CA2756325C - Cathode for electrolytic processes - Google Patents
Cathode for electrolytic processes Download PDFInfo
- Publication number
- CA2756325C CA2756325C CA2756325A CA2756325A CA2756325C CA 2756325 C CA2756325 C CA 2756325C CA 2756325 A CA2756325 A CA 2756325A CA 2756325 A CA2756325 A CA 2756325A CA 2756325 C CA2756325 C CA 2756325C
- Authority
- CA
- Canada
- Prior art keywords
- protective layer
- alloy
- solution
- cathode
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 20
- 230000008569 process Effects 0.000 title claims abstract description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000011241 protective layer Substances 0.000 claims abstract description 21
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 19
- 239000000956 alloy Substances 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 17
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 14
- 229910052702 rhenium Inorganic materials 0.000 claims abstract description 6
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011574 phosphorus Substances 0.000 claims abstract description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052796 boron Inorganic materials 0.000 claims abstract description 4
- 239000010941 cobalt Substances 0.000 claims abstract description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 3
- 229910052755 nonmetal Inorganic materials 0.000 claims abstract description 3
- 230000007704 transition Effects 0.000 claims abstract description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 3
- 239000010937 tungsten Substances 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 25
- 230000008021 deposition Effects 0.000 claims description 22
- 230000003197 catalytic effect Effects 0.000 claims description 21
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(IV) oxide Inorganic materials O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims description 12
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 11
- 238000011068 loading method Methods 0.000 claims description 9
- 238000007598 dipping method Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002243 precursor Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002608 ionic liquid Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 3
- 239000012018 catalyst precursor Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 2
- -1 platinum group metals Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229910021205 NaH2PO2 Inorganic materials 0.000 claims 3
- 229910001096 P alloy Inorganic materials 0.000 claims 1
- 229910002666 PdCl2 Inorganic materials 0.000 claims 1
- 229910019891 RuCl3 Inorganic materials 0.000 claims 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims 1
- 235000011130 ammonium sulphate Nutrition 0.000 claims 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 229910000510 noble metal Inorganic materials 0.000 abstract description 3
- 230000004913 activation Effects 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000000151 deposition Methods 0.000 description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- 238000000576 coating method Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 229910018104 Ni-P Inorganic materials 0.000 description 8
- 229910018536 Ni—P Inorganic materials 0.000 description 8
- 239000011229 interlayer Substances 0.000 description 7
- 238000002484 cyclic voltammetry Methods 0.000 description 6
- 230000009849 deactivation Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000001681 protective effect Effects 0.000 description 6
- 239000000499 gel Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000010561 standard procedure Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000004873 anchoring Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000001427 coherent effect Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910000480 nickel oxide Inorganic materials 0.000 description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Chemically Coating (AREA)
- Secondary Cells (AREA)
- Electrolytic Production Of Metals (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000880A ITMI20090880A1 (it) | 2009-05-19 | 2009-05-19 | Catodo per processi elettrolitici |
| ITMI2009A000880 | 2009-05-19 | ||
| PCT/EP2010/056797 WO2010133583A1 (en) | 2009-05-19 | 2010-05-18 | Cathode for electrolytic processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2756325A1 CA2756325A1 (en) | 2010-11-25 |
| CA2756325C true CA2756325C (en) | 2017-06-27 |
Family
ID=41278459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2756325A Active CA2756325C (en) | 2009-05-19 | 2010-05-18 | Cathode for electrolytic processes |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US20120061237A1 (enExample) |
| EP (1) | EP2432919B1 (enExample) |
| JP (1) | JP5714000B2 (enExample) |
| KR (2) | KR20120030429A (enExample) |
| CN (1) | CN102414346B (enExample) |
| AR (1) | AR076883A1 (enExample) |
| AU (1) | AU2010251231B2 (enExample) |
| BR (1) | BRPI1013071B1 (enExample) |
| CA (1) | CA2756325C (enExample) |
| DK (1) | DK2432919T3 (enExample) |
| EA (1) | EA019816B1 (enExample) |
| EG (1) | EG26415A (enExample) |
| ES (1) | ES2432028T3 (enExample) |
| IL (1) | IL215252A (enExample) |
| IT (1) | ITMI20090880A1 (enExample) |
| MX (1) | MX2011011465A (enExample) |
| PL (1) | PL2432919T3 (enExample) |
