CN103403051B - 发泡催化剂 - Google Patents
发泡催化剂 Download PDFInfo
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- CN103403051B CN103403051B CN201180066563.5A CN201180066563A CN103403051B CN 103403051 B CN103403051 B CN 103403051B CN 201180066563 A CN201180066563 A CN 201180066563A CN 103403051 B CN103403051 B CN 103403051B
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- component
- och
- ethyl
- isocyanate
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- 239000003054 catalyst Substances 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 51
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 38
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 38
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 20
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 16
- 238000001879 gelation Methods 0.000 claims abstract description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 14
- 239000001257 hydrogen Substances 0.000 claims abstract description 14
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 12
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- 239000006260 foam Substances 0.000 claims description 35
- 150000001412 amines Chemical class 0.000 claims description 34
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
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- 238000000034 method Methods 0.000 claims description 10
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C217/06—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
- C07C217/08—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C217/42—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having etherified hydroxy groups and at least two amino groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1841—Catalysts containing secondary or tertiary amines or salts thereof having carbonyl groups which may be linked to one or more nitrogen or oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2290/00—Compositions for creating anti-fogging
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41755110P | 2010-11-29 | 2010-11-29 | |
| US61/417551 | 2010-11-29 | ||
| EP11462001 | 2011-01-07 | ||
| EP11462001.6 | 2011-01-07 | ||
| PCT/EP2011/070611 WO2012072441A1 (en) | 2010-11-29 | 2011-11-22 | Blowing catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103403051A CN103403051A (zh) | 2013-11-20 |
| CN103403051B true CN103403051B (zh) | 2015-10-21 |
Family
ID=44063508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180066563.5A Active CN103403051B (zh) | 2010-11-29 | 2011-11-22 | 发泡催化剂 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9382397B2 (enExample) |
| EP (1) | EP2646489B1 (enExample) |
| JP (1) | JP5726318B2 (enExample) |
| CN (1) | CN103403051B (enExample) |
| CA (1) | CA2817783C (enExample) |
| MX (1) | MX358616B (enExample) |
| WO (1) | WO2012072441A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102013201829A1 (de) | 2013-02-05 | 2014-08-07 | Evonik Industries Ag | Amine, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215387B4 (de) | 2014-08-05 | 2020-06-10 | Evonik Operations Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215382A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| JPWO2017104600A1 (ja) * | 2015-12-16 | 2018-10-04 | 株式会社ブリヂストン | 軟質ポリウレタンフォーム、及びシート用パッド |
| CN110317311A (zh) * | 2018-03-28 | 2019-10-11 | 科思创德国股份有限公司 | 低气味的硬质聚氨酯泡沫 |
| US11801500B2 (en) | 2018-05-16 | 2023-10-31 | Huntsman Petrochemical Llc | Methods for producing tertiary amine catalysts and uses of such |
| US20250333372A1 (en) * | 2020-11-06 | 2025-10-30 | Huntsman Petrochemical Llc | Method for producing secondary and tertiary amines |
| BR112023021217A2 (pt) * | 2021-04-13 | 2023-12-19 | Huntsman Petrochemical Llc | Método de produção de catalisadores de morfolina para sistemas de espuma rígida e usos dos mesmos |
| US11884000B2 (en) | 2021-08-27 | 2024-01-30 | Carbon, Inc. | One part, catalyst containing, moisture curable dual cure resins for additive manufacturing |
