CA2772588C - Zinc cluster - Google Patents

Zinc cluster Download PDF

Info

Publication number
CA2772588C
CA2772588C CA2772588A CA2772588A CA2772588C CA 2772588 C CA2772588 C CA 2772588C CA 2772588 A CA2772588 A CA 2772588A CA 2772588 A CA2772588 A CA 2772588A CA 2772588 C CA2772588 C CA 2772588C
Authority
CA
Canada
Prior art keywords
zinc
cluster
zinc cluster
mmol
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2772588A
Other languages
English (en)
French (fr)
Other versions
CA2772588A1 (en
Inventor
Yoshimasa Matsushima
Hideki Nara
Takahiro Fujiwara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Original Assignee
Takasago International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago International Corp filed Critical Takasago International Corp
Publication of CA2772588A1 publication Critical patent/CA2772588A1/en
Application granted granted Critical
Publication of CA2772588C publication Critical patent/CA2772588C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/12—Formation or introduction of functional groups containing oxygen of carboxylic acid ester groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C269/06—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups by reactions not involving the formation of carbamate groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/15—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen containing halogen
    • C07C53/16—Halogenated acetic acids
    • C07C53/18—Halogenated acetic acids containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/10—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D263/12—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with radicals containing only hydrogen and carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/08—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D309/10—Oxygen atoms
    • C07D309/12—Oxygen atoms only hydrogen atoms and one oxygen atom directly attached to ring carbon atoms, e.g. tetrahydropyranyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/349—1,2- or 1,4-additions in combination with further or prior reactions by the same catalyst, i.e. tandem or domino reactions, e.g. hydrogenation or further addition reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0219—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pyrane Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2772588A 2009-09-11 2010-05-31 Zinc cluster Active CA2772588C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2009210208 2009-09-11
JP2009-210208 2009-09-11
PCT/JP2010/059204 WO2011030591A1 (ja) 2009-09-11 2010-05-31 亜鉛クラスター

Publications (2)

Publication Number Publication Date
CA2772588A1 CA2772588A1 (en) 2011-03-17
CA2772588C true CA2772588C (en) 2016-08-16

Family

ID=43732268

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2772588A Active CA2772588C (en) 2009-09-11 2010-05-31 Zinc cluster

Country Status (8)

Country Link
US (1) US8552204B2 (2)
EP (1) EP2476664B1 (2)
JP (1) JP5634130B2 (2)
KR (1) KR101631351B1 (2)
CN (1) CN102482190B (2)
CA (1) CA2772588C (2)
IN (1) IN2012DN01815A (2)
WO (1) WO2011030591A1 (2)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101927993B1 (ko) * 2011-10-31 2018-12-11 포리프라스틱 가부시키가이샤 액정 폴리에스테르아미드 수지
DE112014001645B4 (de) 2013-03-27 2023-06-29 Takasago International Corp. Zinkkomplex
US10619058B2 (en) * 2015-07-02 2020-04-14 Toagosei Co., Ltd. Curable composition
WO2017002964A1 (ja) * 2015-07-02 2017-01-05 東亞合成株式会社 硬化型組成物
EP3417939A4 (en) 2016-02-16 2020-02-26 Takasago International Corporation MACROMOLECULE SUPPORTED BY A METAL
JP6878877B2 (ja) * 2016-12-22 2021-06-02 住友ゴム工業株式会社 ゴム組成物および架橋ゴム成形体
KR102863135B1 (ko) * 2019-04-11 2025-09-24 덕산네오룩스 주식회사 Ⅲ­ⅴ계 양자점 및 이의 제조방법
WO2020209580A1 (ko) * 2019-04-11 2020-10-15 덕산네오룩스 주식회사 Ⅲ－ⅴ계 양자점 및 이의 제조방법
KR102889136B1 (ko) * 2019-04-11 2025-11-24 덕산네오룩스 주식회사 Ⅲ­ⅴ계 양자점 제조를 위한 활성 나노 클러스터, 이를 포함하는 양자점 및 이들의 제조방법
WO2020209578A1 (ko) * 2019-04-11 2020-10-15 덕산네오룩스 주식회사 Ⅲ－ⅴ계 양자점 제조를 위한 활성 나노 클러스터, 이를 포함하는 양자점 및 이들의 제조방법
KR102566043B1 (ko) * 2020-10-08 2023-08-11 덕산네오룩스 주식회사 성장층을 가지는 ⅲ―ⅴ족계 양자점 및 이의 제조방법
KR102566035B1 (ko) * 2020-10-08 2023-08-11 덕산네오룩스 주식회사 Ⅲ―ⅴ족계 양자점 및 이의 제조방법
KR102566030B1 (ko) * 2020-10-08 2023-08-11 덕산네오룩스 주식회사 Ⅲ―ⅴ족계 양자점의 제조방법 및 iii-v족계 양자점
KR102566038B1 (ko) * 2020-10-08 2023-08-11 덕산네오룩스 주식회사 Ⅲ―ⅴ족계 양자점 및 이의 제조방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HU207089B (en) * 1991-01-18 1993-03-01 Szerves Vegyipari Kutato Int Process for producing basic zinc-2-ethylhexanoate or mixtures comprising basic zinc-2-ethylhexanoate from inorganic zinc salts or waste zinc compounds
JP5095415B2 (ja) 2005-12-05 2012-12-12 高砂香料工業株式会社 金属触媒による縮合反応
CA2700111A1 (en) * 2007-10-11 2009-04-16 Takasago International Corporation Acylation reaction of hydroxyl group
JP5069644B2 (ja) * 2008-08-27 2012-11-07 旭化成株式会社 半導体結晶微粒子薄膜

