CA2783663C - A continuous process for the carbonylation of ethylene - Google Patents

A continuous process for the carbonylation of ethylene Download PDF

Info

Publication number
CA2783663C
CA2783663C CA2783663A CA2783663A CA2783663C CA 2783663 C CA2783663 C CA 2783663C CA 2783663 A CA2783663 A CA 2783663A CA 2783663 A CA2783663 A CA 2783663A CA 2783663 C CA2783663 C CA 2783663C
Authority
CA
Canada
Prior art keywords
ethylene
bis
liquid phase
atoms
benzene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2783663A
Other languages
English (en)
French (fr)
Other versions
CA2783663A1 (en
Inventor
Graham Ronald Eastham
Neil Tindale
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Lucite International UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite International UK Ltd filed Critical Lucite International UK Ltd
Publication of CA2783663A1 publication Critical patent/CA2783663A1/en
Application granted granted Critical
Publication of CA2783663C publication Critical patent/CA2783663C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2783663A 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene Active CA2783663C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0921875.1A GB0921875D0 (en) 2009-12-15 2009-12-15 A continuous process for the carbonylation of ethylene
GB0921875.1 2009-12-15
PCT/GB2010/052095 WO2011073655A1 (en) 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene

Publications (2)

Publication Number Publication Date
CA2783663A1 CA2783663A1 (en) 2011-06-23
CA2783663C true CA2783663C (en) 2019-01-08

Family

ID=41667108

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2783663A Active CA2783663C (en) 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene

Country Status (17)

Country Link
US (1) US8785678B2 (https=)
EP (1) EP2513031B1 (https=)
JP (1) JP5826764B2 (https=)
KR (1) KR101814054B1 (https=)
CN (1) CN102741213B (https=)
AU (1) AU2010332503B2 (https=)
BR (1) BR112012014485B1 (https=)
CA (1) CA2783663C (https=)
EA (1) EA021605B1 (https=)
ES (1) ES2701014T3 (https=)
GB (1) GB0921875D0 (https=)
MX (1) MX2012006716A (https=)
MY (1) MY161937A (https=)
SG (1) SG181519A1 (https=)
TW (1) TWI506017B (https=)
WO (1) WO2011073655A1 (https=)
ZA (1) ZA201204315B (https=)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
US9133079B2 (en) 2012-01-13 2015-09-15 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
US9670113B2 (en) 2012-07-09 2017-06-06 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
MX380525B (es) 2013-09-30 2025-03-12 Dow Global Technologies Llc Producción en fase gaseosa de alcanoato de alquilo.
EP3074119B1 (en) 2013-11-27 2019-01-09 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA3123783A1 (en) 2014-01-08 2015-07-16 Lummus Technology Llc Ethylene-to-liquids systems and methods
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA2935946C (en) 2014-01-09 2022-05-03 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US20170107162A1 (en) 2015-10-16 2017-04-20 Siluria Technologies, Inc. Separation methods and systems for oxidative coupling of methane
US9944573B2 (en) 2016-04-13 2018-04-17 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
US20180169561A1 (en) 2016-12-19 2018-06-21 Siluria Technologies, Inc. Methods and systems for performing chemical separations
HUE064375T2 (hu) 2017-05-23 2024-03-28 Lummus Technology Inc Metán oxidatív csatolási folyamatainak integrálása
AU2018298234B2 (en) 2017-07-07 2022-11-17 Lummus Technology Llc Systems and methods for the oxidative coupling of methane
CN110586102B (zh) * 2019-08-21 2022-09-27 中山大学 一种类杂原子催化剂的制备方法
CN114409541A (zh) * 2020-10-28 2022-04-29 上海浦景化工技术股份有限公司 一种乙烯羰基化制丙酸酯类的系统
TW202313528A (zh) 2021-08-31 2023-04-01 美商祿幕斯科技有限責任公司 用於執行甲烷的氧化耦合的方法及系統
CN116099455B (zh) * 2023-04-12 2023-07-07 西南化工研究设计院有限公司 一种基于多釜串联的羰基化反应系统及方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3175174D1 (en) 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
GB8531624D0 (en) 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
KR880007426A (ko) 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
KR0144567B1 (ko) 1989-03-03 1998-07-15 오노 알버어스 카르보닐화촉매시스템
GB8917579D0 (en) * 1989-08-01 1989-09-13 Shell Int Research Preparation of alkyl propionates
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
ES2077337T3 (es) 1991-01-15 1995-11-16 Shell Int Research Procedimiento para la carbonilacion de olefinas.
DE69210054T2 (de) 1991-01-15 1996-12-12 Shell Int Research Carbonylierung von Olefinen
ES2054519T3 (es) 1991-02-15 1994-08-01 Shell Int Research Sistema de catalizador de carbonilacion.
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
GB9705699D0 (en) 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
US6706912B2 (en) 2000-03-14 2004-03-16 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10228293A1 (de) 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
EP1478463B1 (en) 2002-02-19 2012-04-11 Lucite International UK Limited Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
PL213201B1 (pl) 2002-09-12 2013-01-31 Lucite Int Uk Ltd Zwiazek nadajacy sie w szczególnosci do katalizowania reakcji karbonylowania nienasyconych zwiazków, sposób wytwarzania tych zwiazków, kompozycja zawierajaca takie zwiazki, sposób karbonylowania etylenowo nienasyconych zwiazków z zastosowaniem tych zwiazków, a takze ich zastosowanie
US20060235241A1 (en) 2003-05-22 2006-10-19 Eit Drent Process for the carbonylation of a conuugated diene
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
EP1735263A1 (en) 2004-02-26 2006-12-27 Shell Internationale Researchmaatschappij B.V. Process for the carbonylation of ethylenically or acetylenically unsaturated compounds
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system

