSBJZBYRDHP-UHFFFAOYSA-N acetic acid;methoxymethane Chemical compound COC.CC(O)=O TUVYSBJZBYRDHP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000001668 ameliorated effect Effects 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000009614 chemical analysis method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- RTHYXYOJKHGZJT-UHFFFAOYSA-N rubidium nitrate Chemical class [Rb+].[O-][N+]([O-])=O RTHYXYOJKHGZJT-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 229910052678 stilbite Inorganic materials 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12250048 | 2012-02-23 | ||
| EP12250048.1 | 2012-02-23 | ||
| PCT/EP2013/053570 WO2013124423A1 (en) | 2012-02-23 | 2013-02-22 | Process for the production of acetic acid and diemthyl ether |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2864620A1 true CA2864620A1 (en) | 2013-08-29 |
Family
ID=47827163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2864620A Abandoned CA2864620A1 (en) | 2012-02-23 | 2013-02-22 | Process for the production of acetic acid and dimethyl ether |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9365483B2 (enExample) |
| EP (1) | EP2817283A1 (enExample) |
| JP (1) | JP6082035B2 (enExample) |
| KR (1) | KR20140127265A (enExample) |
| CN (1) | CN104245651B (enExample) |
| BR (1) | BR112014020777A2 (enExample) |
| CA (1) | CA2864620A1 (enExample) |
| IN (1) | IN2014DN06993A (enExample) |
| MY (1) | MY170831A (enExample) |
| RU (1) | RU2630300C2 (enExample) |
| SG (1) | SG11201405101QA (enExample) |
| TW (1) | TWI572586B (enExample) |
| UA (1) | UA112887C2 (enExample) |
| WO (1) | WO2013124423A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104040764B (zh) | 2011-09-07 | 2018-02-27 | 24M技术公司 | 具有多孔集流体的半固体电极电池及其制造方法 |
| US9401501B2 (en) | 2012-05-18 | 2016-07-26 | 24M Technologies, Inc. | Electrochemical cells and methods of manufacturing the same |
| TW201538471A (zh) * | 2014-02-13 | 2015-10-16 | Bp Chem Int Ltd | 脫水－水解之製程及用於該製程之催化劑 |
| EP3131867A1 (en) | 2014-06-20 | 2017-02-22 | BP Chemicals Limited | Process for the co-production of acetic acid and dimethyl ether |
| UA120931C2 (uk) | 2014-06-20 | 2020-03-10 | Бп Кемікалз Лімітед | Спосіб очистки сумішей метилацетату |
| WO2015193188A1 (en) | 2014-06-20 | 2015-12-23 | Bp Chemicals Limited | Process for the co-production of acetic acid and dimethyl ether |
| JP2017521379A (ja) | 2014-06-20 | 2017-08-03 | ビーピー ケミカルズ リミテッドＢｐ Ｃｈｅｍｉｃａｌｓ Ｌｉｍｉｔｅｄ | 酢酸およびジメチルエーテルの併産用プロセス |
| RU2704319C2 (ru) * | 2014-06-20 | 2019-10-28 | Бп Кемикэлз Лимитед | Улучшенные каталитические характеристики в способах получения уксусной кислоты |
| JP2017531983A (ja) | 2014-10-13 | 2017-10-26 | ２４エム・テクノロジーズ・インコーポレイテッド２４Ｍ Ｔｅｃｈｎｏｌｏｇｉｅｓ， Ｉｎｃ． | 直列電池充電及び形成用のシステム及び方法 |
| CN112803057A (zh) | 2014-11-05 | 2021-05-14 | 24M技术公司 | 具有半固体电极的电化学电池及其制造方法 |
| AU2016280285B2 (en) | 2015-06-18 | 2021-07-01 | 24M Technologies, Inc. | Single pouch battery cells and methods of manufacture |
| EP3672928A4 (en) | 2017-08-24 | 2021-05-12 | Bp P.L.C. | PROCESS |
| WO2019037768A1 (en) | 2017-08-24 | 2019-02-28 | Bp P.L.C. | PROCESS |
| WO2019037766A1 (en) | 2017-08-24 | 2019-02-28 | Bp P.L.C. | PROCESS |
| WO2019037760A1 (en) | 2017-08-24 | 2019-02-28 | Bp P.L.C. | PROCESS |
| WO2019037769A1 (en) * | 2017-08-24 | 2019-02-28 | Bp P.L.C. | PROCESS |
| WO2020168548A1 (en) | 2019-02-22 | 2020-08-27 | Bp P.L.C. | Process |
| US12084409B2 (en) | 2019-02-22 | 2024-09-10 | Bp P.L.C. | Process for dehydrating methanol to dimethyl ether |
| US11742525B2 (en) | 2020-02-07 | 2023-08-29 | 24M Technologies, Inc. | Divided energy electrochemical cell systems and methods of producing the same |
