CA2854715C - Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen - Google Patents

Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen Download PDF

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Publication number
CA2854715C
CA2854715C CA2854715A CA2854715A CA2854715C CA 2854715 C CA2854715 C CA 2854715C CA 2854715 A CA2854715 A CA 2854715A CA 2854715 A CA2854715 A CA 2854715A CA 2854715 C CA2854715 C CA 2854715C
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Prior art keywords
mediator
hydrogen
oxygen
oxidised
electrode
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CA2854715A
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English (en)
French (fr)
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CA2854715A1 (en
Inventor
Leroy Cronin
Mark SYMES
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University of Glasgow
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University of Glasgow
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
CA2854715A 2011-11-08 2012-11-08 Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen Active CA2854715C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1119283.8A GB201119283D0 (en) 2011-11-08 2011-11-08 Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen
GB1119283.8 2011-11-08
PCT/GB2012/052784 WO2013068754A1 (en) 2011-11-08 2012-11-08 Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen

Publications (2)

Publication Number Publication Date
CA2854715A1 CA2854715A1 (en) 2013-05-16
CA2854715C true CA2854715C (en) 2021-04-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2854715A Active CA2854715C (en) 2011-11-08 2012-11-08 Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen

Country Status (8)

Country Link
US (1) US10604852B2 (https=)
EP (1) EP2776606B1 (https=)
JP (1) JP6101276B2 (https=)
KR (1) KR101988686B1 (https=)
CN (1) CN104053821B (https=)
CA (1) CA2854715C (https=)
GB (1) GB201119283D0 (https=)
WO (1) WO2013068754A1 (https=)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150077413A (ko) * 2012-09-17 2015-07-07 프레지던트 앤드 펠로우즈 오브 하바드 칼리지 인간의 움직임에 대한 보조를 위한 소프트 엑소슈트
CN109395224A (zh) 2013-06-19 2019-03-01 上海潓美医疗科技有限公司 保健气体产生器
CN105308782A (zh) * 2013-06-20 2016-02-03 加利福尼亚大学董事会 自偏压并可持续的微生物电氢解装置
GB201416062D0 (en) * 2014-09-11 2014-10-29 Univ The Glasgow Hydrogen generation
JP6388820B2 (ja) * 2014-11-10 2018-09-12 国立研究開発法人産業技術総合研究所 光エネルギーの利用方法および光エネルギーの利用装置
JP6418906B2 (ja) * 2014-11-10 2018-11-07 国立研究開発法人産業技術総合研究所 光エネルギーの利用方法および光エネルギーの利用装置
DE102015206288A1 (de) * 2015-04-09 2016-10-13 Robert Bosch Gmbh Vorrichtung, System und Verfahren zum Gewinnen von Wasserstoff aus Wasser unter Verwendung eines Arbeitsstoffs
CN105420748B (zh) * 2015-11-18 2018-01-12 复旦大学 一种基于三电极体系的两步法电解水制氢的方法及装置
CN105463497B (zh) * 2015-11-18 2018-01-12 复旦大学 一种可以电解水制取氢气的电池装置
EP3402912A4 (en) * 2016-01-15 2019-10-23 Skyre, Inc. HYDROGEN SYSTEM AND METHOD OF OPERATION
CN105821436B (zh) * 2016-05-09 2018-07-24 复旦大学 一种基于三电极体系的双电解槽两步法氯碱电解方法及装置
JP2018119204A (ja) * 2016-06-16 2018-08-02 パナソニックＩｐマネジメント株式会社 水素脱離方法および脱水素装置
WO2019118450A1 (en) * 2017-12-11 2019-06-20 Arizona Board Of Regents On Behalf Of The University Of Arizona Enhanced water electrolysis with protic co-catalysts
CN107051565A (zh) * 2017-05-24 2017-08-18 中国科学院化学研究所 一种高性能碱式碳酸盐类电解水催化剂及其制备方法与应用
CN107815699B (zh) * 2017-11-10 2019-03-19 上海应用技术大学 一种POMs-C复合材料、制备方法和应用
GB201801170D0 (en) 2018-01-24 2018-03-07 Univ Court Univ Of Glasgow Use of polyoxometalate mediators
IL258252A (en) * 2018-03-20 2018-06-28 Technion Res & Development Found Ltd System and method for generation of gases
FR3079529B1 (fr) 2018-04-03 2024-04-26 Ergosup Procede electrochimique de production d'hydrogene gazeux sous pression par electrolyse puis par depolarisation
FR3079530B1 (fr) 2018-04-03 2024-04-26 Ergosup Procede electrochimique de production d'hydrogene gazeux sous pression par electrolyse puis par conversion electrochimique
WO2020033018A2 (en) * 2018-04-12 2020-02-13 University Of Houston System High performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting
CN109321936B (zh) * 2018-11-29 2020-06-02 厦门大学 一种基于液流氧化还原媒介分步电解水制氢的装置和方法
DE102019104401A1 (de) * 2019-01-22 2020-07-23 Deutsches Zentrum für Luft- und Raumfahrt e.V. Elektrolyseur und Verfahren zum Aufspalten von Wasser
US11203812B2 (en) * 2019-02-22 2021-12-21 New York University Methods and electrochemical cells for redox mediated hydrogen production
US11313044B2 (en) * 2019-08-20 2022-04-26 Deutsches Zentrum fuer Loft- und Raumfahrt e.V. Electrolyzer and method for splitting water
KR102250826B1 (ko) 2019-09-20 2021-05-11 (주)골드앤스노우 월드와이드 수소 기체 발생 조성물 및 수소 기체 포집 나노구조체
DE102020110633A1 (de) * 2020-04-20 2021-10-21 Deutsches Zentrum für Luft- und Raumfahrt e.V. Verfahren und Apparatur zur elektrochemisch unterstützten thermochemischen Spaltung von Wasser und Kohlendioxid
IL298376A (en) * 2020-05-20 2023-01-01 Harvard College Forward osmosis driven by electrolysis
KR102895243B1 (ko) * 2020-06-22 2025-12-03 현대자동차주식회사 수전해 시스템
CN113026044B (zh) * 2021-01-28 2022-01-07 江西津晶智美环保科技有限公司 一种三室二电源全分解水电解装置及方法
AU2022230462B2 (en) * 2021-03-01 2025-04-03 Verdagy, Inc. Systems and methods to make hydrogen gas
JP2023016252A (ja) * 2021-07-21 2023-02-02 株式会社日立製作所 光化学反応システム及び光化学反応方法
WO2023056292A2 (en) * 2021-09-28 2023-04-06 Verdagy, Inc. Systems and methods to make hydrogen gas with a steady-state ph differential
CN114032571B (zh) * 2021-10-13 2022-12-09 西安交通大学 一种耦合分步电解水装置和水系电池的一体化系统与方法
WO2024013308A2 (en) 2022-07-13 2024-01-18 The University Court Of The University Of Glasgow Method of reducing nitro compounds
CN116609408B (zh) * 2023-04-28 2026-03-24 中国科学院宁波材料技术与工程研究所 一种原位测氢的电还原-电氧化复合电极及其制备方法与应用
WO2025080916A2 (en) * 2023-10-12 2025-04-17 Regents Of The University Of Michigan Method for reversible ph-swing flow cells for co2 capture
WO2025132521A1 (en) 2023-12-19 2025-06-26 Fundación Centro De Investigación Cooperativa De Energías Alternativas Cic Energigune Fundazioa Electrochemical system comprising a gallium redox mediator and uses thereof
WO2025245447A1 (en) * 2024-05-24 2025-11-27 Massachusetts Institute Of Technology Electrochemical hydrogen pumping coupled with catalytic membrane reactor and its applications

