CA2817783C - Blowing catalyst - Google Patents

Blowing catalyst Download PDF

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Publication number
CA2817783C
CA2817783C CA2817783A CA2817783A CA2817783C CA 2817783 C CA2817783 C CA 2817783C CA 2817783 A CA2817783 A CA 2817783A CA 2817783 A CA2817783 A CA 2817783A CA 2817783 C CA2817783 C CA 2817783C
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CA
Canada
Prior art keywords
group
catalyst
component
chosen
isocyanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2817783A
Other languages
English (en)
French (fr)
Other versions
CA2817783A1 (en
Inventor
Zsolt Gaspar
Heiko Heinrich Humbert
Gabor Felber
Attila Gaspar
Robert Allison Grigsby, Jr.
Imre Kordas
Petra Emma Vanderstraeten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Corp Hungary Zrt
Huntsman International LLC
Original Assignee
Huntsman Corp Hungary Zrt
Huntsman International LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Corp Hungary Zrt, Huntsman International LLC filed Critical Huntsman Corp Hungary Zrt
Publication of CA2817783A1 publication Critical patent/CA2817783A1/en
Application granted granted Critical
Publication of CA2817783C publication Critical patent/CA2817783C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/06—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
    • C07C217/08—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/42—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having etherified hydroxy groups and at least two amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1841—Catalysts containing secondary or tertiary amines or salts thereof having carbonyl groups which may be linked to one or more nitrogen or oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2290/00—Compositions for creating anti-fogging

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
CA2817783A 2010-11-29 2011-11-22 Blowing catalyst Active CA2817783C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US41755110P 2010-11-29 2010-11-29
US61/417,551 2010-11-29
EP11462001.6 2011-01-07
EP11462001 2011-01-07
PCT/EP2011/070611 WO2012072441A1 (en) 2010-11-29 2011-11-22 Blowing catalyst

Publications (2)

Publication Number Publication Date
CA2817783A1 CA2817783A1 (en) 2012-06-07
CA2817783C true CA2817783C (en) 2018-10-02

Family

ID=44063508

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2817783A Active CA2817783C (en) 2010-11-29 2011-11-22 Blowing catalyst

Country Status (7)

Country Link
US (1) US9382397B2 (enExample)
EP (1) EP2646489B1 (enExample)
JP (1) JP5726318B2 (enExample)
CN (1) CN103403051B (enExample)
CA (1) CA2817783C (enExample)
MX (1) MX358616B (enExample)
WO (1) WO2012072441A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013201829A1 (de) 2013-02-05 2014-08-07 Evonik Industries Ag Amine, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215382A1 (de) 2014-08-05 2016-02-11 Evonik Degussa Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
DE102014215387B4 (de) 2014-08-05 2020-06-10 Evonik Operations Gmbh Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen
WO2017104600A1 (ja) * 2015-12-16 2017-06-22 株式会社ブリヂストン 軟質ポリウレタンフォーム、及びシート用パッド
CN110317311A (zh) * 2018-03-28 2019-10-11 科思创德国股份有限公司 低气味的硬质聚氨酯泡沫
WO2019222127A1 (en) 2018-05-16 2019-11-21 Huntsman Petrochemical Llc Quaternary ammonium hydroxides of polyamines
KR20230104234A (ko) * 2020-11-06 2023-07-07 헌츠만 페트로케미칼 엘엘씨 2차 및 3차 아민의 제조 방법
KR20230169302A (ko) * 2021-04-13 2023-12-15 헌츠만 페트로케미칼 엘엘씨 경질 폼 시스템을 위한 모르폴린 촉매의 제조 방법 및 이의 용도
US11884000B2 (en) 2021-08-27 2024-01-30 Carbon, Inc. One part, catalyst containing, moisture curable dual cure resins for additive manufacturing
CA3262881A1 (en) 2022-07-28 2024-02-01 Evonik Operations Gmbh METHOD FOR PREPARING A POLYURETHANE FOAM FOR A FLEXIBLE MIXING SHEET
JP2026502423A (ja) * 2022-11-29 2026-01-23 ベクトン・ディキンソン・アンド・カンパニー 可溶化剤、色素、及びバイオ医薬品のためのポリ（エチレングリコール）－ポリオキサゾリン（ｐｅｏｚ）コポリマー

Family Cites Families (15)

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DE848825C (de) 1950-12-14 1952-09-08 Nordmark Werke Gmbh Verfahren zur Herstellung von AEthergruppen enthaltenden tertiaeren und quaternaeren Triaminen
DE2618280A1 (de) * 1976-04-27 1977-11-17 Bayer Ag Neue katalysatoren fuer die herstellung von polyurethanschaumstoffen
CA2020726C (en) * 1989-07-10 1999-01-05 Hiroumi Izaiku Formal compounds, fuel oil additives, and fuel oil compositions
US5756558A (en) * 1996-07-03 1998-05-26 Air Products And Chemicals, Inc. Hydroxyalkylbis(aminoethyl) ether compositions for the production of polyurethanes
JP3860694B2 (ja) * 1999-12-17 2006-12-20 花王株式会社 ポリウレタンフォームの製造法
US6759447B1 (en) * 2003-01-06 2004-07-06 Air Products And Chemicals, Inc. Physical properties of polyurethane foams using tertiary amino alkyl amide catalysts
US6858654B1 (en) * 2003-10-27 2005-02-22 Air Products And Chemicals, Inc. Catalyst blends for producing low thermal desorption polyurethane foams
US20060235098A1 (en) * 2005-04-19 2006-10-19 Burdeniuc Juan J Polyurethane foams made with blowing catalyst compositions containing primary hydroxyl groups and high ethylenediamine backbones
JP4948853B2 (ja) * 2006-03-06 2012-06-06 花王株式会社 硬質ポリウレタンフォームの製造法
US8637584B2 (en) * 2007-05-25 2014-01-28 Air Products And Chemicals, Inc. Polyester polyol-containing polyurethane systems having improved hydrolytic stability
EP2162480A4 (en) * 2007-06-19 2014-01-22 Huntsman Petrochemical Llc REACTIVE AMINE CATALYSTS FOR POLYURETHANE FOAM
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US7872055B2 (en) * 2008-12-11 2011-01-18 Air Products and Chenicals, Inc. Catalyst composition for water blown, low density, rigid polyurethane foam
WO2010139520A1 (en) * 2009-06-02 2010-12-09 Huntsman Corporation Hungary Zrt. A Method for Separating N,N-Dialkylbisaminoalkylether from Mixtures Comprising N,N-Dialkylbisaminoalkylether and at least one of N,N,N'-Trialkylbisaminoalkylether and N,N,N',N'-Tetraalkylbisaminoalkylether
US8664445B2 (en) * 2009-06-02 2014-03-04 Huntsman International Llc Method for providing a secondary or tertiary amine

Also Published As

Publication number Publication date
CN103403051A (zh) 2013-11-20
JP2013544933A (ja) 2013-12-19
JP5726318B2 (ja) 2015-05-27
EP2646489B1 (en) 2018-07-04
CA2817783A1 (en) 2012-06-07
MX2013005878A (es) 2013-10-25
US9382397B2 (en) 2016-07-05
MX358616B (es) 2018-08-29
US20130261199A1 (en) 2013-10-03
CN103403051B (zh) 2015-10-21
WO2012072441A1 (en) 2012-06-07
EP2646489A1 (en) 2013-10-09

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