CA2862774C - Producing rigid polyurethane foams and rigid polyisocyanurate foams - Google Patents

Producing rigid polyurethane foams and rigid polyisocyanurate foams Download PDF

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Publication number
CA2862774C
CA2862774C CA2862774A CA2862774A CA2862774C CA 2862774 C CA2862774 C CA 2862774C CA 2862774 A CA2862774 A CA 2862774A CA 2862774 A CA2862774 A CA 2862774A CA 2862774 C CA2862774 C CA 2862774C
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Canada
Prior art keywords
acid
oil
mol
component
polyol
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CA2862774A
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English (en)
French (fr)
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CA2862774A1 (en
Inventor
Gunnar Kampf
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BASF SE
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BASF SE
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
CA2862774A 2012-01-02 2012-12-13 Producing rigid polyurethane foams and rigid polyisocyanurate foams Active CA2862774C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP12150016 2012-01-02
EP12150016.9 2012-01-02
EP12160927 2012-03-23
EP12160927.5 2012-03-23
PCT/EP2012/075347 WO2013102540A1 (de) 2012-01-02 2012-12-13 Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen

Publications (2)

Publication Number Publication Date
CA2862774A1 CA2862774A1 (en) 2013-07-11
CA2862774C true CA2862774C (en) 2020-08-18

Family

ID=47501145

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2862774A Active CA2862774C (en) 2012-01-02 2012-12-13 Producing rigid polyurethane foams and rigid polyisocyanurate foams

Country Status (19)

Country Link
EP (1) EP2800769B1 (https=)
JP (2) JP2015504113A (https=)
KR (1) KR102018406B1 (https=)
CN (1) CN104039856B (https=)
AU (1) AU2012364369B2 (https=)
BR (1) BR112014016275B1 (https=)
CA (1) CA2862774C (https=)
EA (1) EA027089B1 (https=)
ES (1) ES2560968T3 (https=)
HU (1) HUE027908T2 (https=)
IN (1) IN2014CN04925A (https=)
MX (1) MX339548B (https=)
MY (1) MY167781A (https=)
PH (1) PH12014501409A1 (https=)
PL (1) PL2800769T3 (https=)
RS (1) RS54603B1 (https=)
SG (1) SG11201403796RA (https=)
WO (1) WO2013102540A1 (https=)
ZA (1) ZA201405619B (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8895636B2 (en) 2012-01-02 2014-11-25 Basf Se Producing rigid polyurethane foams and rigid polyisocyanurate foams
KR102023224B1 (ko) * 2012-01-18 2019-09-19 바스프 에스이 경질 폴리우레탄 폼의 제조 방법
US9475220B2 (en) 2013-02-13 2016-10-25 Basf Se Process for producing composite elements
BR112016003497B1 (pt) * 2013-08-20 2020-10-20 Basf Se processo para a produção de espumas rígidas de poliuretano ou de poliisocianurato e mistura de poliol
EP3083784B1 (en) 2013-12-16 2020-06-24 Rockwool International A/S Polyisocyanurate foam composites and their production and use
EP3105274B1 (de) * 2014-02-11 2018-03-14 Basf Se Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen
CN104448186A (zh) * 2014-11-20 2015-03-25 镇江拜因诺生物科技有限公司 一种生物基聚氨酯泡沫保温材料
HUE044702T2 (hu) 2015-03-12 2019-11-28 Huntsman Adv Mat Licensing Switzerland Gmbh Poliol összetevõ pur-habok elõállításához
KR20180041665A (ko) * 2015-08-17 2018-04-24 코베스트로 도이칠란트 아게 촉매로서 시클릭 암모늄 염을 사용하는 이소시아네이트의 개질 방법
US20220227916A1 (en) * 2019-05-16 2022-07-21 Dow Global Technologies Llc Compatibilized blends of terephalate ester polyols and hydrocarbon blowing agents
WO2021012139A1 (en) * 2019-07-22 2021-01-28 Dow Global Technologies Llc Polyurethane compositions, products prepared with same and preparation methods thereof
PT4419574T (pt) 2021-10-18 2025-10-24 Basf Se Processo para a produção de espumas rígidas de poliisocianurato melhoradas à base de poliois poliéster aromáticos e poliois poliéter à base de óxido de etileno
CN116925317B (zh) * 2023-09-19 2023-11-28 南京赛弗尼电气有限公司 一种地面抬升用聚氨酯树脂组合物及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1003714B (de) 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
DE1097671B (de) * 1959-05-23 1961-01-19 Bayer Ag Verfahren zur Herstellung von Urethangruppen enthaltenden harten Schaumstoffen
US3399154A (en) * 1965-10-22 1968-08-27 Witco Chemical Corp Rigid polyurethane foams and polyesters for use therein
US5051528A (en) 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate
EP1058701B2 (en) 1998-02-23 2011-03-16 Stepan Company Low viscosity polyester polyols and methods for preparing same
DE102005041763A1 (de) * 2005-09-01 2007-03-08 Basf Ag Polyisocyanurat Hartschaum und Verfahren zur Herstellung
SI2340269T1 (sl) * 2008-10-15 2013-01-31 Basf Se Poliesterski polioli na bazi terefthalične kisline
EP2492297A1 (de) * 2011-02-23 2012-08-29 Basf Se Polyesterpolyole auf Basis aromatischer Dicarbonsäuren und daraus hergestellte Polyurethanhartschäume
KR102023224B1 (ko) * 2012-01-18 2019-09-19 바스프 에스이 경질 폴리우레탄 폼의 제조 방법

Also Published As

Publication number Publication date
JP2018111818A (ja) 2018-07-19
MX2014007821A (es) 2014-09-01
BR112014016275B1 (pt) 2020-10-27
PL2800769T3 (pl) 2016-06-30
IN2014CN04925A (https=) 2015-09-18
MY167781A (en) 2018-09-25
ZA201405619B (en) 2015-12-23
EP2800769B1 (de) 2015-12-09
RS54603B1 (sr) 2016-08-31
CN104039856A (zh) 2014-09-10
AU2012364369A1 (en) 2014-07-24
KR20140109475A (ko) 2014-09-15
PH12014501409A1 (en) 2014-09-22
SG11201403796RA (en) 2014-11-27
CA2862774A1 (en) 2013-07-11
EA027089B1 (ru) 2017-06-30
ES2560968T3 (es) 2016-02-23
MX339548B (es) 2016-05-30
BR112014016275A8 (pt) 2017-07-04
EP2800769A1 (de) 2014-11-12
JP2015504113A (ja) 2015-02-05
EA201491312A1 (ru) 2014-11-28
KR102018406B1 (ko) 2019-10-21
BR112014016275A2 (pt) 2017-06-13
WO2013102540A1 (de) 2013-07-11
HUE027908T2 (en) 2016-11-28
JP6567709B2 (ja) 2019-08-28
CN104039856B (zh) 2017-03-01
AU2012364369B2 (en) 2016-01-14

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