| PT (1) | PT2432919E (enExample) |
| TW (1) | TWI477654B (enExample) |
| WO (1) | WO2010133583A1 (enExample) |
| ZA (1) | ZA201107126B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20122035A1 (it) * | 2012-11-29 | 2014-05-30 | Industrie De Nora Spa | Elettrodo per evoluzione di ossigeno in processi elettrochimici industriali |
| US10385462B2 (en) | 2015-07-09 | 2019-08-20 | Saudi Arabian Oil Company | Electrode material for electrolytic hydrogen generation |
| CN108337894B (zh) * | 2015-09-14 | 2020-08-25 | 哈佛学院院长及董事 | 碳固定系统和方法 |
| CN105951122A (zh) * | 2016-05-20 | 2016-09-21 | 欧子轩 | 氢能发生器 |
| ES2904890T3 (es) | 2016-07-06 | 2022-04-06 | Harvard College | Métodos y sistemas para la síntesis de amoniaco |
| US11187044B2 (en) | 2019-12-10 | 2021-11-30 | Saudi Arabian Oil Company | Production cavern |
| US11460330B2 (en) | 2020-07-06 | 2022-10-04 | Saudi Arabian Oil Company | Reducing noise in a vortex flow meter |
| RU2765839C1 (ru) * | 2021-03-03 | 2022-02-03 | Герасимов Михаил Владимирович | Коррозионно-устойчивый электрод для электрохимического получения водорода и способ его получения |
| IL292647B2 (en) * | 2022-05-01 | 2024-03-01 | Electriq Global Energy Solutions Ltd | A catalyst for generating hydrogen and a method for its preparation |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4061802A (en) * | 1966-10-24 | 1977-12-06 | Costello Francis E | Plating process and bath |
| SU527488A1 (ru) * | 1974-04-19 | 1976-09-05 | Новочеркасский Ордена Трудового Красного Знамени Политехнический Институт Имени С.Орджоникидзе | Электролит дл осаждени сплавов никел или кобальта с бором |
| US4377454A (en) * | 1980-05-09 | 1983-03-22 | Occidental Chemical Corporation | Noble metal-coated cathode |
| JPS6047911B2 (ja) * | 1980-08-14 | 1985-10-24 | 東亞合成株式会社 | 水素発生用陰極の製法 |
| JPS57207183A (en) * | 1981-06-15 | 1982-12-18 | Tokuyama Soda Co Ltd | Production of cathode |
| US4530742A (en) * | 1983-01-26 | 1985-07-23 | Ppg Industries, Inc. | Electrode and method of preparing same |
| FR2596776B1 (fr) * | 1986-04-03 | 1988-06-03 | Atochem | Cathode pour electrolyse et un procede de fabrication de ladite cathode |
| US5645930A (en) * | 1995-08-11 | 1997-07-08 | The Dow Chemical Company | Durable electrode coatings |
| US6099624A (en) * | 1997-07-09 | 2000-08-08 | Elf Atochem North America, Inc. | Nickel-phosphorus alloy coatings |
| US6203936B1 (en) * | 1999-03-03 | 2001-03-20 | Lynntech Inc. | Lightweight metal bipolar plates and methods for making the same |
| EP1235658B1 (en) * | 1999-10-20 | 2004-07-21 | Dow Global Technologies Inc. | Electrode made with catalytic powder |
-
2009
- 2009-05-19 IT IT000880A patent/ITMI20090880A1/it unknown
-
2010
- 2010-05-07 TW TW099114588A patent/TWI477654B/zh active
- 2010-05-18 ES ES10720911T patent/ES2432028T3/es active Active
- 2010-05-18 DK DK10720911.6T patent/DK2432919T3/da active
- 2010-05-18 PL PL10720911T patent/PL2432919T3/pl unknown
- 2010-05-18 KR KR1020117030290A patent/KR20120030429A/ko not_active Ceased
- 2010-05-18 MX MX2011011465A patent/MX2011011465A/es active IP Right Grant
- 2010-05-18 EA EA201171424A patent/EA019816B1/ru not_active IP Right Cessation
- 2010-05-18 AU AU2010251231A patent/AU2010251231B2/en active Active
- 2010-05-18 CA CA2756325A patent/CA2756325C/en active Active
- 2010-05-18 EP EP10720911.6A patent/EP2432919B1/en active Active
- 2010-05-18 CN CN201080018480.4A patent/CN102414346B/zh active Active
- 2010-05-18 PT PT107209116T patent/PT2432919E/pt unknown
- 2010-05-18 KR KR1020177002247A patent/KR20170013409A/ko not_active Ceased
- 2010-05-18 WO PCT/EP2010/056797 patent/WO2010133583A1/en not_active Ceased
- 2010-05-18 BR BRPI1013071-3A patent/BRPI1013071B1/pt not_active IP Right Cessation
- 2010-05-18 JP JP2012511259A patent/JP5714000B2/ja active Active
- 2010-05-19 AR ARP100101743A patent/AR076883A1/es active IP Right Grant
-
2011
- 2011-09-20 IL IL215252A patent/IL215252A/en active IP Right Grant
- 2011-09-29 ZA ZA2011/07126A patent/ZA201107126B/en unknown
- 2011-11-17 US US13/298,630 patent/US20120061237A1/en not_active Abandoned
- 2011-11-20 EG EG2011111960A patent/EG26415A/en active
Also Published As
| Publication number | Publication date |
|---|---|
| JP5714000B2 (ja) | 2015-05-07 |
| ITMI20090880A1 (it) | 2010-11-20 |
| PT2432919E (pt) | 2013-10-07 |
| US20120061237A1 (en) | 2012-03-15 |
| TWI477654B (zh) | 2015-03-21 |
| EP2432919B1 (en) | 2013-07-24 |
| ZA201107126B (en) | 2012-12-27 |
| KR20120030429A (ko) | 2012-03-28 |
| CA2756325A1 (en) | 2010-11-25 |
| EP2432919A1 (en) | 2012-03-28 |
| KR20170013409A (ko) | 2017-02-06 |
| CN102414346B (zh) | 2017-06-30 |
| WO2010133583A1 (en) | 2010-11-25 |
| JP2012527531A (ja) | 2012-11-08 |
| BRPI1013071B1 (pt) | 2019-11-19 |
| DK2432919T3 (da) | 2013-10-07 |
| AR076883A1 (es) | 2011-07-13 |
| IL215252A (en) | 2015-05-31 |
| AU2010251231A1 (en) | 2011-10-27 |
| MX2011011465A (es) | 2011-11-18 |
| EA019816B1 (ru) | 2014-06-30 |
| ES2432028T3 (es) | 2013-11-29 |
| IL215252A0 (en) | 2011-12-29 |
| TW201042092A (en) | 2010-12-01 |
| AU2010251231B2 (en) | 2014-06-19 |
| CN102414346A (zh) | 2012-04-11 |
| EG26415A (en) | 2013-10-22 |
| PL2432919T3 (pl) | 2013-12-31 |
| EA201171424A1 (ru) | 2012-04-30 |
| BRPI1013071A2 (pt) | 2016-04-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20150501 |