Also Published As

Publication number Publication date
US8552204B2 (en) 2013-10-08
IN2012DN01815A (2) 2015-06-05
EP2476664A1 (en) 2012-07-18
EP2476664A4 (en) 2013-08-21
EP2476664B1 (en) 2015-03-04
JP2011079810A (ja) 2011-04-21
CN102482190B (zh) 2014-05-07
JP5634130B2 (ja) 2014-12-03
WO2011030591A1 (ja) 2011-03-17
KR20120089251A (ko) 2012-08-09
KR101631351B1 (ko) 2016-06-16
CN102482190A (zh) 2012-05-30
CA2772588A1 (en) 2011-03-17
US20120172601A1 (en) 2012-07-05

Similar Documents

Publication Publication Date Title
CA2772588C (en) Zinc cluster
Palomo et al. Enantioselective Aza‐Henry Reactions Assisted by ZnII and N‐Methylephedrine
Ragaini et al. Phosphorus acids as highly efficient promoters for the palladium‐phenanthroline catalyzed carbonylation of nitrobenzene to methyl phenylcarbamate
TW200700425A (en) Processes for the production of organometallic compounds
Palomo et al. Catalytic Enantioselective Conjugate Addition of Nitromethane to α′‐Hydroxy Enones as Surrogates of α, β‐Unsaturated Carboxylic Acids and Aldehydes
Desroches et al. Nitration of thiacalix [4] arene using nitrosium nitrate complexes: synthesis and characterization of tetranitro-, tetraamino-, and tetra (4-pyridylimino) tetrahydroxythiacalix [4] arene
Huang et al. Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant
WO2011043483A1 (ja) 金属錯体、ピリジルホスフィン化合物およびアルキルメタクリレートの製造方法
JP2008239601A (ja) ラクチド化合物の製造方法
TW201615625A (zh) 製備１－烷基－３－二氟甲基－５－氟－１ｈ－吡唑－４－甲醛及１－烷基－３－二氟甲基－５－氟－１ｈ－吡唑－４－羧酸酯之方法
CN1281844A (zh) 氧代异佛尔酮的制备方法
CN102127038B (zh) 一种合成单硫醚类化合物的方法
Naik et al. Tetrabutylammonium tribromide mediated condensation of carboxylic acids with alcohols
WO2016194929A1 (ja) パーフルオロアルカンスルホニルフェノール化合物の製造方法
JP4691084B2 (ja) 白金触媒
Moodi et al. Synthesis and characterization of Ni (II) and Cu (II) complexes based on quercetin Schiff base and using them as heterogeneous catalysts in Henry reaction
JP4591998B2 (ja) 光学活性アルコール誘導体の製造方法
JP2011051904A (ja) 第３級アルコールの製造方法
JP5276339B2 (ja) ジヒドロピラン化合物の製造方法
Çapan et al. Synthesis, characterization and catalytic properties of some transition metal complexes of new phenoxy-imine ligand
Guzal et al. COMPLEX COMPOUNDS OF BENZENE-1, 3, 5-TRICARBOXYLIC ACID WITH COPPER SALTS IN THE PRESENCE OF SULPHUR-CONTAINING BICYCLE LIGANDS
Yavari et al. Reaction between 5-benzylidene-2, 2-dimethyl-1, 3-dioxane-4, 6-dione and tert-butyl isocyanide in the presence of ethane-1, 2-diol or catechol
Voronkov et al. Acyl iodides in organic synthesis: XIII. Reaction of acyl iodides with nitrogen-containing heteroaromatic compounds
Jackson Recent developments in the application of organometallic chemistry to amino acid synthesis
PL212339B1 (pl) Nowy di-p-okso-p-dikarboksylanometyloacetylo-p-izopropanolanoditytan (IV) oraz sposób jego wytwarzania

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20150507

MPN Maintenance fee for patent paid

Free format text: FEE DESCRIPTION TEXT: MF (PATENT, 15TH ANNIV.) - STANDARD

Year of fee payment: 15

U00 Fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U00-U101 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE REQUEST RECEIVED

Effective date: 20250425

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-U102 (AS PROVIDED BY THE NATIONAL OFFICE); EVENT TEXT: MAINTENANCE FEE PAYMENT PAID IN FULL

Effective date: 20250425