EA201290507A1 - Непрерывный способ карбонилирования этилена - Google Patents

Непрерывный способ карбонилирования этилена

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Publication number
EA201290507A1
EA201290507A1 EA201290507A EA201290507A EA201290507A1 EA 201290507 A1 EA201290507 A1 EA 201290507A1 EA 201290507 A EA201290507 A EA 201290507A EA 201290507 A EA201290507 A EA 201290507A EA 201290507 A1 EA201290507 A1 EA 201290507A1
Authority
EA
Eurasian Patent Office
Prior art keywords
ethylene
liquid phase
coreagent
molar ratio
carbon monoxide
Prior art date
Application number
EA201290507A
Other languages
English (en)
Other versions
EA021605B1 (ru
Inventor
Грэхам Рональд Истхэм
Нил Тиндэйл
Original Assignee
ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД filed Critical ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
Publication of EA201290507A1 publication Critical patent/EA201290507A1/ru
Publication of EA021605B1 publication Critical patent/EA021605B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Описан непрерывный способ карбонилирования этилена в жидкой фазе с использованием монооксида углерода, сореагента и подходящей каталитической системы. Способ включает стадии: (i) образования жидкой фазы, содержащей сореагент и подходящую каталитическую систему, получаемую объединением: (a) металла VIII группы/соединения; (b) лиганда общей формулы (I)и (с) необязательно, источника анионов; где Qнеобязательно представляет собой фосфор; (ii) образования газовой фазы в контакте с жидкой фазой путем предоставления, по меньшей мере, входящего подаваемого потока газообразного этилена и входящего подаваемого потока газообразного монооксида углерода, где мольное соотношение этилен:СО, поступающих в жидкую фазу из входящих подаваемых потоков, больше чем 2:1; (iii) взаимодействие этилена с монооксидом углерода в присутствии сореагента и подходящей каталитической системы в жидкой фазе; где мольное соотношение газов этилен:СО в газовой фазе находится в интервале между 20:1 и 1000:1 или где мольное соотношение этилен:СО в жидкой фазе больше чем 10:1.
EA201290507A 2009-12-15 2010-12-15 Непрерывный способ карбонилирования этилена EA021605B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0921875.1A GB0921875D0 (en) 2009-12-15 2009-12-15 A continuous process for the carbonylation of ethylene
PCT/GB2010/052095 WO2011073655A1 (en) 2009-12-15 2010-12-15 A continuous process for the carbonylation of ethylene

Publications (2)

Publication Number Publication Date
EA201290507A1 true EA201290507A1 (ru) 2013-01-30
EA021605B1 EA021605B1 (ru) 2015-07-30

Family

ID=41667108

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290507A EA021605B1 (ru) 2009-12-15 2010-12-15 Непрерывный способ карбонилирования этилена

Country Status (17)

Country Link
US (1) US8785678B2 (ru)
EP (1) EP2513031B1 (ru)
JP (1) JP5826764B2 (ru)
KR (1) KR101814054B1 (ru)
CN (1) CN102741213B (ru)
AU (1) AU2010332503B2 (ru)
BR (1) BR112012014485B1 (ru)
CA (1) CA2783663C (ru)
EA (1) EA021605B1 (ru)
ES (1) ES2701014T3 (ru)
GB (1) GB0921875D0 (ru)
MX (1) MX2012006716A (ru)
MY (1) MY161937A (ru)
SG (1) SG181519A1 (ru)
TW (1) TWI506017B (ru)
WO (1) WO2011073655A1 (ru)
ZA (1) ZA201204315B (ru)

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WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
JP6474794B2 (ja) 2013-09-30 2019-02-27 ダウ グローバル テクノロジーズ エルエルシー アルカン酸アルキルの気相生成
US10047020B2 (en) 2013-11-27 2018-08-14 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
WO2015105911A1 (en) 2014-01-08 2015-07-16 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US9701597B2 (en) 2014-01-09 2017-07-11 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) * 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
WO2017065947A1 (en) 2015-10-16 2017-04-20 Siluria Technologies, Inc. Separation methods and systems for oxidative coupling of methane
US9944573B2 (en) 2016-04-13 2018-04-17 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
US20180169561A1 (en) 2016-12-19 2018-06-21 Siluria Technologies, Inc. Methods and systems for performing chemical separations
JP2020521811A (ja) 2017-05-23 2020-07-27 ラマス テクノロジー リミテッド ライアビリティ カンパニー メタン酸化カップリングプロセスの統合
KR20200051583A (ko) 2017-07-07 2020-05-13 루머스 테크놀로지 엘엘씨 메탄의 산화적 커플링를 위한 시스템 및 방법
CN110586102B (zh) * 2019-08-21 2022-09-27 中山大学 一种类杂原子催化剂的制备方法
CN114409541A (zh) * 2020-10-28 2022-04-29 上海浦景化工技术股份有限公司 一种乙烯羰基化制丙酸酯类的系统
CN116099455B (zh) * 2023-04-12 2023-07-07 西南化工研究设计院有限公司 一种基于多釜串联的羰基化反应系统及方法

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Also Published As

Publication number Publication date
CN102741213B (zh) 2015-05-27
EA021605B1 (ru) 2015-07-30
EP2513031A1 (en) 2012-10-24
CA2783663C (en) 2019-01-08
CA2783663A1 (en) 2011-06-23
MY161937A (en) 2017-05-15
KR101814054B1 (ko) 2018-01-02
MX2012006716A (es) 2012-11-29
ES2701014T3 (es) 2019-02-20
WO2011073655A1 (en) 2011-06-23
US8785678B2 (en) 2014-07-22
BR112012014485A2 (pt) 2016-08-16
AU2010332503B2 (en) 2014-11-20
SG181519A1 (en) 2012-07-30
JP5826764B2 (ja) 2015-12-02
TWI506017B (zh) 2015-11-01
US20120277474A1 (en) 2012-11-01
AU2010332503A1 (en) 2012-07-19
TW201136889A (en) 2011-11-01
KR20120107494A (ko) 2012-10-02
BR112012014485B1 (pt) 2018-12-18
JP2013513654A (ja) 2013-04-22
ZA201204315B (en) 2013-01-31
EP2513031B1 (en) 2018-08-22
GB0921875D0 (en) 2010-01-27
CN102741213A (zh) 2012-10-17

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