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1602963A (en) * 1977-04-13 1981-11-18 Nat Res Dev Catalytic process for photo-oxidation of water
US4492743A (en) * 1982-10-15 1985-01-08 Standard Oil Company (Indiana) Multilayer photoelectrodes and photovoltaic cells
JPS6447890A (en) * 1987-08-13 1989-02-22 Kenzo Yamaguchi Electrolytic synthesis method
US5389356A (en) * 1993-01-05 1995-02-14 Utah State University Foundation Compounds and methods for generating oxygen free radicals used in general oxidation and reduction reactions
US7387719B2 (en) * 2001-04-24 2008-06-17 Scimist, Inc. Mediated electrochemical oxidation of biological waste materials
CN1237208C (zh) * 2001-05-02 2006-01-18 日本科技股份有限公司 氢－氧气体发生装置和使用该装置的氢－氧气体发生方法
US6712949B2 (en) * 2001-07-22 2004-03-30 The Electrosynthesis Company, Inc. Electrochemical synthesis of hydrogen peroxide
WO2003095116A2 (en) * 2001-10-22 2003-11-20 The C & M Group, Llc Mediated electrochemical oxidation of organic waste materials
WO2003091165A1 (en) * 2002-04-26 2003-11-06 The C & M Group, Llc Mediated electrochemical oxidation process used as a hydrogen fuel generator
JP2007516577A (ja) * 2003-05-30 2007-06-21 ザ アリゾナ ボード オブ リージェンツ アクティング オン ビハーフ オブ アリゾナ ステート ユニバーシティ 水素および他の物質の産生における光生物燃料電池の使用方法
US7208244B2 (en) 2003-10-15 2007-04-24 Auburn University Di-ruthenium-substituted polyoxometalate electrocatalyst and method of oxygen generation
JP5114823B2 (ja) * 2004-05-31 2013-01-09 日産自動車株式会社 光電気化学電池
US20070012578A1 (en) 2005-06-30 2007-01-18 Akzo Nobel N.V. Chemical process
JP2009505904A (ja) * 2005-08-31 2009-02-12 バッテル メモリアル インスティテュート 電力デバイスおよび酸素生成装置
GB0608079D0 (en) 2006-04-25 2006-05-31 Acal Energy Ltd Fuel cells
EP2188209A2 (en) 2007-09-07 2010-05-26 Binyomin A. Cohen Apparatus for producing oxygen and/or hydrogen gas
EP2151512A1 (en) 2008-08-01 2010-02-10 Total Petrochemicals Research Feluy Fibers and nonwovens with increased surface roughness.
FI121928B (fi) * 2008-10-08 2011-06-15 Teknillinen Korkeakoulu Sähköntuottojärjestelmä
US8822367B2 (en) * 2009-03-17 2014-09-02 Emory University Polyoxometalate water oxidation catalysts and methods of use thereof
WO2011053250A1 (en) * 2009-10-26 2011-05-05 Agency For Science, Technology And Research Photoelectrode with a polymer layer
GB201017421D0 (en) * 2010-10-14 2010-12-01 Acal Energy Ltd Cell

Also Published As

Publication number Publication date
CA2854715A1 (en) 2013-05-16
JP6101276B2 (ja) 2017-03-22
KR101988686B1 (ko) 2019-06-12
WO2013068754A1 (en) 2013-05-16
JP2014532812A (ja) 2014-12-08
EP2776606A1 (en) 2014-09-17
KR20140093706A (ko) 2014-07-28
US20140318979A1 (en) 2014-10-30
CN104053821B (zh) 2018-09-04
GB201119283D0 (en) 2011-12-21
EP2776606B1 (en) 2020-03-25
CN104053821A (zh) 2014-09-17
US10604852B2 (en) 2020-03-31

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