| EP4562070A1 (en) | 2022-07-28 | 2025-06-04 | Evonik Operations GmbH | Method for preparing flexible slabstock polyurethane foam |
| CN120051508A (zh) * | 2022-11-29 | 2025-05-27 | 贝克顿·迪金森公司 | 聚乙二醇-聚噁唑啉(peoz)共聚物用于溶解药物、染料和生物制药 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2618280A1 (de) * | 1976-04-27 | 1977-11-17 | Bayer Ag | Neue katalysatoren fuer die herstellung von polyurethanschaumstoffen |
| CN1854163A (zh) * | 2005-04-19 | 2006-11-01 | 气体产品与化学公司 | 使用包含伯羟基基团和高乙二胺主链的发泡催化剂组合物制备的聚氨酸泡沫 |
| WO2010139520A1 (en) * | 2009-06-02 | 2010-12-09 | Huntsman Corporation Hungary Zrt. | A Method for Separating N,N-Dialkylbisaminoalkylether from Mixtures Comprising N,N-Dialkylbisaminoalkylether and at least one of N,N,N'-Trialkylbisaminoalkylether and N,N,N',N'-Tetraalkylbisaminoalkylether |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE848825C (de) | 1950-12-14 | 1952-09-08 | Nordmark Werke Gmbh | Verfahren zur Herstellung von AEthergruppen enthaltenden tertiaeren und quaternaeren Triaminen |
| CA2020726C (en) | 1989-07-10 | 1999-01-05 | Hiroumi Izaiku | Formal compounds, fuel oil additives, and fuel oil compositions |
| US5756558A (en) * | 1996-07-03 | 1998-05-26 | Air Products And Chemicals, Inc. | Hydroxyalkylbis(aminoethyl) ether compositions for the production of polyurethanes |
| JP3860694B2 (ja) * | 1999-12-17 | 2006-12-20 | 花王株式会社 | ポリウレタンフォームの製造法 |
| US6759447B1 (en) * | 2003-01-06 | 2004-07-06 | Air Products And Chemicals, Inc. | Physical properties of polyurethane foams using tertiary amino alkyl amide catalysts |
| US6858654B1 (en) * | 2003-10-27 | 2005-02-22 | Air Products And Chemicals, Inc. | Catalyst blends for producing low thermal desorption polyurethane foams |
| JP4948853B2 (ja) * | 2006-03-06 | 2012-06-06 | 花王株式会社 | 硬質ポリウレタンフォームの製造法 |
| US8637584B2 (en) * | 2007-05-25 | 2014-01-28 | Air Products And Chemicals, Inc. | Polyester polyol-containing polyurethane systems having improved hydrolytic stability |
| CA2689510C (en) * | 2007-06-19 | 2015-04-21 | Huntsman Petrochemical Corporation | Reactive amine catalysts for polyurethane foam |
| JP5583112B2 (ja) * | 2008-03-20 | 2014-09-03 | ハンツマン ペトロケミカル エルエルシー | アミン中のアルデヒドの還元 |
| US7872055B2 (en) | 2008-12-11 | 2011-01-18 | Air Products and Chenicals, Inc. | Catalyst composition for water blown, low density, rigid polyurethane foam |
| US8664445B2 (en) | 2009-06-02 | 2014-03-04 | Huntsman International Llc | Method for providing a secondary or tertiary amine |
-
2011
- 2011-11-22 CN CN201180066563.5A patent/CN103403051B/zh active Active
- 2011-11-22 CA CA2817783A patent/CA2817783C/en active Active
- 2011-11-22 EP EP11784707.9A patent/EP2646489B1/en active Active
- 2011-11-22 WO PCT/EP2011/070611 patent/WO2012072441A1/en not_active Ceased
- 2011-11-22 MX MX2013005878A patent/MX358616B/es active IP Right Grant
- 2011-11-22 US US13/990,070 patent/US9382397B2/en active Active
- 2011-11-22 JP JP2013540317A patent/JP5726318B2/ja active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2618280A1 (de) * | 1976-04-27 | 1977-11-17 | Bayer Ag | Neue katalysatoren fuer die herstellung von polyurethanschaumstoffen |
| CN1854163A (zh) * | 2005-04-19 | 2006-11-01 | 气体产品与化学公司 | 使用包含伯羟基基团和高乙二胺主链的发泡催化剂组合物制备的聚氨酸泡沫 |
| WO2010139520A1 (en) * | 2009-06-02 | 2010-12-09 | Huntsman Corporation Hungary Zrt. | A Method for Separating N,N-Dialkylbisaminoalkylether from Mixtures Comprising N,N-Dialkylbisaminoalkylether and at least one of N,N,N'-Trialkylbisaminoalkylether and N,N,N',N'-Tetraalkylbisaminoalkylether |
Also Published As
| Publication number | Publication date |
|---|---|
| US20130261199A1 (en) | 2013-10-03 |
| EP2646489A1 (en) | 2013-10-09 |
| CA2817783A1 (en) | 2012-06-07 |
| WO2012072441A1 (en) | 2012-06-07 |
| MX358616B (es) | 2018-08-29 |
| JP2013544933A (ja) | 2013-12-19 |
| MX2013005878A (es) | 2013-10-25 |
| US9382397B2 (en) | 2016-07-05 |
| EP2646489B1 (en) | 2018-07-04 |
| CN103403051A (zh) | 2013-11-20 |
| JP5726318B2 (ja) | 2015-05-27 |
| CA2817783C (en) | 2018-10-02 |
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