Also Published As

Publication number Publication date
KR20120107494A (ko) 2012-10-02
BR112012014485B1 (pt) 2018-12-18
US20120277474A1 (en) 2012-11-01
EA201290507A1 (ru) 2013-01-30
CN102741213B (zh) 2015-05-27
WO2011073655A1 (en) 2011-06-23
MX2012006716A (es) 2012-11-29
CN102741213A (zh) 2012-10-17
JP2013513654A (ja) 2013-04-22
AU2010332503A1 (en) 2012-07-19
ES2701014T3 (es) 2019-02-20
EA021605B1 (ru) 2015-07-30
US8785678B2 (en) 2014-07-22
TWI506017B (zh) 2015-11-01
KR101814054B1 (ko) 2018-01-02
EP2513031A1 (en) 2012-10-24
ZA201204315B (en) 2013-01-31
SG181519A1 (en) 2012-07-30
EP2513031B1 (en) 2018-08-22
AU2010332503B2 (en) 2014-11-20
TW201136889A (en) 2011-11-01
GB0921875D0 (en) 2010-01-27
CA2783663A1 (en) 2011-06-23
BR112012014485A2 (pt) 2016-08-16
JP5826764B2 (ja) 2015-12-02
MY161937A (en) 2017-05-15

Similar Documents

Publication Publication Date Title
CA2783663C (en) A continuous process for the carbonylation of ethylene
CA2857572C (en) A continuous process for the carbonylation of ethylene
CA2784616C (en) Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands
CA2691698A1 (en) A process for the carbonylation of an ethylenically unsaturated compound and a catalyst system
AU2010332501B2 (en) Improved carbonylation process
CA2626107C (en) Carbonylation of ethylenically unsaturated compounds
WO2008075108A1 (en) Carbonylation of conjugated dienes
AU2007238407A1 (en) Metal complexes for use in the carbonylation of ethylenically unsaturated compounds

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20151030

W00 Other event occurred

Free format text: ST27 STATUS EVENT CODE: A-4-4-W10-W00-W100 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: LETTER SENT

Effective date: 20251020

H13 Ip right lapsed

Free format text: ST27 STATUS EVENT CODE: N-4-6-H10-H13-H100 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE AND LATE FEE NOT PAID BY DEADLINE OF NOTICE

Effective date: 20260202

W00 Other event occurred

Free format text: ST27 STATUS EVENT CODE: N-6-6-W10-W00-W100 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: LETTER SENT

Effective date: 20260203

W00 Other event occurred

Free format text: ST27 STATUS EVENT CODE: N-6-6-W10-W00-W100 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: LETTER SENT

Effective date: 20260205