CA2783663C - A continuous process for the carbonylation of ethylene - Google Patents

A continuous process for the carbonylation of ethylene Download PDF

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Publication number
CA2783663C
CA2783663C CA2783663A CA2783663A CA2783663C CA 2783663 C CA2783663 C CA 2783663C CA 2783663 A CA2783663 A CA 2783663A CA 2783663 A CA2783663 A CA 2783663A CA 2783663 C CA2783663 C CA 2783663C
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CA
Canada
Prior art keywords
ethylene
bis
liquid phase
atoms
benzene
Prior art date
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Active
Application number
CA2783663A
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English (en)
French (fr)
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CA2783663A1 (en
Inventor
Graham Ronald Eastham
Neil Tindale
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Lucite International UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite International UK Ltd filed Critical Lucite International UK Ltd
Publication of CA2783663A1 publication Critical patent/CA2783663A1/en
Application granted granted Critical
Publication of CA2783663C publication Critical patent/CA2783663C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2783663A 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene Active CA2783663C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0921875.1A GB0921875D0 (en) 2009-12-15 2009-12-15 A continuous process for the carbonylation of ethylene
GB0921875.1 2009-12-15
PCT/GB2010/052095 WO2011073655A1 (en) 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene

Publications (2)

Publication Number Publication Date
CA2783663A1 CA2783663A1 (en) 2011-06-23
CA2783663C true CA2783663C (en) 2019-01-08

Family

ID=41667108

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2783663A Active CA2783663C (en) 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene

Country Status (17)

Country Link
US (1) US8785678B2 (https=)
EP (1) EP2513031B1 (https=)
JP (1) JP5826764B2 (https=)
KR (1) KR101814054B1 (https=)
CN (1) CN102741213B (https=)
AU (1) AU2010332503B2 (https=)
BR (1) BR112012014485B1 (https=)
CA (1) CA2783663C (https=)
EA (1) EA021605B1 (https=)
ES (1) ES2701014T3 (https=)
GB (1) GB0921875D0 (https=)
MX (1) MX2012006716A (https=)
MY (1) MY161937A (https=)
SG (1) SG181519A1 (https=)
TW (1) TWI506017B (https=)
WO (1) WO2011073655A1 (https=)
ZA (1) ZA201204315B (https=)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
CA3092028C (en) 2012-01-13 2022-08-30 Lummus Technology Llc Process for separating hydrocarbon compounds
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
SG11201601587UA (en) 2013-09-30 2016-04-28 Dow Global Technologies Llc Gas phase production of alkyl alkanoate
US10047020B2 (en) 2013-11-27 2018-08-14 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
EP3092286A4 (en) 2014-01-08 2017-08-09 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA2935946C (en) 2014-01-09 2022-05-03 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
EP3786138A1 (en) 2015-10-16 2021-03-03 Lummus Technology LLC Oxidative coupling of methane
EP4071131A1 (en) 2016-04-13 2022-10-12 Lummus Technology LLC Apparatus and method for exchanging heat
WO2018118105A1 (en) 2016-12-19 2018-06-28 Siluria Technologies, Inc. Methods and systems for performing chemical separations
KR20200034961A (ko) 2017-05-23 2020-04-01 루머스 테크놀로지 엘엘씨 메탄의 산화적 커플링 공정의 통합
EP3649097A4 (en) 2017-07-07 2021-03-24 Lummus Technology LLC SYSTEMS AND PROCESSES FOR THE OXIDATIVE COUPLING OF METHANE
CN110586102B (zh) * 2019-08-21 2022-09-27 中山大学 一种类杂原子催化剂的制备方法
CN114409541A (zh) * 2020-10-28 2022-04-29 上海浦景化工技术股份有限公司 一种乙烯羰基化制丙酸酯类的系统
US12227466B2 (en) 2021-08-31 2025-02-18 Lummus Technology Llc Methods and systems for performing oxidative coupling of methane
CN116099455B (zh) * 2023-04-12 2023-07-07 西南化工研究设计院有限公司 一种基于多釜串联的羰基化反应系统及方法

Family Cites Families (25)

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EP0055875B1 (en) 1981-01-06 1986-08-20 Shell Internationale Researchmaatschappij B.V. Process for the carbonylation of olefins
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
GB8531624D0 (en) 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
KR880007426A (ko) 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
KR0144567B1 (ko) 1989-03-03 1998-07-15 오노 알버어스 카르보닐화촉매시스템
GB8917579D0 (en) * 1989-08-01 1989-09-13 Shell Int Research Preparation of alkyl propionates
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
SG45352A1 (en) 1991-01-15 1998-01-16 Shell Int Research Carbonylation of olefins
ES2077337T3 (es) 1991-01-15 1995-11-16 Shell Int Research Procedimiento para la carbonilacion de olefinas.
EP0499329B1 (en) 1991-02-15 1994-05-04 Shell Internationale Researchmaatschappij B.V. Carbonylation catalyst system
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
GB9705699D0 (en) * 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
MY127358A (en) 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10228293A1 (de) 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
CA2476736C (en) 2002-02-19 2012-06-05 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
CA2498293C (en) 2002-09-12 2012-05-22 Lucite International Uk Limited Catalyst system comprising chelating ligand and group viiib metal
CA2526348A1 (en) 2003-05-22 2004-12-02 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of a conjugated diene
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
WO2005082830A1 (en) 2004-02-26 2005-09-09 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of ethylenically or acetylenically unsaturated compounds
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system

Also Published As

Publication number Publication date
BR112012014485A2 (pt) 2016-08-16
EP2513031A1 (en) 2012-10-24
JP5826764B2 (ja) 2015-12-02
EA201290507A1 (ru) 2013-01-30
US20120277474A1 (en) 2012-11-01
BR112012014485B1 (pt) 2018-12-18
US8785678B2 (en) 2014-07-22
MY161937A (en) 2017-05-15
ES2701014T3 (es) 2019-02-20
EA021605B1 (ru) 2015-07-30
AU2010332503A1 (en) 2012-07-19
JP2013513654A (ja) 2013-04-22
GB0921875D0 (en) 2010-01-27
CN102741213A (zh) 2012-10-17
CA2783663A1 (en) 2011-06-23
AU2010332503B2 (en) 2014-11-20
MX2012006716A (es) 2012-11-29
KR20120107494A (ko) 2012-10-02
WO2011073655A1 (en) 2011-06-23
CN102741213B (zh) 2015-05-27
EP2513031B1 (en) 2018-08-22
TWI506017B (zh) 2015-11-01
KR101814054B1 (ko) 2018-01-02
TW201136889A (en) 2011-11-01
ZA201204315B (en) 2013-01-31
SG181519A1 (en) 2012-07-30

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