| US12381277B2 (en) | 2020-06-17 | 2025-08-05 | 24M Technologies, Inc. | Electrochemical cells with flame retardant mechanism and methods of producing the same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4612387A (en) * | 1982-01-04 | 1986-09-16 | Air Products And Chemicals, Inc. | Production of carboxylic acids and esters |
| US6521783B1 (en) | 1998-01-29 | 2003-02-18 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for preparing oxygenates |
| KR100454091B1 (ko) * | 2002-12-11 | 2004-10-26 | 한국화학연구원 | 미정제 메탄올로부터 디메틸에테르의 제조방법 |
| KR100629939B1 (ko) * | 2004-10-15 | 2006-09-28 | 에스케이 주식회사 | 단열반응기에서 미정제 메탄올로부터 디메틸에테르의제조방법 |
| TWI465424B (zh) * | 2006-03-21 | 2014-12-21 | Bp Chem Int Ltd | 製造醋酸的方法 |
| KR100926800B1 (ko) * | 2008-03-28 | 2009-11-12 | 한국화학연구원 | 메탄올의 탈수반응에 의한 디메틸에테르 합성용 촉매, 이의제조방법 및 디메틸에테르의 제조방법 |
| KR100966706B1 (ko) * | 2008-06-18 | 2010-06-29 | 아주대학교산학협력단 | 메탄올로부터 디메틸에테르를 제조하는 방법 |
| BRPI0803764A2 (pt) | 2008-06-30 | 2010-03-09 | Petroleo Brasileiro Sa | sistema catalìtico e processo de sìntese direta do éter dimetìlico a partir do gás de sìntese |
| EP2292578A1 (en) * | 2009-09-03 | 2011-03-09 | BP Chemicals Limited | Process for producing acetic acid and dimethyl ether using a zeolite catalyst |
-
2013
- 2013-02-22 US US14/378,690 patent/US9365483B2/en active Active
- 2013-02-22 CA CA2864620A patent/CA2864620A1/en not_active Abandoned
- 2013-02-22 UA UAA201410284A patent/UA112887C2/uk unknown
- 2013-02-22 MY MYPI2014702346A patent/MY170831A/en unknown
- 2013-02-22 EP EP13707589.1A patent/EP2817283A1/en not_active Withdrawn
- 2013-02-22 SG SG11201405101QA patent/SG11201405101QA/en unknown
- 2013-02-22 RU RU2014138168A patent/RU2630300C2/ru active
- 2013-02-22 KR KR1020147023475A patent/KR20140127265A/ko not_active Withdrawn
- 2013-02-22 BR BR112014020777A patent/BR112014020777A2/pt not_active IP Right Cessation
- 2013-02-22 CN CN201380010905.0A patent/CN104245651B/zh active Active
- 2013-02-22 JP JP2014558124A patent/JP6082035B2/ja not_active Expired - Fee Related
- 2013-02-22 IN IN6993DEN2014 patent/IN2014DN06993A/en unknown
- 2013-02-22 WO PCT/EP2013/053570 patent/WO2013124423A1/en not_active Ceased
- 2013-02-22 TW TW102106270A patent/TWI572586B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TWI572586B (zh) | 2017-03-01 |
| MY170831A (en) | 2019-09-05 |
| JP6082035B2 (ja) | 2017-02-15 |
| RU2014138168A (ru) | 2016-04-10 |
| US20160031791A1 (en) | 2016-02-04 |
| RU2630300C2 (ru) | 2017-09-08 |
| EP2817283A1 (en) | 2014-12-31 |
| US9365483B2 (en) | 2016-06-14 |
| KR20140127265A (ko) | 2014-11-03 |
| CN104245651B (zh) | 2016-08-17 |
| TW201343620A (zh) | 2013-11-01 |
| SG11201405101QA (en) | 2014-09-26 |
| UA112887C2 (uk) | 2016-11-10 |
| IN2014DN06993A (enExample) | 2015-04-10 |
| CN104245651A (zh) | 2014-12-24 |
| JP2015512878A (ja) | 2015-04-30 |
| WO2013124423A1 (en) | 2013-08-29 |
| BR112014020777A2 (pt) | 2019-09-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9365483B2 (en) | Process for the production of acetic acid and dimethyl ether | |
| US9302253B2 (en) | Catalyst and process for the production of acetic acid and dimethyl ether | |
| CA2772092C (en) | Process for producing acetic acid and dimethyl ether using a zeolite catalyst | |
| CA2950375A1 (en) | Process for the co-production of acetic acid and dimethyl ether | |
| CA2950363A1 (en) | Improved catalytic performance in processes for preparing acetic acid | |
| CA2950361A1 (en) | Process for purifying methyl acetate mixtures | |
| CA2950358A1 (en) | Process for the co-production of acetic acid and dimethyl ether | |
| CA2950362A1 (en) | Process for the co-production of acetic acid and dimethyl ether | |
| RU2739320C2 (ru) | Способ карбонилирования для получения метилацетата | |
| EP3672930A1 (en) | Process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |
Effective date: 20190222 |